Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad

INTERNAL GRAND TEST

PAPER-1
Time : 3 Hours Maximum Marks : 186

R E AD T H E INSTR U C T IO NS C AR E F U L LY

GENERAL :

1. T h is sea led book le t is you r Q u estion P a pe r . Do not br e a k t h e se a l t i ll you a re tol d

to do so.

2. U se t he O pt ica l Response sheet (O RS) provided sepa r a tely for a nswer ing t he quest ions.

3. B la n k spaces a re provided w it h i n t h is book let for rough wor k.

4. W r ite you r n a me, for m n u mber a nd sign i n t he space provided on t he back cover of t h is
book le t .

5. A fter b rea k ing t he sea l of t he book let, ver ify t h a t t he book let con t a i ns 28 pages a nd
t h a t a ll t he 18 q uest ions i n each subject a nd a long w i t h t he opt ions a re legible. If not,
con t act t he i n vigila tor for replacemen t of t he book let.

6. You a re a llowed to t a k e a w a y t he Q uest ion P a per a t t he end of t he ex a m i n a t ion.

O P TIC A L R ESP O NSE SH E E T :

7. T he O RS w ill be collected by t he i n vigil a tor a t t he end of t he ex a m i n a t ion.

8. Do not t a mper w i t h or m u t ila te t he O RS. D o n o t u se t h e O R S f o r r o u g h w o r k .

9. W rite you r na me, for m n u mbe r a nd sign w i t h pen i n t he space provided for t h is pu rpose
on t he O RS. D o n o t w r i t e a n y o f t h e se d e t a i ls a n y w h e r e e lse o n t h e O R S. D a r k en
t he a pp rop r i a te b ubble u n der each digi t of you r for m n u mber.

D A R K E NIN G T H E B U B B L E S O N T H E O RS :

10. Use a B L A C K B A L L P O I N T P E N to da r k en t he bubbles on t he O RS.

11. D a r ken t he bubble C O M P L E T E L Y.

12. T he cor rect w a y of da r ken ing a bubble is as :

13. T h e O RS is m ach i ne-g r ada ble. E nsu re t h a t t he bu bb les a re da r k ened i n t he cor rect
w a y.

14. D a r ken t he bubbles O N L Y I F you a re su re of t he a nswer. T here is N O W A Y to er ase

or " u n-da r ken " a da r kened bubble.

15. T a ke g = 10 m/s 2 u n less ot her w ise st a ted.

 SOM E USE F U L C O NSTA N TS
A t o m i c N o. : H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, A l = 13, P = 15, S = 16,
C l = 17, B r = 35, Xe = 54, C e = 58
A t o m i c m a sses : H = 1, L i = 7, B = 11, C = 12, N = 14, O = 16, F = 19, N a = 23, M g = 24,
A l = 27, P = 31, S = 32, C l = 35.5, C a =40, F e = 56, B r = 80, I = 127,
Xe = 131, B a =137, C e = 140,

B o l t z m a n n co n st a n t k = 1.38 10–23 J K –1
1
C o u l o m b's l a w c o n s t a n t = 9 10 9
4 0

U n i v e rsa l g r a v i t a t io n a l co n st a n t G = 6.67259 10 –1 1 N –m 2 k g –2
S p ee d of li gh t i n v a c u u m c = 3 10 8 m s–1
S t ef a n–B olt z m a n n const a n t = 5.67 10 –8 W m –2 – K –4
W i e n's d i s p l a c e m e n t l a w c o n s t a n t b = 2.89 10–3 m– K
P e r m e a b ili t y of v ac u u m µ0 = 4 10 –7 N A –2
1
P e r m i t t i v i t y of v ac u u m 0
= 2
0c
P l a n c k c o n st a n t h = 6.63 10 –34 J –s

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 HAVE CONTROL HAVE PATIENCE HAVE CONFIDENCE 100% SUCCESS
BEWARE OF NEGATIVE MARKING
P A R T -1 : P H Y S I C S
S E C T I O N -I ( i ) : ( M a x i m u m M a r k s : 12)
T h is sect ion con t a ins F O U R q u est ions.
E ach quest ion h as F O U R op tions (A), (B), (C) a n d (D). O N L Y O N E of t hese fou r opt ions
is cor rect.
F or e ach q u est ion , d a r k e n t h e b u bb le cor respon d i ng to t h e cor r ect op t ion i n t h e O R S.
F or e ach q u est ion , m a r k s w i l l be a w a r ded i n on e of t h e follow i ng ca t egories :
F u l l M a rks : +3 If on ly t h e bu bb le cor respon di ng to t h e cor rect opt ion is da r k en ed.
Z ero M a r ks : 0 I f non e of t h e b u bb les is d a r k e ned.
Nega tive M a rks : –1 I n a l l ot her cases
1. A m assless inex tensible st ring is w r a pped over a cylinder of r a dius 20 cm a nd m ass of 2 kg.
I t is con nected to a h a ngi ng block of m ass 1 kg. If t he surface is smoot h, t he cyli nder reaches
a dist a nce in t ime t 1 . If t he su rface is sufficien t ly rough, t he cyli nder reaches t he dist a nce
t1
in t ime t 2 . T hen =
t2

