20-07-2025

0999DJA161101250003 JA

PART-1 : PHYSICS

SECTION-I (i)

1)

Which of the following statements is/are INCORRECT about reference frames.

(A) In a non-inertial reference frame, an isolated particle does not retain a constant velocity.
A reference frame travelling with acceleration relative to an inertial reference frame is a non-
(B)
inertial reference frame
In an inertial reference frame, velocity vector of an isolated particle changes neither in
(C)
direction nor in magnitude, with time.
If a block is stationary with respect to an elevator then reference frame fixed to elevator must
(D)
be inertial.

2) Three boxes are pushed with a force F across a frictionless table, as shown in figure. Let N1 be the
normal force between the left two boxes, and let N2 be the normal force between the right two

boxes. Then :-

(A) F + N1 = N2
(B) F > N1 = N2
(C) F < N1 < N2
(D) F > N1 > N2

3) In the figure shown, initially spring is relaxed. Spring constant of spring is k = 100 N/m. Find
minimum value of µ (coefficient of friction) between surface & block so that block remains in

equilibrium in final stage :-

(A) µ = 0.1
(B) µ = 0.2
(C) µ = 0.4
(D) µ = 0.5
4)

If the maximum value of static friction between the two blocks is 9N and ground is perfectly smooth
then the maximum force which can be applied to the block of mass '2kg' to prevent slipping is

(A) 15 N
(B) 20 N
(C) 10 N
(D) 25 N

5) In the arrangement shown. Coefficient of friction between blocks is 0.2 and between block and
walls is 0.7. 250N horizontal force is applied as shown in the figure. Find the friction force acting

between wall and block :

(A) 180 N
(B) 175 N
(C) 150 N
(D) 100 N

6) A 10kg monkey is climbing a massless rope attached to a 15kg mass and is passing over a smooth
pulley. The mass is lying on the ground. In order to raise the mass from the ground he must climb

with

(A) uniform acceleration greater than 5m/sec2.

(B) uniform acceleration greater than 2.5m/sec2.
(C) high speed.
(D) uniform acceleration greater than 10m/sec2.

SECTION-I (ii)

1) A mass 2m suspended from a given spring causes it to stretched relative to its relaxed length.
The mass and the spring are then each cut into two identical pieces and connected as shown in
figure.

(A) Bottom of the lower mass is higher than bottom of the original mass
(B) Bottom of the lower mass is lower than bottom of the original mass
(C) Bottom of the lower mass is at the same level as the bottom of the original mass
Spring constant of new springs obtained after cutting is double than the spring constant of
(D)
original spring.

2)

Choose the correct alternative.

(A) Earth is an inertial frame of reference

A frame P moving with constant velocity with respect to another frame Q. Then both the
(B)
frames may be non-inertial.
Pseudo force on an object when it is seen from a non-inertial frame is always opposite to the
(C)
acceleration of object.
Pseudo force is applied on any object when object is observed by an observer having variable
(D)
velocity.

3) A variable force F = 10 t is applied to block B placed on a smooth surface. The coefficient of

friction between A & B is 0.5. (t is time in seconds. Initial velocities are zero)

(A) block A starts sliding on B at t = 5 seconds

(B) block A starts sliding on B at t = 10 seconds
(C) acceleration of A at 10 seconds is 15 m/s2.
(D) acceleration of A at 10 seconds is 5 m/s2.

4) A cart of mass 0.5 kg is placed on a smooth surface and is connected by a string to a block of
mass 0.2 kg. At the initial moment the cart moves to the left along a horizontal plane at a speed of 7

m/s. (Use g = 9.8 m/s2)

(A)
The acceleration of the cart is towards right.
(B) The cart comes to momentary rest after 2.5 s.
(C) The distance travelled by the cart in the first 5s is 17.5 m.
(D) The velocity of the cart after 5s will be same as initial velocity.

