Solution
Solution
9610WJA802124250010 JA
PART 1 : PHYSICS
SECTION-I (i)
1) Two concentric conducting thin spherical shells have radii a and b (a < b). If they are charged to
+Q and –2Q, the E-r graph is :
(A)
(B)
(C)
(D)
2) Three large conducting plates are arranged as shown in diagram. If potential difference between
(A) 6
(B) 4
(C) 2
(D) 1
3) Rod is released from horizontal position. Find the angular velocity of rod when it becomes
vertical. 10 kg mass is fixed on the other end of the rod as shown in figure. The rod has mass 20kg
and length 10 meter :-
(A)
rad/sec
(B)
rad/sec
(C)
rad/sec
(D) 12 rad/sec
4) A block of mass m is placed on rough horizontal floor. Coefficient of friction between block and
floor is µ & force F is applied as shown in diagram & block is accelerating towards right. Then its
(A)
(B)
(C)
(D)
SECTION-I (ii)
If f is increased keeping I and work function constant then maximum kinetic energy of
(A)
photoelectron increases.
(B) If distance between cathode and anode is increased stopping potential increases
If I is increased keeping f and work function constant then stopping potential remains same and
(C)
saturation current increases.
(D) Work function is decreased keeping f and I constant then stopping potential increases
2) The disc of radius r is confined to roll without slipping at A and B. If the plates have the velocities
shown, then
(B)
angular velocity of disc is
(C)
angular velocity of disc is
(D) None of these
3) The potential energy of a particle of mass 1 kg in a conservative field is given as U = (3x2y2 + 6x)
J, where x and y are measured in meter. Initially particle is at (1,1) & at rest then :
SECTION-II (i)
1) On a semicircular ring of radius 4R, charge +3q is distributed in such a way that on one quarter
+q is uniformly distributed and on another quarter +2q is uniformly distributed. Along its axis a
smooth non-conducting and uncharged pipe of length 6R is fixed in such a way that the center of
both coincide as shown. A ball of mass m and charge +q is thrown from one end of the pipe with
speed u. The minimum speed ‘u’ so that ball will come out from the other end of pipe should be
2)
A block of mass 5 kg is placed between two spring, just touching them and not connected to any of
the spring. If the block is displaced slightly and released, then the time period of resulting oscillation
A particle of mass 5 × 10–5 kg is placed at the lowest point of a smooth parabola having the equation
20x2 = y (x,y in m), here y is the vertical height. If it is displaced slightly and it moves such that it is
constrained to move along the parabola, the angular frequency of oscillation will be, (in rad/s). If
your answer is 5N fill value of N.
4) A uniform semicircular disc of mass ‘M’ and radius ‘R’ hinged at point O as shown in figure is
released from rest from a vertical position as shown. If the initial magnitude of angular acceleration
5) A uniform disc of radius R = 0.2 m is projected along a rough horizontal surface with initial linear
velocity v0 = 2m/s and initial angular velocty ω0 = 5 rad/sec as shown in the figure. Coefficient of
friction is µ = 0.1. The time (in second) at which it starts pure rolling is. (Take g = 10 m/s2)
6) A spherical region of radius 3R have three different volume charge density +ρ, –2ρ and +3ρ as
SECTION-II (ii)
2) If the total distance traveled by the elevator before coming to rest is A meter, then find the value
of 3A.
PART 2 : CHEMISTRY
SECTION-I (i)
(A) 3-Cyclopropane-1-propene
(B) 1-Allyl cyclopropane
(C) 3-Cyclopropyl-1-propene
(D) 2-Propenylcyclopropane
2) Correct order of basic strength in aqueous solution is-
(A)
(B)
(C)
(D)
(A) 0.58 V
(B) 0.48 V
(C) 0.38 V
(D) 0.28 V
(A) 10.63
(B) 9.37
(C) 8.63
(D) 8.37
SECTION-I (ii)
1) When AgNO3 is added to a solution of Co(NH3)5 Cl3 , the precipitate of AgCl shows two ionized
chloride ions. This means –
(A) Only two chlorine atoms satisfy primary valency and one secondary valency
(B) One chlorine atom satisfies primary as well as secondary valency
(C) Three chlorine atoms satisfy primary valency
(D) Three chlorine atoms satisfy secondary valency.
