GOVT.
GRADUATE COLLEGE SATELLITE TOWN GUJRANWALA
Chemistry-I, Expected Papers for Annual Examinations-2025
Intermediate Part-I, Class 11th Time: 20 Minutes Marks: 17
3
OBJECTIVE
Note: You have four choices for each objective type question as A, B, C and D. The choice which you think is correct; fill
that circle in front of that question number. Use marker or pen to fill in the circles. Cutting or filling of two or more
circles will result zero mark in that question.
1. 1. Many elements have fractional atomic masses. This is because:
(A)The mass of atom is itself fractional
(B)Atomic masses are average masses of isobars
(C)Atomic masses are average masses of isotopes
(D)Atomic masses are average masses of isotopes proportional to their relative abundances
2. The atomicity of the molecules, He, O2, O3, P4, NH3, H2SO4 is respectively:
(A) 1, 2, 3, 4, 4, 7 (B) 2, 2, 1, 1, 2, 3 (C) 1, 1, 2, 4, 5, 7 (D) 1, 2, 3, 4, 5, 6
3. Solvent extraction in an equilibrium process and it is controlled by:
(A) Law of mass action (B) The amount of solvent used
(C) Distribution law (D) The amount of solute
4. Which has same number of molecules at S.T.P?
(A) 11.2 dm3 of O2 and 32g of O2 (B) 44g of CO2 and 1 dm3 of CO
(C) 28 g of N2 and 5.6 dm3 of O2 (D)280 ml of CO2 and 280 cm3 of N2O
5. The colour of NO2 gas is:
(A) yellow (B) green (C) brown (D) blue
6. In order to mention the boiling point of water of 110°C, the external pressure should be:
(A)between 760 torr and 1200 torr (B) between 200 torr and 760 torr
(C) 765 torr (D) any value of pressure
7. At Murree Hills water boils at:
(A) 98°C (B) 100°C (C) 0°C (D) 50°C
8. Bohr's model of atom is contradicted by:
(A) Photo electric effect (B) Paul's exclusion principle
(C) Heisenberg's uncertainty principle (D) Aufbau principle
9. Splitting of spectral lines when atoms are subjected to a strong electric field is called:
(A) Zeeman effect (B) Stark effect (C)Compton effect (D) Photoelectric effect
10. Which of the hydrogen halide has highest percentage of ionic character:
(A) HBr (B) HCl (C) HI (D) HF
11. Which has unpaired electrons in antibonding molecular orbitals?
(A) N2-2 (B) O2+2 (C) B2 (D) F2
12. The change in heat energy of a chemical reaction at constant temperature and pressure is called:
(A) Enthalpy (B) Heat of sublimation (C) Bond energy (D) Internal energy change
13. An excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by filtration.
What are the main ions in the filtrate?
(A)Ag+ and NO3- only (B) Ag+ and Ba2+ and NO3-
(C) Ba+2 and NO3- only (D) Ba2+ and NO3- and Cl-
14. pH of rain water is:
(A)5.0 (B) 6.0 (C)6.2 (D) 7.0
15. A solution of glucose is 10% w/v. The volume in which lg mole of it is dissolved will be:
(A) 1 dm3 (B) 1.8dm3 (C) 200 cm3 (D) 900 cm3
16. Stronger the oxidizing agent greater is the:
(A) oxidation potential (B)reduction potential (C) redox potential (D)EMF of cell
17. The rate of reaction:
(A)Increases as the reaction proceeds (B)Decreases as reaction proceeds
(C) Remains the same as reaction proceeds (D)May decrease or increase as the reaction proceeds
9270
GOVT. GRADUATE COLLEGE SATELLITE TOWN GUJRANWALA
Chemistry-I, Expected Papers for Annual Examinations-2025
Intermediate Part-I, Class 11th Time: 2.40 Hours Marks: 68
3
SUBJECTIVE
Note: Section I is compulsory. Attempt any THREE (3) questions from Section II.
(SECTION -I)
2. Write short answers to any EIGHT (8) questions: 2 8 = 16
i. N2 and CO have same number of electrons, protons, and neutrons? Justify.
ii. How can the efficiency of a chemical reaction be expressed?
iii. How limiting reactant is identified?
iv. Define crystallization. What is the basic principle of crystallization?
v. State sublimation with two examples. How this process is carried out?
vi. High pressure and low temperature make the gases non-ideal. Explain why?
vii. Give the S.I units of general gas constant (R).
viii. What do you mean by absolute zero temperature? How is absolute zero explained by drawing graph
ix. Differentiate between primary and secondary cells with examples.
x. A porous plate or a salt bridge is not required in lead storage cell. Give reason.
xi. Define activation energy and activated complex.
xii. How surface area and light affect the rate of a reaction.
3. Write short answers to any EIGHT (8) questions: 2 8 = 16
i. What are Debye forces?
ii. Earthenware vessels keep water cool. Why?
iii. What is anisotropy? Give one example.
iv. What is symmetry? Write names of various different symmetry elements.
v. What is discharge tube? Draw its diagram. And why positive rays are also called canal rays?
vi. The e/m value for positive rays obtained from hydrogen gas is 1836 times less than that of cathode rays. Why?
vii. What is Mosley’s law? Give its signification.
viii. Give reasons for the production of positive rays.
ix. State Le-Chatelier's principle and discuss the change in concentration of a product on the reversible reaction.
x. What are Kc and Kp and how these are related?
xi. What is state of chemical equilibrium? Justify that chemical equilibrium is dynamic in nature.
xii. Discuss effect of catalyst on equilibrium constant.
4. Write short answers to any SIX (6) questions: 2 6 = 12
i. How electronegativity changes in a group?
ii. How the nature of the chemical bond is predicted with the help of electronegativity values of bonded atoms?
iii. What is coordinate covalent bond? Give an example.
iv. Why the distinction between a coordinate covalent bond and covalent bond vanishes after bond formation in NH 4+
and H3O+?
v. Define system and surrounding with one example
vi. Define state and state function and give two examples?
vii. The sum of mole fractions of all the components is always equal to unity for any solution. Justify it.
viii. Define parts per million. Write its mathematical expression.
ix. Define azeotropic solution with one example.
x. The boiling point of one molal urea solution is 100.52 °C but the boiling point of two molal urea solution is less than
101.04°C. Give reason.
(SECTION -II)
5. (a) Mg metal reacts with HCl to give hydrogen gas. What is the minimum volume of HCl solution (27% by weight)
required to produce 12.1 g of H2.The density of HCl solution is l.14g/cm3. Mg (S) + 2HCl → MgCl2(aq) + H2(l)
(b) Write down the postulates of kinetic molecular theory of gases 4
6. (a) What are liquid crystals? Give their uses. 4
(b) Explain sp2 and sp hybridization by taking one example of each type. 4
7. (a) Derive the equation for the radius of nth orbit of hydrogen atom using Bohr’s model. 4
(b) Write a note on construction and working of bomb calorimeter. 4
8. (a) Calculate the pH of a buffer solution in which 0.11 molar CH 3COONa and 0.09 molar acetic acid solutions are
present Ka for CH3COOH is l.85×l0-5. 4
(b) Give names of different types of methods for determining order of a reaction and describe two methods for finding
order of reaction. 4
9. (a) What is solubility curve? Discuss its types with examples. 4
(b) Explain electrolysis of fused salt and aqueous solution of salts. 9270 4