7 10 1
(A) 1 (B) (C) (D)
10 7 2
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2. A n equ i-con vex lens (µ = 1.5) is combined w it h a n equ i conca ve lens (µ = 1.3). T he r a dii of
cu rva t u re of all su rfaces is t he sa me. (Assu me t h in lenses)
(A) T he combi n a t ion beh a ves li k e a con vergi ng le ns i n m ediu m of refr act ive i n dex 1.4 a nd
diverging lens in a mediu m of refr act ive index 1.6.
(B) T he combi n a t ion beh a ves lik e a con vergi ng lens in a mediu m of refr act ive index 1.2 as well as
1.4.
(C) T he combi n a t ion beh a ves li ke a divergi ng lens i n mediu m of refr act ive i ndex 1.2 as well as
1.6.
(D) T he combin ation beh aves like a diverging lens in mediu m of refr act ive index 1.4 and converging
lens in a mediu m of refr act ive index 1.6.
3. A cer t a in subst a nce (not a n idea l gas) h as a P V gr a ph as a st r a igh t line A B w hen subjected to a n
adi aba t ic process. If t he sa me subst a nce goes t hrough process A C B , w h a t is the hea t given
to it ?

P
5 A C
2 10 P a

5
1 10 P a B

V
1 l it re 2 l it re

(A) 50 J (B) 200 J (C) 150 J (D) 100 J

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4. A ch a rge of +10µ C a nd m ass of 1gm is moving w it h velocit y of 10 6 m/s a t a n a ngle of 45° to
x & y a xis as show n. I t exper iences a m agnet ic force a long –ve z-direct ion. W hen i t is projected
w it h 10 6 m/s a long + ve z-direct ion, i t exper iences a m agnet ic force of 10 –2 N in +ve x-direction.
T he m agnetic field B is :

y
v

45°
x

(A) 10 T ˆi ˆj ˆj kˆ
3
(C) 10 3 ˆi (D) 10 3 T ˆj
3
(B) 10

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 S E C T I O N -I ( i i) : ( M a x i m u m M a r k s: 32)
T h is sect ion con t a i ns E I G H T q u est ions.
E ach q uestion h as F O U R opt ions for cor rect a nswer(s). O N E O R M O R E T H A N O N E of t hese
fou r option(s) is (a re) cor rect option(s).
F or each qu est ion, choose t he cor rect opt ion(s) to a nswer t h e quest ion.
A nswer to each quest ion w ill be ev a l u a ted according to t h e follow i ng m a r k i ng sch eme:
F u ll M a rks : +4 If only (al l) t he cor rect option(s) is (a re) chosen.
P a rt i a l M a rks : +3 If a ll t he fou r opt ions a re correct bu t O N L Y t h ree opt ions a re chosen.
P a rt i a l M a rks : +2 If t h ree or more opt ions a re correct bu t O N L Y t wo opt ions a re chosen,
bot h of w h ich a r e cor r ect op t ions.
P a r t i a l M a r ks : +1 I f t wo or more opt ions a re cor rect bu t O N L Y on e opt ion is chose n
a n d i t is a cor rect op t ion.
Z ero M a r ks : 0 I f non e of t h e op t ions is chose n (i.e. t h e q uest ion is u n a nsw e red).
N ega t i ve M a r ks : –1 I n a l l ot her cases.
F o r E x a m p l e : If first, t hird a n d fou r t h a re t he O N L Y t h r ee correct opt ions for a q uest ion w i t h
second opt ion bei ng a n i ncor rect opt ion; select ing on ly a ll t he t h ree cor rect opt ions w ill resu l t
i n + 4 m a r ks. Select i ng on ly t wo of t he t h ree cor rect opt ions (e.g. t he fi rst a nd fou r t h opt ions),
w i t hou t select i ng a n y i ncor rect opt ion (second opt ion i n t h is case), w ill resu l t i n +2 m a r ks.
Select i ng on ly one of t he t h ree cor rect opt ions (ei t her fi rst or t h ird or fou r t h opt ion), w i t hou t
selecting a ny incor rect op tion (second option in t h is case), w ill result in +1 m a r ks. Selecting
a n y incorrect option(s) (second option in t his case), w it h or w it hout select ion of a ny cor rect opt ion(s)
will resu lt in –1 m a r ks.
5. In the given circuit the potential difference between a & b is 300 V. T he resistors are of 100 each.

M1

a b
R R R
M2

(A) If the upper meter M 1 is ideal voltmeter & lower is ideal ammeter M 2 , reading of voltmeter
is 300 V.
(B) If bot h meters a re idea l vol t meters, t hey show 200 V each.
(C) If bot h meters a re idea l a m meters, t hey read 6 A each.
(D) If the upper meter M 1 is idea l voltmeter and lower is ideal ammeter M 2 , rea ding of am meter
is 3A.
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6. A pl a st ic body of densi t y is to be h eld i n a i r of de nsi t y a
fi rst a n d t h e n i n w a t e r of
densit y w . F or holding, we need to apply a force on it.

w a
(A) I t is easier to hold it in w a ter if > a
& .
2
(B) I t is easier to hold it in w a ter if > w
.

w a
(C) I t is easier to hold it in a ir if < w
& .
2

w a
(D) I t is easier to hold it in w a ter if < w
& .
2
7. A long meta llic rod of mass m is being moved on t wo smooth horizont al met allic rails w ith const an t
velocit y v. T he a ngle bet ween t he r a ils is . A u n ifor m m agnetic field (B) in ver t ica l direct ion is
p rese n t a s show n. T h e ca p aci tor is i n it i a ll y u nch a rged. T h e resist a nce of ci rcu it is ze ro.
C hoose C O R R E C T gr a ph(s) :-

