SAFETY DATA SHEET
Issue Date 20-Jul-2018 Revision Date 20-Jul-2018 Version 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier
Product Name Alkaline pH Booster
Other means of identification
Product Code NL195500
Synonyms None
Details of the supplier of the safety data sheet
Company Name Basic Integrated Oil Services
Emergency telephone number
Emergency Telephone Chemtrec 1-800-424-9300
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Not classified
Acute toxicity - Dermal Not classified
Skin corrosion/irritation Category 1 Sub-category A
Serious eye damage/eye irritation Category 1
Label elements
Emergency Overview
Danger
Hazard statements
Causes severe skin burns and eye damage
Appearance Clear Colorless Physical state Liquid Odor Nil
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Precautionary Statements - Prevention
Do not breathe dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after
handling Wear protective gloves/protective clothing/eye
protection/face protection
Precautionary Statements - Response
Specific Treatment (See Section 4 on the SDS)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing Immediately call a POISON CENTER or doctor/physician
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower Wash contaminated clothing before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing Immediately call a POISON CENTER or doctor/physician
IF SWALLOWED: Rinse mouth. DO NOT induce
vomiting Drink plenty of water
Immediately call a POISON CENTER or doctor/physician
Precautionary Statements - Storage
Store locked up
Precautionary Statements - Disposal
Disposal should be in accordance with applicable regional, national and local laws and regulations
Hazards not otherwise classified (HNOC)
Other Information
•Harmful to aquatic life with long lasting effects
•Harmful to aquatic life
Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Weight-% Trade Secret
Sodium Hydroxide 1310-73-2 10-30 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures
General advice Immediate medical attention is required.
Skin Contact Immediate medical attention is required. Wash off immediately with soap
and plenty of water while removing all contaminated clothes and shoes. For
minor skin contact, avoid spreading material on unaffected skin. For severe
burns, immediate medical attention is required.
Eye contact Immediate medical attention is required. Rinse immediately with plenty of
water, also under the eyelids, for at least 15 minutes. Keep eye wide open while
rinsing. Do not rub affected area. Immediately flush with plenty of water. After
initial flushing, remove any contact lenses and continue flushing for at least 15
minutes.
Inhalation Remove to fresh air. Call a physician or poison control center immediately. If
not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Ingestion Immediate medical attention is required. Do NOT induce vomiting. Drink plenty
of water.
Never give anything by mouth to an unconscious person. Remove from
exposure, lie down. Clean mouth with water and drink afterwards plenty of
water. Call a physician or poison control center immediately.
Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or
NL195500 Alkaline pH Booster Revision Date 20-Jul-
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clothing.
NL195500 Alkaline pH Booster Revision Date 20-Jul-
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Most important symptoms and effects, both acute and delayed
Symptoms Any additional important symptoms and effects are described in Section 11:
Toxicology Information.
Indication of any immediate medical attention and special treatment needed
Note to physicians Product is a corrosive material. Use of gastric lavage or emesis is
contraindicated.
Possible perforation of stomach or esophagus should be investigated. Do not
give chemical antidotes. Asphyxia from glottal edema may occur. Marked
decrease in blood pressure may occur with moist rales, frothy sputum, and
high pulse pressure. Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the chemical
The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of
irritating and toxic gases and vapors. In the event of fire and/or explosion do not breathe fumes.
Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Evacuate personnel to safe areas. Use personal protective equipment as
required. Avoid
contact with skin, eyes or clothing. Keep people away from and upwind of
spill/leak.
Environmental precautions
Environmental precautions Do not allow into any storm sewer drains, lakes, streams, ponds, estuaries,
oceans or other
surface water bodies. Should not be released into the environment. Dispose of
according to all local city, state and federal rules and regulations.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent
material. Take
up mechanically, placing in appropriate containers for disposal. Clean
contaminated surface thoroughly. Prevent product from entering drains. Dam
up. After cleaning, flush away traces with water.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Use personal protective equipment as required. Avoid contact with skin, eyes or
clothing.
Ensure adequate ventilation, especially in confined areas. In case of insufficient
ventilation, wear suitable respiratory equipment. Use only with adequate
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ventilation and in closed systems.
Conditions for safe storage, including any incompatibilities
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Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Keep out of the
reach of
children. Keep containers tightly closed in a dry, cool and well-ventilated place.
Keep in properly labeled containers.
Incompatible materials Incompatible with strong acids and bases. Incompatible with oxidizing agents.
Strong acids.
Aluminum.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines .
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Sodium Hydroxide Ceiling: 2 mg/m3 TWA: 2 mg/m3 IDLH: 10 mg/m3
1310-73-2 (vacated) Ceiling: 2 mg/m3 Ceiling: 2 mg/m3
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965
F.2d 962 (11th Cir., 1992).
Appropriate engineering controls
Engineering Controls Showers, Eyewash stations & Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection Tight sealing safety goggles. Face protection shield.
Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron
or coveralls, as appropriate, to prevent skin contact.
Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA
approved respiratory protection should be worn. Positive-pressure supplied
air respirators may be required for high airborne contaminant
concentrations. Respiratory protection must be provided in accordance with
current local regulations.
General Hygiene When using do not eat, drink or smoke. Keep away from food, drink and animal
feeding
stuffs. Contaminated work clothing should not be allowed out of the workplace.
