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Ammonium Nitrate Solution 50% 4.0 20250113

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0% found this document useful (0 votes)
29 views17 pages

Ammonium Nitrate Solution 50% 4.0 20250113

fds
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 17

Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by Commission


Regulation (EU) 2020/878 - Spain
Date of issue/ Date of revision : 20.01.2023
Date of previous issue : 04.02.2021
Version : 4.0

SAFETY DATA SHEET

AMMONIUM NITRATE SOLUTION 50%

SECTION 1: Identification of the substance/mixture and of


the company/undertaking
1.1 Product identifier

Product name : AMMONIUM NITRATE SOLUTION 50%


Product code : PA06GL
Product type : Liquid

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses
Industrial distribution.
Industrial USE to formulate chemical product mixtures.
Industrial USE to formulate fertilisers product mixtures.
Professional formulation of fertiliser products.
Professional USE as fertiliser at Farm - loading and spreading.
Professional USE as fertiliser in Greenhouse.
Professional USE as liquid fertiliser in open field.
Professional USE as fertiliser - maintenance of equipment.

Uses advised against : Other non-specified industry


Reason : Due to lack of related experience or data, the supplier
cannot approve this use.

1.3 Details of the supplier of the safety data sheet

Yara Iberian S.A.


Address
Street : Infanta de las Mercedes st.
2nd floor
Number : 31
Postal code : 28020
City : Madrid
Country : Spain
Telephone number : +34 91 42 63 500
Fax no. : +34 91 745 18 88
e-mail address of person : yaraiberian@yara.com
responsible for this SDS

Date of issue : 20.01.2023 Page:1/17


AMMONIUM NITRATE SOLUTION 50%

1.4 Emergency telephone number

National advisory body/Poison Center


Name : Instituto Nacional de Toxicologia
Telephone number : +34 915620420

Supplier
Emergency telephone number : +34 9 1114 2520, +351 30 880 4750 (digite 1) (7/24)
(with hours of operation)

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture.
Product definition : Mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification : Eye Irrit. 2, H319

The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.

See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Warning

Hazard statements : H319 Causes serious eye irritation.

Precautionary statements

Prevention : P280-a Wear eye protection.


P264-a Wash hands thoroughly after handling.
Response : P305 IF IN EYES:
P351 Rinse cautiously with water for several
minutes.
P338 Remove contact lenses, if present and easy
to do. Continue rinsing.
P337 If eye irritation persists:
P313 Get medical attention.

EU Regulation (EC) No. : Applicable, Table 3, 65.


1907/2006 (REACH) Annex XVII
- Restrictions on the
manufacture, placing on the
market and use of certain
dangerous substances,
mixtures and articles

Date of issue : 20.01.2023 Page:2/17


AMMONIUM NITRATE SOLUTION 50%

Special packaging requirements

Containers to be fitted with : Not applicable.


child-resistant fastenings
Tactile warning of danger : Not applicable.

2.3 Other hazards

Product meets the : This mixture does not contain any substances that are assessed to be a
criteria for PBT or vPvB PBT or a vPvB.
according to
Regulation (EC) No.
1907/2006, Annex XIII

Other hazards which do not : None known.


result in classification
Additional information : None.

SECTION 3: Composition/information on ingredients


3.2 Mixtures : Mixture

Product/ingredie Specific Conc. Limits,


Identifiers % Classification Type
nt name M-factors and ATEs

ammonium nitrate REACH #: >= 50 - <= 65 Ox. Sol. 3, H272 [1]


01-2119490981-27 Eye Irrit. 2, H319 -
EC :
229-347-8
CAS :
6484-52-2
See Section 16 for the full text of the H statements declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in
the concentrations applicable, are classified as hazardous to health or the environment, are PBTs,
vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and
hence require reporting in this section.
Type
[1] Substance classified with a physical, health or environmental hazard
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures


4.1 Description of first aid measures

Eye contact : Rinse with plenty of running water. Check for and remove any
contact lenses. If irritation persists, get medical attention.

Inhalation : Avoid inhalation of vapor, spray or mist. If inhaled, remove to


fresh air.

Skin contact : Wash with soap and water. Get medical attention if irritation
develops.

Ingestion : Wash out mouth with water. If material has been swallowed and
the exposed person is conscious, give small quantities of water
Date of issue : 20.01.2023 Page:3/17
AMMONIUM NITRATE SOLUTION 50%

to drink.

Protection of first-aiders : No action shall be taken involving any personal risk or without
suitable training.