(A)
(B)
(C)
(D)
SECTION-II (i)
1) At 25°C, the degree of dissociation of pure water is 1.9 × 10–9. If the specific conductance of
water at this temperature is x × 10–6 Sm–1. Calculate the value of x. Given ionic molar conductances
at infinite dilution for H+ and OH– ions are 350 × 10–4 and 200 × 10–4 Sm2 mole–1 respectively
2) 11.2 ml of a H2O2 solution require 30 ml of K2Cr2O7 solution for complete oxidation. Hence
volume strength of H2O2 is _____.
4) How many of the following carbocations have stability greater than an isopropyl cation
(CH3)2CH⊕ ?
5) When 0.01 mole of NaOH are added to a litre of buffer solution, it’s pH changes from 4.745 to
4.815. The buffer capacity of the buffer solution is 0.07 y. The value of y is :
6) 2 moles of an ideal diatomic gas is subjected to the following process, value of workdone is-
[Given : R = 2 Cal/inol K]
SECTION-II (ii)
2) Consider the y-axis as an internuclear axis, how many of the following will lead to bond
formation:
(i) py – py (ii) px – px
(iii) pz – pz (iv) dxy – dxy
(v) dyz – dyz (vi) px – dxy
(vii) dxy – pz (viii) dxz – dxz
3) The initial decrease in free energy during the cell reaction in is____________
× 105 J (report the value to nearest integer
4) Calculate
PART 3 : MATHEMATICS
SECTION-I (i)
(A)
(B)
(C)
(D)
3) Let f(x) = x2 – 2ax + a – 2 and g(x) = If the complete set of real values of 'a'
for which ∀ x ∈ R is (k1, k2) then the value of (10k1 + 3k2) is equal to
[Note : [k] denotes greatest integer less than or equal to k.]
(A) 35
(B) 27
(C) 20
(D) 8
4) If P, Q, R are three points on the parabola y2 = 4ax such that the ordinates of the points are in A.
P. If area of triangle PQR is 2a2 sq units, the locus of centroid of the PQR is a parabola with
latusrectum
(A) 2a
(B) 8a
(C) 4a
(D) 16a
SECTION-I (ii)
(C)
If , then x is a composite number
(D)
If , then x is a prime number
2) Let then
(A)
number of real solution of is 0
(B) minimum value of f (x) is – 1
(C) minimum value of f (x) is 1
(D)
number of real solution of is 16
3) Let r be the range and be the S.D. of a set of observations x1, x2, ....., xn,
then find the relation between S, r and n also relate S when r = 2 and n = 9 :
(A)
(B)
(C)
(D)
SECTION-II (i)
1) Let A1 and A2 are the vertices of the conic C1 : 4(x – 3)2 + 9(y – 2)2 – 36 = 0 and a point P is moving
in the plane such that , then locus of P is another conic C2. If D1 denotes distance
between foci of conic C2. D2 denotes product of the perpendiculars from the points A1,A2 upon any
tangent drawn to conic C2 and D3 denotes length of the tangent drawn from any point on auxiliary
circle of conic C1 to the auxiliary circle of the conic C2, then is equal to :
2) A ray emanating from the point (-4, 0) is incident on the ellipse 9x2 + 25y2 = 225 at the point P
with abscissa 3. If the equation of the reflected ray after first reflection is ax + by + c = 0, then find
value of .
3) Chords of the hyperbola are tangents to the circle drawn on the line joining the foci
as diameter. If the locus of the point of intersection of tangents at the extremities of the chords is
, then find
4) Let S1 and S2 are focii of the hyperbola with length of transverse axis equal to 20. Perpendicular
distance of S1 on normal at P is 20. If the normal at P divides the line segment joining S1 and S2 in
ratio 5 : 1 externally then find the square of length of semi-conjugate axis.
