BHOPAL SAHODAYA COMPLEX

PRE - BOARD EXAMINATION (2020-21)

CLASS – XII
SUBJECT – CHEMISTRY
Date:-
Time:- M.M.:- 70

Section A ( 1 Marks Each )

Q-1 Define activation energy.

Q-2 Define mole fraction of substance in solution.
Q-3The decomposition reaction of NH3 on platinium surface has K= 2.5×10-4mol L-1sec-1.What
is the order of rection?
Q-4 Identify the chiral molecule in the following pair :
Cl
Cl
Q-5 Solution of CHCl3 and CH3COCH3 is example of ---------- azeotrope .
Q-6 Write 𝐼𝑈𝑃𝐴𝐶 of 𝐶𝐻3 − 𝐶 = 𝐶 − 𝐶𝐻2 𝐶𝑙 .
Q-7 On the bases of C.F.T , write electronic configuration for 𝑑 4 ion if ∆0 < P .
Q-8 Why a solution of [𝑁𝑖(𝐻2 𝑂)6 ]+2 is green while solution of [𝑁𝑖(𝐶𝑁)4 ]−2 is colourless.
Q-9 Which would undergo SN2 reaction faster in the following :

C6H5 -CH2-CH2-Br And C6H5-CH-CH3

Br
Q-10 Explain the Ambidentate ligand giving suitable example .
Question 11 to 15 are multiple choice questions
Q-11 Which of the following is correctly mached
(i) Emulsion – Smoke (ii) Foam – Mist (iii) Aerosol – Hair cream (iv) Gel – Cheese
Q-12 Oxidising property is highest in
(i) I2 (ii) Br2 (iii) F2 (iv) Cl2
Q-13 Cell constant is
𝐴 𝑙 𝑙
(i) (ii) (iii) lA ii) 𝑒𝐴
𝑙 𝐴
Q-14 Conductance of electrolyte ------ with increase in temperature
(i) Increases (ii) decreases (iii) Both (iv) Depends on nature of electrolyte
-3
Q-15 Oxidation state of iron in [Fe(CN)6] is
(i) +2 (ii) +3 (iii) + 6 (iv) - 3
Q16 to 20
(A)Both assertion and reason are correct and reason is correct explanation of the assertion.
(B)Both assertion and reason are correct and reason is not correct explanation of the assertion.
(C) Assertion is correct and reason is wrong statement
(D) Assertion is wrong and reason is correct

Q-16 Assertion : Molarity of a solution in liquid state changes with temperature.

Reason : The volume of a solution changes with change in temperature.
Q-17 Assertion : Cooking time in pressure cooker is reduced .
Reason : Boiling point inside the pressure cooker is raised .
1
Q-18 Assertion : The half life period for first order reaction is independent of initial
concentration
0.693
Reason : For first order reaction t1/2 = 𝑘
Q-19 Assertion :Ni(CO)4 is diamagnetic complex .
Reason : It involves SP3hybridisation and there is no unpaired electrons .
Q-20 Assertion : SN2 reaction proceed with inversion of configuration .
Reason : SN2 reaction occurs in one step .
Section B ( 2 Marks Each )

Q-21 Calculate degree of dissociation and dissociation constant of 0.1 M 𝐶𝐻3 𝐶𝑂𝑂𝐻 .

(Given ʌ0𝑚 (𝐶𝐻3 𝐶𝑂𝑂𝐻) = 39 𝑆 𝑐𝑚2 𝑚𝑜𝑙 −1 , ʌ0𝑚 (𝐶𝐻3 𝐶𝑂𝑂− ) = 40.9 𝑆 𝑐𝑚2 𝑚𝑜𝑙 −1
ʌ0𝑚 (𝐻 + ) = 349.1 𝑆 𝑐𝑚2 𝑚𝑜𝑙 −1
Q-22 Explain Kohlarous law and mention its application.
Q-23Distinguish between order of reaction and moleculerty of reaction. When order and
molecularity of reaction will be same.
Q-24Solution containing 8 gm of solute in 100 gm of ether , solution boils at 36.860C where the
boiling point of pure ether is 35.600C. Calculate moleculer mass of solute. (Kb=2.02
Kkg/mol).
Q-25 Calculate molarity and molalty of 15% (w/w)solution of H2SO4.Density of solution is
1.02g/cm3
Or

If density of some lake water is 1.25g/ml and contains 92 g of Na+ per kg of water . Calculate
molalty ,molarity of Na+in the lake .

