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Carbon & Its Compound Carbon & Its Compound: Page Number: 25

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CARBON & ITS COMPOUND

Page Number: 25

Question 1
What would be the electron dot structure of carbon dioxide which has the formula CO2 ?
Answer:

Question 2
What would be electron dot structure of sulphur which is made up of eight atoms of sulphur.
Answer:

Page Number: 32

Question 1
How many structural isomers can you draw for pentane ?
Answer:
Three, these are n-pentane, iso-pentane
pentane and neo-pentane.
neo

Question 2
What are the two properties of carbon which lead to the huge number of carbon compound
compounds
we see around us ?
Answer:
(i) Tetravalency
(ii) Catenation.

Question 3
What will be the formula and electron dot structure of cyclopentane ?
Answer:
The molecular formula of cyclopentane is C5 H10 .
The electron dot structure of cyclopentane is given on the next page.

Question 4
Draw the structures for the following compounds :
(i) Ethanoic acid
(ii) Bromopentane
(iii) Butanone
(iv) Hexanal
Answer:
(i) Ethanoic acid (CH3COOH)

(ii) Bromopentane (C5H11Br)

(iii) Butanone (CH3 — CH2 — COCH3)


(iv) Hexanal (C5H11CHO)

Structural isomers for bromopentane: There are three structural isomers for bromopentane
depending on the position of Br at carbon 1, 2, 3.

Positions 4 and 5 are same as 1, 2.

Question 5
How would you name the following compounds ?

Answer:
(i) Bromoethane
(ii) Methanal
(iii) 1 – Hexyne

Page Number: 35

Question 1
Why is the conversion of ethanol to ethanoic acid an oxidation reaction ?
Answer:
Conversion of ethanol into ethanoic acid is an oxidation reaction because addition of oxygen
to a substance is called oxidation. Here, oxygen is added to ethanol by oxidising agent like
alkaline potassium permanganate or acidified potassium dichromate and it is converted into
acid.

Question 2
A mixture of oxygen and ethyne is burnt for welding. Can you tell why a mixture of ethyne
and air is not used ?
Answer:
A mixture of ethyne and air is not used for welding because burning of ethyne in air produces
a sooty flame due to incomplete combustion, which is not enough to melt metals for welding.

Page Number: 38

Test Alcohol Carboxylic acid

(i) Litmus test No change in colour. Blue litmus solution turns red.

CH3COOH + NaHCO3 → CH3COONa +


(ii) Sodium hydrogen C2H5OH + NaHCO3 → No
H2O + CO2 Brisk effervescence due to
carbonate test reaction No brisk effervescence.
evolution of CO2.

(iii) Alkaline potassium On heating, pink colour


Does not happen so.
permanganate disappears.

Question 1
How would you distinguish experimentally between an alcohol and a carboxylic acid ?
Answer:
Differences between alcohol and carboxylic acid

Question 2
What are oxidising agents ?
Answer:
Oxidising agents are the substances which give oxygen to another substances or which
remove hydrogen from a substance.
For example, acidic K2Cr2O7 is an oxidising agent, that converts (oxidises) ethanol into
ethanoic acid.

Page Number: 40

Question 1
Would you be able to check if water is hard by using a detergent ?
Answer:
No, because detergents can lather well even in hard water. They do not form insoluble
calcium or magnesium salts (scum). On reacting with the calcium ions and magnesium ions
present in the hard water.

Question 2
People use a variety of methods to wash clothes. Usually after adding the soap, they ‘beat’
the clothes on a stone, or beat it with a paddle, scrub with a brush or the mixture is agitated in
a washing machine. Why is agitation necessary to get clean clothes ?
Answer:
It is necessary to agitate to get clean clothes because the soap micelles which entrap oily or
greasy particles on the surface of dirty cloth have to be removed from its surface. When the
cloth wetted in soap solution is agitated or beaten, the micelles containing oily or greasy dirt
get removed from the surface of dirty cloth and go into water and the dirty cloth gets cleaned.

NCERT Solutions for Class 10 Science Chapter 4 Textbook


Chapter End Questions
Question 1
Ethane, with the molecular formula C2H6 has
(a) 6 covalent bonds
(b) 7 covalent bonds
(c) 8 covalent bonds
(d) 9 covalent bonds
Answer:
(b) 7 covalent bonds.

Question 2
Butanone is a four-carbon compound with the functional group
(a) carboxylic acid
(b) aldehyde
(c) ketone
(d) alcohol
Answer:
(c) Ketone.

Question 3
While cooking, if the bottom of the vessel is getting blackened on the outside, it means that
(a) the food is not cooked completely.
(b) the fuel is not burning completely.
(c) the fuel is wet.
(d) the fuel is burning completely.
Answer:
(b) The fuel is not burning completely.

Question 4
Explain the nature of the covalent bond using the bond formation in CH3Cl.
Answer:
Covalent bond is formed by sharing of electrons so that the combining atoms complete their
outermost shell.

In CH3Cl : C = 6, H = 1 and Cl = 17 And their electronic configuration is C – 2,4, H – 1 and


Cl – 2, 8, 7

Three hydrogen atoms complete their shells by sharing three electrons (one electron each) of
carbon atom.
Chlorine completes its outer shell by sharing its one out of seven electrons with one electron
of carbon atom.
Thus carbon atom shares all its four electrons with three hydrogen atoms and one of chlorine
atom and completes its outermost shell and single covalent bonds are formed in CH3Cl.