5) The centres of two circles C1 and C2 of radii 4 and 9 respectively are at a distance of 15 units from
each other. Let L1 be one direct common tangent to these circles and there are 'n' circle which
touches given both circle and line L. Let r1, r2, ...... rn be the radii of these circles then 18 is
equal to
6) A circle with diameter of length 10 is internally tangent at P to a circle of radius 20. Square
ABCD is constructed with A and B on the large circle, tangent at Q to the smaller circle , and the
smaller circle outside ABCD. The length of can be written in the form where m and n
SECTION-II (ii)
PART 1 : PHYSICS
SECTION-I (i)
Q. 1 2 3 4
A. A A C C
SECTION-I (ii)
Q. 5 6 7
A. A,C,D A,C A,C
SECTION-II (i)
Q. 8 9 10 11 12 13
A. 3 7 4 8 1 4
SECTION-II (ii)
Q. 14 15 16 17
A. 60.00 250.00 1.00 10.00
PART 2 : CHEMISTRY
SECTION-I (i)
Q. 18 19 20 21
A. C C D B
SECTION-I (ii)
Q. 22 23 24
A. B,C A,D A,B,D
SECTION-II (i)
Q. 25 26 27 28 29 30
A. 6 5 8 4 2 0
SECTION-II (ii)
Q. 31 32 33 34
A. 7.00 5.00 2.00 0.32 to 0.33
PART 3 : MATHEMATICS
SECTION-I (i)
Q. 35 36 37 38
A. C D C C
SECTION-I (ii)
Q. 39 40 41
A. B,D A,B A,B
SECTION-II (i)
Q. 42 43 44 45 46 47
A. 18 41 25 45 1261 4
SECTION-II (ii)
Q. 48 49 50 51
A. 3999.00 2.00 3.00 1280.00
SOLUTIONS
PART 1 : PHYSICS
1)
Explain Question:
Concept :
Gauss law
Solution :
2)
Explain Question:
Concept :
Solution :
3)
Explain Question:
To find angular vel. in pure rotation.
Concept :
Energy conservation.
Solution :
20 × g × 5 + 10 × g × 10
4)
Explain Question:
Concept :
Solution :
N = mg – F sin θ
a= (cos θ + µ sin θ) – µg
Final Answer: (3)
5)
Explain Question:
Analysis photo stopping potential and current with frequency, work function and intensity
Concept :
Solution :
KEmax = hf – ϕwf
6)
Explain Question:
Concept :
Solution :
vB = ω0r – v0 = v
ω0r – v0 = v ...(i)
vA = ω0 r + v0 = 3v ...(ii)
From equation (i) and (ii)
2ω0r = 4V
⇒ ω0r = 2v
ω =
0
From (1) v0 = v
7)
Explain Question:
Concept :
8)
Explain Question:
Concept :
Energy conservation.
Solution :
Apply energy conservation at point ‘A’ and ‘O’
9)
Explain Question:
Concept :
Solution :
T=
= =
⇒
Answer (q – p) = 7
10)
Explain Question:
Concept :
Solution :
F = mg sin θ ~ mg tan θ
tan θ = = 40 x
2
–mω x = –mg × 40 x
w= = 20 rad/s
11)
Explain Question:
Concept :
Angular acceleration due to torque.
Solution :
τ = Iα ; τ = mg ; ,
12)
Explain Question:
Concept :
Solution :
fr = macm
R fr = Iα
I = 1/2 mR2
N = mg
fr = µN
acm = µg
α = 2µg / R
0
v – µgt =
t = 1 sec.
13)
Explain Question:
Concept :
Gauss law
Solution :
Q = net charge in sphere of radius 3R
Q=ρ –2ρ π ((2R)3 – R3) + 3ρ π ((3R)3 – (2R)3)
then E =
Final Answer: (4)
14)
Explain Question:
Concept :
Solution :
Velocity is maximum at a = 0
N = mpg
15)
Explain Question:
Concept :
Solution :
16)
Explain Question:
Solution :
Time of flight for the man from B to ground is
17)
Explain Question:
Concept :
Solution :
As per question
PART 2 : CHEMISTRY
19) Explain Question: Find correct order of basic strength in aqueous solution.
Concept: Basic strength of aliphatic amines.
Solution:
Basic strength order of aliphatic amines in aqueous solution is
20) Explain Question: Find the cell potential for given electrochemical cell
Concept: Nernst equation
Solution:
E1 = E° – log
0.3095 = E° – log
0.3095 = E° – ×3
E° = 0.3095 + 0.0885 = 0.398
E = 0.398 – log
= 0.398 – ×4
= 0.398 – 0.118
= 0.28 V
Final Answer: (D)
22) Explain Question: Find the correct statement for give co-ordination compound.
Concept: Primary and secondary valency.
Solution:
[Co(NH3)5]Cl2 ⇒
Final Answer: (BC)
23) Explain Question: Find the compound in which -CHO is given top most priority
Concept: Priority order of functional group
Solution:
Functionality priority among given groups is
–COOH > –CN > –CHO > –CO– > –OH > –NH2 > –NO2 and –OCH3.