C v

A
x0

i E x ter n a l
cu r ren t force to be
i n t he a ppl ied
r a il on t he rod
(A) (B)

t ime t ime

Dist ance of E nergy

point of stored in
applica tion capacitor
of force
(C) from lower (D)
end
t ime t ime
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8. A ra dioact ive n ucle us A deca ys to C a ft er e m it t i ng t wo a nd t h ree – pa r t icles. A not he r
n ucleus B deca ys to C by em it t ing one a nd five – pa r t icles. H a lf lives of A & B a re 1 h r a nd
2h r respect ively a nd in ter media ries h a ve negligible h a lf lives. A t t ime t = 0; popula t ion of A
is 4 N 0 , of B is N 0 a nd of C is zero.
(A) A tom ic m ass n u mber of A – A tom ic m ass n u mber of B = 4
(B) A tom ic n u mber of A – A tom ic n u mber of B = – 2
9N 0
(C) W hen A & B h a ve equ a l popula tion, popula tion of C = .
2
(D) T he deca y r a te of A & B a re equ a l a t t = 6h r.
9. W hen a n a r row reson a nce colu m n a ppa r a t us is filled w it h ozone gas ( = 4/3), it reson a tes in
1 st reson a nce w it h a t u ning for k . W hen it is filled w it h nit rogen gas (N 2), it reson a tes w it h t he
sa me tu ning for k in 1 st reson a nce w hen w a ter colu m n is sh ifted dow n by 10 cm. (T a k e 5 = 2.25)
(A) W a velengt h of sou nd i n O zone is approxi m a tely 1 m.
(B) W a velengt h of sou nd i n N i t rogen is approxi m a tely 1.6 m.
(C) F or second reson a nce in O zone gas, t he w a ter colu m n shou ld be sh ifted dow n by 60 cm.
(D) F or second reson a nce i n N it rogen gas, t he w a ter col u m n shou ld be sh ifted dow n by 80 cm.
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1 0. I n a n A C circu it, box m a y con t a in a n inductor or a ca pacitor.

Box

T he vol t age across sou rce is show n by given gr aph

V

H ere V box versus time & V resista nce versus t ime gr aphs a re plot ted. C hoose t he possible C O R R E C T
a lter n a tive(s) :
V box

(A) If box con t a ins inductor, t

V resista nce

(B) If box con t a ins inductor, t

V resistace

(C) I f box con t a ins capacitor, t

V box

(D) If box con t a ins capacitor, t

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1 1. A body of m ass m exper iences a cen t r a l force F k r . H ere r is t he posit ion from cen t re of
force a nd k is a positive const a n t. I t moves in a closed circula r pa t h such t h a t it's a ngula r
nh
momen t u m a bou t cen t re of force is qu a n t ized L . T a ke poten t ia l energy = 0 a t r = 0.
2
(A) I t's possible r a dius is qu a n t ized such t h a t r n 1/2 .
(B) I t's possible mech a nica l energy is qu a n tized such t h a t E n.
(C) I t's speed is qu a n t ized such t h a t v n 1/2 .
(D) I t's a ngu l a r veloci t y is qu a n t ized such t h a t n.
12. 5 elast ic ba lls A , B , C , D a nd E of sa me m ass a re moving on a long frict ionless horizon t a l w ire. A
gr aph is dr a w n for t hei r posi t ion x aga i nst t ime. Select t he possible C O R R E C T st a temen t(s) on
basis of gra ph.

4m A

3m B

2m C
1.5 m
D
1m
E
0 1 sec. 1.8 sec.

(A) T here a re a tot a l of 10 collisions.

(B) B a ll A fin a lly moves wit h a velocity of +1.5 m/s.
(C) B a ll C fin a lly moves wit h a velocity of 0.5 m/s.
10
(D) B a ll D fi na lly moves w it h a velocit y of m /s .
9
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 S E C T I O N -I I : ( M a x i m u m M a r k s: 18)
T h is sect ion con t a i ns S I X quest ions.
T he a nswer to each q uest ion is a N U M E R I C A L V A L U E .
F or each qu est ion, en ter t he cor rect n u mer ica l v a l ue (i n deci m a l not a t ion, t r u nca t ed/rou nded-
off to the seco n d d eci m a l p la c e; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30, if answer is 11.36777.....
t hen bot h 11.36 a nd 11.37 w ill be correct) by da r k en t he corresponding bubbles in t he O RS.
F o r E x a m p l e : I f a nswer is –77.25, 5.2 t hen fi ll t he bubbles as follows.
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9

A nswer to each quest ion w ill be ev a l u a ted according to t h e follow i ng m a r k i ng sch eme:
F u ll M a rks : +3 If O N L Y t he cor rect n u mer ica l v a lue is en tered as a nswer.
Zero M a rks : 0 I n a ll ot her cases.
1. E lect rom agnet ic w a ves of w a velengt h = 500 nm a re incident on a Y D S E a ppa r a t us. Bot h slits
a re of sa me w idt h. H ere d = 3 m m, D = 2 m. I ntensit y a t cent ra l m a xim a is 1 W/m 2 , w ha t is t he
in tensity (in W/m 2) a t a poin t 1 m m above m a xim a of order 1?
2. A poin t sou rce a nd a receiver a re st a t ion a ry . Source sends a w a ve of frequency 256 H z, w h ich
direct ly reaches to receiver a nd a lso after being reflected from a w a ll. T he w a ll is movi ng a t speed
of 1 m/s. F ind bea t frequency (in H z) hea rd by receiver. V elocit y of sou nd = 321 m/s.

