MX2018009534A - Catalizador de chabazita cointercambiada con cobre y hierro. - Google Patents
Catalizador de chabazita cointercambiada con cobre y hierro.Info
- Publication number
- MX2018009534A MX2018009534A MX2018009534A MX2018009534A MX2018009534A MX 2018009534 A MX2018009534 A MX 2018009534A MX 2018009534 A MX2018009534 A MX 2018009534A MX 2018009534 A MX2018009534 A MX 2018009534A MX 2018009534 A MX2018009534 A MX 2018009534A
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst
- iron
- copper
- cointercambiada
- chabazita
- Prior art date
Links
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/763—CHA-type, e.g. Chabazite, LZ-218
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
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- B01D53/9477—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
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- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Processes For Solid Components From Exhaust (AREA)
Abstract
La presente descripción provee en general catalizadores, artículos catalíticos y sistemas catalizadores que comprenden tales artículos catalíticos. En particular, la composición catalizadora comprende una zeolita que posee una estructura de cristal de chabazita (CHA) con intercambio iónico con hierro y cobre. Se proveen también métodos para preparar y usar la composición catalizadora así como también sistemas de tratamiento de emisiones que comprenden un artículo catalizador recubierto con la composición catalizadora. El articulo catalizador presente en dichos sistemas de tratamiento de emisiones es útil para catalizar la reducción de óxidos de nitrógeno en el escape de gases en presencia de un reductor.
Applications Claiming Priority (2)
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US201662290634P | 2016-02-03 | 2016-02-03 | |
PCT/IB2017/050545 WO2017134581A1 (en) | 2016-02-03 | 2017-02-01 | Copper and iron co-exchanged chabazite catalyst |
Publications (1)
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MX2018009534A true MX2018009534A (es) | 2018-09-06 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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MX2018009534A MX2018009534A (es) | 2016-02-03 | 2017-02-01 | Catalizador de chabazita cointercambiada con cobre y hierro. |
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US (1) | US11311867B2 (es) |
EP (1) | EP3411145A4 (es) |
JP (1) | JP6925350B2 (es) |
KR (1) | KR20180102199A (es) |
CN (2) | CN119215975A (es) |
BR (1) | BR112018015842B1 (es) |
CA (1) | CA3013546A1 (es) |
MX (1) | MX2018009534A (es) |
RU (1) | RU2018131407A (es) |
WO (1) | WO2017134581A1 (es) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017085646A1 (en) * | 2015-11-17 | 2017-05-26 | Basf Corporation | Exhaust gas treatment catalyst |
JP2020533164A (ja) * | 2017-09-07 | 2020-11-19 | ビーエーエスエフ コーポレーション | 骨格外アルミニウムを減じたゼオライト |
EP3727685A4 (en) | 2018-01-03 | 2021-08-25 | BASF Corporation | SURFACE TREATED SILICOALUMINOPHOSPHATE MOLECULAR SIEVE |
JP7410048B2 (ja) * | 2018-03-21 | 2024-01-09 | ビーエーエスエフ コーポレーション | Chaゼオライト材料および関連する合成方法 |
EP3873663A4 (en) * | 2018-10-30 | 2022-09-07 | BASF Corporation | IN-SITU COPPER ION EXCHANGE ON PRE-EXCHANGED COPPER ZEOLITHIC MATERIAL |
JP2022509023A (ja) * | 2018-10-31 | 2022-01-20 | ビーエーエスエフ コーポレーション | Noxを低減するための銅トラップ成分を添加した触媒組成物 |
CN112969535A (zh) | 2018-10-31 | 2021-06-15 | 巴斯夫公司 | 用于消除NOx的添加了氧化铝的催化洗涂层 |
US20220016607A1 (en) * | 2018-12-03 | 2022-01-20 | National University Corporation Hokkaido University | Functional structure precursor and functional structure |
KR102224614B1 (ko) * | 2018-12-31 | 2021-03-05 | 포항공과대학교 산학협력단 | 무기 금속 성분을 포함하는 cha형 sapo 및 그 제조 방법 |
US20220331787A1 (en) * | 2019-09-25 | 2022-10-20 | Basf Corporation | Cu-cha scr catalysts having specific lattice strain and domain size characteristics |
JP2023522840A (ja) * | 2020-03-30 | 2023-06-01 | ビーエーエスエフ コーポレーション | 選択的触媒還元触媒、及び選択的触媒還元触媒の調製方法 |
KR20220156087A (ko) * | 2020-04-01 | 2022-11-24 | 바스프 코포레이션 | 암모니아 저장 용량이 높은 scr 촉매 |
US20230249164A1 (en) * | 2020-06-25 | 2023-08-10 | Basf Corporation | Zeolite-Containing SCR Catalyst |
CN114054075B (zh) * | 2020-07-31 | 2023-04-25 | 大连理工大学 | 一种复合改性沸石分子筛催化剂的制备方法 |
CN112604703B (zh) * | 2020-10-27 | 2021-11-02 | 中国环境科学研究院 | 一种石墨化碳负载纳米零价铁材料及其制备方法和应用 |
CN116406316A (zh) | 2020-10-30 | 2023-07-07 | 巴斯夫公司 | 用于增强高温转化和减少n2o生成的催化剂 |
EP4259329A1 (en) | 2020-12-09 | 2023-10-18 | BASF Corporation | Preparation process of scr catalyst comprising cu and fe-exchanged zeolite, said catalyst, system comprising said catalyst and exhaust gas treatment using such |
JP2023554318A (ja) | 2020-12-09 | 2023-12-27 | ビーエーエスエフ コーポレーション | Cu及びFeを含む低N2OのSCR触媒を製造するための方法 |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3841990A1 (de) * | 1988-12-14 | 1990-06-21 | Degussa | Verfahren zur reduktion von stickoxiden aus abgasen |
US6946013B2 (en) * | 2002-10-28 | 2005-09-20 | Geo2 Technologies, Inc. | Ceramic exhaust filter |
EP1810751A1 (de) * | 2006-01-20 | 2007-07-25 | Universität Karlsruhe (TH) | Verfahren zur Herstellung eines eisenhaltigen SCR-Katalysators |
US7998423B2 (en) * | 2007-02-27 | 2011-08-16 | Basf Corporation | SCR on low thermal mass filter substrates |
WO2008106519A1 (en) | 2007-02-27 | 2008-09-04 | Basf Catalysts Llc | Copper cha zeolite catalysts |
EP2136916A1 (en) | 2007-03-26 | 2009-12-30 | PQ Corporation | Novel microporous crystalline material comprising a molecular sieve or zeolite having an 8-ring pore opening structure and methods of making and using same |
US10384162B2 (en) * | 2007-03-26 | 2019-08-20 | Pq Corporation | High silica chabazite for selective catalytic reduction, methods of making and using same |
EP2517775B1 (en) * | 2007-04-26 | 2016-12-21 | Johnson Matthey Public Limited Company | Transition metal/afx-zeolite scr catalyst |
US8715618B2 (en) | 2008-05-21 | 2014-05-06 | Basf Se | Process for the direct synthesis of Cu containing zeolites having CHA structure |
US7880069B2 (en) | 2009-03-25 | 2011-02-01 | Monsanto Technology Llc | Plants and seeds of corn variety CV729740 |
WO2011061841A1 (ja) * | 2009-11-19 | 2011-05-26 | イビデン株式会社 | ハニカム構造体及び排ガス浄化装置 |
WO2011064186A1 (en) | 2009-11-24 | 2011-06-03 | Basf Se | Process for the preparation of zeolites having cha structure |
GB2475740B (en) * | 2009-11-30 | 2017-06-07 | Johnson Matthey Plc | Catalysts for treating transient NOx emissions |
US8293198B2 (en) * | 2009-12-18 | 2012-10-23 | Basf Corporation | Process of direct copper exchange into Na+-form of chabazite molecular sieve, and catalysts, systems and methods |
