21-09-2025

9610WJA802124250009 JA

PART 1 : PHYSICS

SECTION-I (i)

1) A point charge (+q) of mass m is released from a distance from the centre of a solid sphere
of radius R and charge Q (uniformly charged in volume). The speed of the point charge when it
reaches a distance R from the surface of the sphere (there is no interaction between sphere and

point charge other than electrostatic). k =

(A)

(B)

(C)

(D)

2) Consider a system of three charges and placed at points A, B and C, respectively, as

shown in the figure. Take O to be the centre of the circle of radius R and angle CAB = 60°.

(A)
The electric field at point O is directed along the negative x–axis
(B) The potential energy of the system is zero

(C)
The magnitude of the force between the charges at C and B is
 The potential at point O is
(D)

3) Which of the following quantities are always positive in a simple harmonic motion?

(A)
(B)
(C)
(D)

4) The equation of motion of a particle of mass 1 gm is + π2x = 0 where x is displacement (in m)

from mean position. The frequency of oscillation is (in Hz):

(A)

(B) 2
(C)

(D)

SECTION-I (ii)

1) A block of mass m is attached to a spring of spring constant k and is placed on a horizontal

smooth surface as shown in which spring is unstretched. Now the spring is given an initial
compression 2x0 and block is released from rest. Collisions with the wall PQ are elastic. Treating
position of block in unstretched position of spring as origin, mark the CORRECT statement(s) :

(A)
Time taken to reach wall is .

(B)
Velocity at the instant of collision with the wall is .

(C)
Acceleration at the instant just before collision with the wall is .

(D)
The time period of motion of one complete cycle of the block is .

2) For which of the following continuous charge system magnitude of electric field at point P is

0
where λ is linear charge density?
(A)

(B)

(C)

(D)

3) An electron is placed just in the middle between two long fixed line charges of charge density +λ
each. The wires are in the xy plane (Do not consider gravity)

(A) The equilibrium of the electron will be unstable along x-direction

(B) The equilibrium of the electron will be neutral along y-direction
(C) The equilibrium of the electron will be stable along z-direction
(D) The equilibrium of the electron will be stable along y-direction

SECTION-II

1) On a smooth horizontal surface we have a point charge attached to the free end of a massless rod
hinged at other end as shown. We apply a uniform electric field (E) and slightly deflect the rod. The
force on charge accelerate it during half rotation then the direction of electric field is suddenly
reversed, so that the charge remain accelerating, assuming q = 1C, m = 1kg E = 1N/C, length of rod
L = 1m. The total angle rotated when the point charge attains a speed of 5 m/s is 38 π/n. Then value

of n is.

2)

The three 200 g masses in figure are connected by massless, rigid rods to form a triangle. The
rotational kinetic energy of triangle’s is n × 0.144 (in joule) if it rotates at 3 rad/s about an axis
through the center. What will be the value of n.

3) A uniform rod of mass 12 kg and length 4 m is hung from two string of equal length from a ceiling
as shown in fig. Determine the tension T1 (in N) in the string. (take g = 10 m/s2)

4) A uniform thin rod of length 8m is released from rest from the position shown. The acceleration of

point at just after release is N m/s2. Find the value of N.

5)

Two small dipoles and are located at (0, 5, 0) and (1, 5, 2) respectively. The magnitude of

resultant electric field due to the two dipoles at the point (1, 5, 0) is given as find value of n.

6) A large sheet carries uniform surface charge density σ. A rod of length 2ℓ has a linear charge
density on one half and –λ on the second half. The rod is hinged at mid-point O and makes angle

with the normal to the sheet. The electric force experienced by the rod is . Write in

OMR sheet.

SECTION-I (iii)

1) Two small positively charged spheres are suspended from a common point at the ceiling by the
insulating light strings. The first sphere has mass m1 and charge q1 while the second one has mass
m2 and charge q2. The masses are in equilibrium. Match List–I with best possible entry in List– II.

List-I List-II

(P) (1) m 1 < m2

ℓ1 > ℓ2

(Q) (2) m 1 > m2

ℓ1 > ℓ2

Relation between m1 and

(R) (3)
m2 can't be decided.

ℓ1 = ℓ2
 (S) (4) m 1 = m2

ℓ1 = ℓ2
(5) None of these
(A) P → 1;Q → 1;R → 2;S → 4
(B) P → 3;Q → 1;R → 1;S → 4
(C) P → 1;Q → 3;R → 2;S → 4
(D) P → 3;Q → 2;R → 3;S → 4

2)

Match the entries on left side with entries on right side when left most plate is grounded. Then

List-I List-II
(P) The charge appearing on outer surface of right most plate is (1) 0
(Q) The charge appearing on outer surface of left most plate is (2) Q
(R) The charge appearing on left surface of middle plate is (3) –Q
(S) The charge appearing on right surface of middle plate is (4) 2Q
(5) –2Q
(A) P → 1;Q → 2;R → 3;S → 5
(B) P → 1;Q → 1;R → 5;S → 5
(C) P → 1;Q → 1;R → 5;S → 4
(D) P → 2;Q → 2;R → 3;S → 4

3) List-I contains some continuous mass system and list-II contain their moment of inertia about axis
shown in list-I. Match the following list.

List–I List–II
 (A) (P)

Uniform rod

(B) (Q)

Uniform semicircular ring. Axis is perpendicular to plane of ring.