1m/s

S R

Sp ace for Rou g h Wor k

3. Su rface tension of a liquid is being est im a ted by measu ring heigh t of liq uid rises in a ca pilla ry.
T he t r a velling m icroscope h as ver n ier sca le w hose reading for w a ter level B is 2.3 cm on m a i n
sca le a nd 4 t h ver nier sca le division coinciding. T he rea ding for lower level of meniscus A is 4.7 cm
on m a in sca le a nd 9 t h ver n ier sca le division coi ncidi ng. F or measu r ing t he dia meter, t he left end
of t he ca pilla ry C measu res 3.1 cm on m a in sca le a nd 1 st ver n ier sca le div ision coinciding. T he
righ t en d of ca pilla ry D measu res 3.2 cm on m a in sca le a n d 4 t h ver nier sca le division coinciding.
H ere a ngle of con t act = 0°, densi t y is 10 3 kg/m 3 a nd acceler a t ion due to gr a vit y = 10 m/s2 a nd
10 ver nier sca le divisions = 9 m a in sca le divisions. W h a t is va lue of su rface tension (in N/m) ?

C D

4. A ch a rge of 8µ C is given to poin t A a nd poin t B is ea r t hed. If each ca pacit a nce is 1 µ F , w h a t is t he

tot a l energy (in µ J) of t he system ?

B
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 r2
5. T h e ch a rge de nsi t y i nside a n ucle us is gi ve n by 0 1 w h e re r a , a = r a di us of
a2

n ucle us = 3 fm a nd 0 = 5 10 25 C/m 3 . T he elect ric field is m a xim u m a t r = r 0 . F ind r 0 (in fm)

a nd fill it in O M R sheet.
6. T wo rigid w a lls a t a dist a nce of 1m act as a hea t reservoir a t 100 °C a n d 0°C . A well lagged
u n ifor m rod h a vi ng lengt h of 1m a t 0°C is held bet ween bot h t he w a lls. I t is fou nd t h a t w hen t he
system reaches steady st a te, t he suppor t ing force ca n be removed a nd lim i t ing fr ict ion acts on t he
rod a t bot h t he ends. H ere for rod = 10 –5/°C , Y = 2 10 11 N/m 2 , µ w a lls = 0.3 a n d a rea = 4m m 2 .
W h a t is t he m ass of t he rod (in K g) ?

100° C 0° C

Sp ace for Rou g h Wor k

 P A R T -2 : C H E M I S T R Y
S E C T I O N -I ( i ) : ( M a x i m u m M a r k s : 12)
T h is sect ion con t a ins F O U R q u est ions.
E ach quest ion h as F O U R op tions (A), (B), (C) a n d (D). O N L Y O N E of t hese fou r opt ions
is cor rect.
F or e ach q u est ion , d a r k e n t h e b u bb le cor respon d i ng to t h e cor r ect op t ion i n t h e O R S.
F or e ach q u est ion , m a r k s w i l l be a w a r ded i n on e of t h e follow i ng ca t egories :
F u l l M a rks : +3 If on ly t h e bu bb le cor respon di ng to t h e cor rect opt ion is da r k en ed.
Z ero M a r ks : 0 I f non e of t h e b u bb les is d a r k e ned.
N ega t i ve M a r ks : –1 I n a l l ot h e r cases
1. Se lect react ion(s) w h ich w i l l fa vou r i n for w a r d di rect ion

O OH O ONa

(A) + Na H C O3 + C O2 + H 2O
O OH (excess) O ONa

(B ) M e – C C – Me + N a N H2 MeC H2 – C C Na N H3
(C) E t O H + N a O H E tO N a + H2O
( D ) N on e of t h ese
2. Se lect a n op t ion h a v i ng i ncor rect m a jor p rod uct?
MeO H
(A ) M e 3 C – C l + M e O N a M e3 C – O M e

