Punjab College P.D.

Khan Campus
Pre-Board Examination 2024 Roll No: ________
Section: ________ Name:
Class: Inter Part–I Max. Marks: 17
Subject: Chemistry Time Allowed: 20Minutes

Objective
Q1. You have four choices for each objective type question as A, B, C and D. The choice which you think is correct; fill
that circle in front of that question number on given objective answer sheet. Use blue marker or pen to fill the circles.
Cutting or filling two or more circles will result in zero mark in that question.
1) The atomicity of C6H12O6 is
(a) 6 (b) 12 (c) 3 (d) 24
2) The number of moles of CO2 which contain 8g of oxygen
(a) 0.25 (b) 0.15 (c) 0.5 (d) 1.5
3) The drying agent in vacuum desiccator is:
(a) AgCl (b) NH4Cl (c) P2O5 (d) AlCl3
4) Solvent extraction in equilibrium process is controlled by
(a) Law of mass action (c) Law of definite proportion
(b) Distribution law (d) Rf value
5) The SI unit of pressure is
(a) torr (b) mm of Hg (c) Nm-2 (d) psi
6) Equal masses of CH4 and O2 are mixed in an empty container, what is the total pressure exerted by O2?
(a) 1/3 (b) 8/9 (c) 1/9 (d) 16/17
7) Which of the following has hydrogen bonding?
(a) CH4 (b) CCl4 (c) NH3 (d) NaCl
8) Which impurity makes the shape of sodium chloride crystals needle like?
(a) Sugar (b) Urea (c) Glucose (d) Sucrose
9) Brackett lie in the region:
(a) UV (b) IR (c) Visible (d) X-rays
10) Quantum number value for 4d sub-shell is:
(a) n=4 , l=1 (b) n=3 , l=1 (c) n=4 , l=2 (d) n=3 , l=0
11) Which of the following molecule has tetrahedral shape?
(a) SnCl2 (b) SO2 (c) BF3 (d) CH4
12) Which of following specie has highest number of unpaired electrons?
(a) O2 (b) N2-2 (c) B2 (d) F2
13) The total heat content of the system is called:
(a) Enthalpy (b) Internal energy (c) Temperature (d) Entropy
-3 3
14) pH of 10 mol/dm of aqueous solution H2SO4 is:
(a) 3.0 (b) 2.0 (c) 2.7 (d) 1.5
15) Molarity of pure water is:
(a) 1.0 (b) 18 (c) 16 (d) 55.5
16) Standard Hydrogen Electrode is made of?
(b) Ag foil (b) Au foil (c) Cu foil (d) Pt foil
17) Sum of exponents of the concentration terms in the rate equation is called?
(a) Rate of reaction (b) order of reaction (c) specific rate (d) active mass
 Punjab College P.D. Khan Campus
Pre-Board Examination 2024 Name: _______________
Section: ________ Roll No: _____________
Class: Inter Part–I Max. Marks: 68
Subject: Chemistry Time Allowed: 2:40 Hrs

Subjective
SECTION-I
Q.2 Answer any eight parts from the followings. 2*8=16
i. N2 and CO have same number of electron, proton and neutron. Explain.
ii. What is limiting reactant? How does it control the rate of reaction?
iii. Differentiate between actual yield and theoretical yield.
iv. Define crystallization. Write the name of steps involved in this process.
v. What is difference between adsorption and partition chromatography?
vi. Why Sintered glass crucible is preferred over Gouch crucible?
vii. State Dalton’s law of partial pressure. Give its mathematical form.
viii. Write two uses of plasma.
ix. Derive SI and Standard units of “R”.
x. Calculate the pH of 10-4 moles/dm3 of Ba(OH)2?
xi. Differentiate between Acidic buffer and Basic buffer with example of each.
xii. State common ion effect. How does it help for the purification of NaCl?
Q.3 Answer any eight parts from the followings. 2*8=16
i. One feels sense of cooling under the fan after taking bath. Why?
ii. Why boiling point of water is different at Murree hills and at Mount Everest?
iii. The electrical conductivity of metals decreases with increase in temperature. Why?
iv. Define transition temperature. Write its two examples.
v. Why positive rays are also called canal rays?
vi. Differentiate between Atomic emission and Atomic adsorption spectrum with diagrams.
vii. Define Hund’s rule and Pauli Exclusion Principle with examples.
viii. Prove that sum of mole fraction of all the components is always unity.
ix. In summer the antifreeze solutions protect water of radiator from boiling over. How?
x. Differentiate between Ideal and Non-Ideal solution.
xi. State rate of reaction and write its unit.
xii. How does rate of reaction depend upon the surface area and temperature?
Q.4 Answer any six parts from the followings. 2*6=12
i. Why π bond is more diffused than σ bond?
ii. Justify the non-existence of He2 according to MOT.
iii. Why dipole moment of CO2 zero while that of H2O is 1.85D?
iv. Justify that burning of candle is spontaneous process.
v. Differentiate between system and surrounding with labeled diagram.
vi. Define the terms enthalpy of Neutralization and enthalpy of Atomization with example of each.
vii. What is SHE. Draw its diagram.
viii. What is function of salt bridge in galvanic cell?
ix. Write down the reactions involving alkaline battery.

SECTION-II
Attempt any three questions from the following. 8*3=24
Q.5.(a)Explain construction and working of mass spectrometer. (4)
(b) Describe Manometric method for the determination of vapour pressure. (4)
Q.6.(a).Calculate the mass of 1dm3 of NH3 at 30 oC and 1000 mm of Hg pressure, considering it ideal gas. (4)
(b). Derive the expression for radius of H atom. (4)
Q.7.(a).How does MOT explain the paramagnetic behavior of O2? (4)
(b). The solubility product of Ag2CrO4 is 2.6x 10-2 at 25 oC. calculate the solubility of compound. (4)
Q.8.(a). Describe and explain Hess’s law with an example. (4)
(b). Write a comprehensive note on “Fuel Cell”. (4)
Q.9.(a). Explain graphical presentation of elevation of boiling point. (4)
(b). How does half life method help for the determination of order of reaction (n)? (4)