(C) (R)

Uniform Triangular plate of mass M

(D) (S)

Uniform disk of initial mass M from which circular portion of radius R is

then removed. M.I. of remaining mass about axis which is perpendicular
to plane of plate.

(T)

(A) A → P;B → Q;C → R;D → S

(B) A → Q;B → P;C → T;D → R
(C) A → P;B → Q;C → R;D → T
(D) A → Q;B → P;C → S;D → T

4) List-I shows different cases of a particle and list-II contains values of tension in string at the
instants shown. (Assume mass of particle is equal to m)

List-I List-II

(P) (1)

Extreme position in simple pendulum

 (Q) (2)

Conical pendulum

(R) (3)

Cart is accelerated such that

particle remains at rest as shown
w.r.t. cart

(S) (4)

Cart is accelerating freely on the

incline. Particle remains at rest w.r.t.
cart as shown.
(A) P → 3;Q → 2;R → 4;S → 1
(B) P → 2;Q → 4;R → 3;S → 1
(C) P → 4;Q → 3;R → 1;S → 2
(D) P → 3;Q → 4;R → 1;S → 2

PART 2 : CHEMISTRY

SECTION-I (i)

1)
Compare x, y, z bond angle from the above given molecule :

(A) x > y > z

(B) x > z > y
(C) x > z > y
(D) z > y > x

2) An ideal diatomic gas is caused to pass through a cycle shown on the P−V diagram in figure,
where V2 = 3.00V1.
If P1,V1 and T1 specify the state 1, then the temperature of the state 3 is:

1
(A) (T1/3)
4
(B) (T1/3)
0.4
(C) T1 / (3)
2
(D) (T1/3)

3) For the process: Cu2+ + 2e− → Cu; log[Cu2+] vs. Ered graph is shown in the figure, where OA = 0.34
V. The electrode potential of the half-cell of Cu|Cu2+ (0.1 M) will be [2.303 RT/F = 0.06]

(A) −0.31 V
(B) +0.31 V
(C) −0.37 V
(D) +0.37 V

4) IUPAC name of is:

(A) 4–Bromo–6–chloro–2–ethyl–1–methylcyclohex–1–ene
(B) 5–Bromo–1–chloro–3–ethyl–2–methylcyclohex–2–ene
(C) 5–Bromo–3–chloro–1–ethyl–2–methylcyclohex–1–ene
(D) 1–Bromo–5–chloro–3–ethyl–4–methylcyclohex–3–ene

SECTION-I (ii)

1) Which of the following order of melting point is "INCORRECT" ?

(A) BeO > CaO > MgO > SrO > BaO
(B) CaF2 > MgF2 > SrF2 > BaF2 > BeF2
(C) NaI > KI > RbI > CsI > LiI
(D) AℓF3 > AℓCℓ3 > AℓI3 > AℓBr3

2) An element of 3d-transition series shows two oxidation states x and y, differ by two units then

(A) compounds in oxidation state x are ionic if x > y

(B) compounds in oxidation state x are ionic if x < y
(C) compounds in oxidation state y are covalent if x < y
(D) compounds in oxidation state y are covalent if y < x

3) NO and Br2 at initial pressures of 98.4 and 41.3 torr respectively were allowed to react at 300K.
At equilibrium the total pressure was 110.5 torr. Select the correct statements after the reaction
Given

(A)
(B)
(C)
(D)

SECTION-II

1) ΔHf of hypothetical Mg+Cl– is –125 kJ/mole and for MgCl2 is –642 kJ/mole. The enthalpy of
disproportionation of MgCl in MgCl2(s) and Mg(s) is –49x (kJ/mole). The value of x will be.

2)

0.1 M of HA is titrated with 0.1 M NaOH, calculate the pH at end point. Given Ka(HA) = 5 × 10–6
and a << 1.

3) In 10 L solution at what maximum pH, 0.01 mol Cr(OH)3 will go into solution as Cr3+ (aq.) ?
[Given : Ksp [Cr(OH)3] = 10–30]

4) The number of correct statements from the following is ________

(A) Conductivity always decreases with decrease in concentration for both strong and weak
electrolytes.
(B) The number of ions per unit volume that carry current in a solution increases on dilution.
(C) Molar conductivity increases with decrease in concentration.
(D) The variation in molar conductivity is different for strong and weak electrolytes.
(E) For weak electrolytes, the change in molar conductivity with dilution is due to decrease in
degree of dissociation.

5) 2.24 L of CO2 at 1 atm and 273 K was passed in 2L of NaOH solution of unknown molarity.
Resulting solution when titrated with 0.5 M HCl required 120 ml for phenolphthalein end point and
after that remaining solution again required 500 ml 0.2M HCl for methyl orange end point. Calculate
molarity of NaOH solution.
[Give your answer by multiplying it by 100]

6) Total number of functional groups present is the following compound is :-

SECTION-I (iii)

1) For a tribasic acid, H3A, Ka1 = 10–4, Ka2 = 10–8 and Ka3 = 10–12. Match the pH (List II) of the
resulting solution (List I) at 25°C.