4.2 Most important symptoms and effects, both acute and delayed

Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following: pain or irritation,
watering, redness
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician : Treat symptomatically. Contact poison treatment specialist


immediately if large quantities have been ingested or inhaled. In
case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept
under medical surveillance for 48 hours.

Specific treatments : No specific treatment.

SECTION 5: Firefighting measures


5.1 Extinguishing media

Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing : None identified.


media

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or : In a fire or if heated, a pressure increase will occur and the
mixture container may burst.

Hazardous combustion : Decomposition products may include the following


products materials: nitrogen oxides, ammonia, Avoid breathing
dusts, vapors or fumes from burning materials., In case of
inhalation of decomposition products in a fire, symptoms
may be delayed.

5.3 Advice for firefighters

Special protective actions for : Promptly isolate the scene by removing all persons from the
fire-fighters vicinity of the incident if there is a fire. No action shall be taken
involving any personal risk or without suitable training.

Special protective equipment : Fire-fighters should wear appropriate protective equipment


for fire-fighters and self-contained breathing apparatus (SCBA) with a full
face-piece operated in positive pressure mode. Clothing for
fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic
level of protection for chemical incidents.

Date of issue : 20.01.2023 Page:4/17


AMMONIUM NITRATE SOLUTION 50%

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel : No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep
unnecessary and unprotected personnel from entering. Do not
touch or walk through spilled material. Avoid breathing vapor
or mist. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate
personal protective equipment (see Section 8).

For emergency responders : If specialized clothing is required to deal with the spillage, take
note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non-emergency
personnel".

6.2 Environmental precautions : Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers. Inform the relevant
authorities if the product has caused environmental pollution
(sewers, waterways, soil or air).

6.3 Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area.
Dilute with water and mop up if water-soluble. Alternatively, or
if water-insoluble, absorb with an inert dry material and place
in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.

Large spill : Stop leak if without risk. Move containers from spill area.
Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages
into an effluent treatment plant or proceed as follows. Contain
and collect spillage with non-combustible, absorbent material
e.g. sand, earth, vermiculite or diatomaceous earth and place
in container for disposal according to local regulations.
Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard
as the spilled product.

6.4 Reference to other : See Section 1 for emergency contact information.


sections See Section 8 for information on appropriate personal
protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage


The information in this section contains generic advice and guidance. The list of Identified Uses in
Section 1 should be consulted for any available use-specific information provided in the Exposure
Scenario(s).

7.1 Precautions for safe handling

Not for human or animal consumption.

Date of issue : 20.01.2023 Page:5/17


AMMONIUM NITRATE SOLUTION 50%

Protective measures : Put on appropriate personal protective equipment (see


Section 8). Do not ingest. Avoid contact with eyes, skin and
clothing. Avoid breathing vapor or mist. Keep in the original
container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty
containers retain product residue and can be hazardous. Do
not reuse container.

Advice on general : Eating, drinking and smoking should be prohibited in areas


occupational hygiene where this material is handled, stored and processed.
Workers should wash hands and face before eating, drinking
and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8
for additional information on hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities


Store in accordance with local regulations. Store in original container protected from direct sunlight
in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Keep container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination. Bund storage
facilities to prevent soil and water pollution in the event of spillage.

7.3 Specific end use(s)

Recommendations : Not available.

SECTION 8: Exposure controls/personal protection


The information in this section contains generic advice and guidance. Information is provided based on
typical anticipated uses of the product. Additional measures might be required for bulk handling or other
uses that could significantly increase worker exposure or environmental releases.

8.1 Control parameters

Occupational exposure limits

Remark : No exposure limit value known.

Recommended monitoring : If this product contains ingredients with exposure limits,


procedures personal, workplace atmosphere or biological monitoring may be
required to determine the effectiveness of the ventilation or other
control measures and/or the necessity to use respiratory
protective equipment.
Reference should be made to monitoring standards, such as the
following:
European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to
chemical agents for comparison with limit values and
measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide
for the application and use of procedures for the assessment of
exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents)
Reference to national guidance documents for methods for the

Date of issue : 20.01.2023 Page:6/17


AMMONIUM NITRATE SOLUTION 50%

determination of hazardous substances will also be required.

DNELs/DMELs
Product/ingredie Type Exposure Value Population Effects
nt name
ammonium DNEL Long term 5,12 mg/kg Workers Systemic
nitrate Dermal bw/day
DNEL Long term 36 mg/m³ Workers Systemic
Inhalation

PNECs
Product/ingredient Type Compartment Detail Value Method Detail
name
ammonium nitrate PNEC Sewage Treatment 18 mg/l Assessment
Plant Factors

8.2 Exposure controls

Appropriate engineering : Good general ventilation should be sufficient to control worker


controls exposure to airborne contaminants.

