AR081918A1 - Un proceso para eliminar compuestos reductores de permanganato (prc) de una corriente en bruto que contiene acido acetico - Google Patents
Un proceso para eliminar compuestos reductores de permanganato (prc) de una corriente en bruto que contiene acido aceticoInfo
- Publication number
- AR081918A1 AR081918A1 ARP110101711A ARP110101711A AR081918A1 AR 081918 A1 AR081918 A1 AR 081918A1 AR P110101711 A ARP110101711 A AR P110101711A AR P110101711 A ARP110101711 A AR P110101711A AR 081918 A1 AR081918 A1 AR 081918A1
- Authority
- AR
- Argentina
- Prior art keywords
- prc
- acetic acid
- column
- processes
- eliminate
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 18
- 238000000034 method Methods 0.000 title abstract 9
- 150000001875 compounds Chemical class 0.000 title abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 230000006315 carbonylation Effects 0.000 abstract 3
- 238000005810 carbonylation reaction Methods 0.000 abstract 3
- 238000004821 distillation Methods 0.000 abstract 3
- 239000008346 aqueous phase Substances 0.000 abstract 2
- 238000000605 extraction Methods 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0492—Applications, solvents used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Procesos para reducir y/o eliminar los compuestos reductores de permanganato (PRC, por sus iniciales en inglés) que se forman con la carbonilación del metanol en presencia de un catalizador de la carbonilación de metales del grupo VIII para producir ácido acético. Más particularmente, procesos para reducir y/o eliminar los PRC o sus precursores de las corrientes intermediarias durante la formación de ácido acético en dichos procesos de carbonilación. En particular, procesos en los cuales se somete a destilación a una corriente de vapor de cabeza con bajo punto de ebullición proveniente de una columna de fracciones volátiles para obtener una cabeza que se somete a una extracción con el fin de eliminar y/o reducir selectivamente los PRC del proceso. Los procesos incluyen los pasos de reciclar una o más corrientes de retorno derivadas del paso de destilación y/o del paso de extracción hacia una columna de fracciones livianas y/o una columna de secado con el fin de mejorar el control del agua en el sistema de reacción general.Reivindicación 1: Un proceso para eliminar compuestos reductores de permanganato (PRC, por sus iniciales en inglés) de una composición en bruto que comprende ácido acético y uno o más PRC, donde el proceso comprende los pasos de: (a) separar la composición en bruto que contiene ácido acético en una columna de fracciones volátiles para dar una corriente enriquecida en PRC y una corriente de ácido acético; (b) separar la corriente enriquecida en PRC para obtener una fase acuosa y una fase orgánica; (c) separar la fase acuosa en una columna de destilación para dar una corriente de cabeza y una corriente del fondo; y (d) dirigir hacia la columna de fracciones volátiles a una primera corriente de retorno que comprende una porción de alícuota de la corriente del fondo.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US34583310P | 2010-05-18 | 2010-05-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR081918A1 true AR081918A1 (es) | 2012-10-31 |
Family
ID=44579122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP110101711A AR081918A1 (es) | 2010-05-18 | 2011-05-18 | Un proceso para eliminar compuestos reductores de permanganato (prc) de una corriente en bruto que contiene acido acetico |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US8889904B2 (es) |
| JP (2) | JP5837576B2 (es) |
| CN (2) | CN105111067B (es) |
| AR (1) | AR081918A1 (es) |
| TW (1) | TWI518068B (es) |
| WO (1) | WO2011146446A1 (es) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070161970A1 (en) | 2004-04-16 | 2007-07-12 | Medrad, Inc. | Fluid Delivery System, Fluid Path Set, and Pressure Isolation Mechanism with Hemodynamic Pressure Dampening Correction |
| US8852167B2 (en) | 2005-12-01 | 2014-10-07 | Bayer Medical Care Inc. | Medical connector |