List-I List-II

(A) Equimolar mixture of H3A and NaH2A (P) 12.0

(B) Equimolar mixture of NaH2A and Na2HA (Q) 8.0

(C) Equimolar mixture of Na2HA and Na3A (R) 4.0

(D) Equimolar mixture of H3A and NaOH (S) 6.0

(T)` 10.0
(A) A → P;B → Q;C → R;D → S
(B) A → R;B → T;C → P;D → S
(C) A → P;B → Q;C → R;D → T
(D) A → R;B → Q;C → P;D → S

2)

List-I List-II
Compound IUPAC Name

(P) (1) 1-bromo-3-chlorocyclopentane

(Q) (2) 3-Chloro-1-bromo cyclopentane

 (R) (3) 3,3-Dimethyl cyclohexene

(S) (4) Cyclopentanol

(5) 1,6 - Dimethyl cyclohexene

(A) P → 3;Q → 5;R → 2;S → 4
(B) P → 3;Q → 5;R → 1;S → 4
(C) P → 3;Q → 1;R → 4;S → 5
(D) P → 3;Q → 4;R → 2;S → 3

3) Match the list :

List-I List-II

Correct order of stability of

(P) (1)
alkene

Correct order of heat of

(Q) (2)
combustion

Correct order of heat of

(R) (3)
hydrogenation

Correct order of C=C bond

(S) (4)
length

Correct order of C=C bond

(5)
energy
(A) P → 1,2,4;Q → 2,3,5;R → 1,2,4;S → 1,4
(B) P → 1,3,5;Q → 3,4,5;R → 1,2,3;S → 2,4
(C) P → 1,2,4;Q → 2,3,4;R → 3,4,5;S → 2,3
(D) P → 1,3,4;Q → 1,3,5;R → 2,3,4;S → 4,5

4) Match the electronic configurations in List-I with appropriate metal complex ions in List-II and
choose the correct option.
[Atomic Number: Fe = 26, Mn = 25, Co = 27]

List-I List-II

(P) (1) [Fe(H2O)6]2+

(Q) (2) [Mn(H2O)6]2+

(R) (3) [Co(NH3)6]3+

 (S) (4) [FeCl4]–

(5) [CoCl4]2–
(A) P → 1;Q → 4;R → 2;S → 3
(B) P → 1;Q → 2;R → 4;S → 5
(C) P → 3;Q → 2;R → 5;S → 1
(D) P → 3;Q → 2;R → 4;S → 1

PART 3 : MATHEMATICS

SECTION-I (i)

1) Let (a, b) ⊂ (0,​ 2π) be the largest interval for which sin–1(sinθ) – cos–1(sinθ ) > 0, θ ∈ (0, 2π), holds.
If
αx2 + βx + sin–1(x2 – 6x + 10) + cos–1
(x2 – 6x + 10) = 0
and α – β = b – a, then α is equal to :

(A)

(B)

(C)

(D)

2) The range of the function f(x) = sin–1 + cos–1 , where [ ] is the greatest integer
function, is:

(A) {π}

(B)

(C)

(D)

3) Let f(x) = sin–1 x – x and g(x) = x2 + 5x + 6 + cos–1 x. If , then

the true set of real values of x, is

(A)

(B)

(C)
(D)

4) Sum of all different values of y satisfying the equation y([cotx]2 + 7[cotx] + 12) = 6, where

and [.] represent greatest integer function

(A)

(B)

(C) 2
(D) 4

SECTION-I (ii)

1) Let f,g and h be three function defined as follows :

and h(x) = –x2 – 3x + k. Identify which of the following statement(s)

is(are) correct ?

(A) Number of integers in the range of f(x) is 8.

(B) Number of integral value of k for which h(f(x)) > 0 and h(g(x)) < 0 ∀ x ∈ R is 20
(C) Number of integral value of k for which h(f(x)) > 0 and h(g(x)) < 0 ∀ x ∈ R is 19
(D) Maximum value of g(f(x)) is 73.

2) The number of elements in the range of of for ,

(where and [.] denotes greatest integer function) is m. Then which of the following is/are
CORRECT?

(A) If n = 3k, then m = 30 k + 1

(B) If n = 3k + 1, then m = 30 k + 11
(C) If n = 3k + 2, then m = 30 k + 19
(D) If n = 3k, then m = 30 k

3) Let (x1, y1) and (x2, y2) where x1 > 0, x2 < 0 be two points lying on the curve x(y – x) = 1 and (x3, y3)
be a point from where two tangents drawn to the curve are perpendicular to each other. Which of
the following option(s) is/are correct ?

(A) The minimum possible value of (x1 – x2)2 + (y1 – y2)2 is

2 2
(B) The minimum possible value of (x1 – x2) + (y1 – y2) is 20
2 2
(C) x3 + y3 = 4
(D)

SECTION-II
1) PQ is variable chord of the parabola y2 = 4x such that its projection on a line with gradient unity
has magnitude equal to 10. If the locus of the middle point of PQ has the equation (y2 – 4x) (y + 2)2 +
λ = 0 where λ ∈ N, then find λ.

2) Consider a line L, with slope m ∈ (0,1) passing through point P(k,1) intersects the parabola y2 =
kx (k > 0) at two points Q and R, where Q,R are on opposite sides of P. Line L also intersects
coordinate axes at M and N. If complete set of values of k for which PQ.PR = PM.PN is (k1,k2) and

4(k2 – k1)2 = then the value of λ, is

3) On the axis of parabola y2 = 8x there is a point P(4,0). A chord L1 making an angle θ1 with the
positive direction of x-axis through P meets the parabola at A1 and B1, and a chord L2 making an
angle θ2 with the positive direction of x-axis through P meets the parabola at A2 and B2 , and a chord
L3 making an angle θ3 with the positive direction of x-axis through P meets the parabola at A3 and
B3 and also a chord L4 making an angel θ4 with the positive direction of x-axis through P meets the

parabola at A4 and B4, then the value of

is k then 8 k is equal to

4) Let and

.
The n(S ∩ T) is equal to_____.