Final Answer: (AD)
25)
Sm2 Mol–1
λm = 1.9 × 10 × 550 × 10 = 1045 × 10–13 = 1.045 × 10–10 Sm2 mole–1
–9 –4
11.2 × N =
N=
x=5
Final Answer: (5)
28) Explain Question: Find number of compounds having Stability greater than (CH3)2CH+
Concept: Stability of carbocation.
Solution:
1, 2, 6, 7
Final Answer: (4)
Buffer capacity =
⇒ 0.14 = 0.07 y
y=2
Final Answer: (2)
∵ dV = 0, ω = 0
Final Answer: (0)
31) Explain Question: Find total number of species having bent shape
Concept: VSEPR Table
Solution:
The shapes of these species are shown below.
Hence, among the given species, the following seven species have bent shapes around the
central atom.
SnCl2, H2O, NOCl, O3, , OF2, ,
therefore, x = 7
Answer = x = 7
Final Answer: (7.00)
32) Explain Question: Find total number of Orientation of orbitals from given which will lead
to formation of π-bond
Concept: Over lapping of orbitals along different axis
Solution:
σ bond formation : (i)
π bond formation : (ii), (iii), (iv), (v), (vi)
No bond formation: (vii)
bond formation : (viii)
Final Answer: (5.00)
Anode :
Cathode :
Overall :
ΔG = –nFE
= – 2 mole × 96500 C mol–1 × 1.055 JC–1
= – 203615 J = – 2.03615 × 105 J
Decrease in free energy = 2 × 105 J
Final Answer: (2.00)
= 0.325 V
Final Answer: (0.32-0.33)
PART 3 : MATHEMATICS
35) Explain Question: In this question we have to identify the types of relation.
Concept: In this we have to explain different type of relation (reflexive, symmetric, transitive)
Solution:
For R, xRy ⇒ x = wy
For reflexive
xRx ⇒ x = wx
Which is true then w = 1
For symmetric
consider x = 0, y ≠ 0
xRy ⇒ 0Ry ⇒ 0 = wy
which is true when w = 0
Now
yRx ⇒ yR0 ⇒ y = w × 0
There is no rational value of w
for which y = w × 0
Hence relation is not symmetric and hence not an equivalence relation
Now for S
For reflexive
S ⇒ mn = nm
which is true
For symmetric
Let S ⇒ qm = np
S ⇒ pn = mq
which is true
Relation is symmetric
For transitive
Let S ⇒ qm = pn ...(1)
S ⇒ ps = rq ...(2)
From Equation (1) and equation (2)
⇒ ms = nr
∴ S
S is transitive
∴ S is equivalence.
Final Answer: (C)
36) Explain Question: In this question we need to solve the inverse trigonometry series.
Concept: Just convert in tan (inverse) then solved the series.
Solution:
37) Explain Question: This question is mix type of inequality and ITF we need to solve the
inequality.
Concept: Used the concept of ITF and then using inequality we solve the question.
Solution:
As, sin–1 ∈
∴ = – 2, – 1, 0, 1.
Range of g(x) = {0, 1, 2, 3} for < 0 ∀ x ∈ R
⇒ f(0) < 0 and f(3) < 0
a>
∴ a∈
Hence, k1 = , k2 = 2
∴ (10k1 + 3k2) = 14 + 6 = 20. Ans.
Final Answer: (C)
38) Explain Question: In this question they ask about locus in parabola.
Concept: Used the formula of area of triangle then got the locus of centroid.
Solution:
Final Answer: (C)
39) Explain Question: In this question they used the concept of composite function.
Concept: used the concept of composite function and using functional equation they got the
answer.
Solution:
g2(x)
g3(x) = x
∴ g3n+1(x) = g1(x), g3n+2(x) = g2(x), g3n+3(x) = g3(x)
Given f(f(g51(2))) = 4
⇒ f(f(2)) = 4 ⇒ f(3) = 4
By using f(x + 2) + f(x) = f(x + 1) we get
f(4) = 1, f(6) = –4, f(7) = –1
Final Answer: (B,D)
i.e.
has no real solution
Also, when z = 0
Again no solution
Final Answer: (A,B)
41) Explain Question: In this question they gave standard deviation and we need to find
relation between parameters.
Concept: Used the formula of standard deviation.
Solution:
We have and
Now
,
[∵ |xi – xj| ≤ r]
⇒
Final Answer: (A,B)
42) Explain Question: In this question they ask about distance b/w foci, length of tangent to
conic.