MY160970A (en) * | 2010-04-08 | 2017-03-31 | Basf Se | A catalyst for use in selective catalytic reduction comprising zeolites of the cha structure type comprising cu and zeolites of the mfi structure type comprising fe, an exhaust gas treatment system comprising this catalyst, a process for the treatment of a gas stream comprising nox using the catalyst |
US8421830B2 (en) * | 2010-09-29 | 2013-04-16 | Fujifilm Corporation | Method of forming image using heat-sensitive transfer image-receiving sheet having a lenticular lens |
DK2646149T3 (da) * | 2010-12-02 | 2020-06-29 | Johnson Matthey Plc | Metalholdig zeolitkatalysator |
WO2012131914A1 (ja) * | 2011-03-29 | 2012-10-04 | イビデン株式会社 | ハニカム構造体及び排ガス浄化装置 |
US9254481B2 (en) * | 2011-07-27 | 2016-02-09 | Johnson Matthey Public Limited Company | Low phosphorus chabazites |
CN102614910B (zh) * | 2012-03-16 | 2014-01-01 | 北京工业大学 | 用于氨选择性催化消除NOx的SAPO-34负载Cu-Fe催化剂的制备方法 |
CN102614908A (zh) * | 2012-03-16 | 2012-08-01 | 北京工业大学 | 用于氨选择性催化消除NOx的SSZ-13负载Cu-Fe催化剂的制备方法 |
SG10201703183UA (en) * | 2012-10-18 | 2017-06-29 | Basf Se | Post-treatment of a zeolitic material |
RU2704617C2 (ru) * | 2012-10-19 | 2019-10-30 | Басф Корпорейшн | 8-кольцевое молекулярное сито с малыми порами в качестве высокотемпературного катализатора скв |
CA2888512C (en) * | 2012-10-19 | 2020-09-22 | Basf Corporation | Mixed metal 8-ring small pore molecular sieve catalyst compositions, catalytic articles, systems and methods |
DE102014117669A1 (de) * | 2013-12-02 | 2015-06-03 | Johnson Matthey Public Limited Company | Struktursteuerungsmittelgemisch umfassende Synthese eines Cu-CHA mit hohem Siliciumdioxid-Anteil |
US20150290632A1 (en) * | 2014-04-09 | 2015-10-15 | Ford Global Technologies, Llc | IRON AND COPPER-CONTAINING CHABAZITE ZEOLITE CATALYST FOR USE IN NOx REDUCTION |
DE102015209987A1 (de) * | 2014-06-04 | 2015-12-10 | Johnson Matthey Public Limited Company | Nicht-PGM-Ammoniakschlupfkatalysator |
CN104607239A (zh) * | 2014-12-29 | 2015-05-13 | 清华大学苏州汽车研究院(吴江) | 铜铁复合基scr催化剂及其制备方法 |
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2017
- 2017-02-01 CA CA3013546A patent/CA3013546A1/en not_active Abandoned
- 2017-02-01 EP EP17747081.2A patent/EP3411145A4/en active Pending
- 2017-02-01 CN CN202411348035.4A patent/CN119215975A/zh active Pending
- 2017-02-01 BR BR112018015842-9A patent/BR112018015842B1/pt active IP Right Grant
- 2017-02-01 RU RU2018131407A patent/RU2018131407A/ru not_active Application Discontinuation
- 2017-02-01 CN CN201780019587.2A patent/CN108883403A/zh active Pending
- 2017-02-01 MX MX2018009534A patent/MX2018009534A/es unknown
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- 2017-02-01 WO PCT/IB2017/050545 patent/WO2017134581A1/en active Application Filing
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Also Published As
Publication number | Publication date |
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KR20180102199A (ko) | 2018-09-14 |
US11311867B2 (en) | 2022-04-26 |
RU2018131407A (ru) | 2020-03-03 |
EP3411145A1 (en) | 2018-12-12 |
US20180339288A1 (en) | 2018-11-29 |
CA3013546A1 (en) | 2017-08-10 |
CN108883403A (zh) | 2018-11-23 |
BR112018015842A2 (pt) | 2018-12-26 |
CN119215975A (zh) | 2024-12-31 |
JP6925350B2 (ja) | 2021-08-25 |
JP2019511354A (ja) | 2019-04-25 |
BR112018015842B1 (pt) | 2022-10-11 |
EP3411145A4 (en) | 2019-10-02 |
WO2017134581A1 (en) | 2017-08-10 |
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