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SAFETY DATA SHEET

(according to Regulation (EC) No 1907/2006 (REACH), ANNEX II)

UAN + S
Revision date: 01.10.2024 Version 4.4

SECTION 1: IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY

1.1 Product identifier
Trade name: Liquid Nitrogen Fertilizer (UAN + S)
Other names: Urea-Ammonium Nitrate Solution with Ammonium Sulphate
INDEX No. as listed in Annex VI of CLP: Not listed
Not available as the product is a mixture.
Relevant registration number of the components:
REACH registration No.: Ammonium Nitrate - 01-2119490981-27-0042
Urea - 01-2119463277-33-0048
Ammonium Sulphate - 01-2119455044-46-0050
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Fertilizers
Uses advised against: None
1.3 Details of the supplier of the safety data sheet
Zangas Hoch-und Tiefbau GmbH
Schwindgasse 5/1/4
1040 Vienna Austria
Phone: +43 1 274 16 366
Only Representative:
www.zangasgroup.com
E-mail: info@zangasgroup.com

PrJSC “AZOT”
72, Heroiv Kholodnoho Yaru Str., Cherkassy, Ukraine
Phone: +38 0472 39-63-03
+38 0472 39-23-33
Manufacturer:
URL website: http://www.azot.ck.ua
Email: let@azot.ck.ua
sale@azot.ck.ua

PrJSC “AZOT”
E-mail address of the person responsible
REACH Department
for this Safety Data Sheet:
onr@azot.ck.ua
National contact: Not available
1.4 Emergency telephone number
Phone: +43 1 274 16 366
Opening hours: 9-18 (CET)
Languages of the phone service: German, English
Emergency phone number:
Phone: + 38 (0472) 39 61 17
Opening hours: 0-24
Languages of the phone service: Ukrainian
SECTION 2: HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Product definition: Mixture
The mixture is not classified as hazardous in accordance with Regulation 1272/2008 (CLP).
2.2 Label elements
Hazard pictograms: Not applicable
Signal word: No signal word
Hazard statements: Not applicable
Precautionary statements
Prevention: Not applicable
Response: Not applicable
Storage: Not applicable
Disposal: Not applicable
2.3 Other hazards:
Mixture meets the criteria for PBT
No.
according to Regulation (EC)
P: Not available. B: Not available. T: No.
No.1207/2006, Annex XIII
Mixture meets the criteria for vPvB
Not available
according to Regulation (EC)
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SAFETY DATA SHEET

(according to Regulation (EC) No 1907/2006 (REACH), ANNEX II)

UAN + S
Revision date: 01.10.2024 Version 4.4

No.1207/2006, Annex XIII

Other hazards which do not result in
Not available
classification
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2 Mixtures
Description of the mixture: Mixture of urea, ammonium nitrate and ammonium sulphate
REACH Classification
Components CAS No. Concentration
Registration No. Regulation (EC) No.1272/2008 [CLP]
01-2119463277-33-
Urea 57-13-6 27.0-30.0 % Not classified
0048
01-2119490981-27- H272
Ammonium nitrate 6484-52-2 35.0-37.0 %
0042 H319
01-2119455044-46-
Ammonium sulphate 7783-20-2 8.2-8.6 % Not classified
0050
Note: The product is treated with corrosion inhibitor.
See Section 16 for the full text of the H-statements and R-phrases declared above.
SECTION 4: FIRST-AID MEASURES
4.1 Description of first aid measures
Appropriate first-aid equipment should be provided. No action shall be taken involving
General notes:
any personal risk or without suitable training.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
Following eye contact: eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
Following skin contact:
shoes. Get medical attention if symptoms occur.
Wash out mouth with water. Remove victim to fresh air and keep at rest in a position
Following ingestion: comfortable for breathing. Do not induce vomiting unless directed to do so by medical
personnel. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if symptoms occur. In case of inhalation of decomposition products in
Following inhalation:
a fire, symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Self-protection for the first-aider: None
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact: No known significant effects or critical hazards
Exposure to decomposition products may cause a health hazard. Serious effects may
Inhalation:
be delayed following exposure.
Skin contact: No known significant effects or critical hazards
Ingestion: Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact: No specific data.
Inhalation: No specific data.
Skin contact: No specific data.
Ingestion: No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments: No specific treatment
SECTION 5: FIRE-FIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media: Use extinguishing media suitable for surrounding materials.
Not suitable extinguishing media: None
5.2 Special hazards arising from the substance or mixture
Hazards from the
None.
substance or mixture:
Hazardous combustion Decomposition products may include the following materials:
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SAFETY DATA SHEET

(according to Regulation (EC) No 1907/2006 (REACH), ANNEX II)

UAN + S
Revision date: 01.10.2024 Version 4.4

products: carbon dioxide, carbon monoxide, nitrogen oxides, ammonia, amines

5.3 Advice for firefighters
Special precautions for fire-fighters: No special measures required
Fire-fighters should wear appropriate protective equipment and self-contained breathing
Special protective equipment apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for
for fire-fighters: firefighters (including helmets, protective boots and gloves) conforming to European
standard EN 469 will provide a basic level of protection for chemical incidents.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1 For non-emergency personnel
Protective equipment: Put on appropriate personal protective equipment if necessary.
Emergency procedures: Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material.
Avoid breathing vapour or mist. Provide adequate ventilation.
6.1.2 For emergency responders:
If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non-emergency personnel".
6.2 Environmental precautions
Avoid dispersal of spilt material and runoff and contact with waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways or air).
6.3 Methods and material for containment and cleaning up
6.3.1 For containment: Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses,
basements or confined areas.
6.3.2 For cleaning up: Contain and collect spillage with non-combustible, absorbent material, e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations.
6.3.3 Other information
Dispose of via a licensed waste disposal contractor.
6.4 Reference to other sections
See section 8 for personal protective equipment and section 13 for waste disposal.
SECTION 7: HANDLING AND STORAGE
7.1 Precautions for safe handling
Protective measures: Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin
and clothing. Avoid breathing vapour or mist. Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use.
Measures to prevent fire: Keep away from heat. Keep away from sources of ignition.
Measures to prevent aerosol and dust generation: Store in a well ventilated area.
Measures to protect the environment: Empty containers retain product residue and can be hazardous.
Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled,
stored and processed. Remove contaminated clothing and protective equipment before entering eating areas. Wash hands,
forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the
working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing
before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Do not store in unlabelled containers. Use
appropriate containment to avoid environmental contamination.
Technical measures/Storage conditions:
Suitable packing material: stainless steel, synthetic material.
Not suitable packing material: zinc and copper.
Packing materials: Use dedicated containers
Requirements for storage rooms and
vessels:
Storage class: 12
Further information on storage conditions: None
Incompatible products: Strong acids, strong bases, organic materials, chromates, zinc, copper and nickel.
7.3 Specific end use(s): None
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SAFETY DATA SHEET

(according to Regulation (EC) No 1907/2006 (REACH), ANNEX II)

UAN + S
Revision date: 01.10.2024 Version 4.4

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters
8.1.1 National occupational exposure limit values (urea, ammonium nitrate): Not available
8.1.2 National biological limit values (urea, ammonium nitrate): Not available
8.1.3 PNEC (Predicted No Effect Concentration):
PNEC
Environmental protection target
Urea Ammonium nitrate Ammonium sulphate
Aqua – freshwater 0.047 mg/L 0.45 mg/L 0.312 mg/L
Aqua – salt/marine water 0.047 mg/L 0.045 mg/L 0.0312 mg/L
Aqua – intermittent releases No exposure expected 4.5 mg/L 0.53 mg/L
Sediment No exposure expected No hazard identified 0.063 mg/kg sediment dw
Soil No exposure expected No hazard identified 62.6 mg/kg soil dw
Sewage treatment plant No exposure expected 18 mg/L 16.18 mg/L
Food chain: oral (secondary poisoning) No exposure expected No exposure expected No exposure expected
Air: No exposure expected No hazard identified Not relevant
8.1.4 DNEL
ACUTE
Derived No Effect Level (DNEL)
Route
Workers General population
Oral Not applicable 42 mg/kg bw/day
Dermal 580 mg/kg bw/day 580 mg/kg bw/day
3 3
Inhalation 292 mg/m 125 mg/m
LONG TERM
Derived No Effect Level (DNEL)
Route
UREA Workers General population
Oral Not applicable 42 mg/kg bw/day
Dermal 580 mg/kg bw/day 580 mg/kg bw/day
3 3
Inhalation 292 mg/m 125 mg/m

No evidence of local effects is seen in any of the dermal studies performed with urea;
there is no evidence of local effects from human studies or from experience of human
exposure. Respiratory irritation is not predicted. DNELs for local effects are therefore
not relevant and are not calculated for urea.

Derived No Effect Level (DNEL)

Route
Workers General population
1
Oral Not applicable 12.8 mg/kg bw/d
1
Dermal 21.3 mg/kg bw/day 12.8 mg/kg bw/day
1 3 3
Inhalation 37.6 mg/m 11.1 mg/m
AMMONIUM NITRATE 1
: As an acute toxicity hazard leading to Classification and Labeling of the substance
has not been identified, the long-term DNEL is considered sufficient to ensure that
effects from acute exposure to the substance do not occur (in accordance with ECHA
Guidance on information requirements and chemical safety assessment: Chapter R.8:
Characterisation of dose [concentration]-response for human health, May 2008 and Part
B: Hazard Assessment, Draft new chapter B.8 Scope of Exposure Assessment, March
2010).
ACUTE
Derived No Effect Level (DNEL)
Route
Workers General population
Oral Not applicable Not applicable
Dermal Not applicable Not applicable
Inhalation Not applicable Not applicable
AMMONIUM SULPHATE
LONG TERM (Systemic effects)
Derived No Effect Level (DNEL)
Route
Workers General population
Oral Not applicable 6.4 mg/kg bw/day
42.667 mg/kg
Dermal 12.8 mg/kg bw/day
bw/day
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SAFETY DATA SHEET

(according to Regulation (EC) No 1907/2006 (REACH), ANNEX II)

UAN + S
Revision date: 01.10.2024 Version 4.4

3 3
Inhalation 11.167 mg/m 1.667 mg/m
Acute/short-term DNELs were not calculated as they are covered by calculation of long-
term DNELs. No local dermal or irritating effects were observed in repeated dose
studies
8.1.5 Monitoring procedures: Not available
8.2 Exposure controls
8.2.1 Appropriate engineering controls:
Substance/mixture related measures to prevent exposure during identified uses: The usual precautions for the handling of chemicals
must be observed. Before direct contact with the substance use personal protection equipment.
Technical measures to prevent exposure: No special ventilation requirements. Good general ventilation should be sufficient to
control worker exposure to airborne contaminants.
8.2.2 Personal protection equipment:
No special protection is required. In case of insufficient ventilation, wear suitable
8.2.2.1 Respiratory protection:
respiratory equipment.
8.2.2.2 Skin protection:
Hand protection: Gloves: leather, butyl rubber and neoprene.
Other skin protection: Working clothes
8.2.2.3 Eye and face protection: Safety glasses with side shields.
8.2.2.4 Thermal hazards: None
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
8.2.3 Environmental exposure controls:
cases, fume scrubbers, filters or engineering modifications to the process equipment will
be necessary to reduce emissions to acceptable levels.
Advice on personal protection is applicable for high exposure levels.
Select proper personal protection based on a risk assessment of the actual exposure situation
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance: Colourless liquid
Odour: Odourless or mild ammonia odour
Odour threshold: Not available
pH: 7.0-8.5
Melting point/Freezing point: - 18-20°C
Initial boiling point and boiling range: >100°C
Flash-point: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Auto-ignition temperature: Not applicable.
Upper/lower flammability or explosive
Not applicable
limits:
Vapour density: Not available.
Oxidising properties: Non-classified as oxidizing substance in compliance with Directive 1999/45 EC.
Vapour pressure: Not available.
Relative density: Not available.
Solubility in water: The preparation is water solution, so it may be diluted with water without any limits.
Partition coefficient n-octanol/water: Not available.
Viscosity: Not available.
Explosive properties: None
Decomposition temperature: Not available
9.2 Other information
SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity
No specific test data related to reactivity available for this product.
10.2 Chemical stability
The product is stable.
10.3 Possibility of hazardous reactions
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SAFETY DATA SHEET

(according to Regulation (EC) No 1907/2006 (REACH), ANNEX II)

UAN + S
Revision date: 01.10.2024 Version 4.4

No hazardous reaction when handled and stored according to these provisions (see section 7, handling and storage).
10.4 Conditions to avoid
Possible dangerous reactions with other chemicals are unknown; do not mix with other substances. After defreezing, the properties
are not changed.
10.5 Incompatible materials
Reducing agents, strong acids and bases, metal powders, combustible materials, chromates, zinc, copper and copper alloys,
chlorates
10.6 Hazardous decomposition products
Carbon monoxide, ammonia (NH 3 ), nitrogen oxides (NO, NO 2 etc.)
SECTION 11: TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
LD50(rats) > 2950mg NH 4 NO 3 / kg;
Oral:
LD50(rats) > 14300mg CO(NH 2 ) 2 / kg
11.1.1 Acute toxicity Dermal: Not available
Inhalation: Not available
Oral: Not available
11.1.2 Repeated dose toxicity Dermal: Not available
Inhalation: Not available
11.1.3 Irritation: Not available
11.1.4 Corrosivity: Not available
11.1.5 Sensitization: Not available
11.1.6 Toxicity for reproduction: Not available
11.1.7 Mutagenicity : No known significant effects or critical hazards
11.1.8 Carcinogenicity: Not available
SECTION 12: ECOLOGICAL INFORMATION
12.1 Toxicity
Fish (freshwater, short-term): Not available
Fish (long-term): Not available
Freshwater invertebrates (short-term): Not available
Freshwater invertebrates (long-term): Not available
Freshwater algae: Not available
Terrestrial plants: Not available
Soil macro-organisms: Not available
Birds: Not available
Mammals: Not available
12.2 Persistence and degradability
Abiotic degradation:
Phototransformation/photolysis Not available
Biodegradation: Not available
Hydrolysis: Not available
12.3 Bioaccumulative potential
Not available.
12.4 Mobility in soil
Known or predicted distribution to Not available
environmental compartments:
Surface tension: Not available
Adsorption coefficient: Not available
12.5 Results of PBT and vPvB assessment
Not applicable.
12.6 Other adverse effects :No known significant effects or critical hazards.
Remarks: No ecological problems are to be expected when the product is handled and used with due care and attention.
12.7 Additional information: None
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SAFETY DATA SHEET

(according to Regulation (EC) No 1907/2006 (REACH), ANNEX II)

UAN + S
Revision date: 01.10.2024 Version 4.4

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Empty containers or liners may retain some product residues. This material and its container must
be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
13.1.1 Product / Packaging disposal: waste disposal contractor. Disposal of this product, solutions and any by-products should at all
times comply with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements.
Waste codes / waste designations
according to LoW (Commission Decision 06 10 99 Wastes not otherwise specified
2001/118/EC):
13.1.2 Waste treatment-relevant
The generation of waste should be avoided or minimised wherever possible.
information:
13.1.3 Sewage disposal-relevant
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
information:
Within the present knowledge of the supplier, this product is not regarded as hazardous
13.1.4 Other disposal recommendations:
waste, as defined by EU Directive 91/689/EEC.
SECTION 14: TRANSPORT INFORMATION
The product is not classified as dangerous when carried by road (ADR), train (RID) or maritime (IMDG)
ADR/RID ADN/ADNR IMDG IATA
14.1 UN number Not regulated Not regulated Not regulated Not regulated
14.2 UN proper shipping name – – – –
14.3 Transport hazard class(es) – – – –
14.4 Packing group – – – –
14.5 Environmental hazards No No No No
14.6 Special precautions for user Not available Not available Not available Not available
Additional information – – – –
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not available
SECTION 15: REGULATORY INFORMATION
15.1 Safety, health and environmental regulation/legislation specific for the substance or mixture
EU Regulations
Authorisations and\or restrictions on
use:
Authorisation:
EU Regulation (EC) No. 1907/2006
(REACH)
Annex XIV - List of substances subject to
authorisation None of the components are listed
Substances of very high concern
Restrictions on use:
Annex XVII - Restrictions on the
manufacture, placing on the market and
use of certain dangerous substances, Not applicable
mixtures and articles
National regulations (country): Not available
15.2 Chemical safety assessment: Not applicable
SECTION 16: OTHER INFORMATION
The information provided in this safety data sheet is correct to the best of our knowledge, information, and belief at the date of its
publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal,
and release and is not to be considered a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or in any proceed, unless specified
in the text.
v. 3.0: Changes were made to comply with the Guidance on the compilation of safety
data sheets (version 1.1)
16.1 Indication of changes:
v. 3.1: Changes were made to comply with Article 61 (CLP)
v. 4.0: Change of contact details
v. 3.0: Page header; 1.1; 1.3; 1.4; 3.2; 4.1; 5.1; 6.1; 6.3; 7.1; 7.2; 7.3; 8.1; 8.2; 9.1; 9.2; 11.1; 12.2; 12.4; 12.7; 13.1; 15.1
v. 3.1: Page header; 2.1; 16.2
v. 4.0: Page header; 1.3
v. 4.1: Page header; 1.3
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SAFETY DATA SHEET

(according to Regulation (EC) No 1907/2006 (REACH), ANNEX II)

UAN + S
Revision date: 01.10.2024 Version 4.4

v. 4.2: Page header; 1.3

v. 4.3: Page header; 1.3, 1.4
v. 4.4: Page header; 1.4
16.2 Abbreviations and acronyms:
• ADN - European Agreement concerning the International Carriage of Dangerous Goods on Inland Waterway
• ADNR - ADN Rhine
• ADR - Agreement on Dangerous Goods by Road
• CAS - Chemical Abstracts Service
• CLP - Classification, Labelling and Packaging of chemicals
• EC - European Commission
• IATA - International Air Transport Association
• IBC Code - International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk
• IMDG - International Maritime Dangerous Goods
• LD50 - Lethal Dose
• LoW - List of Wastes
• MARPOL - International Convention for the Prevention of Pollution From Ships
• PBT - Persistent, bioaccumulative, toxic chemical
• PJSC - Public Joint-Stock Company
• REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals
• RID - International Rule for Transport of Dangerous Substances by Railway
• UN - United Nations
• vPvB - very persistent, very bioaccumulative
16.3 Key literature references and sources for data: CSR (Chemical Safety Report), Guidance on safe use etc.
16.4 Training advice: In accordance with the local regulations
16.5 Further information: None
16.6 Full text of classifications May intensify fire; oxidiser. (H272)
[CLP/GHS]: Causes serious eye irritation (H319)