SECTION-I (iii)

Common Content for Question No. 1 to 2

Two blocks P and Q in the figure have mass 'm' each. The strings AB & CD are light, having tension
T1 & T2 (in N) respectively. The system is in equilibrium and spring is stretched through a distance x

= mg/k then

1)

If F = 0 and system is in equilibrium then find T1/T2

(A)

(B)

(C)

(D)

2)

If F = mg and system is in equilibrium then value of (T1/T2) is

(A)
(B) 2

(C)

(D)

Common Content for Question No. 3 to 4

A system of two blocks are connected by the heavy rod of mass 10 kg and length is 5m. Forces of
100 N and 40 N are applied on block of 8 kg and 2kg respectively. All surfaces are smooth.
3) Find the tension at point A on heavy rod which is 2 m away from the end of 2 kg block as shown in
figure :-

(A) 42 N
(B) 52 N
(C) 58 N
(D) 62 N

4) Find the acceleration of 2kg block :-

(A) 3 m/s2
(B) 6 m/s2
(C) 5 m/s2
(D) 10 m/s2

SECTION-II

1) A 2 kg block is kept at rest on a rough horizontal surface having coefficient of static and kinetic
friction as µs = 0.2 and µk = 0.1 respectively. A Force F = 2t starts acting on the object (where 't' is
in seconds). Find the speed 'v' (in m/s) of the block at t = 3 s. (g = 10 m/s2)

2) What is the maximum value (in N) of the force F such that the block shown in the arrangement

does not move :

3) There is no slipping between the two blocks. The force of friction between two blocks is ______

newton.

4) In the figure shown, the mass of block A as well as that of B is same, say m. The system is held at
rest by applying a force F as shown. If the force is removed, what is the acceleration (in m/s2) of
Block A?

PART-2 : CHEMISTRY

SECTION-I (i)

1) S1 : Oxidation number of N in N2O5 is 5

S2 : The anhydride of Hypochlorous acid is Cl2O
S3 : Hybridisation of central atom in SF6 is sp3d2
S4 : For heteronuclear diatomic species A–B, the bond length decreases as the difference in
electronegativity values increases (considering A and B of similar size) in all compound.

(A) T T T F
(B) F T T T
(C) F F T F
(D) T T T T

2) The correct order of boiling point is :

(A) H2O < H2S < H2Se < H2Te

(B) H2O > H2Se > H2Te > H2S
(C) H2O > H2S > H2Se > H2Te
(D) H2O > H2Te > H2Se > H2S

3) Of the following molecules, the one, which has permanent dipole moment, is :

(A) SiF4
(B) BF3
(C) PF3
(D) PF5

4) Correct order of dipole moment of the given molecules is :

(A) HF > CHCl3 > NH3 > CCl4

(B) H F > NH3 > CHCl3 > CCl4
(C) CHCl3 > HF > NH3 > CCl4
(D) NH3 > HF > CCl4 > CHCl3
5) Match List I and with List II

List-I (Molecule) List-II(Shape)

A NH3 I. Square pyramidal
B. BrF5 II. Tetrahedral
C. PCl5 III Trigonal pyramidal
D. CH4 IV Trigonal bipyramidal
Choose the correct answer from the option below:

(A) A-IV, B-III, C-I, D-II

(B) A-II, B-IV, C-I, D-III
(C) A-III, B-I, C-IV, D-II
(D) A-III, B-IV, C-I, D-II

6) Which of the following oxyacid contains P – P bond?

(A) H4P2O8
(B) H4P2O5
(C) H4P2O7
(D) H4P2O6

SECTION-I (ii)

1) Which of the following molecule do not have co-ordinate bond in it's Lewis structure.

(A)

(B) SO3

(C)

(D) HCN

2) Which of the following statement is/are correct ?

(A) dp – Cℓ (equatorial) > dp – F (axial) in PCℓ3F2

(B) dp – F (in PF2(CH3)3) > dp – F (in PF2(CF3))
⊕
(C) CH4 = CH3 (dC – H)
(D) CH2F2 > CHF3 (dC – H)

3) Which of the following statement is/are incorrect ?

(A) Ethanol is more viscous as compared to glycerol.

(B)

: Stability order
(C) HCℓ < HBr < HI < HF (order of melting point)
(D) H2S < H2Se < H2Te < H2O ( Heat of vapourization)

4) Select correctly matched.

