Rose Mary H. S.
School, Kolar Road
I term examination 2023-24
Class 12th
Subject- Chemistry
Time:- 3:00 hrs M.M.:-70
Instructions:-
(i) All questions are compulsory.
(ii) Question no. 1-4 are objective type questions, each question carries 1 mark.
(iii) Question no. 5-12 each question carries 2 marks.
(iv) Question no. 13-16 each question carries 3 marks.
(v) Question no. 17 carries 4 marks.
(vi) Question no. 18-19 carries 5 marks.
(vii) Internal choice is given in every question.
Section-A
Q.1 Choose the correct answers.
(a) If boiling point of solution is T1 and boiling point of solvent is T2, then elevation in boiling
point will be-
(i) T1+T2 (ii) T1-T2
(iii) T2-T1 (iv) T1T2
(b) Molality of pure water is
(i) 55.6 (ii) 50
(iii) 100 (iv) 18
(c) conductivity is equal to
(i) A/l (ii) 1/R x A/l
(iii) 1/R x l/A (iv) l/A
(d) if the concentration of any solution is C g equivalent/litre and specific resistance is A, it's
equivalent conductance will be-
(i) 1000A/C (ii) AxC/1000
(iii) 1000/AxC (iv) C/1000A
(e) The number of total known essential Amino acids are
(i) 10 (ii) 8
(iii) 6 (iv) 2
(f) For the first order reaction the value of t1/2 is:
(i) 0.693/k1 (ii) 2.303/K1
(iii) 0.303/k1 (iv) 0.693/t
(g) Antibodies are-
(i) Enzymes (ii) Proteins
(iii) Lipids (iv) Vitamins
Q.2:-Fill in the blanks –
(a) Rate of reaction is__________to the concentration of reactant.
(b) Fast reactions are completed in less than.....seconds.
(c)BHC is an insecticide whose commercial name is__________
(d) SN1 reaction occur in _______________steps.
(e) Ratified spirit is a mixture of ..... % alcohol and ....... Ether.
(f) Lucas reagent is________________
(g) Protein is a polymer of______
Q.3 Give answer in one sentence.
(a) Name the alcohol which gives iodoform test?
(b) In Victor Meyer method, 1° alcohol gives which colour with base?
(c)Give an example of non ideal solution showing positive deviation.
(d) What is the unit of Molality.
(e) SI unit of equivalent conductance.
(f) Write the name of protein which is present in hair, wool and silk?
(g) In RNA which pyrimidine is present in place of thymine?
Q.4 Make the correct pair from column 'A' choosing from column 'B'
'A' 'B'
(a) Arrhenius equation - 2-acetoxy benzoic acid
(b) Aspirin - K=Ae^-E/RT
(c) Spirit of wine - 2.303/t x log(a/a-x)
(d) freon - Gammaxane
(e) BHC- Dichloro-difluoro methane
(f) Half life period of zero order reaction Peptide bond
(g)Amino acid ethyl alcohol
Iron complex
Section-B
Q.5 define mole fraction ?
Or
What is Colligative property write it's type.
Q.6 What is azeotropic mixture? They are of how many types.
Or
Explain molal freezing point depression constant.
Q.7 What is salt bridge? Write it's two functions.
Or
Write statements of faradays laws of electrolysis.
Q.8 Define cell constant. Develop a relation between specific conductance and cell constant.
Or
Suggest a way to determine the ∆°m value of water.
Q.9 What are pseudo unimolecular reactions?
Or
Explain rate determining step.
Q.10 Explain sandmeyer's reaction with example.
Or
Boiling point of ethyl iodide is higher than alkyl bromide. Give reason.
Q.11 Define antibiotics. Give an example.
Or
Define antiseptic. Give an example
Q.12 write difference between molarity and molality.
Or
Find molality of water.
Section-C
Q.13 State Raoult’s law. How is it formulated for solutions of non-volatile solutes?
Or
State Henry’s law. What is the effect of temperature on the solubility of a gas in a liquid?
Q.14 Define order of a reaction. And derive expression rate constant for the reaction of zero
order.
Or
Derive expression for the EMF of a cell by using Nernst equation.
Q.15 How will you convert
(i) Propene to propan-2-ol?
(ii) Phenol to 2, 4, 6-trinitrophenol?
Or
Write the equations involved in the following reactions:
(i) Reimer – Tiemann reaction
(ii) Williamson synthesis
(iii)Kolbe’s electrolysis
Q16 Explain denaturation of proteins. With examples.
Or
Write difference between DNA and RNA.
Section-D
Q.17 Explain the following reaction by giving chemical equation.
(i) Wurtz fitting reaction
(ii) Hunsdeicker reaction
(iii) Carbyl amine reaction.
(iv) Reimer-Tieman reaction
Or
Explain nucleophilic substitution and its mechanism in haloalkanes.
Section-E
Q.18
Or
What is standard hydrogen Electrode? Describe its construction with diagram and write Its two
limitations.
Q19) Differentiate between phenol and alcohol and write Libermann's reaction related to phenol.
Or
Write Victor Meyer method to distinguish primary, secondary and tertiary alcohol.
Prepared by: - Rahul Ingle
Rose Mary H. S. School, Kolar road.
