[go: up one dir, main page]

ATE286919T1 - Metallocenkatalysator und katalysatorsystem für die herstellung von polypropylenemischungen aus iso- und syndiotaktischem polypropylene - Google Patents

Metallocenkatalysator und katalysatorsystem für die herstellung von polypropylenemischungen aus iso- und syndiotaktischem polypropylene

Info

Publication number
ATE286919T1
ATE286919T1 AT98201086T AT98201086T ATE286919T1 AT E286919 T1 ATE286919 T1 AT E286919T1 AT 98201086 T AT98201086 T AT 98201086T AT 98201086 T AT98201086 T AT 98201086T AT E286919 T1 ATE286919 T1 AT E286919T1
Authority
AT
Austria
Prior art keywords
catalyst
polypropylene
metallocene
iso
production
Prior art date
Application number
AT98201086T
Other languages
English (en)
Inventor
Edwar S Shamshoum
Margarito Lopez
Ted G Harris Iii
Sehyun Kim
Original Assignee
Fina Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology filed Critical Fina Technology
Application granted granted Critical
Publication of ATE286919T1 publication Critical patent/ATE286919T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT98201086T 1997-04-09 1998-04-09 Metallocenkatalysator und katalysatorsystem für die herstellung von polypropylenemischungen aus iso- und syndiotaktischem polypropylene ATE286919T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/835,618 US6143683A (en) 1997-04-09 1997-04-09 Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms

Publications (1)

Publication Number Publication Date
ATE286919T1 true ATE286919T1 (de) 2005-01-15

Family

ID=25269989

Family Applications (1)

Application Number Title Priority Date Filing Date
AT98201086T ATE286919T1 (de) 1997-04-09 1998-04-09 Metallocenkatalysator und katalysatorsystem für die herstellung von polypropylenemischungen aus iso- und syndiotaktischem polypropylene

Country Status (6)

Country Link
US (3) US6143683A (de)
EP (1) EP0870779B1 (de)
JP (1) JPH10338703A (de)
AT (1) ATE286919T1 (de)
DE (1) DE69828543T2 (de)
ES (1) ES2236863T3 (de)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6143854A (en) * 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
US6143683A (en) * 1997-04-09 2000-11-07 Fina Technology, Inc. Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms
US6245857B1 (en) * 1999-02-22 2001-06-12 Fina Technology, Inc. Compositions useful for tough, high crystallinity films
EP1031582A1 (de) * 1999-02-26 2000-08-30 Fina Research S.A. Verwendung und Herstellung von Polypropylen
KR100745495B1 (ko) 1999-03-10 2007-08-03 동경 엘렉트론 주식회사 반도체 제조방법 및 반도체 제조장치
EP1041180A1 (de) * 1999-03-30 2000-10-04 Fina Research S.A. Polypropylenfasern
JP4837879B2 (ja) * 2001-01-16 2011-12-14 エクソンモービル・ケミカル・パテンツ・インク 混合触媒組成物による重合法
US6777367B2 (en) 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
US6777366B2 (en) * 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
EP1300423A1 (de) * 2001-09-27 2003-04-09 Atofina Research S.A. Katalysatorsystem aus einer Mischung von Katalysatorbestandteilen zur Herstellung einer Polyolefinmischung
AU2003226284A1 (en) * 2002-04-12 2003-10-27 Milliken And Company Highly nucleated syndiotactic polypropylene
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
CA2488551A1 (en) 2002-06-26 2004-01-08 Avery Dennison Corporation Oriented films comprising polypropylene / olefin elastomer blends
EP1405866A1 (de) * 2002-09-27 2004-04-07 ATOFINA Research Produktion von Polyolefinen
WO2005108442A1 (en) 2002-10-15 2005-11-17 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
EP1493778A1 (de) * 2003-07-04 2005-01-05 Total Petrochemicals Research Feluy Herstellung von Polyolefinen
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
US8981028B2 (en) * 2005-03-17 2015-03-17 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
US7413812B2 (en) 2005-04-26 2008-08-19 Fina Technology, Inc. Polypropylene article and method of preparing polypropylene article
US20070040292A1 (en) * 2005-08-22 2007-02-22 Fina Technology, Inc. Polypropylene composition for high gloss retention
EP1762577A1 (de) * 2005-09-02 2007-03-14 Total Petrochemicals Research Feluy Schlagfeste propylen-copolymere vorbereitet in einem reactor
US8003739B2 (en) * 2007-10-17 2011-08-23 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins
US9662867B2 (en) 2006-06-14 2017-05-30 Avery Dennison Corporation Conformable and die-cuttable machine direction oriented labelstocks and labels, and process for preparing
EP2035226A2 (de) * 2006-06-20 2009-03-18 Avery Dennison Corporation Mehrschichtige polymerfolie für schmelzklebeetikettierung, etikettenrolle sowie etikett dafür
US7589138B2 (en) * 2006-12-05 2009-09-15 Fina Technology, Inc. Injection molding process
US20140051816A9 (en) * 2007-10-17 2014-02-20 Fina Technology, Inc. Multi-component catalyst systems for the production of reactor blends of polypropylene
US20130023755A1 (en) 2010-02-15 2013-01-24 Schrader Eugene F Syringe Products and Related Methods and Uses
TW201313762A (zh) * 2011-06-16 2013-04-01 Fina Technology 用於在反應器中產製聚丙烯摻合物之多組份二茂金屬觸媒系統
TW201313761A (zh) * 2011-06-16 2013-04-01 Fina Technology 用於在反應器中產製聚丙烯摻合物之多組份觸媒系統
US9676532B2 (en) 2012-08-15 2017-06-13 Avery Dennison Corporation Packaging reclosure label for high alcohol content products
WO2015187646A1 (en) 2014-06-02 2015-12-10 Avery Dennison Corporation Films with enhanced scuff resistance, clarity, and conformability
CN118202023A (zh) 2021-11-05 2024-06-14 埃克森美孚化学专利公司 聚丙烯粘度改性剂及其润滑油