Concept: Using the concept of locus of conic then use the formula of length of tangent
Solution:
C1 :
D2 = b2
43) Explain Question: In this question they ask about properties of ellipse (Reflection
property).
Concept: Used the basic of ellipse and then got the equation of line using point form.
Solution:
Given ellipse is 9x2 + 25y2 = 225
or
a2 = 25 Þ a = 5 (length of semi major axis)
b2 = 9 Þ b = 3 (length of semi minor axis)
eccentricity of given ellipse is
or
now focus of ellipse ⇒ S1(ae, 0) and S2 (–ae, 0)
or and
or and
Thus the given point (–4, 0) from where a ray is incidenting on ellipse at point P since (–4, 0) is
a focus of ellipse and therefore the reflected ray will pass through the second focus of ellipse.
or y = ±
Now equation of first reflected ray ⇒ passing through two points (y, 0) and
⇒
⇒ 5y = – 12x + 48
or ...(1)
now equation of second reflected ray ⇒
so the value of
= 52 + 42
= 41.
Final Answer: (41)
44) Explain Question: In this question they ask about locus of point of intersection of tangent
at extremities of chords.
Concept: Used the concept of C.O.C. of hyperbola and then got the locus of the point.
Solution:
x2 + y2 = a2e2
x2 + y2 = (a2 + b2) ...(1)
C.O.C. of P(h, k)
...(2)
This must be the same as that of the tangent at (x1, y1) to the circle
xx1 + yy1 = (a2 + b2)
;
Hence locus of P is
⇒ α = a2 , β = b2
Final Answer: (25)
45) Explain Question: In this question they ask about basic of hyperbola (semi-conjugate)
axis.
Concept: In this they applied property of hyperbola and external ratio formula to solve this
question.
Solution:
........ (1)
⇒
(tangent is the internal angle bisector)
Distance of S2 from tangent at P is
46) Explain Question: In this question, they ask about direct common tangent and radius of
the circles.
Concept: In this question, they used the concept of direct common tangent and used formula
to solve question.
Solution:
AB = AC + BC
r=2
AB = AB
AC – BC = AB
r = 50
=
Final Answer: (1261)
47) Explain Question: In this question they ask about side of square with given condition of
circles.
Concept: They used the concept of pythagoras theorem them with given condition to find the
side of square.
Solution:
48) Explain Question: In this question functional equation is given, we have to find the value
of function at given parameter.
Concept: They used the concept of functional equation to solve the equation by using
transformation of parameters.
Solution:
ƒ(a,b) = ƒ(a –1, b) + (a – 1)
= ƒ(a – 2, b) + (a – 2) + (a – 1)
= ƒ(1, b) +
= ƒ(1, b – 1) – (b – 1) +
= ƒ(1, 1) – +
⇒
⇒ (a – b)(a + b – 1) = 2.1999
then 1999 is prime and a – b < a + b – 1
⇒ a – b = 1, a + b – 1 = 3998
⇒ a = 2000
b = 1999
If a – b = 2, a + b – 1 = 1999
⇒ a = 1001, b = 999
⇒ (a, b) = (2000, 1999) or (1001, 999)
Final Answer: (3999.00)
49) Explain Question: In this question functional equations is given, we have to find the value
of function at given parameter.
Concept: They used the concept of functional equation to solve the equation by using
transformation of parameter.
Solution:
ƒ(a,b) = ƒ(a –1, b) + (a – 1)
= ƒ(a – 2, b) + (a – 2) + (a – 1)
= ƒ(1, b) +
= ƒ(1, b – 1) – (b – 1) +
= ƒ(1, 1) – +
⇒
⇒ (a – b)(a + b – 1) = 2.1999
then 1999 is prime and a – b < a + b – 1
⇒ a – b = 1, a + b – 1 = 3998
⇒ a = 2000
b = 1999
If a – b = 2, a + b – 1 = 1999
⇒ a = 1001, b = 999
⇒ (a, b) = (2000, 1999) or (1001, 999)
Final Answer: (2.00)
50) Explain Question: In this question they ask about intercept of line with given condition
with parabola and square.
Concept: In this they used the concept of length of chord with parabola.
Solution:
y intercept
slope
From (1),
y intercept of CD is
Final Answer: (3.00)
51) Explain Question: In this question they ask about area of square with given condition of
parabola.
Concept: In this they used the concept of length of chord with parabola to find the side of
square.
Solution:
y intercept
slope
From (1),
y intercept of CD is
Final Answer: (1280.00)