[go: up one dir, main page]

BR112018070703A2 - processos para preparação de uma composição catalisadora e para produção de glicóis. - Google Patents

processos para preparação de uma composição catalisadora e para produção de glicóis.

Info

Publication number
BR112018070703A2
BR112018070703A2 BR112018070703-1A BR112018070703A BR112018070703A2 BR 112018070703 A2 BR112018070703 A2 BR 112018070703A2 BR 112018070703 A BR112018070703 A BR 112018070703A BR 112018070703 A2 BR112018070703 A2 BR 112018070703A2
Authority
BR
Brazil
Prior art keywords
preparing
catalyst composition
processes
reactor vessel
metal impregnated
Prior art date
Application number
BR112018070703-1A
Other languages
English (en)
Other versions
BR112018070703B1 (pt
Inventor
Albertus Colijn Hendrik
Jacobus Maria De Vlieger Dionysius
Original Assignee
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij B.V. filed Critical Shell Internationale Research Maatschappij B.V.
Publication of BR112018070703A2 publication Critical patent/BR112018070703A2/pt
Publication of BR112018070703B1 publication Critical patent/BR112018070703B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/468—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/202—Ethylene glycol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/205—1,3-Propanediol; 1,2-Propanediol
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

trata-se de um processo para a preparação de uma composição catalisadora para catalisar reações de hidrogenação e de hidrogenólise em que (a) um suporte de carbono é colocado em contato com uma solução precursora catalítica que compreende pelo menos um elemento dos grupos 7, 8, 9, 10 e 11 da tabela periódica para formar um carbono impregnado com metal; (b) o carbono impregnado com metal é seco a uma temperatura de, no máximo, 400°c e colocado em um vaso de reator; (c) o vaso de reator é vedado; e (d) o carbono impregnado com metal é tratado no vaso de reator 10 em uma atmosfera que compreende hidrogênio a uma temperatura de 25°c a 350°c.
BR112018070703-1A 2016-04-11 2017-04-07 Processo para produção de glicóis BR112018070703B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16164685 2016-04-11
EP16164685,6 2016-04-11
PCT/EP2017/058465 WO2017178391A1 (en) 2016-04-11 2017-04-07 A process for the preparation of a catalyst and a process for producing glycols using the catalyst

Publications (2)

Publication Number Publication Date
BR112018070703A2 true BR112018070703A2 (pt) 2019-02-12
BR112018070703B1 BR112018070703B1 (pt) 2022-05-03

Family

ID=55745613

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018070703-1A BR112018070703B1 (pt) 2016-04-11 2017-04-07 Processo para produção de glicóis

Country Status (5)

Country Link
US (1) US10562012B2 (pt)
EP (1) EP3442937B1 (pt)
CN (1) CN109071388B (pt)
BR (1) BR112018070703B1 (pt)
WO (1) WO2017178391A1 (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3155648A1 (en) 2019-09-24 2021-04-01 Iowa Corn Promotion Board Continuous, carbohydrate to ethylene glycol processes
US11680031B2 (en) 2020-09-24 2023-06-20 T. EN Process Technology, Inc. Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
US11319269B2 (en) 2020-09-24 2022-05-03 Iowa Corn Promotion Board Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
CN112264007B (zh) * 2020-11-13 2021-07-20 中南大学 一种芳香化合物催化燃烧催化剂及其制备和应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4476331A (en) 1982-02-11 1984-10-09 Ethyl Corporation Two stage hydrogenolysis of carbohydrate to glycols using sulfide modified ruthenium catalyst in second stage
US4503274A (en) 1983-08-08 1985-03-05 Uop Inc. Ruthenium hydrogenation catalyst with increased activity
CN1021224C (zh) * 1985-04-01 1993-06-16 纳幕尔杜邦公司 用钯/铼氢化催化剂制造四氢呋喃、1，4-丁二醇或其混合物的方法
SG74602A1 (en) * 1996-12-20 2000-08-22 Standard Oil Co Improved catalysts for the hydrogenation of maleic acid to 1,4-butanediol
CN102190562B (zh) * 2010-03-17 2014-03-05 中国科学院大连化学物理研究所 一种多羟基化合物制乙二醇的方法
EP3039001B1 (en) 2013-08-26 2018-07-25 Shell International Research Maatschappij B.V. Process for the preparation of glycols