Individual protection measures


Hygiene measures : A washing facility or water for eye and skin cleaning
purposes should be present. Wash hands, forearms and
face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of
the working period. Wash contaminated clothing before
reusing.

Eye/face protection : Safety eyewear complying with an approved standard


should be used when a risk assessment indicates this is
necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
Recommended: Tightly-fitting goggles, Europe:, CEN:
EN166,

Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when
handling chemical products if a risk assessment indicates
this is necessary. For general applications, we
recommend gloves with a thickness typically greater than
0.35 mm. It should be emphasized that glove thickness is
not necessarily a good predictor of glove resistance to a
specific chemical, as the permeation efficiency of the
glove will be dependent on the exact composition of the
glove material.

Body protection : Personal protective equipment for the body should be


selected based on the task being performed and the risks
involved.

Other skin protection : Appropriate footwear and any additional skin protection
measures should be selected based on the task being
performed and the risks involved and should be approved
by a specialist before handling this product.

Date of issue : 20.01.2023 Page:7/17


AMMONIUM NITRATE SOLUTION 50%

Respiratory protection : In case of inadequate ventilation wear respiratory


protection.

Environmental exposure : Emissions from ventilation or work process equipment


controls should be checked to ensure they comply with the
requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering
modifications to the process equipment will be necessary
to reduce emissions to acceptable levels.

Personal protective equipment :


(Pictograms)

SECTION 9: Physical and chemical properties


The conditions of measurement of all properties are at standard temperature and pressure unless
otherwise indicated.

9.1 Information on basic physical and chemical properties

Appearance
Physical state : Liquid
Color : Colorless.,
Odor : odorless or slight ammoniacal
Melting point/freezing point : < 0 °C
Initial boiling point and boiling : 110 °C
range
Flammability : Non-flammable.
Lower and upper explosion : Lower: Not applicable.
limit Upper: Not applicable.
Flash point : Not applicable.
Auto-ignition temperature : Not applicable.
Decomposition temperature : Not applicable.
pH : 5-7

Viscosity : Kinematic: Not determined.


Solubility(ies) : Easily soluble in the following materials:
hot water
cold water

Miscibility with water : Miscible in water.


Partition coefficient: n- : Not applicable.
octanol/water
Vapor pressure : < 23 hPa
Relative density : 1,2

Relative vapour density : < 1 [Air = 1]

Explosive properties : Non-explosive.


Oxidizing properties : None UN Model Regualtions

Date of issue : 20.01.2023 Page:8/17


AMMONIUM NITRATE SOLUTION 50%

Particle characteristics

Median particle size : Not applicable.

9.2 Other information


No additional information.

SECTION 10: Stability and reactivity


10.1 Reactivity : No specific test data related to reactivity available for this
product or its ingredients.

10.2 Chemical stability : The product is stable.

10.3 Possibility of hazardous : Under normal conditions of storage and use, hazardous
reactions reactions will not occur.

10.4 Conditions to avoid : Avoid contamination by any source including metals, dust
and organic materials.

10.5 Incompatible materials : alkalis combustible materials, reducing materials, organic


materials, Acids

10.6 Hazardous : Under normal conditions of storage and use, hazardous


decomposition products decomposition products should not be produced.

SECTION 11: Toxicological information


11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity
Product/ingredient Method Species Result Exposure
name
ammonium nitrate
OECD 401 Rat 2.950 mg/kg Not applicable.
LD50 Oral
OECD 402 Rat > 5.000 mg/kg Not applicable.
LD50 Dermal
Conclusion/Summary : No known significant effects or critical hazards.

Acute toxicity estimates

Product/ingredient Oral Dermal Inhalation Inhalation Inhalation


name (gases) (vapors) (dusts and
mists)
ammonium nitrate 2.950 N/A N/A N/A N/A
mg/kg

Irritation/Corrosion
Product/ingredient Method Species Result Exposure

Date of issue : 20.01.2023 Page:9/17


AMMONIUM NITRATE SOLUTION 50%

name
ammonium nitrate
OECD 405 Rabbit Irritant
Eyes
Conclusion/Summary
Skin : No known significant effects or critical hazards.
Eyes : Causes serious eye irritation.
Respiratory : No known significant effects or critical hazards.

Sensitization
Product/ingredient name Method Species Result
ammonium nitrate
OECD 429 Mouse Not sensitizing
Skin
Conclusion/Summary
Skin : No known significant effects or critical hazards.
Respiratory : No known significant effects or critical hazards.