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US5064797A (en) * 1987-04-03 1991-11-12 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US4939217A (en) * 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US4975403A (en) * 1987-09-11 1990-12-04 Fina Technology, Inc. Catalyst systems for producing polyolefins having a broad molecular weight distribution
US4939202A (en) * 1988-03-09 1990-07-03 The International Group, Inc. Barrier guard moisture-proof adhesive
KR100197327B1 (ko) * 1988-07-15 1999-06-15 치어즈 엠. 노우드 신디오택틱 폴리프로필렌
US5124404A (en) * 1990-08-21 1992-06-23 Great Lakes Chemical Corp. Flame retardant polypropylene molding compositions
JP3176386B2 (ja) * 1991-04-30 2001-06-18 三菱化学株式会社 アミノ基含有重合体
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5191132A (en) * 1991-05-09 1993-03-02 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
ATE199911T1 (de) * 1991-05-27 2001-04-15 Targor Gmbh Verfahren zur herstellung von polyolefinen mit breiter molmassenverteilung
AU657589B2 (en) * 1991-11-07 1995-03-16 Exxon Chemical Patents Inc. Process for producing polyolefin
JPH072936A (ja) * 1992-07-10 1995-01-06 Fina Technol Inc アイソタクチツクポリオレフイン製造のための方法及び触媒
US5269807A (en) * 1992-08-27 1993-12-14 United States Surgical Corporation Suture fabricated from syndiotactic polypropylene
US5643846A (en) * 1993-04-28 1997-07-01 Fina Technology, Inc. Process for a isotactic/syndiotactic polymer blend in a single reactor
CA2120315C (en) * 1993-04-30 2001-05-15 Joel L. Williams Medical articles and process therefor
CA2163789C (en) * 1993-05-25 2006-10-24 Terry John Burkhardt Supported metallocene catalyst systems for the polymerization of olefins, preparation and use thereof
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US5455305A (en) * 1993-07-12 1995-10-03 Montell North America Inc. Propylene polymer yarn and articles made therefrom
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
US5631202A (en) * 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
EP0650816A1 (de) * 1993-10-28 1995-05-03 Mitsui Toatsu Chemicals, Incorporated Verfahren zum Spritzgiessen von Mischungen aus syndiotaktischem Polypropylen und isotaktischem Polypropylen und damit erzeugte Produkte
JP3398439B2 (ja) * 1993-11-22 2003-04-21 三井化学株式会社 ポリ−α−オレフィンの製造方法
US5576262A (en) * 1994-06-02 1996-11-19 W. R. Grace & Co.-Conn. Glycol ether compounds for the production of polyolefin catalysts and supports
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
US6143683A (en) * 1997-04-09 2000-11-07 Fina Technology, Inc. Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms
US5892079A (en) * 1997-10-17 1999-04-06 Sri International Metallocene catalysts and associated methods of preparation and use
US6207606B1 (en) * 1998-05-15 2001-03-27 Univation Technologies, Llc Mixed catalysts and their use in a polymerization process