Question 5
Draw the electron dot structures for
(a) ethanoic acid
(b) propanone
(c) H2S
(d) F2.
Answer:

Question 6
What is a homologous series ? Explain with an example.
Answer:
Homologous series : A homologous series is a group of organic compounds having
similar structures and similar chemical properties in which the successive compounds differ
by -CH2 group.

Characteristics of homologous series :


(i) All members of a homologous series can be represented by the same general formula. For
example, the general formula of the homologous series of alkanes is CnH2n+2, in which ‘n’
denotes number of carbon and hydrogen atoms in one molecule of alkane.
(ii) Any two adjacent homologues differ by one carbon atom and two hydrogen atoms in their
molecular formulae.
(iii) The difference in the molecular masses of any two adjacent homologues is 14u.
(iv) All the compounds of a homologous series show similar chemical properties.
(v) The members of a homologous series show a gradual change in their physical properties
with increase in molecular mass.

For example, general formula of the homologous series of alkanes is CnH2n+2, in which ‘n’
denotes number of carbon atoms in one molecule of alkane. Following are the first five
members of the homologous series of alkanes (general formula CnH2n+2).
Value of n Molecular formula Name of compound

1 CH4 Methane

2 C2H6 Ethane

3 C3H8 Propane

4 C4H10 Butane

5 C5H12 Pentane
Property Ethanol Ethanoic acid

(i) State Liquid Liquid

(ii) Odour Sweet smell Pungent vinegar-like smell

(iii) Melting point 156 K 290 K

(iv) Boiling point 351 K 391 K

Question 7
How can ethanol and ethanoic acid he differentiated on the basis of their physical and
chemical properties ?
Answer:
Difference on the basis of physical properties

Difference on the basis of chemical properties

Test Ethanol Ethanoic acid

No change in the colour of


(i) Litmus test Blue litmus solution turns red.
litmus solution.

(ii) Sodium hydrogen carbonate C2H5OH + NaHCO3 → No CH3COOH + NaHCO3 → CH3COONa +


test reaction No brisk effervescence. H2O + CO2 Brisk effervescence due to

evolution of CO2.

(iii) Alkaline potassium On heating, pink colour


Does not happen so.
permanganate disappears.

Question 8
Why does micelle formation take place when soap is added to water ? Will a micell be
formed in other solvents such as ethanol also ?
Answer:
Micelle formation takes place when soap is added to water because the hydrocarbon chains of
soap molecules are hydrophobic (water repelling) which are insoluble in water, but the ionic
ends of soap molecules are hydrophilic (water attracting) and hence soluble in water.
Such micelle formation will not be possible in other solvents like ethanol in which sodium
salt of fatty acids do not dissolve.

Question 9
Why are carbon and its compounds used as fuels for most applications ?
Answer:
Carbon and its compounds give a large amount of heat per unit weight and are therefore, used
as fuels for most applications.

Question 10
Explain the formation of scum when hard water is treated with soap.
Answer:
Hard water contains salts of calcium and magnesium. Calcium and magnesium on reacting
with soap form insoluble precipitate called scum. The scum formation lessens the cleansing
property of soaps in hard water.

Question 11
What change will you observe if you test soap with litmus paper (red and blue)?
Answer:
Red litmus will turn blue because soap is alkaline in nature. Blue litmus remains blue in soap
solution.

Question 12
What is hydrogenation ? What is its industrial application ?
Answer:
The addition of hydrogen to an unsaturated hydrocarbon to obtain a saturated hydro-carbon is
called hydrogenation. The process of hydrogenation takes place in the presence of nickel (Ni)
or palladium (Pd) metals as catalyst.

Application : The process of hydrogenation has an important industrial application. It is used


to prepare vegetable ghee (or vanaspati ghee) from vegetable oils.

Question 13
Which of the following hydrocarbons undergo addition reactions :
C2H6, C3H8, C3H6, C2H2 and CH4
Answer:
Addition reactions take place only in unsaturated hydrocarbons. So addition reaction take
place only in C3H6 and C2H2.

Question 14
Give a test that can be used to differentiate chemically between butter and cooking oil.
Answer:
Butter is a saturated carbon compound while cooking oil is an unsaturated carbon compound.
An unsaturated compound decolourises bromine water, while a saturated compound cannot
decolourise it. So we can distinguish chemically between a cooking oil and butter by the
bromine water. Add bromine water to a little of cooking oil and butter taken in separate test-
tubes.

• Cooking oil decolourises bromine water showing that it is an unsaturated


compound.
• Butter does not decolourise bromine water showing that it is a saturated
compound.

Question 15
Explain the mechanism of the cleaning action of soaps.
OR
Explain the cleansing action of soaps. [CBSE 2015 (Delhi)]
Answer:
When a dirty cloth is put in water containing dissolved soap, then the hydrocarbon end of the
soap molecules in micelle attach to the oil or grease particles present on the surface of dirty
cloth. In this way the soap micelle entraps the oily or greasy particles by using its
hydrocarbon ends. The ionic ends of the soap molecules in the micelles, however, remain
attached to water. When the dirty cloth is agitated in soap solution, the oily and greasy
particles present on its surface and entrapped by soap micelles get dispersed in water due to
which the soap water becomes dirty but the cloth gets cleaned. The cloth is cleaned
thoroughly by rinsing in clean water a number of times.

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