5) Consider the ellipse Let S2 = 0 be a parabola on the right of y-axis confocal

with S1 = 0 having vertex at the centre of S1 = 0. Let P be the point of intersection of the parabola
and directrix of the ellipse in the 1st quadrant. If tangent at point Q in 1st quadrant on S1 = 0 and the
line joining point P with the focus of S2 = 0 intersect on the auxillary circle of S1 = 0 then the value
of 9sin2θ is _____. (θ is the eccentric angle fo the point Q).

6) A frequency distribution table is given.

Variable 10 – 20 20 – 30 30 – 40 40 – 50 50 – 60 60 – 70 70 – 80 Total

Frequency 12 30 α 65 β 25 18 229
Given that the median value is 46 and α, β are missing frequencies (where α, β are integers and β >

α) and sum of all {x} of the equation ((β – α) {x}) + 2[x] = 3 is (where p, q are coprime positive
integers, {x} denotes fractional part of x, [x] denotes greatest integer function less than or equal to
x) then p + q is equal to _____.

SECTION-I (iii)
1) Let A = {1,3,5,7} and B = {2,4,6,8} ƒ : A → B, then the total number of function's 'ƒ' possible for
Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) i + ƒ(i) < 10, ∀ i ∈ {1,3,5,7} (1) 16

(Q) ƒ(i) – i > 2 ∀ i ∈ {1,3,5,7} (2) 24

(R) ƒ(i) > 6 ∀ i ∈ A (3) 0

(S) ƒ(i) ≠ i + 1 ∀ i ∈ A (4) 81

(A) P → 2;Q → 3;R → 1;S → 4
(B) P → 2;Q → 1;R → 3;S → 4
(C) P → 1;Q → 3;R → 2;S → 4
(D) P → 4;Q → 2;R → 3;S → 1

2)

List-I List-II

Number of integral solution of the

equation x – 1 = (x – [x])(x – {x})
(I) (P) 1
([ ] is greatest integer and { } is
fractional part function)

Number of integral values of x

(II) (Q) 5
satisfying

Sum of integral values which lies in

(III) (R) 3
range of

(IV) (S) 4
, then number of real
values of x satisfying equation

(T) 2
(A) I → P;II → R
(B) I → R;II → P
(C) I → Q;II → S
(D) I → S;II → Q

3)

List-I List-II

The number of integral values of k for which the equation

(P) (1) 1
sin–1 x2 + tan–1 x2 = 2k + 1 has a solution
 (Q) (2) 2
Let where is rational in its
lowest form, then find |q – p|

(R) If , (3) 3
then the value of cos2y – sin θ

Minimum positive integral value of x such that f(x) is

(S) (4) 0
defined,

(5) 5
(A) P → 3;Q → 1;R → 2;S → 2
(B) P → 4;Q → 3;R → 1;S → 4
(C) P → 1;Q → 3;R → 2;S → 3
(D) P → 1;Q → 4;R → 3;S → 2

4) Answer the following by appropriately matching the lists based on the information given
in the paragraph
Let the circles C1 : x2 + y2 = 9 and C2 : (x– 3)2 + (y – 4)2 = 16, intersect at the points X and Y. Suppose
that another circle C3 : (x – h)2 + (y – k)2 = r2 satisfies the following conditions :
(i) centre of C3 is collinear with the centres of C1 and C2
(ii) C1 and C2 both lie inside C3, and
(iii) C3 touches C1 at M and C2 at N.
Let the line through X and Y intersect C3 at Z and W, and let a common tangent of C1 and C3 be a
tangent to the parabola x2 = 8αy.
There are some expression given in the List-I whose values are given in List-II below:

List-I List-II

(P) 2h + k (1) 6

(Q) (2)

(R) (3)

(S) α (4)

(5)

Which of the following is the only CORRECT combination ?

(A) P → 1;Q → 3;R → 2;S → 4
(B) P → 1;Q → 2;R → 3;S → 5
(C) P → 3;Q → 2;R → 4;S → 1
(D) P → 3;Q → 4;R → 2;S → 1
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B C A A

SECTION-I (ii)

Q. 5 6 7
A. A,B,C,D A,B A,B,C

SECTION-II

Q. 8 9 10 11 12 13
A. 6 100 40 5 7 0

SECTION-I (iii)

Q. 14 15 16 17
A. A C B A

PART 2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. B C A C

SECTION-I (ii)

Q. 22 23 24
A. A,C B,C A,C

SECTION-II

Q. 25 26 27 28 29 30
A. 8 9 5 3 8 6

SECTION-I (iii)

Q. 31 32 33 34
A. D B A D

PART 3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. D A C C

SECTION-I (ii)

Q. 39 40 41
A. A,C,D A,B A,C

SECTION-II

Q. 42 43 44 45 46 47
A. 200 4 2 27 3 36

SECTION-I (iii)

Q. 48 49 50 51
A. A A C B
 SOLUTIONS

PART 1 : PHYSICS

1)

Explain Question:

Loss of electrostatic P.E. from R/2 ⇒ R

Concept :

Energy conservation in electric field of solid sphere.