Mutagenicity
Product/ingredient name Method Test detail Result
ammonium nitrate
OECD 473 Mammalian Toxicity - Negative
Genotoxicity - In vitro
Mammalian
Chromosome
Aberration Test or
Mammalian Bone
Marrow Chromosomal
Abberation Test or
Mammalian
Erythrocyte
Micronucleus Test
In vitro
OECD 471 Bacteria Negative
In vitro
Conclusion/Summary : No known significant effects or critical hazards.

Carcinogenicity

Conclusion/Summary : No known significant effects or critical hazards.

Reproductive toxicity
Product/ingredient name Method Species Result Exposure
ammonium nitrate
OECD 422 Rat Fertility effects- 28 days
Oral Negative
Developmental-
Negative
NOAEL
> 1500 mg/kg
bw/day
Conclusion/Summary : No known significant effects or critical hazards.

Information on the likely : Not available.


Date of issue : 20.01.2023 Page:10/17
AMMONIUM NITRATE SOLUTION 50%

routes of exposure

Potential acute health effects

Inhalation : Exposure to decomposition products may cause a health


hazard. Serious effects may be delayed following
exposure.

Ingestion : Irritating to mouth, throat and stomach.

Skin contact : No known significant effects or critical hazards.

Eye contact : Causes serious eye irritation.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : No specific data.


Ingestion : No specific data.
Skin contact : No specific data.
Eye contact : Adverse symptoms may include the following: pain or
irritation, watering, redness

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No known significant effects or critical hazards.

Potential delayed effects : No known significant effects or critical hazards.

Long term exposure


Potential immediate effects : No known significant effects or critical hazards.

Potential delayed effects : No known significant effects or critical hazards.

Potential chronic health effects

Product/ingredient Method Species Result Exposure


name
ammonium nitrate
OECD 422 Rat 256 mg/kg 28 days
Chronic NOAEL
Oral
OECD 412 Rat > 185 mg/m³ 2 weeks 5
Sub-acute NOEC hours per day
Inhalation

Carcinogenicity : No known significant effects or critical hazards.

Mutagenicity : No known significant effects or critical hazards.

Reproductive toxicity : No known significant effects or critical hazards.

Effects on or via lactation : No known significant effects or critical hazards.

Other effects : No known significant effects or critical hazards.

11.2. Information on other hazards

Date of issue : 20.01.2023 Page:11/17


AMMONIUM NITRATE SOLUTION 50%

11.2.1 Endocrine disrupting : Not available.


properties
11.2.2 Other information : Not available.

SECTION 12: Ecological information


12.1 Toxicity
Product/ingredien Method Species Result Exposure
t name
ammonium nitrate
Acute LC50 Fish 447 mg/l 48 h
Fresh water
Acute EC50 Daphnia 490 mg/l 48 h
Fresh water
Acute EC50 Algae 1.700 mg/l 10 d
Salt water
Conclusion/Summary : No known significant effects or critical hazards.

12.2 Persistence and degradability

Conclusion/Summary : No known significant effects or critical hazards.

12.3 Bioaccumulative potential

Conclusion/Summary : No known significant effects or critical hazards.

12.4 Mobility in soil


Soil/water partition coefficient : Not available.
(KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment


This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Endocrine disrupting properties : Not available.

12.7 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations


The information in this section contains generic advice and guidance. The list of Identified Uses in
Section 1 should be consulted for any available use-specific information provided in the Exposure
Scenario(s).

13.1 Waste treatment methods


Product
Methods of disposal : The generation of waste should be avoided or minimized
wherever possible. Disposal of this product, solutions and
any by-products should at all times comply with the
requirements of environmental protection and waste
disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste
Date of issue : 20.01.2023 Page:12/17
AMMONIUM NITRATE SOLUTION 50%

should not be disposed of untreated to the sewer unless


fully compliant with the requirements of all authorities with
jurisdiction.
Hazardous waste : Yes.

European waste catalogue (EWC)

Waste code Waste designation


06 10 02* wastes containing hazardous substances

Packaging
Methods of disposal : The generation of waste should be avoided or minimized
wherever possible. Waste packaging should be recycled.
Incineration or landfill should only be considered when
recycling is not feasible.

Special precautions : This material and its container must be disposed of in a


safe way.
Care should be taken when handling emptied containers
that have not been cleaned or rinsed out.
Empty containers or liners may retain some product
residues.
Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.