Q-26 1 gm of non electrolyte is dissolved in 50 gm o benzene lowers the freezing point

by 0.40K . Calculate Molecular mass of solute. ( Kb for benzene is 5.12 k kg-1mol-1)
Q-27 For the reaction: 2𝑆𝑂2 + 𝑂2 → 2𝑆𝑂3. Rate of formation of 𝑆𝑂3is 2x10-3 mol/sec.
Calculate rate of disappearance of 𝑆𝑂2 and 𝑂2 .

Section C ( 3 Marks Each )

Q-28Calculate e.m.f f cell Mg/Mg+2(0.1M)//Cu+2(0.001M)/Cu .

E0 Cu+2/Cu = +3.4 V , Mg+2/Mg = -2.37 V
Q-29Decomposition of PH3 proceeds according to following equation 4PH3→ P4 +6H2.
The half life of PH3 is 37.9 min at 1200C. How much time is required for ¾ of PH3 to
decompose.
Or
The rate of reaction doubles when temperature is raised from 298K to 308 K .Calculate
activation energy of reaction . (R= 8.314Jmol-1K-1)
Q-30 In following first order reaction taking place at318 K.
2𝑁2 𝑂5 → 4𝑁𝑂2 + 𝑂2 Calculate rate constant .if [𝑁2 𝑂5]0 =1.24 x10-2 Mol/L ,and
[𝑁2 𝑂5]t = .24 x10-2 Mol/L after 60 min .
Or

2
 For a certain chemical reaction variation in concentration [A] vs time (s) plot is given
below
(i) Predict the order of reaction ?
(ii) What does the slope of graph indicate ? graph
(iii) What is unit of rate constant ?
Q-31 How would you differentiate between SN1 and SN2 mechanisms of substitution reactions .
Q- 32Compare the following with respect to shape ,hybridization and magnetic behaviour .
(i)⌊𝑁𝑖(𝐶𝑁)4 ⌋-2 (ii) ⌊𝑁𝑖(𝐶𝑙)4 ⌋-2
Q33-Name the following 𝐾4 ⌊𝑀𝑛(𝐶𝑁)4 ⌋ (ii) 𝐾2 ⌊𝑁𝑖(𝐶𝑁)4 ⌋ ⌊𝐶𝑜(𝑁𝐻3 )5 𝐶𝑙⌋𝐶𝑙2
Or
Using IUPAC Write formula of the following
(i) 𝑆𝑜𝑑𝑖𝑢𝑚𝑑𝑖𝑐𝑦𝑛𝑖𝑑𝑜𝑎𝑢𝑟𝑎𝑡𝑒(𝐼)
(ii) 𝑇𝑒𝑡𝑟𝑎𝑎𝑚𝑚𝑖𝑛𝑒𝑐ℎ𝑙𝑜𝑟𝑖𝑑𝑜𝑝𝑙𝑎𝑡𝑖𝑛𝑖𝑢𝑚(𝐼𝑉)𝑠𝑢𝑙𝑝ℎ𝑎𝑡𝑒
(iii)𝑃𝑜𝑡𝑡𝑎𝑠𝑖𝑢𝑚𝑡𝑟𝑖𝑜𝑥𝑙𝑎𝑡𝑒𝑎𝑙𝑢𝑚𝑖𝑛𝑎𝑡𝑒(𝐼𝐼𝐼)
Q-34 Derive an expression for first order reaction and show that the time required for half the
change is independent of initial concentration.
Section D ( 5 Marks Each )

Q-35 Explain the following name reactions ;

(i) Swartz reaction
(ii) Hundisker reaction
(iii) Carbalimine reaction
(iv) Frakland’s reaction
(v) Sandmayer’s reaction
Or
(i) Finklistien reaction
(ii) Wurtz reaction
(iii) Gattermann’s reaction
(iv) Balzschimann reaction
(v) Halloform reaction
Q- 36 The resistance of a conductivity cell when filled with 0.05M solution of an electrolyte ‘X’
Is 100 Ω . The same cell is filled with 0.01M solution of electrolyte ‘Y ’has resistance of
50 Ω .conductivity of 0.05 M solution of an electrolyte ‘X ’ is 0.0001 S cm-1. Calculate
(i) Cell constant .
(ii) Conductivity of 0.01 M ‘Y ’ solution .
(iii) Molar Conductivity of 0.01 M ‘Y ’ solution .
Or
For the reaction Mg(s) +2 Ag (0.0001M) ⟶ Mg+2(0.10M) + 2Ag(s)
+

E0 electrode values are Mg+2/Mg = -2.36 V & Ag+/Ag =0.81 V .