(B) + M e2 N H

Cl N M e2

(C)
O Ac

Conc. H 2 S O 4
(D) 2 C a t alyt ic

3. C hoose C O R R E C T ou t er elect ron ic configu r a t ion of C u, C r & P d a re respect i vel y.

(A) 3d 10 4s 1 , 3d 5 4s 1 , 4d 10 5s 0 (B) 3d 9 4s2 , 3d 4 4s2 , 4d 8 5s 2
(C) 3d 10 4s1 , 3d 5 4s1 , 4d 8 5s 2 (D) 3d 9 4s1 , 3d 5 4s2 , 4d 10 5s 0
4. T he solubili t y of Ag 2 C O 3 in w a ter is 5520 g/L . K sp of Ag 2 C O 3 is (A g = 108)
(A) 4.0 10 –10 (B) 8.0 10 –15 (C) 3.2 10 –14 (D) 1.6 10 –11
Sp ace fo r R o u g h Wo r k
 S E C T I O N -I ( i i) : ( M a x i m u m M a r k s: 32)
T h is sect ion con t a i ns E I G H T q u est ions.
E ach question h as F O U R options for cor rect a nswe r(s). O N E O R M O R E T H A N O N E of
t h ese fou r opt ion(s) is (a r e) cor r ect op t ion(s).
F or e ach q u est ion , choose t h e cor r ect op t ion(s) to a nsw e r t h e q u est ion .
A nsw er to e ach q u est ion w i ll be ev a l u a t ed accord i ng to t h e fol low i ng m a r k i ng sch e m e:
F u l l M a rks : +4 I f on ly (a l l) t h e cor rect op t ion(s) is (a r e) chose n .
P a r t i a l M a r ks : +3 If a ll t he fou r opt ions a re correct bu t O N L Y t h ree opt ions a re chosen.
P a r t i a l M a r ks : +2 If t h ree or more opt ions a re correct bu t O N L Y t wo opt ions a re chosen,
bot h of w h ich a r e cor r ect op t ions.
P a r t i a l M a r ks : +1 I f t wo or more opt ions a re cor rect bu t O N L Y on e opt ion is chose n
a n d i t is a cor rect op t ion.
Z ero M a r ks : 0 I f non e of t h e op t ions is chose n (i.e. t h e q uest ion is u n a nsw e red).
N ega t i ve M a r ks : –1 I n a l l ot her cases.
F o r E x a m p l e : If first, t hird a n d fou r t h a re t he O N L Y t h r ee correct opt ions for a q uest ion w i t h
second opt ion bei ng a n i ncor rect opt ion; select ing on ly a ll t he t h ree cor rect opt ions w ill resu l t
i n + 4 m a r ks. Select i ng on ly t wo of t he t h ree cor rect opt ions (e.g. t he fi rst a nd fou r t h opt ions),
w i t hou t select i ng a n y i ncor rect opt ion (second opt ion i n t h is case), w ill resu l t i n +2 m a r ks.
Select i ng on ly one of t he t h ree cor rect opt ions (ei t her fi rst or t h ird or fou r t h opt ion), w i t hou t
selecting a ny incor rect op tion (second option in t h is case), w ill result in +1 m a r ks. Selecting
a n y i ncor rect opt ion(s) (second opt ion i n t h is case), w i t h or w i t hou t select ion of a n y cor rect
op t ion(s) w i l l resu l t in –1 m a r ks.
5. W h ich of t he follow i ng a tom/s h as low ion i z a t ion en ergy t h a n N i t rogen a tom.
(A) L i (B) F (C) O (D) N e
6. C hoose C O R R E C T st a t em e n ts.
(A) T he bond dissociat ion energy of C 2 decreases on form ing C 2 a nd increases on for ming C 2
( B) F or m a t ion of O 2 from O 2 elect ron is remov ed from ger ade bon ding molecu la r orbi t a l
(C) H O M O of F 2 is ge r a de w hi le L U M O of C l 2 is u nger a de
( D) I n H a loge n colou r in te nsi t y i ncre ases F 2 to I 2
7. W hich of t h e fol low i ng st a t e me n t(s) is/a re cor r ect a bou t coagu la t ion ?
(A) T a n ning of lea t h er is a n ex a m ple of m u t u a l coagu l a t ion.
( B) D el t a for m a t ion is a n exa m ple of coagul a t ion by elect roly t e.
( C ) C ot t rel l p recip i t a tor coag u l a t e by elect rop horesis.
( D) L yoph il ic colloi ds m a y be coagu la t ed by addi ng ot h er su it a ble sol ve n t .
Sp ace fo r R o u g h Wo r k
8. T he mol a r con d uct a nce of H + ion a n d C H 3 C O O – ion a t 2 98 K a n d a t i n fi n i te di l u t ion a r e
3.474 10 –2 oh m –1 m 2 mol –1 a nd 1.351 10 –2 oh m –1 m 2 mol –1 , respect ively. T he resist a nce of
0.1 M C H 3 C O O H solu tion is 2000 ohm a t 298 K in a conduct iv it y cell of cell const a n t 20m –1 .
T h e co r r ec t i n fo r m a t i o n (s) r e l a t e d w i t h t h e g i v e n p a r a m e t e r s a t 2 9 8 K i s/ a r e-
(1 F = 96500 C/mol)
0
(A) m ( C H 3 C O O H ) = 4.825 10 –2 oh m –1 m 2 mol –1
(B) = 1.0 10 –2 oh m –1 m –1

(C) m = 1.0 10 –4 oh m –1 m 2 mol –1

(D) [ H +] = 2.07 10 –3 M
9. W h ich of t h e fol low i ng w i l l gi v e a l k a ne a s p rod uct w i t h R M g C l?
O

(A) P h O M e (B) M e 3 N (C ) M e 3 C – C l (D)

O
1 0. N eopen t a ne ca n be p rep a red i n good y ield b y
(A) C a t a l y t ic red uct ion ( B ) Wolf- K isch n e r's r ed uct ion
(C) W u r t z react ion (D ) D eca rbox y l a t ion usi ng sod a l i m e
Sp ace fo r R o u g h Wo r k
 C H3

KO
Cl C H3

C H3 O3
1 1. (X) (A) + ( B)
Zn / H 2 O
M ajor
product
P roduct A a nd B a re sepr a t ed a n d t h a n h ea t ed w it h N a O H . A g a v e C w h ere as B g a v e
D and E
C or rect st a t e m e n t(s) is/a r e :
O