Also Published As

Publication number Publication date
CN109071388B (zh) 2021-12-10
US10562012B2 (en) 2020-02-18
EP3442937B1 (en) 2023-07-19
CN109071388A (zh) 2018-12-21
EP3442937A1 (en) 2019-02-20
US20190111413A1 (en) 2019-04-18
BR112018070703B1 (pt) 2022-05-03
WO2017178391A1 (en) 2017-10-19

Similar Documents

Publication Publication Date Title
BR112018070703A2 (pt) processos para preparação de uma composição catalisadora e para produção de glicóis.
MX2019002769A (es) Metodos de preparacion de un catalizador.
BR112018003639A2 (pt) processo de controle da morfologia de grafite
BR112018006410A2 (pt) processo para a preparação de glicóis
BR112018006403A2 (pt) processo para a preparação de glicóis
MX2019000422A (es) Proceso para producir petroleo renovable que contiene oxigeno, bajo en azufre.
BR112018009561A2 (pt) reciclagem química de tereftalato de polietileno por irradiação de micro-ondas
BR112018012211A2 (pt) ?artigo de catalisador, sistema de tratamento de gás de escape, e, métodos de tratamento de uma corrente de gás de escape e para preparação de um artigo de catalisador de trimetal?
BR112016030951A2 (pt) Método para preparar grafeno poroso
MX2018009534A (es) Catalizador de chabazita cointercambiada con cobre y hierro.
MX2018001489A (es) Isomerizacion catalitica de z-1,1,14,4,4,-hexafluoro-2-buteno a e-1,1,1,4,4,4-hexafluoro-2-buteno.
AU2018260817A1 (en) Method for storage and release of hydrogen
BR112018008620A2 (pt) ?processos para preparar um produto de metal-carbono conformado poroso e para produzir um composto, e, produtos de metal-carbono conformados carbonizado e poroso?
DK3878806T3 (da) Fremgangsmåde til fremstilling af hydrogen eller hydrogenholdige brændstoffer ved katalytisk ammoniakspaltning
BR112017005851A2 (pt) método de produção e aparelho de produção de oligômero de a-olefina
BR112015025838A2 (pt) dispositivo para a geração de plasma a frio e método relacionado para a produção das substâncias químicas
BR112019002217A2 (pt) processo de conversão de biomassa aperfeiçoado
BR112019007810A2 (pt) processo para produzir catalisadores de desidrogenação oxidativa usando tratamento hidrotérmico e tratamento com peróxido
SA520410943B1 (ar) تخفيض نسبة استرات الجليسيديل في زيوت صالحة للأكل
RU2016120009A (ru) Способ изготовления катализатора гидроочистки
SA521421676B1 (ar) طرق الهدرجة الانتقائية
EA202092100A1 (ru) Непрерывный или полунепрерывный способ получения этиленгликоля и система катализаторов для применения в нем
AR129529A2 (es) Aparato reactor, procedimiento para calentar un medio de intercambio de calor utilizándolo, procedimiento para combustión por vía catalítica de una mezcla de combustible con el mismo y sistema de combustión catalítica que lo comprende
BR112018006413A2 (pt) processo para preparação de glicóis
BR112018006399A2 (pt) processo para a preparação de um catalisador de hidrogenação e seu uso para a preparação de glicóis

Legal Events

Date Code Title Description
B06W Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 07/04/2017, OBSERVADAS AS CONDICOES LEGAIS.

B24B Patent annual fee: requirement for complementing annual fee

Free format text: COMPLEMENTAR A RETRIBUICAO DA(S) 6A ANUIDADE(S), DE ACORDO COM TABELA VIGENTE, REFERENTE A(S) GUIA(S) DE RECOLHIMENTO 29409161949630942. UMA VEZ QUE A ANUIDADE FOI RECOLHIDA COMO PEDIDO.

B24D Patent annual fee: restoration after fee payment