Calculate (i) Standard cell potential
(ii) Cell potential
(iii) Gibbs free energy .
Q- 37 (i) State Roult’s law for a solution containing volatile solute.
(ii) 1gm of non electrolyte is dissolved in 50 gm of benzene lowers the freezing point by
0.40 K. Calculate Molecular mass of solute. ( Kb for benzene is 5.12 k kg-1mol-1)

3
 Or
How do you convert the following :
(a) (i) Prop-1-ene to propan-2-ol
(ii) Bromobenzene to 2-bromoacetophenone
(iii) 2- Bromobutane to But-2-ene
(b) Complete the reactions;
(i) 𝐶6 𝐻5 𝑁𝐻2 + 𝐶𝐻𝐶𝑙3 + 𝐾𝑂𝐻(𝑎𝑙𝑐) →
(ii) 𝐶𝐻3 𝐶𝐻2 𝐶𝑙 + 𝐿𝑖 →

Q- 38 Explain the following terms giving suitable examples in each case :

(i) Ambidentate ligand
(ii) Dendicity of a ligand
(iii) Crystal field splitting in an octrahydral complexes

4
 BHOPAL SAHODAYA COMPLEX
Pre –Board Examination (2021)
Answer Sheet
(Marking scheme)

Q-1 (i) (a) (ii) (a) (iii) (a) (iv) (c) or (d)

Q- 2 (i) C (ii) B (iii) D (iv) B

Q-3 (a)

Q-4 (b)

Q-5 (b)

Q-6 (b)

Q-7 (b)

Q-8 (a)

Q-9 (b)

Q-10 (a)

Q-11 (c)

Q-12 (a) Or (b)

Q-13 (b)

Q-14 (d)

Q-15 (a)

Q-16 (c)

Q-17 for first Order reaction:

𝐴
𝑘𝑡 = 2.303 log [ 𝐴0 ]

𝐴0
Whens 𝑡 = 𝑡1/2 𝐴 = 2

[𝐴 ]
𝑘 𝑡1/2 = 2.303 log [ 𝐴00 ]
[ ]
2

𝑘𝑡1/2 = 2.303 log 2 [log 2 = 0.3010 ]

𝑘𝑡1/2 = 0.693
0.693
𝑡1/2 =
𝑘
 For first order reaction half life is independent of initial concentration .
Q- 18 Tetraamminediaquachromium (III) chloride
Or
K4Fe(CN)6

Q-19 Given Kf=5.12 W 2=1.8 g M2=256 W 1=75 g

𝑘𝑓 ×𝑊2 ×1000 5.12 ×1.8×1000
Δ T𝑓 = = = 0.48 K
𝑀2 ×𝑤1 256×75
Or

Azeotropic mixture : Mixture of two component at definite proportion have constant

boiling point like pure liquid called azeotropic mixture . Positive daviation

Q-20 (i)On moving down the group steady decrease in atomic size of lanthanoids is
observed this is called lanthanoid contraction . this is due to entry of new electron
in (n-2) f subshell instead of outer most shell and electron do not have shielding
effect due to shape of f orbital .
(ii)Yb Eu and Ce and Tb

Q-21 (i) 4 hydroxy pent -2 ene oic acid

(ii) Ethyl ethnoate is formed C2H5Cl + CH3COOAg ⟶ CH3COOC2H5 + AgCl

Q-22 (a) Invert sugar - Mixture containing equal amount of d (+) glucose and l (-)
fructose called invert sugar .