(A) ⇒ two tetrahedral units are joined by their common corner

(B) ⇒ centre of one tetrahedral is the corner of other tetrahedral
(C) S2F10 ⇒ two octahedral joined together
(D) ⇒ two tetrahedral unit joined by their corners

SECTION-I (iii)

Common Content for Question No. 1 to 2

Covalent bonds are formed when two valence orbitals belonging to two different atoms overlap on
each other. The electron density in the area between the two bonding atoms increases as a result of
this overlapping, thereby increasing the stability of the resulting molecule.

1)

Which of the following statement is/are incorrect ?

(A) Generally pure orbitals ( s and p) do not have contribution in dipole moment.

(B)
(π bond strength)
(C) 3pπ – 3pπ > 3pπ – 3dπ > 3dπ – 3dπ (π bond strength)
(D) In 3d subshell, 3 axial and 2 non axial orbitals are present.

2)

If the internuclear axis is Z then which of the following combination do not overlap.

(A) dxy + dxy

(B)
(C) s + pz
(D) s + px

Common Content for Question No. 3 to 4

Hydrogen bonding is observed generally in those molecules in which hydrogen is bonded with F, O
and N.

3) In which of the following molecule, intramolecular H-bonding is observed?

(A) p-nitrophenol
(B) Marshall acid
(C) Caro's acid
(D) Chloral hydrate

4) Which of the following molecule shows H-bonding?

(A) NaH2PO2
(B) Na2HPO3
(C) Na2HPO4
(D) K2CO3

SECTION-II

1) Find our number of transformation among following which involves the change of hybridisation of
underlines atom.
(A) (B)
(C) (D)
(E)

2) In how many of the following all bond lengths are not equal?
, O3, BF3, P4(white), PCl5, SF4, CIF3, XeF2, XeF4, [CIF4]+

3) Among the triatomic molecules/ions,

, the total number of linear molecule(s)/ion(s)
where the hybridization of the central atom does not have contribution from the d-orbital(s)
is (Atomic number: S = 16, Cl = 17, I = 53 and Xe = 54)

4) Find the number of S – S linkages in H2S4O6.

PART-3 : MATHEMATICS

SECTION-I (i)

1) The numerical value of tan20°.tan80°.cot50° is equal to -

(A)

(B)

(C)

(D)
2) The value of

is -

(A) 2
(B) 1
(C) 4
(D) 5

3) ABC is a triangle such that

sin(2A + B) = sin(C – A) = and A + C = 2B, then

Which of the following is correct ?

(A)

(B)

(C)

(D)

4) If a1, a2, ...an are in A.P. with common difference d ≠ 0, then sum of the series (sin d) × [sec a1.sec
a2 + sec a2.sec a3+.....+sec an–1 sec an] is :

(A) cosec an – cosec a1

(B) cot an – cot a1
(C) sec an – sec a1
(D) tan an – tan a1

5) Let . The value

of F(1) + F(2) + F(3) is equal to :

(A)

(B)

(C)

(D)

6) (0 < θ < 90°), then

(A)
(B)
(C)
(D)

SECTION-I (ii)

1) In ΔABC, and , then an angle of the triangle

can be

(A) 30°
(B) 45°
(C) 60°
(D) 75°

2)

If , then which of the following statement(s) is/are correct ?

(A)
can be equal to

(B)
sin(θ – 83°) can be equal to

(C)
sin(θ – 83°) can be equal to

(D)
tan(θ + 67°) can be equal to

3) The expression (tan4x + 2tan2x + 1)cos2x when can be equal to

(A)

(B)

(C)

(D)

4) If (n is integer), then the expression is equivalent to

(A)

(B)

(C)
(D)

SECTION-I (iii)

Common Content for Question No. 1 to 2

Let x = sinα, u = cosα,

, ,

, .
On the basis of above information, answer the following questions :

1) (x + y + z) is equal to -

(A) 0
(B) 1
(C) –1
(D) an irrational number

2) (u2 + v2 + w2) is equal to -

(A)

(B) 0

(C)

(D)

Common Content for Question No. 3 to 4

If x = cosec2θ, y = sec2θ, .