Solution :

2)

Explain Question:

Net field potential force calculation by super position

Concept :

Principle of super position

Solution :
By applying geometry

3)

Explain Question:

F||a F.a > 0

Concept :

SHM restoring force

 Solution :
In any motion, the acceleration vector must be in the direction of resultant force.

So = Facos0° ⇒ (+ve)

4)

Explain Question:

Compare & ω = 2πf

Concept :

Frequency obtained by matching SHM equation with standard form.

Solution :

⇒ Compare with

so ω = π so f = Hz

5)

Explain Question:

Motion analysis using SHM + elastic collision

Concept :

SHM with amplitude 2x0 + energy conservation + elastic refraction.

Solution :
(a) Treat initial position of block as origin O. Had wall not been ........... motion would have
been normal SHM with amplitude 2x0 say ........... point.

Given A and B

But in the given situation velocity of block at P will get with same
magnitude, mass PA part of motion will be .............. Equation of motion
x = –2x0cosωt
for tBP x = x0
⇒ x0 = –2x0cosωtBP

⇒ ωtBP = ⇒ tBP = ;
tPB = tBP

Net time period T = 2tBP = =

 6)

Explain Question:

Net field of line/arc charges

Concept :

Superposition principle + field of line/arc change.

Solution :

Electric field at ∴

E|| =

and for charged circular arc E =

7) Explain Question:
Stability depends on restoring/ repelling force dielectric unstable in x neutral in y & stable in z

Concept :equilibrium small displacement + electrostatic force.

Solution :
Opposite charge attract each other.

8)

Explain Question:

Work done by electric force in each reversal add - gives total KE & angle

Concept :

Energy conservation + WET

Solution :
At each reversal, work done by electric force = qE(2L), and KE keeps on increasing after N

reversal, work done = NqE(2L) =

work done in rotating θ angle,

F × L(1 – cos θ) = ΔKE =

so total work done,

NqE(2L) + F × L(1 – cosθ) =

& F = qE,

we get v2 =

for v = 5 ; N = 6 and θ =

so, total angle rotated is, =

9)

Explain Question:

Rotational KE for arrangement

Concept :

KE of mass in rotational frame.

Solution :

KErot = = =

= = = 0.14

10)

Explain Question:

Force & torque analysis.

 Concept :

Using force & torque equation

Solution :

Total mass of complete length = 12kg. for length

Therefore, for , mass is 3kg. And for , mass is 9kg

A/Q T1 + T2 = mg (translational equilibrium)
T1 + T2 = 120 ____ (1)
About (A) τA = 0 (rotational equilibrium)

↓ + T2 ×
Let say A.C.W = +ve

And, T1 + T2 = 120
⇒ T1 = 120 - 80 = 40

11)

Explain Question:

Acceleration of hinge rod at point P.

Concept :

Find & by using

Solution :
Calculate α by applying τ = Iα

12)

Explain Question:
 Electric field due to two dipole

Concept :

Dipole vector form equation.

Solution :
Both dipole lie in x, z plane

13)

Explain Question:
Uniform field F = qE (depend only on net charge)

Concept :
Net charge = 0 Net force = 0

Solution :
Since net charge = 0

∴ Fnet = 0 as electric field is uniform.

14) Explain Question:

If tension is greater or angle is smaller the corresponding mass is larger if angle or tension are
equal, the masses are equal.

Concept :Same electric force acts angle depends inversly on mass. Tension depends on mass.

Solution :

(P)
τ1 = τ2
(m1g)ℓ1sin θ1 = m2g ℓ2 sinθ2
m1ℓ1 = m2ℓ2
∵ ℓ1 > ℓ 2
∴ m1 < m2
(Q) mgℓ1sinθ1 = m2gℓ2sinθ2
m1ℓ1sinθ1 = m2ℓ2sinθ2
∵ ℓ1sinθ1 > ℓ2sinθ2
∴ m1 < m2
(R) m1gℓ1 sinθ1 = m2gℓ2 sinθ2
m1 sin θ1 = m2 sinθ2
∵ sin θ2 > sin θ1
∴ m1 > m2
(S) m1g sinθ1 = m2 gℓ2sinθ1
 ∵ ℓ1 = ℓ2, sin θ1 = sin θ2
∴ m1 = m2

15)

Explain Question:

Outer right plate O outer left plate +Q left surface of middle plate –2Q right surface of middle
plate Q

Concept :

Ground plate fixes potential at zero induce charges total by gauss law.

Solution :
As potential of left most plate is zero. By using Gauss law we get above options.

16)

Explain Question:

Moment of inertia for different bodies

Concept :

MOI is calculated using parallel & perpendicular axis theorem.