| WO2011146446A1 (en) | 2010-05-18 | 2011-11-24 | Celanese International Corporation | Process for purifying acetic acid streams by removing permanganate reducing compounds |
| JP6166043B2 (ja) | 2010-12-15 | 2017-07-19 | 株式会社ダイセル | 酢酸の製造方法 |
| TWI547477B (zh) | 2012-03-14 | 2016-09-01 | 大賽璐股份有限公司 | 醋酸之製造方法 |
| US9889288B2 (en) | 2012-06-07 | 2018-02-13 | Bayer Healthcare Llc | Tubing connectors |
| US8859810B2 (en) * | 2012-08-21 | 2014-10-14 | Celanese International Corporation | Process for recovering permanganate reducing compounds from an acetic acid production process |
| WO2016054608A1 (en) | 2014-10-02 | 2016-04-07 | Celanese International Corporation | Process for producing acetic acid |
| US9340481B1 (en) | 2014-11-14 | 2016-05-17 | Celanese International Corporation | Process for flashing a reaction medium comprising lithium acetate |
| ES2807618T3 (es) * | 2014-11-14 | 2021-02-23 | Celanese Int Corp | Procesos para producir ácido acético a partir de un medio de reacción que tiene bajo contenido de yoduro de etilo |
| US9260369B1 (en) | 2014-11-14 | 2016-02-16 | Celanese International Corporation | Processes for producing acetic acid product having low butyl acetate content |
| US9233907B1 (en) | 2014-11-14 | 2016-01-12 | Celanese International Corporation | Reducing hydrogen iodide content in carbonylation processes |
| CN107108430B (zh) * | 2014-11-14 | 2019-05-10 | 国际人造丝公司 | 具有倾析器控制的生产乙酸的方法 |
| US9302975B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for flashing a reaction medium |
| US9487464B2 (en) | 2015-01-30 | 2016-11-08 | Celanese International Corporation | Processes for producing acetic acid |
| WO2016122727A1 (en) | 2015-01-30 | 2016-08-04 | Celanese International Corporation | Processes for producing acetic acid |
| SG11201706008YA (en) | 2015-01-30 | 2017-08-30 | Celanese Int Corp | Processes for producing acetic acid |
| US9561994B2 (en) | 2015-01-30 | 2017-02-07 | Celanese International Corporation | Processes for producing acetic acid |
| US10413840B2 (en) | 2015-02-04 | 2019-09-17 | Celanese International Coporation | Process to control HI concentration in residuum stream |
| US9512056B2 (en) * | 2015-02-04 | 2016-12-06 | Celanese International Corporation | Process to control HI concentration in residuum stream |
| US9505696B2 (en) * | 2015-02-04 | 2016-11-29 | Celanese International Corporation | Process to control HI concentration in residuum stream |
| US9382183B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for flashing a reaction medium |
| US9302974B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for producing acetic acid |
| US9416088B1 (en) | 2015-10-02 | 2016-08-16 | Celanese International Corporation | Process to produce acetic acid with recycle of water |
| KR102438920B1 (ko) * | 2015-10-02 | 2022-08-31 | 셀라니즈 인터내셔날 코포레이션 | 물의 재순환과 함께 아세트산을 생산하는 방법 |
| US9908835B2 (en) | 2015-11-13 | 2018-03-06 | Celanese International Corporation | Processes for purifying acetic and hydrating anhydride |
| US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
| BR112018074026A2 (pt) * | 2016-07-07 | 2019-02-26 | Daicel Corporation | processos para separação ou remoção de compostos redutores de permanganato (prc?s) de uma primeira mistura e para produção de ácido acético |
| BR112019008340A2 (pt) | 2016-10-28 | 2019-08-06 | Daicel Corp | método para produzir ácido acético |
| US10308581B2 (en) | 2017-03-28 | 2019-06-04 | Daicel Corporation | Method for producing acetic acid |
| ES2779805T3 (es) * | 2017-03-28 | 2020-08-19 | Daicel Corp | Método para la producción de ácido acético |
| US10807935B2 (en) | 2018-11-02 | 2020-10-20 | Celanese International Corporation | Process for continuous acetic acid production |
| EP3838363A1 (en) * | 2019-12-17 | 2021-06-23 | BP Chemicals Limited | Separation process and apparatus |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3769329A (en) | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
| CA1228867A (en) | 1984-05-03 | 1987-11-03 | G. Paull Torrence | Methanol carbonylation process |
