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AR111791A1 - HETEROARILO COMPOUNDS AS AGROCHEMICAL FUNGICIDES - Google Patents

HETEROARILO COMPOUNDS AS AGROCHEMICAL FUNGICIDES

Info

Publication number
AR111791A1
AR111791A1 ARP180101263A ARP180101263A AR111791A1 AR 111791 A1 AR111791 A1 AR 111791A1 AR P180101263 A ARP180101263 A AR P180101263A AR P180101263 A ARP180101263 A AR P180101263A AR 111791 A1 AR111791 A1 AR 111791A1
Authority
AR
Argentina
Prior art keywords
unsubstituted
substituted
heterocycloalkenyl
heterocycloalkyl
heteroaryl
Prior art date
Application number
ARP180101263A
Other languages
Spanish (es)
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of AR111791A1 publication Critical patent/AR111791A1/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Reivindicación 1: Uso de un compuesto de heteroarilo caracterizado por la fórmula (1), en donde X indica CR⁴ o N; Y indica CR⁵ o N; A se selecciona del grupo que consiste en un arilo no sustituido o sustituido de 6 miembros; heterocicloalquilo no sustituido o sustituido de 5 ó 6 miembros; heterocicloalquenilo no sustituido o sustituido de 5 ó 6 miembros; y un heteroarilo no sustituido o sustituido de 5 ó 6 miembros; en donde el heterocicloalquilo, heterocicloalquenilo y heteroarilo contienen, además de átomos de carbono, 1, 2, 3 ó 4 heteroátomos seleccionados independientemente de O, N o S como miembros del anillo; R¹ se selecciona del grupo que consiste en hidrógeno; -(CH₂)ₐOR⁶; -(CH₂)ᵇC(=O)-R⁷; -C(=O)-(CH₂)ᶜ=-R⁸; -C(=O)-(CH₂)ᵈ-OR⁹; -C(=O)-CR¹⁰(=CR¹¹); -C(=O)-(CH₂)ₑ-SR¹²; -(CH₂)ᶠ-O-C(=O)-R¹³; -(CH₂)ᵍ-C(=O)-OR¹⁴; -C(=O)-O-(CH₂)ₕ-R¹⁵; -O-C(=O)-O-(CH₂)ⁱ-R¹⁶; -C(=O)-NR¹⁷R¹⁸; -C(=S)-NR¹⁹R²⁰; -NR²¹R²²; -S(=O)ʲ-R²³; -(CH₂)ₖSi-(R²⁴)ₗ y -(CH₂)ₘ-O-(CH₂)ₙ-Si-(R²⁵)ₒ; R² se selecciona del grupo que consiste en hidrógeno; halógeno; CN; -C(=O)-OR¹⁴; alquilo no sustituido o sustituido; cicloalquilo no sustituido o sustituido y cicloalquenilo no sustituido o sustituido; R³ se selecciona del grupo que consiste en hidrógeno, halógeno; CN; -OR⁶, -C(=O)-OR¹⁴, alquilo no sustituido o sustituido; heteroalquilo no sustituido o sustituido; alquenilo no sustituido o sustituido; alquinilo no sustituido o sustituido; cicloalquilo no sustituido o sustituido; cicloalquenilo no sustituido o sustituido; heterocicloalquilo no sustituido o sustituido; y heterocicloalquenilo no sustituido o sustituido; R⁴ se selecciona del grupo que consiste en hidrógeno y halógeno; R⁵ se selecciona del grupo que consiste en hidrógeno; halógeno; CN; alquilo no sustituido o sustituido; alquenilo no sustituido o sustituido; alquinilo no sustituido o sustituido; cicloalquilo no sustituido o sustituido; cicloalquenilo no sustituido o sustituido; heterocicloalquilo no sustituido o sustituido y heterocicloalquenilo no sustituido o sustituido; R⁶, R⁷, R⁸, R⁹, R¹⁰, R¹¹, R¹², R¹³, R¹⁴, R¹⁵, R¹⁶, R¹⁷, R¹⁸, R¹⁹, R²⁰, R²¹, R²², R²³, R²⁴ y R²⁵ se seleccionan, independientemente entre sí, del grupo que consiste en hidrógeno; halógeno; CN; alquilo no sustituido o sustituido; alquenilo no sustituido o sustituido; alquinilo no sustituido o sustituido; cicloalquilo no sustituido o sustituido; cicloalquenilo no sustituido o sustituido; arilo no sustituido o sustituido; (alquilen)-arilo no sustituido o sustituido; heterocicloalquilo no sustituido o sustituido; heterocicloalquenilo no sustituido o sustituido; heteroarilo no sustituido o sustituido; o R¹⁷ junto con R¹⁸ forman un heterocicloalquilo, heterocicloalquenilo o heteroarilo; en donde el heterocicloalquilo, heterocicloalquenilo o heteroarilo es no sustituido o sustituido; o R¹⁹ junto con R²⁰ forman un heterocicloalquilo, heterocicloalquenilo o heteroarilo; en donde el heterocicloalquilo, heterocicloalquenilo o heteroarilo es no sustituido o sustituido; o R²¹ junto con R²² forman un heterocicloalquilo, heterocicloalquenilo o heteroarilo; en donde el heterocicloalquilo, heterocicloalquenilo o heteroarilo es no sustituido o sustituido; a es 0, 1, 2 ó 3; b es 0, 1, 2 ó 3; c es 0, 1, 2 ó 3; d es 0, 1, 2 ó 3; e es 0, 1, 2 ó 3; f es 0, 1, 2 ó 3; g es 0, 1, 2 ó 3; h es 1, 2 ó 3; i es 1, 2 ó 3; j es 0, 1, 2 ó 3; k es 0, 1, 2 ó 3; l es 0, 1, 2 ó 3; m es 0, 1, 2 ó 3; n es 0, 1, 2 ó 3; o es 1, 2 ó 3; o cada compuesto en forma de un estereoisómero, una sal aceptable en la agricultura, un profármaco, un tautómero, una forma isotópica, un N-óxido, un S-óxido o una mezcla de estos, como un fungicida agrícola.Claim 1: Use of a heteroaryl compound characterized by the formula (1), wherein X indicates CR⁴ or N; Y indicates CR⁵ or N; A is selected from the group consisting of an unsubstituted or substituted 6-membered aryl; 5 or 6-membered unsubstituted or substituted heterocycloalkyl; 5 or 6-membered unsubstituted or substituted heterocycloalkenyl; and an unsubstituted or substituted 5 or 6 membered heteroaryl; wherein the heterocycloalkyl, heterocycloalkenyl and heteroaryl contain, in addition to carbon atoms, 1, 2, 3 or 4 heteroatoms independently selected from O, N or S as ring members; R¹ is selected from the group consisting of hydrogen; - (CH₂) ₐOR⁶; - (CH₂) ᵇC (= O) -R⁷; -C (= O) - (CH₂) ᶜ = -R⁸; -C (= O) - (CH₂) ᵈ-OR⁹; -C (= O) -CR¹⁰ (= CR¹¹); -C (= O) - (CH₂) ₑ-SR¹²; - (CH₂) ᶠ-O-C (= O) -R¹³; - (CH₂) ᵍ-C (= O) -OR¹⁴; -C (= O) -O- (CH₂) ₕ-R¹⁵; -O-C (= O) -O- (CH₂) ⁱ-R¹⁶; -C (= O) -NR¹⁷R¹⁸; -C (= S) -NR¹⁹R²⁰; -NR²¹R²²; -S (= O) ʲ-R²³; - (CH₂) ₖSi- (R²⁴) ₗ and - (CH₂) ₘ-O- (CH₂) ₙ-Si- (R²⁵) ₒ; R² is selected from the group consisting of hydrogen; halogen; CN; -C (= O) -OR¹⁴; unsubstituted or substituted alkyl; unsubstituted or substituted cycloalkyl and unsubstituted or substituted cycloalkenyl; R³ is selected from the group consisting of hydrogen, halogen; CN; -OR⁶, -C (= O) -OR¹⁴, unsubstituted or substituted alkyl; unsubstituted