(A) P rod uct C is

O
(B) P rod uct D is H – C – O

(C) P rod uct E is C H 3 – O H

(D) M a jor p rod uct (X) is

1 2. C hoose C O R R E C T st a t em e n ts.
(A) T he da r k bl ue colou r of t he sol u t ion formed w hen excess of a m mon i a is added to a solu t ion
of coppe r(I I) su l ph a t e is du e t he form a t ion of di a m agn e t ic [ C u( N H 3) 4] 2 ion
(B) [C r( H 2 O) 6] 3 h a ve more pa r a m agn e tism t h a n [ N i(H 2 O) 6 ]2
(C) [ N i(C O)4] is tet r a hed ra l a nd pa r a m ag net ic com plex
(D ) [N i(D M G) 2 ] is low spi n sq u a r e pl a n a r comp lex

Sp ace fo r R o u g h Wo r k
 S E C T I O N -I I : ( M a x i m u m M a r k s: 18)
T h is sect ion con t a i ns S I X q u est ions.
T h e a nsw er to each q u est ion is a N U M E R I C A L V A L U E .
F or each qu est ion, en ter t he cor rect n u mer ica l v a l ue (i n deci m a l not a t ion, t r u nca t ed/rou nded-
off to t h e s e c o n d d e c i m a l p l a c e; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30, if a nswer is
11.36777..... t hen bot h 11.36 a n d 11.37 w ill be correct) by da r ken t he cor responding bubbles
in t he O R S.
F o r E x a m p l e : I f a nswer is –77.25, 5.2 t hen fi ll t he bubbles as follows.
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9

A nsw er to e ach q u est ion w i ll be ev a l u a t ed accord i ng to t h e fol low i ng m a r k i ng sch e m e:

F u l l M a rks : +3 I f O N L Y t h e cor rect n u me r ica l v a l ue is en tere d as a nsw er.
Z ero M a r ks : 0 I n a l l ot her ca ses.
1. T he nor m a l boiling poin t of p u re w a ter is 373.15 K . C a lcu la te t he boiling poin t (in K ) of a n
aqueous solu tion cont a in ing 11.7 gm N a C l a n d 34.2 gm suga r, C 12 H 22 O 11 , in 260 gm w a ter. F or
w a ter, K b = 0.52 K – K g/mol. [A tomic m ass of N a = 23, C l = 35.5]
2. T h e react ion : A(g) 2 B(g) + C ( l ) follows first or de r k i net ics. T he re action is st a r ted w i t h
A(g) on ly. C a lcu l a t e t he r a te const a n t of react ion ( i n m i n –1 ) from t he follow ing da t a :
(ln2 = 0.6931)

T i m e ( m i n .) 0 10
Tot al p r essu r e of
0.080 0.125 0.165
syst e m (bar)
3. O ne mole of non-idea l gas u ndergoes a process (10 L , 2 a t m, 300 K ) to (10 L , 5 a t m, 800 K ).
T h e mol a r en t h a lpy ch a nge of gas in t h is process (i n L -a t m/mole) is
(G iven : C v, m = 3.2R, C p, m = 4.1 R , R = 0.08 L-a t m/ K -mole).
Sp ace fo r R o u g h Wo r k
4. H ow m a n y of t h e follow i ng a r e mor e r e act i ve t h a n be n zen e for elect rop h ile su bst i t u t ion
re a ct ion?
(1) A n isole (2) Ace t a n i l ide (3) C a rbol ic acid (4) T N T
(5) M esi t y le n e (6) B en z a ldeh y de (7) A ce top h e non e (8) P h en y l ben zoa t e
(9) M et a-X y lene (10) E t h y l ben zoa t e
5. T ot a l n u m ber of plot(s) i n w h ich slope is not cor rect ly rep resen ted.

– 100

– 200 4Cu + O2 2Cu2O

G /kJ mol or O2

– 300
2C + O2 2CO
–1

– 400 2C O 2
+O2
2C O
– 500
nO
O 2Z C+
2Z n + 2 O
– 600 2
CO
2

– 700

– 800
A
– 900
O2 2/3Al2O 3
4/3Al +
– 1000
2MgO
– 1100 2 Mg + O 2

– 1200

0°C 400°C 800°C 1200°C 1600°C 2000°C

273K 673K 1073K 1473K 1873K 2273K
Temperature
6. Tot a l n u m ber of a nion w h ich give w hit e ppt . w it h a qu eous sol u t ion of A g N O 3 .
S 2– , H S O 3 , S O 32 , S 2 O 32 , C H 3 C O O , C l , I , B O 33
Sp ace fo r R o u g h Wo r k
 P A R T -3 : M A T H E M A T I C S
S E C T I O N -I ( i ) : ( M a x i m u m M a r k s : 12)
T h is sect ion con t a ins F O U R q u est ions.
E ach quest ion h as F O U R op tions (A), (B), (C) a n d (D). O N L Y O N E of t hese fou r opt ions
is cor rect.
F or e ach q u est ion , d a r k e n t h e b u bb le cor respon d i ng to t h e cor r ect op t ion i n t h e O R S.
F or e ach q u est ion , m a r k s w i l l be a w a r ded i n on e of t h e follow i ng ca t egories :
F u l l M a rks : +3 If on ly t h e bu bb le cor respon di ng to t h e cor rect opt ion is da r k en ed.
Z ero M a r ks : 0 I f non e of t h e b u bb les is d a r k e ned.
N ega t i ve M a r ks : –1 I n a l l ot h e r cases
1. T he su m of t he series sinx sec3x + sin3x sec3 2 x + sin3 2 x sec3 3 x +....upto n terms is