Solution :

(I) =

(II)

MR2 = I2 = IC +

I1 = IC +
On subtracting

MR2 – I1 = M

I1 = MR2 – MR2

=
(III) For Δ → I =

for equilateral Δ → h =

I=
(IV) Mass of cut portion = M/4
Mass of remaining portion = 3M/4
Irem = Itotal – Icut

= MR2 =

17)

(P) ⇒ T = mgcos53° =

(Q) ⇒ Tcos37°= mg

⇒T =

(R)
⇒ Tcos53° = mg ⇒

T=
 (S)

⇒ T = mg cos37° ⇒ T =

PART 2 : CHEMISTRY

18) Explain Question: Find the correct order of bond Angle

Concept: Use VSEPR and Bent Rule
Solution:

Final Answer: (B)

19) Explain Question: Find temperature at state 3

Concept: Use Adiabatic relation.
Solution:
V2 = 3V1
= Constant.
γ
RTV /V = Constant
Vγ–1 . T = Constant
(γ for diatomic gas = 7/5)

T1 = (3)0.4T3 ∴ T3 = T1/(3)0.4
Final Answer: (C)

20) Explain Question: Calculate electrode potential of half cell Cu/Cu2+

Concept: Use Nernst equation.
Solution:

= + 0.03 log [Cu2+]

= 0.34 + 0.03 × log(0.1) = 0.31 V
∴ = − 0.31 V
Final Answer: (A)

21) Explain Question: Write the correct IUPAC name of given compound.
Concept: Use lowest locant rule.
Solution:
Lowest locant rule is followed.
Final Answer: (C)

22) Explain Question: Find incorrect order of melting point

Concept: Melting point (Using L.E. and polarisation)
Solution:
(A) MgO > CaO > BeO > SrO < BaO
↓
High polarisatio by Be2+
(C) KI > NaI > RbI > CsI > LiI
I− can be easily polarised
Final Answer: (AC)

23) Explain Question: Find the correct option

Concept: Fajan's rule
Solution:
M+x M+y
(i) if +x > +y then polarization of M+x is greater than M+y i.e. compound in which M+x is
present having more covalent character
(ii) And if +x < +y then polarization of M+y is greater than M+x i.e. compound in which M+y
is present having more covalent character
Final Answer: (BC)

24) Explain Question: Find the equlibirium constant (Kp) at different temperature.
Concept: Van't Hoff equation
Solution:
Final Answer: (AC)

25) Explain Question: Calculate Enthalpy for given disproportionation reaction

Concept: Factors affecting enthalpy of reaction
Solution:

Mg(s) + Cl2(g) → MgCl ; ΔH1 = –125

Mg(s) + Cl2(g) → MgCl2 ; ΔH2 = –642
Disp. 2MgCl → Mg + MgCl2 ΔH = ?
ΔH = ΔH2 – 2ΔH1 ⇒ –642 – 2 (–125) = –392
Also –49x = –392
x=8
Final Answer: (8)

26) Explain Question: Calculate pH and end point

Concept: Salt hydrolysis
Solution:
pH = 9
HA + NaOH → NaA + H2O

Initially:

At end-point: x
Note: At end point equal volume of reagents is added so concentration becomes 1/2 of initial

kh =

x = [OH–] =
pOH = 5 ⇒ pH = 14 – 5 = 9
Final Answer: (9)

27) Explain Question: Calculate pH for the given Condition

Concept: Use concept of solubility product
Solution:
Cr(OH)3(s) Cr3+ (aq.) + 3OH– (aq.)
0.01 mol gives 0.01 mol

∴
∴ Ksp = 10–3 × [OH–]3= 10–30
⇒ [OH–] = 10–9
∴ pOH = 9
∴ pH = 14 – 9 = 5
Final Answer: (5)

28)

Explain Question: Find number of correct option from following

Concept: Concept of conductance and molar conductivity
Solution:
(A) Conductivity decreases with dilution for strong electrolyte as well as weak
electrolyte.
(B) On dilution, The number of ions per unit volume that carry current in a solution
decreases.
(C) Molar conductivity increases with dilution.
(D) Molar conductivity of strong electrolyte follows DHO equation but it is not applicable for
weak electrolyte.
(E) On dilution degree of dissociation of weak electrolyte increases.
So answer is (A), (C) & (D).
Final Answer: (3)

29) Explain Question: Calculate molarity of NaOH

Concept: Double titration
Solution:
mmole of HCl used for Hph end point = 60
mmole of HCl used for MeOH end point = 100
after Hph end point
Case1 if CO2 is L.R. then products will be
CO2 + NaOH → NaHCO3
NaHCO3 + NaOH → Na2CO3 + H2O
Final product may be NaOH + Na2CO3 or NaHCO3 + Na2CO3
if mixture is NaOH + Na2CO3 VHph > VMeOH
NaHCO3 + Na2CO3 VHph < VMeOH which is
the part of problem.
Now let mmole of NaHCO3 = a
mmole of Na2CO3 = b
b = 60
a + b = 100
a = 40 ; b = 60
applying POAC for Na

nNaOH × 1 =

nNaOH =

molarity of NaOH =
Final Answer: (8)

30) Explain Question: Find total number of functional group in given compound.
Concept: Functional groups and their types.
Solution:
Final Answer: (6)

31) Explain Question:

Find the correct option.

Concept:
This question is based on Buffer solution.

Solution:
(A) Buffer solution of H3A and NaH2A

∴
(B) Buffer solution of NaH2A and Na2HA

(C) Buffer solution of Na2HA and Na3A

∴
(D) Equal amount of H3A and NaOH will form NaH2A

Final Answer: (4)

32)

Explain Question: To match compounds in column-I with their IUPAC names in column-II.
Concept: This question is based on Nomenclature of cyclic compounds.
Solution:

(P) (3) 3,3-Dimethyl cyclohexene

(Q) (5) 1,6-Dimethyl cyclohexene

(R) (1) 1-Bromo-3-chloro cyclopentane

(S) (4) Cyclopentanol

P→3;Q→5;R→1;S→4
Final Answer: (B)

33) Explain Question: Find the correct option using given order and properties
Concept: Hyperconjugation, Heat of hydrogenation.
Solution:
Stability of alkene ∝ number of α - H
Heat of combustion ∝ no. of carbon

Heat of Hydrogenation ∝ No. of π - bond

Bond order ∝ bond energy

Final Answer: (A)

34) Explain Question: Find the correct option

Concept: Crystal field theory.
Solution:

1.