3)

xyz is equal to -

(A) x – y + z
(B) xy + z
(C) x + y – z

(D)

4) is equal to -

(A)
(B)

(C)

(D)

SECTION-II

1) If , then sum of all integral values of n for which , when

θ ∈ [0, 4π] is

2) If then the value of :

4 3 2
3) Let A denotes the value of expression x + 4x + 2x – 4x + 7, where x = and B denotes

the value of the expression , where θ = 9°, then the product of A and B is:

4) If 7α = 2π, then the absolute value of the expression y = sec α + sec 2α + sec4α is:
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. D D D A C A

SECTION-I (ii)

Q. 7 8 9 10
A. A,D B,D A,D A,B,C

SECTION-I (iii)

Q. 11 12 13 14
A. A B C A

SECTION-II

Q. 15 16 17 18
A. 1.50 40.00 6.00 7.10 to 7.20

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. D D C B C D

SECTION-I (ii)

Q. 25 26 27 28
A. A,C,D A,B,D B,C A,B,C,D

SECTION-I (iii)

Q. 29 30 31 32
A. C D D C

SECTION-II

Q. 33 34 35 36
A. 3.00 4.00 4.00 3.00

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 37 38 39 40 41 42
A. A A A D D B

SECTION-I (ii)

Q. 43 44 45 46
A. B,C,D A,B,C,D B,D A,D

SECTION-I (iii)

Q. 47 48 49 50
A. A A B B

SECTION-II

Q. 51 52 53 54
A. 12.00 0.00 12.00 4.00
 SOLUTIONS

PART-1 : PHYSICS

1) Since the elevator may have an acceleration even though the block may remain stationary
w.r.t. the elevator.

2)

F – N1 = m a

N1 =

N2 = 3m a

N2 =

3)
x = 0.25 m

100 × .25 × = µ × (50 – 100 × .25 × )

µ=

4)
given max friction = 9 N

a = 9/3 = 3
∵ There is no slipping so both blocks will move together with a = 3
5)

6)
⇒ T = (10 + a)g ...(1)
for lift off
T – m2g = 15g = 150 N ...(2)
⇒ from (1) & (2)
(10 + a)g = 15g ⇒ a = 5 m/s2

7)

Before cutting
2mg = kx
after cutting
extention in lower spring

x1 =
extension in upper spring

x2 =

x1 + x2 =

8)

Earth is a non inertial frame of reference.

9)
fmax = µmg = 0.5 × 5 × 10 = 25 N
F = ma
25 = 5.9
a = 5 m/s2
F – 25 = 5a
10t – 25 = 5/5
10t = 50
t = 5 sec
F = 10 × 10 = 100 N

F = ma
25 = 5 × a
a = 5 m/s2

10)

(A)

(B)
t = 2.5 sec.

(C) in 2.5 sec.

in next 2.5 sec.

in 5 sec. S1 + S2 = 17.5 m.

(D)

11)

T1sin θ1 = T2 sin θ2 + mg
F = T1 cosθ1– T2cosθ2
T2sinθ2 = mg
T2cosθ2 = kx0 = mg

12)

T1sin θ1 = T2 sin θ2 + mg
F = T1 cosθ1– T2cosθ2
T2sinθ2 = mg
T2cosθ2 = kx0 = mg

13)
T – 40 = 6 × 3
TA = [2 + 4] × 3 + 40 = 58 N
14)

15)
2t – 2 = 2a

⇒v=

16)

N = F sin60° + Mg
F cm 60° = HN = N (F sin60°+Mg)

F= =

17)

18)
a = g sin θ = 5 m/s2
0.2 N ≥ f = 5 m cos 30°
N + 5 m sin 30° = mg
N = 7.5 m
0.2 N = 1.5 m <
⇒ both move separately
 mg – N = m × a cos60°

mgsin30° + N sin 30 – µ N cos 30 = ma

PART-2 : CHEMISTRY

19)

Oxidation no. of N in N2O5 is +5, anhydride of HOCl is Cl2O.