(b)Nucleoside - Ribose or deoxyribose sugar containing hetrocyclic base like

A,U,T,C,G called Nucleoside
Or
(i) Gluconic acid is formed
CHO- (CHOH)4-CH2OH ⟶ COOH -(CHOH)4-CH2OH
(ii) Gloublar protein – Albumin Fibrous protein – Keretin

Q-23 (i) (ii)

Q-24 (i) [Fe(CN)6]-4 it contain unpaired electrons (ii) dsp2 Squre plannar
𝑍𝑀 𝑑×𝑎3 ×𝑁𝑎 8×(2.5×(2.5× 10−8 )3 ×(6.022× 1023
Q-25 𝑑 = = = = 37.63 g/mol
𝑎3 ×𝑁𝑎 𝑍 2

Q-26 (i) it is because oxygen is diatomic and hasless intermolecular force of attraction
where is Sulphur is octaatomic and has more intermolecular force of attraction

(ii) It is due to presence of triple Bond which has high bond dissociation enthalpy
(iii)It is because NF3 is more stable due to stronger n f Bond than NCl3 e florine
is stronger oxidising agent than chlorine

Q-27 (i) Wolf kishner reaction :

𝑁𝐻2 −𝑁𝐻2
CH3COCH3 CH3CH2CH3
𝐾𝑂𝐻/𝑔𝑙𝑦𝑐𝑜𝑙
(ii) Aldol condensation
𝑂𝐻 −
2 CH3CHO → CH3CH(OH)CH2CHO
(iii) Hundisker reaction
RCOOAg + Br2 ⟶ R-X + AgX + CO2

Q-28 (i) due to resonance , lone pair of e- on nitrogen atom in CH3CONH2 is

delocalized over keto group . there is no such effect in CH3CH2NH2
(ii) In chloro benzene C-Cl bond is sp2 hybridised where as in cyclohexyl
chloride is sp3 hybridized . sp2 has more s character than sp3

(iii) This is because lone pair on oxygen atom attached to hydrogen atom in
COOH group involved in resonance thereby making carbon less
electrophillic

Q-29 Henary’s law : Mass of gas dissolved in given volume of liquid at constant
temprature is directly propotional to the pressure of gas present in equlibrium
with liquid

Or
Solubility of gas in liquid at a particular temprature is directly propotional to the
pressure of gas present in equlibrium at that temprature .

Application : i) in the production of carbonated beaverges .

ii) in deep sea diving .
iii) in fuction of lungs .
iv) for climbers or peoples at high altitudes .

Q-30 (i) The moment of choice colloidal particle under the influence of current is
known As electrophoresis
(ii) Greater the valency of the active Ion or flocculating ion greater will be the
coagulating power
(iii) convergence of freshly prepared precipitate into colliders solution is known as
peptization

Q-31 (a)
(i) carboxylate ions are more stable than phenoxide ion as negative charge is
delocalized on two oxygen atoms on carboxylate ions .

(ii) CH3COOH <C6H5COOH < HCOOH

(b)

Or

(a)

(b) (i) nitro group is an electron withdrawing group . presence of this group
electrondensity decreases in O-H bond .
(ii)Inter molecular hydrogen bonding in butan-1-ol

Q- 32 (i) A= CH3COOH B= CH3NH2

(ii) A = CH3CH2CH2NH2 B = CH3CH2CH2OH C= CH3CH2CH2Cl

Or

(i) HNO2/00C , HBF4

(ii) CH3COCl in presence of anhydrous AlCl3
(iii) CH3CH2OH + KCN ⟶ CH3CH2CN + KOH

(b) (i) C6H11Cl + SO2+HCl

(ii)

Q- 33 (a) W2(cane sugar)= 5 g,W 2(glucose) = 5 g,M2(cane sugar) = 342,

M2 (glucose)= 18 , Tf for cane sugar = 271 0C Tf for glucose = ?

𝑘𝑓 ×𝑊2 ×1000 𝑘𝑓 ×𝑊2 ×1000
Forcane sugar Δ T𝑓 = and for glucose Δ T𝑓 =
𝑀2 ×𝑤1 𝑀2 ×𝑤1

𝑘𝑓 ×5×1000 𝑘𝑓 ×5×1000
𝟐= ------(i) and Δ T𝑓 = -------(ii)
342×95 180×95

From (i) and (ii)

2×95×342 𝑥×95×180
= = 3.8 K
1000×5 1000×5

Δ T𝑓 = 𝑇𝑓0 − T𝑓 = 273 – 3.8 = 269.20C

(b) KCl ionizes in aq solution and urea do not and osmotic pressure is colligative
property
Or
𝑊2 ×𝑅×𝑇 2.5×10−2 ×0.0821×298
𝝅= == = 0.175 x 10−2 atm
𝑀2 ×𝑉 174×2

(b) (i) due to formation of H- bond (ii) Positive daviation