| US5026908A (en) | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5001259A (en) | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
| TW283702B (es) | 1993-07-08 | 1996-08-21 | Daicel Chem | |
| SG44317A1 (en) | 1994-06-15 | 1997-12-19 | Daicel Chem | Process for producing high purity acetic acid |
| US6339171B1 (en) * | 1996-10-18 | 2002-01-15 | Celanese International Corporation | Removal or reduction of permanganate reducing compounds and alkyl iodides from a carbonylation process stream |
| IN192600B (es) | 1996-10-18 | 2004-05-08 | Hoechst Celanese Corp | |
| US7223886B2 (en) | 2004-03-02 | 2007-05-29 | Celanese International Corporation | Removal of permanganate reducing compounds from methanol carbonylation process stream |
| US7271293B2 (en) | 2004-03-02 | 2007-09-18 | Celanese International Corporation | Control method for process of removing permanganate reducing compounds from methanol carbonylation process |
| US7223883B2 (en) * | 2004-03-02 | 2007-05-29 | Celanese International Corporation | Removal of permanganate reducing compounds from methanol carbonylation process stream |
| US20060247266A1 (en) | 2004-11-26 | 2006-11-02 | Asahi Kasei Pharma Corporation | Nitrogen-containing tricyclic compounds |
| US7855306B2 (en) * | 2005-04-28 | 2010-12-21 | Celanese International Corporation | Process for the production of acetic acid |
| JP2007284404A (ja) | 2006-04-20 | 2007-11-01 | Daicel Chem Ind Ltd | アセトアルデヒドの除去方法 |
| US7524988B2 (en) | 2006-08-01 | 2009-04-28 | Lyondell Chemical Technology, L.P. | Preparation of acetic acid |
| US7208625B1 (en) | 2006-08-04 | 2007-04-24 | Lyondell Chemical Technology, L.P. | Removing permanganate-reducing impurities from acetic acid |
| US7989659B2 (en) | 2007-05-17 | 2011-08-02 | Celanese International Corporation | Method and apparatus for making acetic acid with improved light ends column productivity |
| US7902397B2 (en) * | 2007-10-11 | 2011-03-08 | Celanese International Corporation | Method and apparatus for making acetic acid with improved productivity |
| CN101391946A (zh) | 2008-11-04 | 2009-03-25 | 江苏索普（集团）有限公司 | 甲醇羰基化合成醋酸过程中乙醛含量的控制方法 |
| US7884237B2 (en) | 2008-11-07 | 2011-02-08 | Celanese International Corp. | Methanol carbonylation with improved aldehyde removal |
| US8076508B2 (en) * | 2008-12-08 | 2011-12-13 | Lyondell Chemical Technology | Preparation of acetic acid |
| WO2011146446A1 (en) | 2010-05-18 | 2011-11-24 | Celanese International Corporation | Process for purifying acetic acid streams by removing permanganate reducing compounds |
-
2011
- 2011-05-17 WO PCT/US2011/036765 patent/WO2011146446A1/en active Application Filing
- 2011-05-17 CN CN201510544513.3A patent/CN105111067B/zh active Active
- 2011-05-17 CN CN201180032069.7A patent/CN102971284B/zh active Active
- 2011-05-17 JP JP2013511279A patent/JP5837576B2/ja active Active
- 2011-05-17 US US13/109,348 patent/US8889904B2/en active Active
- 2011-05-18 AR ARP110101711A patent/AR081918A1/es unknown
- 2011-05-18 TW TW100117371A patent/TWI518068B/zh active
-
2014
- 2014-09-17 US US14/488,900 patent/US9149735B2/en active Active
-
2015
- 2015-09-09 US US14/849,003 patent/US9409848B2/en active Active
- 2015-10-22 JP JP2015207985A patent/JP6165820B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105111067A (zh) | 2015-12-02 |
| WO2011146446A1 (en) | 2011-11-24 |
| CN102971284A (zh) | 2013-03-13 |
| US20150021160A1 (en) | 2015-01-22 |
| CN105111067B (zh) | 2018-02-06 |
| JP2016040305A (ja) | 2016-03-24 |
| JP2013526571A (ja) | 2013-06-24 |
| TWI518068B (zh) | 2016-01-21 |
| US9149735B2 (en) | 2015-10-06 |
| TW201141828A (en) | 2011-12-01 |
| US9409848B2 (en) | 2016-08-09 |
| US20150376105A1 (en) | 2015-12-31 |
| CN102971284B (zh) | 2016-01-27 |
| US8889904B2 (en) | 2014-11-18 |
| JP5837576B2 (ja) | 2015-12-24 |
| JP6165820B2 (ja) | 2017-07-19 |
| US20110288333A1 (en) | 2011-11-24 |
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| FB | Suspension of granting procedure |