SECTION 14: Transport information


ADR/RID ADN IMDG IATA

14.1 UN number Not regulated. Not regulated. Not regulated. Not regulated.
or ID number
14.2 UN proper Not applicable. Not applicable. Not applicable. Not applicable.
shipping name
14.3 Transport Not applicable. Not applicable. Not applicable. Not applicable.
hazard
class(es)
14.4 Packing Not applicable. Not applicable. Not applicable. Not applicable.
group
14.5. No. No. No. No.
Environmental
hazards

Additional information
ADR/RID :
ADN : Danger code Not applicable.
IMDG :
IATA :

14.6 Special precautions for : Transport within user’s premises: Ensure that persons
user transporting the product know what to do in the event of
an accident or spillage.

14.7 Maritime transport in bulk Proper shipping name : Ammonium nitrate solution
according to IMO instruments (93% or less)
Remarks : Liquid bulk cargoes
Ship type: 2
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AMMONIUM NITRATE SOLUTION 50%

Pollution category: Z

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture

EU Regulation (EC) No. 1907/2006 (REACH)


Annex XIV - List of substances subject to authorization
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
EU Regulation (EC) No. : Applicable, Table 3, 65.
1907/2006 (REACH) Annex XVII
- Restrictions on the
manufacture, placing on the
market and use of certain
dangerous substances,
mixtures and articles

Other EU regulations
Ozone depleting substances (1005/2009/EU)
None of the components are listed.

Prior Informed Consent (PIC) (649/2012/EU)


None of the components are listed.

Persistent Organic Pollutants


None of the components are listed.

Seveso Directive
This product is not controlled under the Seveso Directive.

Other regulations : Acquisition, introduction, possession or use of this product


by the general public is restricted by Regulation (EU)
2019/1148. All suspicious transactions, and significant
disappearances and thefts should be reported to the
relevant national contact point.

National regulations

Biocidal products regulation : Not applicable.

Notes : To our knowledge no other country or state specific


regulations are applicable.

15.2 Chemical Safety : Complete.


Assessment

SECTION 16: Other information


Date of issue : 20.01.2023 Page:14/17
AMMONIUM NITRATE SOLUTION 50%

Abbreviations and acronyms : ATE = Acute Toxicity Estimate


CLP = Classification, Labelling and Packaging Regulation
[Regulation (EC) No. 1272/2008]
DNEL = Derived No Effect Level
DMEL = Derived Minimal Effect Level
EUH statement = CLP-specific Hazard statement
N/A = Not available
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
SGG = Segregation Group
PBT = Persistent, Bioaccumulative and Toxic
vPvB = Very Persistent and Very Bioaccumulative
bw = Body weight

Key data sources : EU REACH ECHA/IUCLID5 CSR.


National Institute for Occupational Safety and Health, U.S.
Dept. of Health, Education, and Welfare, Reports and
Memoranda Registry of Toxic Effects of Chemical
Substances.
Sphera Solutions Inc., 4777 Levy Street, St Laurent,
Quebec HAR 2P9, Canada.
Regulation (EC) No 1272/2008 Annex VI.

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008
[CLP/GHS]

Classification Justification
Eye Irrit. 2, H319 Calculation method

Full text of abbreviated H statements

H272 May intensify fire; oxidizer.


H319 Causes serious eye irritation.

Full text of classifications [CLP/GHS]

Eye Irrit. 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2


Ox. Sol. 3 OXIDIZING SOLIDS - Category 3

Revision comments : The safety data sheet has been revised according to
Commission Regulation (EU) 2020/878.

Date of printing : 26.06.2023


Date of issue/ Date of revision : 20.01.2023
Date of previous issue : 04.02.2021
Version : 4.0
Prepared by : Product Stewardship and Compliance (PSC).
|| Indicates information that has changed from previously issued version.

Notice to reader
To the best of our knowledge, the information provided in this Safety Data Sheet is
accurate as at the date of its issue. The information it contains is being given for safety
guidance purposes and relates only to the specific material and uses described in it. This
information does not necessarily apply to that material when combined with other
material(s) or when used otherwise than as described herein, since all materials may
represent unknown hazards and should be used with caution. Final determination of the
suitability of any material is the sole responsibility of the user.

Date of issue : 20.01.2023 Page:15/17


AMMONIUM NITRATE SOLUTION 50%

Annex to the extended Safety Data Sheet (eSDS) -


Exposure Scenario/Safe Use Information:

Identification of the substance or mixture


Product definition : Mixture

Product name : AMMONIUM NITRATE SOLUTION 50%

Exposure Scenario/Safe : Exposure Scenarios are not attached for corrosive or irritant
Use Information hazards, relevant information on safe use is included in section 8.

Date of issue : 20.01.2023 Page:16/17


AMMONIUM NITRATE SOLUTION 50%

Date of issue : 20.01.2023 Page:17/17

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