or substituted heteroalkyl; unsubstituted or substituted alkenyl; unsubstituted or substituted alkynyl; unsubstituted or substituted cycloalkyl; unsubstituted or substituted cycloalkenyl; unsubstituted or substituted heterocycloalkyl; and unsubstituted or substituted heterocycloalkenyl; R⁴ is selected from the group consisting of hydrogen and halogen; R⁵ is selected from the group consisting of hydrogen; halogen; CN; unsubstituted or substituted alkyl; unsubstituted or substituted alkenyl; unsubstituted or substituted alkynyl; unsubstituted or substituted cycloalkyl; unsubstituted or substituted cycloalkenyl; unsubstituted or substituted heterocycloalkyl and unsubstituted or substituted heterocycloalkenyl; R⁶, R⁷, R⁸, R⁹, R¹⁰, R¹¹, R¹², R¹³, R¹⁴, R¹⁵, R¹⁶, R¹⁷, R¹⁸, R¹⁹, R²⁰, R²¹, R²², R²³, R²⁴ and R²⁵ are selected, independently of each other, from the group consisting in hydrogen; halogen; CN; unsubstituted or substituted alkyl; unsubstituted or substituted alkenyl; unsubstituted or substituted alkynyl; unsubstituted or substituted cycloalkyl; unsubstituted or substituted cycloalkenyl; unsubstituted or substituted aryl; (alkylene) unsubstituted or substituted aryl; unsubstituted or substituted heterocycloalkyl; unsubstituted or substituted heterocycloalkenyl; unsubstituted or substituted heteroaryl; or R¹⁷ together with R¹⁸ form a heterocycloalkyl, heterocycloalkenyl or heteroaryl; wherein the heterocycloalkyl, heterocycloalkenyl or heteroaryl is unsubstituted or substituted; or R¹⁹ together with R²⁰ form a heterocycloalkyl, heterocycloalkenyl or heteroaryl; wherein the heterocycloalkyl, heterocycloalkenyl or heteroaryl is unsubstituted or substituted; or R²¹ together with R²² form a heterocycloalkyl, heterocycloalkenyl or heteroaryl; wherein the heterocycloalkyl, heterocycloalkenyl or heteroaryl is unsubstituted or substituted; a is 0, 1, 2 or 3; b is 0, 1, 2 or 3; c is 0, 1, 2 or 3; d is 0, 1, 2 or 3; e is 0, 1, 2 or 3; f is 0, 1, 2 or 3; g is 0, 1, 2 or 3; h is 1, 2 or 3; i is 1, 2 or 3; j is 0, 1, 2 or 3; k is 0, 1, 2 or 3; l is 0, 1, 2 or 3; m is 0, 1, 2 or 3; n is 0, 1, 2 or 3; or is 1, 2 or 3; or each compound in the form of a stereoisomer, an acceptable salt in agriculture, a prodrug, a tautomer, an isotopic form, an N-oxide, an S-oxide or a mixture thereof, as an agricultural fungicide.

ARP180101263A 2017-05-15 2018-05-14 HETEROARILO COMPOUNDS AS AGROCHEMICAL FUNGICIDES AR111791A1 (en)

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EP17171109 2017-05-15

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EP3730489A1 (en) * 2019-04-25 2020-10-28 Basf Se Heteroaryl compounds as agrochemical fungicides
AR120374A1 (en) * 2019-11-08 2022-02-09 Pi Industries Ltd OXADIAZOLE COMPOUNDS CONTAINING FUSED HETEROCYCYL RINGS TO CONTROL OR PREVENT PHYTOPATHOGENIC FUNGI

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