Regular cleaning of equipment, work area and clothing is recommended. Avoid
contact with skin, eyes or clothing. Take off all contaminated clothing and wash
it before reuse. Wear suitable gloves and eye/face protection.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical
properties Physical state Liquid
Appearance Clear Colorless
Color Colorless
Odor Nil
Odor threshold No Information available
Property Values Remarks • Method
pH 13.0 - 14.0
Specific Gravity 1.20
Viscosity < 25 cP @ 25°C
Melting point/freezing point No Information available
Flash point None
Boiling point / boiling range 143 °C / 290 ° F
Degrees Evaporation rate No Information
available Flammability (solid, gas) No data available
Flammability Limits in Air
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Upper flammability limit: No Information
available Lower flammability limit: No Information
available Vapor pressure No Information
available
Vapor density No Information available
Water solubility Complete
Partition coefficient No Information
available Autoignition temperature No Information
available Decomposition temperature No
Information available
Other Information
Density Lbs/Gal 9.99
VOC Content (%) Not Applicable
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Exposure to air or moisture over prolonged periods.
Incompatible materials
Incompatible with strong acids and bases. Incompatible with oxidizing agents. Strong acids. Aluminum.
Hazardous Decomposition Products
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information The primary effects and toxicity of this material are due to it corrosive nature.
Inhalation Avoid breathing vapors or mists. Breathing of vapor can cause respiratory
irritation and inflammation. Breathing of mist or liquid can cause burns to
the respiratory tract.
Eye contact Avoid contact with eyes. Corrosive. Causes severe eye damage.
Skin Contact Avoid contact with skin. Corrosive. Contact with skin may cause severe irritation
and burns.
Ingestion Causes burns.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Sodium - = 1350 mg/kg ( Rabbit ) -
Hydroxide
1310-73-2
Information on toxicological effects
Symptoms No Information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Corrosivity Causes burns. Extremely corrosive and destructive to tissue. Risk of serious
damage to eyes.
NL195500 Alkaline pH Booster Revision Date 20-Jul-
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Sensitization No Information available.
Germ cell mutagenicity No Information available.
Carcinogenicity No Information available.
NL195500 Alkaline pH Booster Revision Date 20-Jul-
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Reproductive toxicity No Information available.
STOT - single exposure No Information available.
STOT - repeated exposure No Information available.
Chronic toxicity Chronic exposure to corrosive fumes/gases may cause erosion of the teeth
followed by jaw necrosis. Bronchial irritation with chronic cough and frequent
attacks of pneumonia are common. Gastrointestinal disturbances may also be
seen. Avoid repeated exposure.
Possible risk of irreversible effects.
Target organ effects EYES, Respiratory system, Skin.
Aspiration hazard No Information available.
Numerical measures of toxicity - Product Information
Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (dermal) 5,400.00
12. ECOLOGICAL INFORMATION
Ecotoxicity
0% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
Sodium - 45.4: 96 h Oncorhynchus -
Hydroxide mykiss mg/L LC50
1310-73-2 static
Persistence and degradability
No Information available.
Bioaccumulation
No Information available.
Other adverse effects No Information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local
laws and
regulations.
Contaminated packaging Do not reuse container.
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
Sodium Toxic
Hydroxide Corrosiv
1310-73-2 e
14. TRANSPORT INFORMATION
The basic description below is specific to the container size. This information is provided for at a glance DOT
information. Please refer to the container and/or shipping papers for the appropriate shipping description before
tendering this material for shipment. For additional information, please contact the distributor listed in section 1 of
this SDS.
DOT
UN/ID No. UN3266
Proper shipping name Corrosive liquid, basic, inorganic, n.o.s.
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Hazard Class 8
Packing Group II
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Special Provisions B2, IB2, T11, TP2, TP27
Description UN3266, Corrosive liquid, basic, inorganic, n.o.s. (contains Sodium Hydroxide),
8, II
TDG
UN/ID No. UN3266
Proper shipping name Corrosive liquid, basic, inorganic, n.o.s.
Hazard Class 8
Packing Group II
Description UN3266, Corrosive liquid, basic, inorganic, n.o.s. (contains Sodium Hydroxide),
8, II
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does
not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of
Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act
(40 CFR 122.21 and 40 CFR 122.42)
Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
Sodium 1000 lb - - X
Hydroxide
1310-73-2
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the
Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
Sodium 1000 lb - RQ 1000 lb final RQ
Hydroxide RQ 454 kg final RQ
1310-73-2
US State Regulations
California Proposition 65
This product has been evaluated and does not require warning labeling under California Proposition 65.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Sodium X X X
Hydroxide
1310-73-2
U.S. EPA Label Information
NL195500 Alkaline pH Booster Revision Date 20-Jul-
2018
EPA Pesticide Registration Number Not Applicable
NL195500 Alkaline pH Booster Revision Date 20-Jul-
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16. OTHER INFORMATION
NFPA Health hazards 3 Flammability 0 Instability 0 Physical and Chemical
Properties -
HMIS Health hazards 3 Flammability 0 Physical hazards 0 Personal protection D
Issue Date 20-Jul-2018
Revision Date 20-Jul-2018
Revision Note
No Information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet