Sulfan 26N 35SO3 8.0 20241227
Sulfan 26N 35SO3 8.0 20241227
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Industrial distribution.
Industrial USE to formulate chemical product mixtures.
Professional formulation of fertiliser products.
Professional USE as fertiliser at Farm - loading and spreading.
Professional USE as fertiliser in Greenhouse.
Professional USE as liquid fertiliser in open field.
Professional USE as fertiliser - maintenance of equipment.
Yara UK Limited
Address
Street : Pocklington Industrial Estate
Pocklington
Postal code : YO42 1DN
City : York
Country : United Kingdom
Telephone number : +44 1759 302545
Fax no. : +44 1759 303650
e-mail address of person : yarauk.hesq@yara.com
responsible for this SDS
Supplier
Emergency telephone number : National Chemical Emergency Centre
(with hours of operation) +44 (0) 1865 407333 (24h)
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
Hazard pictograms :
Precautionary statements
Product meets the : This mixture does not contain any substances that are assessed to be a
criteria for PBT or vPvB PBT or a vPvB.
according to
Regulation (EC) No.
1907/2006, Annex XIII
ammonium nitrate REACH #: 01- >= 35 - <= 45 Ox. Sol. 3, H272 [1]
2119490981-27 Eye Irrit. 2, H319
EC : 229-347-8
CAS : 6484-52-2
amines, C16-18-alkyl REACH #: 01- >= 0.01 - < Skin Irrit. 2, H315 [1]
2119473799-15 Eye Dam. 1, H318
0.025
EC : 292-550-5 STOT RE 2, H373 (gastrointestinal
CAS : 90640-32- tract, immune system, liver) (oral)
7 Asp. Tox. 1, H304
Index : 612-285- Aquatic Acute 1, H400 (M=10)
00-4 Aquatic Chronic 1, H410 (M=10)
See Section 16 for the full text of the H statements declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in
the concentrations applicable, are classified as hazardous to health or the environment, are PBTs,
vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and
hence require reporting in this section.
Type
[1] Substance classified with a physical, health or environmental hazard
Occupational exposure limits, if available, are listed in Section 8.
Eye contact : Rinse with plenty of running water. Check for and remove any
contact lenses. If irritation persists, get medical attention.
Skin contact : Wash with soap and water. Get medical attention if irritation
develops.
Ingestion : Wash out mouth with water. If material has been swallowed and
the exposed person is conscious, give small quantities of water
to drink. Do not induce vomiting unless directed to do so by
medical personnel.
Protection of first-aiders : No action shall be taken involving any personal risk or without
suitable training.
4.2 Most important symptoms and effects, both acute and delayed
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following: pain or irritation,
watering, redness
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Special protective actions for : Promptly isolate the scene by removing all persons from the
fire-fighters vicinity of the incident if there is a fire. No action shall be taken
involving any personal risk or without suitable training.
For non-emergency personnel : No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep
unnecessary and unprotected personnel from entering. Do not
touch or walk through spilled material. Provide adequate
ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment
(see Section 8).
For emergency responders : If specialized clothing is required to deal with the spillage, take
note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non-emergency
personnel".
6.2 Environmental precautions : Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers. Inform the relevant
authorities if the product has caused environmental pollution
(sewers, waterways, soil or air).
Small spill : Move containers from spill area. Avoid dust generation. Using
a vacuum with HEPA filter will reduce dust dispersal. Place
spilled material in a designated, labeled waste container.
Dispose of via a licensed waste disposal contractor.
Large spill : Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements
or confined areas. Avoid dust generation. Do not dry sweep.
Vacuum dust with equipment fitted with a HEPA filter and
place in a closed, labeled waste container. Dispose of via a
licensed waste disposal contractor. Note: see Section 1 for
emergency contact information and Section 13 for waste
disposal.
Section 8). Do not ingest. Avoid contact with eyes, skin and
clothing. Keep in the original container or an approved
alternative made from a compatible material, kept tightly
closed when not in use. Empty containers retain product
residue and can be hazardous. Do not reuse container.
DNELs/DMELs
Product/ingredient Type Exposure Value Population Effects
name
ammonium nitrate DNEL Long term 5.12 mg/kg Workers Systemic
Dermal bw/day
DNEL Long term 36 mg/m³ Workers Systemic
Inhalation
amines, C16-18- DNEL Long term 0.38 mg/m³ Workers Systemic
alkyl Inhalation
PNECs
Product/ingredient Type Compartment Detail Value Method Detail
name
ammonium nitrate PNEC Sewage Treatment 18 mg/l Assessment
Plant Factors
amines, C16-18-alkyl PNEC Fresh water 0.26 µg/l Assessment
Factors
PNEC Marine water 0.026 µg/l Assessment
Factors
PNEC Sewage Treatment 550 µg/l Assessment
Plant Factors
PNEC Fresh water sediment 3.76 mg/kg Assessment
dwt Factors
PNEC Marine water sediment 0.376 mg/kg Assessment
dwt Factors
PNEC Soil 10 mg/kg dwt Assessment
Factors
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when
handling chemical products if a risk assessment indicates
this is necessary. For general applications, we
recommend gloves with a thickness typically greater than
0.35 mm. It should be emphasized that glove thickness is
not necessarily a good predictor of glove resistance to a
specific chemical, as the permeation efficiency of the
glove will be dependent on the exact composition of the
glove material.
Other skin protection : Appropriate footwear and any additional skin protection
measures should be selected based on the task being
performed and the risks involved and should be approved
Date of issue : 29.03.2023 Page:7/18
Sulfan 26N 35SO3
Appearance
Physical state : Solid (granulates)
Color : Brown.,
Odor : Odorless.
Melting point/freezing point : Decomposes.
Initial boiling point and boiling : Not applicable.
range
Flammability : Non-flammable.
Upper/lower flammability or : Lower: Not applicable.
explosive limits Upper: Not applicable.
Flash point : Not applicable.
Auto-ignition temperature : Not applicable.
Decomposition temperature : > 255 °C
pH : 4.5 - 7 [Conc. (% w/w): 100 g/l ]
Particle characteristics
10.3 Possibility of hazardous : Under normal conditions of storage and use, hazardous
reactions reactions will not occur.
10.4 Conditions to avoid : Avoid contamination by any source including metals, dust
and organic materials.
Acute toxicity
Product/ingredient Method Species Result Exposure
name
ammonium nitrate
OECD 401 Rat 2,950 mg/kg Not applicable.
LD50 Oral
OECD 402 Rat > 5,000 mg/kg Not applicable.
LD50 Dermal
amines, C16-18-alkyl
OECD 401 Rat > 5,000 mg/kg Not applicable.
LD50 Oral
OECD 402 Rat > 5,000 mg/kg Not applicable.
LD50 Dermal
Conclusion/Summary : No known significant effects or critical hazards.
Irritation/Corrosion
Product/ingredient Method Species Result Exposure
name
ammonium nitrate
OECD 405 Rabbit Irritant
Eyes
Conclusion/Summary
Skin : No known significant effects or critical hazards.
Eyes : Causes serious eye irritation.
Respiratory : No known significant effects or critical hazards.
Sensitization
Product/ingredient name Method Species Result
ammonium nitrate
OECD 429 Mouse Not sensitizing
Skin
amines, C16-18-alkyl
OECD 406 Guinea pig Not sensitizing
Skin
Remarks: Non-sensitizer.
Conclusion/Summary
Skin : No known significant effects or critical hazards.
Respiratory : No known significant effects or critical hazards.
Mutagenicity
Product/ingredient name Method Test detail Result
ammonium nitrate
OECD 473 Mammalian Toxicity - Negative
Genotoxicity - In vitro
Mammalian
Chromosome
Aberration Test or
Mammalian Bone
Marrow Chromosomal
Abberation Test or
Mammalian
Erythrocyte
Micronucleus Test
In vitro
OECD 471 Bacteria Negative
In vitro
Conclusion/Summary : No known significant effects or critical hazards.
Carcinogenicity
Reproductive toxicity
Aspiration hazard
Product/ingredient name Result
amines, C16-18-alkyl ASPIRATION HAZARD - Category 1
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No known significant effects or critical hazards.
Waste catalogue
Packaging
Methods of disposal : The generation of waste should be avoided or minimized
wherever possible. Waste packaging should be recycled.
Incineration or landfill should only be considered when
recycling is not feasible. Empty the bag by shaking to
remove as much as possible of its contents. Empty bags
may be disposed of as non-hazardous material or
returned for recycling.
14.1 UN number Not regulated. Not regulated. Not regulated. Not regulated.
14.2 UN proper Not applicable. Not applicable. Not applicable. Not applicable.
shipping name
14.3 Transport Not applicable. Not applicable. Not applicable. Not applicable.
hazard
Date of issue : 29.03.2023 Page:13/18
Sulfan 26N 35SO3
class(es)
14.4 Packing Not applicable. Not applicable. Not applicable. Not applicable.
group
14.5. No. No. No. No.
Environmental
hazards
14.6 Special precautions for : Transport within user’s premises: Ensure that persons
user transporting the product know what to do in the event of
an accident or spillage.
UK (GB) /REACH
Annex XIV - List of substances subject to authorization
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Ozone depleting substances
None of the components are listed.
Seveso Directive
This product is not controlled under the Seveso Directive.
National regulations
EU regulations
Classification Justification
Eye Irrit. 2, H319 Calculation method
Revision comments : The safety data sheet has been revised according to UK
REACH Regulation SI 2019/758.
Notice to reader
To the best of our knowledge, the information provided in this Safety Data Sheet is
accurate as at the date of its issue. The information it contains is being given for safety
guidance purposes and relates only to the specific material and uses described in it. This
information does not necessarily apply to that material when combined with other
material(s) or when used otherwise than as described herein, since all materials may
represent unknown hazards and should be used with caution. Final determination of the
suitability of any material is the sole responsibility of the user.
Exposure Scenario/Safe : Exposure Scenarios are not attached for corrosive or irritant
Use Information hazards, relevant information on safe use is included in section 8.