2.

3.
 4.

5.

Final Answer: (D)

PART 3 : MATHEMATICS

35) Explain Question: Using the properties of ITF simplify function.

Concept: Domain and Range of ITF
Solution:

So,

⇒
Final Answer: (D)

36) Explain Question: Use properties of ITF to find range of function

Concept: Range of ITF
Solution:

f(x) = sin–1 + cos–1

Domain :- ≤ ≤1⇒x∈

and –1 ≤ ≤1⇒x∈

⇒ domain is x ∈ or x2 ∈

if (i) x2 ∈ , then f(x) = π

if (ii) x2 ∈ , then f(x) = π

if (iii) x2 ∈ , then f(x) = π ⇒ range = {π}

Final Answer: (A)

37) Explain Question: Use properties of modulus to get the expression of ITF
Concept: Domain of ITF
Solution:

As, | x | + | y | = | x + y | is true if xy ≥ 0. So, (sin–1x – x) ≥0

⇒ sin–1x – x ≥ 0 ⇒ sin–1x ≥ x
Hence, x ∈ [0, 1]. Ans.
Final Answer: (C)

38) Explain Question: In this question, the form of telescopic series is generated.
Concept: Form telescopic series
Solution:
 As

Let [cot x] = n

y=2
Final Answer: (C)

39) Explain Question: For finding the range of composite function, get range of one function
and put it in another one.
Concept: Range of composite function
Solution:

f(x) =

(A)
Range of f is (0, 8]
(B) h(f(x)) > 0 and h(g(x)) < 0
⇒ h(0) > 0 ⇒ k > 0
and h(8) > 0 ⇒ –64 – 24 + k > 0 ⇒ k > 88
Also, h(9) < 0 ⇒ –81 – 27 + k < 0 ⇒ k < 108
⇒ Number of integral value of k is 19.
(D) Maximum value of g(f(x)) is g(8) = 64 + 9 = 73.
Final Answer: (A,C,D)

40) Explain Question: Using properties of GIF function, the domain is decided and then
range is found.
Concept: Range of GIF function.
Solution:

[kx] changes at every integral multiple of .

They will change simultaneously at every multiple of LCM of

.
Number of total points at which f(x) will change in the integral [0, 3) will depend on the total
number of different terms in the following series:
[x] = 0, 1, 2
 Total number of different terms
= 9 + 12 + 15 – (2 + 2 + 2) = 30.
If
(i) If n = 3k, then the number of terms in the range = 30k + 1.
(ii) If n = 3k + 1, then the number of terms in the range
= 30k + (3 + 4 + 5 + 1) – 2 = 30k + 11
(iii) If n = 3k + 2, then the number of terms in the range
= 30k + (6 + 8 + 10 + 1) – (2 + 2) = 30k + 21.
Final Answer: (A,B)

41) Explain Question: In this question, the asymptotes are used to get equation of
Hyperbolas.
Concept: Equation of Hyperbolas.
Solution:
x(y – x) = 1 is a hyperbola with asymptotes x = 0, y = x

The transverse axis will be i.e., the line

solving with the hyperbola ;

⇒
For (A), the square of the distance between vertices

For (C), the equation of director circle :

x2 + y2 = a2 – b2 = a2 (2 – e2)

Final Answer: (A,C)

42) Explain Question: Projection of chord is to be found to get the locus of midpoint.
Concept: Locus of midpoint of a chord.
Solution:

Unit vector along the line with gradient unity is

Final Answer: (200)

Also vector
Now projection on n is 10

Squaring both sides substituting α = 45°

(t2 – t1)2 [(t2 + t1) + 2]2 = 100 . 2
[(t2 + t1)2 – 4t1t2] [(t2 + t1) + 2]2 = 200
(k2 – 2k2 + 4h) (k + 2)2 = 200
(k2 – 4h) (k + 2)2 + 200 = 0
Locus is (y2 – 4x) ( y + 2)2 + 200 = 0
Hence λ = 200

43) Explain Question: By assuming a parametric point, get the enquired expression.
Concept: Chord of Parabola.
Solution:
Let a variable point on the line of slope m ∈ (0,1)
A(k + rcosθ, 1 + rsinθ)
y2 = kx and xy = 0

from (1)

sin2θ r2 + r(2 sinθ – k cosθ) + 1 – k2 = 0

PQ.PR = – r1r2 = –
from (2)

sinθ cosθ r2 + r (cosθ + k sinθ) + k = 0

PM.PN = r1r2 =
Final Answer: (4)

44) Explain Question: By putting parametric points, required expression in to be formed.

