2.10 hw
2.10 hw
2.10 hw
Year 12 80% A
70% B
AS Level Chemistry 60% C
2008-9 50% D
40% E
Below U
2.10
Questions on %
Alcohols
33
1. (a) Ethanol can be manufactured by the direct hydration of ethene and by the fermentation
of sugars.
......................................................................................................................
Advantage ....................................................................................................
......................................................................................................................
Disadvantage ...............................................................................................
......................................................................................................................
(3)
(i) Draw the structure of this aldehyde and of this carboxylic acid.
(ii) Give a suitable reagent and reaction conditions for the oxidation of ethanol to
form the carboxylic acid as the major product.
Reagent .........................................................................................................
Conditions ....................................................................................................
......................................................................................................................
(5)
(c) (i) Draw the structure of an alcohol containing four carbon atoms which is resistant
to oxidation.
(ii) Draw the structure of an alcohol containing four carbon atoms which can be
oxidised to a ketone.
(2)
......................................................................................................................
(1)
(Total 11 marks)
2. (a) (i) Give a suitable reagent and state the necessary conditions for the conversion of
propan-2-ol into propanone. Name the type of reaction.
Reagent…………………………………………………………………….…..
Conditions……………………………….……………………………………..
(ii) A chemical test can be used to distinguish between separate samples of propanone
and propanal. Give a suitable reagent for the test and describe what you would
observe with propanone and with propanal.
Isomer Name
CH3CH2CH2CH2OH butan-1-ol
CH 3
CH 3 C CH 3 2-methylpropan-2-ol
OH
CH3 C CH 2 OH
CH 3
CH 3 CH 2 CH CH 3
OH
.....................................................................................................................................
(Total 3 marks)
4. (a) One of the isomers in part (a) is resistant to oxidation by acidified potassium
dichromate(VI).
...........................................................................................................................
(ii) This isomer can be dehydrated. Give a suitable dehydrating agent and write an
equation for this dehydration reaction.
Dehydrating agent.............................................................................................
Equation ...........................................................................................................
(3)
(b) (i) Identify the isomer in part (a) which can be oxidised to a ketone. Give the
structure of the ketone formed.
Isomer ...............................................................................................................
(ii) Identify one of the isomers in part (a) which can be oxidised to an aldehyde. Give
the structure of the aldehyde formed.
Isomer ...............................................................................................................
(iii) Give a reagent that can be used in a test to distinguish between a ketone and an
aldehyde. State what you would observe in the test.
Reagent .............................................................................................................
...........................................................................................................................
...........................................................................................................................
(7)
(c) Butan-1-ol can be oxidised to form a carboxylic acid. Using [O] to represent the
oxidising agent, write an equation for this reaction and name the product.
Equation .....................................................................................................................