The bond length decreases with increase in difference of electronegativity

20)

(i) H2O has highest boiling point because of H-bonding.

(ii) Boiling point also depends on the magnitude of van der Waal's force of attraction, which
depends on molecular weight of the compounds. Thus, the correct order is H2O > H2Te > H2Se
> H2S.

21)
SiF4 , BF3 and PF5 are symmetrical molecules thus m = 0.

22)

23)
24)

25) H – C ≡ N:

26) (A) P – Cl > P – F

Size Cl > Size F
(B) According to Bent's rule

(C)
(D) According to Bent's rule
%S ↑ bond length

27) (A) Viscosity α no. of H-bonds (extent of H-bonding)

(B)
(C) HCℓ < HBr < HF < HI (Melting point)

28) (A)
(B)

(C)

(D)

29) (A) Pure atomic orbitals are symmetrical in nature So µ = zero

(B) Size of atom bond strength
(C) 3pπ – 3pπ < 3pπ – 3dπ < 3dπ – 3dπ
Directional character bond strength
(D) 3dxy, 3dyz , dxz = Non axial orbitals
= Axial orbitals

30)

31)

32)

A)

B)
 C)
Here O–H bond show H bonding

D)

33)

34)

In , O3, BF3, P4, XeF2, XeF4 all bond lengths same

35)

36)

PART-3 : MATHEMATICS

37)

38)

put :
39) A + C = 2B ⇒ B = 60°

sin(C – A) = ⇒ C – A = 30° or 150°

sin(2A + B) =
⇒ 2A + B = 30° or 150° or 390°
∴ B = 60°, 2A + B = 150°, C – A = 30°
⇒ A = 45°, B = 60°, C = 75°

40) As a1, a2, a3 ..., an–1, an are in A.P., hence

d = a2 - a1 = a3 - a2 = ... = an - an–1
sin d[sec a1 sec a2 + sec a2 sec a3 + ... + sec an–1 sec an]

= (tan a – tan a1) + (tan a3 – tan a2) + ... + (tan an – tan an–1)
= tan an – tan a1

41) We have

Now,

and
∴ F(1) + F(2) + F(3)

= Ans.

42)

= cot3° θ=3
43)
= tanA + tanB + tanC
Using the identity,
cos(A + B + C) = cosAcosBcosC[1–ΣtanAtanB]
⇒
Now,

;
x = tanA, tanB, tanC
It is not hard to observe that x = 1, is one of the root
Hence

44) ⇒

45) (tan4x + 2tan2x + 1)cos2x when

= (tan2x + 1)2.cos2x
= (sec4x)cos2x = sec2x

⇒
=1+4+3–
=8–

46)
= sinx(1 – cosx) + cosx(1 + sinx)
= sinx + cosx

47) x = sinα, ,
u = cosα, ,
(x + y + z)

48) u2 + v2 + w2

49) xyz =

=
xy + z

50) x = cosec2θ, y = sec2θ,

= 2(1 – sin2θ . cos2θ) – 1

= 1 – 2sin2θ cos2θ = sin4θ + cos4θ

51)

= –2cos

&

lies in IIIrd quadrant

 ,n∈π

For n = 0,
So n = 3, 4, 5, sum = 12

52)

53) (A) We have

⇒ (x + 1)2 = 2
∴ x2 + 2x – 1 = 0
Now, consider
x4 + 4x3 + 2x2 – 4x + 7

+ 2x3 + 3x2 – 4x + 7
= 2x3 + 3x2 – 4x + 7

= – x2 – 2x + 7

= –x2 – 2x + 7 =
∴ A=6

(B) We have,

∴ AB = 12

54) Let E = sec α + sec 2α + sec 4α,

where 7α = 2π
=

But cos α cos2α cos4α = where

Hence E = 4[2cos2α cos4α + 2cos4α cosα
+ 2cosα cos2α]
= 4[cos6α + cos2α + cos5α + cos3α
+ cos3α + cosα]
= 8[cosα + cos2α + cos3α]
(As cos6α = cosα and cos5α = cos2α)
Now let S = cosα + cos2α + cos3α

∴
Hence E = – 4
⇒ |E| = 4