Also Published As

Publication number Publication date
DE69828543D1 (de) 2005-02-17
EP0870779A1 (de) 1998-10-14
JPH10338703A (ja) 1998-12-22
US6518377B1 (en) 2003-02-11
EP0870779B1 (de) 2005-01-12
US6143683A (en) 2000-11-07
DE69828543T2 (de) 2006-04-13
ES2236863T3 (es) 2005-07-16
US6362125B1 (en) 2002-03-26

Similar Documents

Publication Publication Date Title
ATE286919T1 (de) Metallocenkatalysator und katalysatorsystem für die herstellung von polypropylenemischungen aus iso- und syndiotaktischem polypropylene
DE69532461D1 (de) Katalysatorsysteme und Verfahren zur Herstellung von Polyolefinen mit breiter Molekulargewichtverteilung
RU93004723A (ru) Катализатор для полимеризации олефинов, способ его получения и способ гомо- или сополимеризации олефинов
ATE291030T1 (de) Substituierte metallocenverbindungen für olefinpolymerisationkatalysatorsystemen, deren zwischenverbindungen und verfahren zu ihrer herstellung
ES2163404T3 (es) Procedimiento para la produccion de poliolefinas y catalizador poliolefinico.
DE60034308D1 (de) Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationkatalysator, und ein Verfahren zur Herstellung von Polyolefinen
NO952217L (no) Etylenselektive metallocener med höy aktivitet
DE69408989D1 (de) Metallocen-katalysatorsysteme auf einem träger für die olefinpolymerisation, ihre herstellung und verwendung
DE69603811D1 (de) Träger für Olefinpolymerisationkatalysator, Olefinpolymerisationkatalysator und Verfahren zur Herstellung von Olefinpolymeren
ATE167198T1 (de) Katalysator für die olefinpolymerisation, verfahren zu seiner herstellung und seine verwendung
EA199800005A1 (ru) Способ взаимного перехода несовместимых катализаторов полимеризации
ATE179995T1 (de) Fester katalysatorbestandteil für die (co)polymerisation von ethylen, verfahren zu seiner herstellung, katalysator für die (co)polymerisation von ethylen und verfahren zur ethylen (co)polymerisation
DE68911812D1 (de) Katalysatorbestandteil für Olefinpolymerisation, Verfahren zur Herstellung davon, Olefinpolymerisationskatalysator und Verfahren zur Polymerisation von Olefinen.
DE69802500D1 (de) Katalysatorsysteme für die polymerisation, enthaltend heterozyklisch kondensierte cyclopentadienyl-liganden
DE69919102D1 (de) Metallocenkatalysatoren für Olefinpolymerisation, Verfahren zur Herstellung von Olefinpolymeren mit Metallocenkatalysatoren
DE69823988D1 (de) Gruppe 8-10 übergangsmetallkatalysator für die polymerisation von olefinen
DE60018775D1 (de) Geträgerter und modifizierter katalysator für die polymerisation von olefine
DE69609186D1 (de) Verbrückte metallocenverbindungen, verfahren zu deren herstellung und deren verwendung als olefinpolymerisationskatalysator
DE69904521D1 (de) Verbrückte Zirconocene, deren Herstellung und deren Verwendung als Katalysatorkomponente für die Polymerisation von Olefinen
DE69605372D1 (de) Katalysatorbestandteil für Olefinpolymerisation, Katalysator für Olefinpolymerisation, und Verfahren zur Herstellung von Olefinpolymeren
ATE185819T1 (de) Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen
IT1275812B1 (it) Sistema catalitico attivato per la (co)polimerizzazione delle alfa-olefine
DE19981705T1 (de) y-Oxo-Bis-Metallocen-Komplexvrbindungen und Katalysatoren, die dieselben für die Polymerisation von Olefinen verwenden, sowie Polymerisationsverfahren
BR9914828B1 (pt) processo para a polimerizaÇço de pelo menos uma ou mais olefinas.
DE69601760D1 (de) Katalysator für die Olefinpolymerisation und Verfahren zur Herstellung von Olefinpolymeren unter Verwendung desselben

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification

Ref document number: 0870779

Country of ref document: EP

REN Ceased due to non-payment of the annual fee