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Electrochemistry Revision-3 Online

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0% found this document useful (0 votes)
95 views10 pages

Electrochemistry Revision-3 Online

Uploaded by

tumimogotsi14
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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Electrochemistry Revision - Online

1
1

1
2

i
2

2
3

x3

3
3
3

3
3
3
4

x4

4
E

,
S
S

S
29/26

TABLE 4 STANDARD ELECTRODE POTENTIALS 4B table


Half-reaction E°/volt
Li+ + e– Li –3,05
+ –
K +e K –2,93
+ –
Cs + e Cs –2,92
2+ –
Ba + 2e Ba –2,90
Sr2+ + 2e– Sr –2,89
2+ –
Ca + 2e Ca –2,87
+ –
Na + e Na –2,71
2+ –
Mg + 2e Mg –2,37
3+
+ 3e– –1,66
Mn2+ + 2e– Mn –1,18

2H2O + 2e H2(g) + 2OH– –0,83
Zn2+ + 2e– Zn –0,76
3+ –
Cr + 3e Cr –0,74
2+ –
Fe + 2e Fe –0,44
2+ –
Cd + 2e Cd –0,40
Co2+ + 2e– Co –0,28
2+ –
Ni + 2e Ni –0,25
Increasing oxidising ability

Increasing reducing ability


2+ –
Sn + 2e Sn –0,14
2+ –
Pb + 2e Pb –0,13
Fe3+ + 3e– Fe –0,04
+ –
2H + 2e H2(g) 0,00
+ –
S + 2H + 2e H2S(g) +0,14
Sn4+ + 2e– Sn2+ +0,15
SO42– + 4H+ + 2e– SO2(g) + 2H2O +0,17
2+ –
Cu + 2e Cu +0,34

2H2O + O2 + 4e 4OH– +0,40
SO2 + 4H+ + 4e– S + 2H2O +0,45

I2 + 2e 2I– +0,54
+ –
O2(g) + 2H + 2e H2O2 +0,68
3+ –
Fe + e Fe2+ +0,77
Hg2+ + 2e– Hg +0,79
– + –
NO3 + 2H + e NO2(g) + H2O +0,80
+ –
Ag + e Ag +0,80
NO3– + 4H+ + 3e– NO(g) + 2H2O +0,96

Br2 + 2e 2Br– +1,09
2+ –
Pt + 2e Pt +1,20
+ –
MnO2 + 4H + 2e Mn2+ + 2H2O +1,21
O2 + 4H+ + 4e– 2H2O +1,23
2– + –
Cr2O7 + 14H + 6e 2Cr3+ + 7H2O +1,33
– –
2(g) + 2e +1,36
Au3+ + 3e– Au +1,42
– + –
MnO4 + 8H + 5e Mn2+ + 4H2O +1,51
H2O2 + 2H+ + 2e– 2H2O +1,77

F2(g) + 2e 2F– +2,87

IEB Copyright © 2014–2018 NATIONAL SENIOR CERTIFICATE HANDBOOK


IMPLEMENTATION DATE: GRADE 11, 2018; GRADE 12, 2019
NATIONAL SENIOR CERTIFICATE: PHYSICAL SCIENCES: PAPER II – DATA SHEET Page i of iii

EXAMINATION DATA SHEET FOR THE PHYSICAL SCIENCES


(CHEMISTRY)

TABLE 1 PHYSICAL CONSTANTS

NAME SYMBOL VALUE


Magnitude of charge on electron e 1,6 × 10–19 C
Mass of an electron me 9,1 × 10–31 kg
Standard pressure pθ 1,01 × 105 Pa
Molar gas volume at STP Vm 22,4 dm3∙mol–1
Standard temperature Tθ 273 K
Avogadro's constant NA 6,02 × mol–1
Faraday's constant F 96 500 C∙mol–1

TABLE 2 CHEMISTRY FORMULAE

m N V
n= n= n=
M NA Vm

n m
c= OR c =
V MV K w = [ H 3O + ] ⋅ [OH − ] = 1 × 10–14 at 298 K

Eθcell = Eθcathode − Eθanode


Q = It
Eθcell = Eθoxidising agent − Eθreducing agent

n
=

IEB Copyright © 2016 PLEASE TURN OVER


NATIONAL SENIOR CERTIFICATE: PHYSICAL SCIENCES: PAPER II – DATA SHEET Page ii of iii

TABLE 3 PERIODIC TABLE

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
1 2,1 Atomic number (Z) 1 2,1 Electronegativity 2
1 H He
1 H 4
3 1,0 4 1,5 5 2,0 6 2,5 7 3,0 8 3,5 9 4,0 10
1
2 Li Be Relative atomic mass B C N O F Ne
7 9 10,8 12 14 16 19 20
11 0,9 12 1,2 13 1,5 14 1,8 15 2,1 16 2,5 17 3,0 18
3 Na Mg Aℓ Si P S Cℓ Ar
23 24,3 27 28 31 32 35,5 40
19 0,8 20 1,0 21 1,3 22 1,5 23 1,6 24 1,6 25 1,5 26 1,8 27 1,8 28 1,8 29 1,9 30 1,6 31 1,6 32 1,8 33 2,0 34 2,4 35 2,8 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39 40 45 48 51 52 55 56 59 59 63,5 65,4 70 72,6 75 79 80 84
37 0,8 38 1,0 39 1,2 40 1,4 41 1,6 42 1,8 43 1,9 44 2,2 45 2,2 46 2,2 47 1,9 48 1,7 49 1,7 50 1,8 51 1,9 52 2,1 53 2,5 54
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85,5 88 89 91 93 96 99 101 103 106 108 112 115 119 121 128 127 131
55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tℓ Pb Bi Po At Rn
133 137,3 178,5 181 184 186 190 192 195 197 200,6 204,4 207 209 – – –
87 88
7 Fr Ra

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lw

IEB Copyright © 2016

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