Concept: Chord of Parabola
Solution:
Since we are dealing with distances here, it would be best if we use the polar form of a line's
equation to represent the points A and B. Thus, we use (h + r cosθ, r sinθ) as any point lying
on A B. If this lies on the parabola, then
(r sinθ)2 = 8(h + r cosθ) ⇒ (sin2θ)r2 – (8 cosθ)r – 8h = 0
Let the two roots of this equation be r1 and r2 (corresponding to AP and BP)

Final Answer: (2)

45) Explain Question: By finding intersection points of circle and ellipse, get the appropriate
values of x and y.
Concept: Equation of Ellipse.
Solution:

; x, y ∈ {1, 2, 3, .......}
2 2
T : (x – 7) + (y – 4) ≤ 36 x, y ∈ R
Let x – 3 = x : y – 4 = y

; x ∈ {–2, –1, 0, 1, .......}

2 2
T : (x – 4) + y ≤ 36; y ∈ {–3, –2, –1, 0, .......}

S ∩ T = (–2, 0), (–1, 0), .....(4, 0) → (7)

(–1, 1), (0, 1), ........(3, 1) → (5)
(–1, –1), (0, –1), ........(3, –1) → (5)
(–1, 2), (0, 2), (1, 2), (2, 2) → (4)
(–1, –2), (0, –2), (1, –2), (2, –2) → (4)
(0, 3) (0, –3) → (2)
Final Answer: (27)

46) Explain Question: Take a variable point on ellipse and get the tangent and required
values.
Concept: Tangent to Ellipse.
Solution:

Let Q be

Slope of tangent at point Q to the ellipse is

But tangent at Q will be perpendicular to the line joining P to the focus of parabola.

So

Final Answer: (3)

47) Explain Question: Use formula of median for continuous classified data.
Concept: Median of Classified data
Solution:
Frequency of the class 30 – 40 is α and that of 50 – 60 is β
∴ α + β = 229 – (12 + 30 + 65 + 25 + 18) = 79
But given that median is 46 and the class 40–50 is the median class

But median =

Replace t → x

∴ [t] = –3, –2, –1, 0, 1

p + q = 36
Final Answer: (36)

48) Explain Question: By putting one by one value of i, just calculate number of functions
possible.
Concept: Number of functions
Solution:
(A) for 1,3,5,7 ∈ A we have 4,3,2,1 choice respectively.
(B) Image of ƒ(7) should be greater then 9.
(C) for 1,3,5,7 ∈ A we have 2,2,2,2 choice respectively
(D) for any i ∈ A we have 3 choices.
Final Answer: (A)

49) Explain Question: Use Properties of different functions to find domain of each funciton.
Concept: Domain of function
Solution:
(I) x – 1= {x}. [x]
[x] + {x} – 1 = {x} . [x]
[x] (1 – {x}) – 1 (1 – {x}) = 0
([x] – 1) ({x} – 1 ) = 0
[x] = 1 {x} ≠ 1
∴ x=1
(II)
(x – 8) (x – 2) < 0
x ∈ [2,8]
∴ x ∈ (2,8]
– x2 + 10x – 16 < x2 – 4x + 4
∴ 2x2 – 14x + 20 > 0
x2 – 7x + 10 > 0
(x – 5) (x– 2) > 0
x ∈ (–∞,2) ∪ (5,∞) ∴ x = 6,7,8

(III)
2x2 (y – 1) + x(y – 7) + y – 3 = 0
y ≠ 1 ∴ (y – 7)2 – 4(y – 3) (2y – 2) > 0
–7y2 + 18y + 25 > 0
(y + 1) (7y – 25 ) < 0

–1 + 0 + 1 + 2 + 3 = 5
(IV) |x2 – 4x| + 3 = x2 + |x – 5|

Case I : x < 0 x2 – 4x + 3 = x2 – (x – 5) ∴ –3x = 2 ∴x=

Case II : 0 < x < 4 –x2 + 4x + 3 = x2 – x+ 5 ∴ 2x2 – 5x + 2

(2x – 1) (x–2) ∴
2 2
Case III : 4 < x < 5 x – 4x + 3 = x – (x – 5)
 (reject)
x – 4x + 3 = x2 + x – 5
2
Case IV : x > 5

7 = 5x ∴ (rejected)
Final Answer: (A)

50) Explain Question: By using expansion, properties of ITF terms, get required vlaue.
Concept: Properties of ITF
Solution:
(P) Let f(x) = sin–1x2 + tan–1x2 is even function and domain is [–1, 1]

If k = 0, 2k + 1 = 1, possible

If k = 1, 2k + 1 = 3 > Not possible

i.e. only one integral value of k is possible.

(Q)

:
:

Sum =
(2π is sum of last four term)

(R) we know
according to question

Only possible ⇒ sinθ – 1 = –2

sinθ = –1
(S) or
1 – | x | > 2 or 3 ≤ | x |
–1 > | x | or x ∈ (–∞, –3] ∪ [3, ∞)
Not possible
least positive integer is 3
Final Answer: (C)

51) Explain Question: Find tangent and condition of circles touching externally to get the
answers.
Concept: System of circles
Solution:

MC1 + C1C2 + C2N = 2r

⇒ 3 + 5 + 4 = 2r ⇒ r = 6 ⇒ Radius of C3 = 6

Suppose centre of C3 be ,

= (h,k) ⇒ 2h + k = 6
Equation of ZW and XY is 3x + 4y – 9 = 0
(common chord of circle C1 = 0 and C2 = 0)

(where r = 6 and )

(where r1 = 3 and )

Let length of perpendicular from M to ZW be λ,

C3 :
C1 : x2 + y2 – 9 = 0
common tangent to C1 and C3 is common chord of C1 and C3 is 3x + 4y + 15 = 0.
Now 3x + 4y + 15 = 0 is tangent to parabola x2 = 8αy.

Final Answer: (B)