1 1
(A) cot 3 n x cot x (B) t a n 3n x t an x
2 2
(C) [t a n3 n x – t a n x] (D) cot3 n x – cot x
2. If a x + y – 16 = 0 a nd x + a y – 6 = 0 represent t wo a dj acent sides of a rhombus w hose diagona ls
in tersect a t (3,5) t hen su m of possible v a lue of a is
9
(A) 4 (B) 2 (C) –2 (D)
4
3. Locus of a v a r iable poin t P(x,y) is given by x 3 + y 3 + 3xy = 1 w here (x,y) (–1,–1). T he equa t ion
of circle touching t he locus of P a t (–1,2) a nd passing t h rough (1,–2) is given by
(A) x 2 + y 2 + 2x + y – 5 = 0 (B) x 2 + y 2 + 12x + 6y – 5 = 0
(C) x 2 + y 2 + 4x + 2y – 5 = 0 (D) x 2 + y 2 – 4x – 2y – 5 = 0

sin x 1
4. If ƒ : R R, ƒ x 2`
2x 1 x x 1(w here [x] denotes grea test i n tegr a l v a l ue
x 2x 3 4
less t h a n or equ a l to x) denotes a fu nct ion, t hen n u mber of rea l sol ut ions of equ a t ion
ƒ(x) = ƒ –1(x) is
(A) 0 (B) 1 (C) 2 (D) 3
Sp ace fo r R o u g h Wo r k
 S E C T I O N -I ( i i) : ( M a x i m u m M a r k s: 32)
T h is sect ion con t a i ns E I G H T q u est ions.
E ach question h as F O U R options for cor rect a nswe r(s). O N E O R M O R E T H A N O N E of
t h ese fou r opt ion(s) is (a r e) cor r ect op t ion(s).
F or e ach q u est ion , choose t h e cor r ect op t ion(s) to a nsw e r t h e q u est ion .
A nsw er to e ach q u est ion w i ll be ev a l u a t ed accord i ng to t h e fol low i ng m a r k i ng sch e m e:
F u l l M a rks : +4 I f on ly (a l l) t h e cor rect op t ion(s) is (a r e) chose n .
P a r t i a l M a r ks : +3 If a ll t he fou r opt ions a re correct bu t O N L Y t h ree opt ions a re chosen.
P a r t i a l M a r ks : +2 If t h ree or more opt ions a re correct bu t O N L Y t wo opt ions a re chosen,
bot h of w h ich a r e cor r ect op t ions.
P a r t i a l M a r ks : +1 I f t wo or more opt ions a re cor rect bu t O N L Y on e opt ion is chose n
a n d i t is a cor rect op t ion.
Z ero M a r ks : 0 I f non e of t h e op t ions is chose n (i.e. t h e q uest ion is u n a nsw e red).
N ega t i ve M a r ks : –1 I n a l l ot her cases.
F o r E x a m p l e : If first, t hird a n d fou r t h a re t he O N L Y t h r ee correct opt ions for a q uest ion w i t h
second opt ion bei ng a n i ncor rect opt ion; select ing on ly a ll t he t h ree cor rect opt ions w ill resu l t
i n + 4 m a r ks. Select i ng on ly t wo of t he t h ree cor rect opt ions (e.g. t he fi rst a nd fou r t h opt ions),
w i t hou t select i ng a n y i ncor rect opt ion (second opt ion i n t h is case), w ill resu l t i n +2 m a r ks.
Select i ng on ly one of t he t h ree cor rect opt ions (ei t her fi rst or t h ird or fou r t h opt ion), w i t hou t
selecting a ny incor rect op tion (second option in t h is case), w ill result in +1 m a r ks. Selecting
a n y i ncor rect opt ion(s) (second opt ion i n t h is case), w i t h or w i t hou t select ion of a n y cor rect
op t ion(s) w i l l resu l t in –1 m a r ks.
5. L et ƒ be a t w ice different iable fu nct ion defined in [–4,4] such t ha t ƒ'(–4) = 10, ƒ'(4) = –14 a n d
x

ƒ "(x) > – 3 x [–4,4]. If g x ƒ t dt a nd ƒ(0) = 0, t hen

0
(A) g(x) increases in (–4,0)
(B) g(x) decreases in (0,4)
(C) gr aph of g(x) is concave dow n in (0,4)
(D) ƒ(x) has m a xi m um v a l ue a t x = 2
Sp ace fo r R o u g h Wo r k
 x4 1
6. W h ich of t he follow i ng ca n be a n t ideriv a t ive of ƒ x ? (W here 'C' is t he const an t of
x6 1
i n tegr a t ion)
1 1 1 2 1
(A) t a n
1
x ta n 1
x3 C (B) t a n x tan x3 C
3 x 3

1 2 1 1 1
(C) t an 1
x ta n 1
x3 C (D) tan x t an x3 C
3 3 x
1 it
7. L et z c w here c is a complex n u mber, a nd t a re rea l pa r a meters t hen
1 it
(A) if z = c a nd = 0 t hen t is u ndefined
(B) if z – c t hen = z – c a nd t = 0
Im z c
(C) if z c t hen = ± | z – c | a nd t
z c Re z c
Im z c
(D) I f z c t hen = ± | z – c | a nd t
z c Re z c
Sp ace fo r R o u g h Wo r k
8. L et | r | < 1 a nd S n k n r k , t hen w h ich of t he follow i ng opt ions is/a re correct ?
k 1

1 2 d
(A) S 0 (B) rS1 S0 (C) S n 1 r S (D) rS 2 S 02 2S 03
1 r dr n
9. I n a ga me show a con test a n t selects one of t h ree doors. B eh ind one of t he doors t here is a
prize a nd beh i nd ot her t wo t here is no prize. E ach door h as equ a l proba bili t y of h a vi ng a
prize. A fter con test a n t selects a door, t he ga me show host w ho k nows w h a t's beh i nd each of
t he doors, deliber a tely opens one of t he rem a i n ing doors a nd revea ls t here is no pr ize beh i nd
i t. T he host t hen asks t he con test a n t w het her he w a n t to S W I T C H h is choice to ot her u nopened
door or S T I C K to h is or igi n a l choice. W h ich of t he follow i ng opt ions is/a re cor rect ?

(A) P roba bilit y of w in n i ng t he pr ize is sa me w het her con test a n t S T I C K or S W I T C H

1
(B) P roba bilit y of w in n i ng t he prize w hen con test a n t S T I C K , is
3

2
(C) P roba bility of w in ning t he prize w hen con test a n t S W I T C H , is
3
(D) I t is adv a n t ageous for con test a n t to S W I T C H t h a n to S T I C K
Sp ace fo r R o u g h Wo r k
1 0. Consider a system of li nea r equ a t ions in t h ree v a r i ables

–x + y + z = a
x–y+z=b

x+y–z=c

then
a b b c a c
(A) x y c (B) y z a (C) x z b (D) x + y + z = a + b + c
2 2 2
1 1. T wo t a ngen ts a re dr a w n from poin t P( ) to t he h yperbola. 3x 2 – 2y 2 = 6 a nd a re i nclined a t
a ngles A a nd B to posit ive direct ion of x-a x is. L et t a n A .t a n B = k, t hen
2 2 2 2
(A) if k = 2 t hen =2 +7 (B) if k = 2 t hen =2 –7
2 2 2 2
(C) if k = 3 t hen =3 –9 (D) if k = 3 t hen =3 +9
1 2. If 2 n–1 T n = 2n C
0
+ 3(2n C 2) + 3 2 (2n C 4) + ....+3 n(2n C 2n), n N , t hen

(A) T n , T n +1 , T n +2 a re in A P (B) T n , 2 T n +1 , T n +2 a re in A P

(C) T 4 = 192 (D) T 4 = 194

Sp ace fo r R o u g h Wo r k
 S E C T I O N -I I : ( M a x i m u m M a r k s: 18)
T h is sect ion con t a i ns S I X q u est ions.
T h e a nsw er to each q u est ion is a N U M E R I C A L V A L U E .
F or each qu est ion, en ter t he cor rect n u mer ica l v a l ue (i n deci m a l not a t ion, t r u nca t ed/rou nded-
off to t h e s e c o n d d e c i m a l p l a c e; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30, if a nswer is
11.36777..... t hen bot h 11.36 a n d 11.37 w ill be correct) by da r ken t he cor responding bubbles
in t he O R S.
F o r E x a m p l e : I f a nswer is –77.25, 5.2 t hen fi ll t he bubbles as follows.
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9

A nsw er to e ach q u est ion w i ll be ev a l u a t ed accord i ng to t h e fol low i ng m a r k i ng sch e m e:

F u l l M a rks : +3 I f O N L Y t h e cor rect n u me r ica l v a l ue is en tere d as a nsw er.
Z ero M a r ks : 0 I n a l l ot her ca ses.
tan x
tan x x tan x
1. E v a l u a t e li m (consider e = 2.7)
x 0 x

1 1 1 1
2. If ƒ x for x , x [0,1], n N a nd ƒ(0) = 0. F ind t he v a lue of ƒ x dx
2n 1
2n 2n 1
0

3. If a cu rve represen ted by differen t i a l equ a t ion (t a n –1 y – x)dy = (1 + y 2)dx, passes t h rough (0, t a n1)

a nd 1, b , t hen v a lue of b is
3
Sp ace fo r R o u g h Wo r k
4. If a a nd b a re perpendicula r vectors wit h a 2, b 3 a nd c a b , t hen t he least v a lue

of c a
5. If x + 13y + m z + n = 0 is a pl a ne t h rough i n tersect ion of pl a nes 2x + 3y – z + 1 = 0 a nd
n
x + y – 2z + 3 = 0 a nd is perpendicula r to pla ne 3x – y – 2z = 4, t hen equa ls
m
6. D efi ne per m u t a t ion of set {1,2,3,.....,n} to be sort able if upon ca ncelling one appropr ia te ter m
of such per m u t a t ion rem a i n i ng n – 1 ter ms a re i n i ncreasi ng order. If ƒ(n) is t he n u mber of
ƒ 5
such sort a ble per m u t a t ions t h en equ a ls
ƒ 4
Sp ace fo r R o u g h Wo r k