ASSIGNMENT- 1
Mole Concept (Abhimanyu-Batch)
Mix Problems Stoichiometry
Select the Correct Alternative (Only One Correct Answer)
1. A sample of ammonium phosphate, (NH4)3PO4, contains 3.18 mol of hydrogen atoms.
The number of moles of oxygen atoms in the sample is :
(a) 0.265 (b) 0.795 (c)1.06 (d)3.18
2. How many moles of electron weight one kilogram:
1 6.023 1
(a) 6.023 × 1023 (b) 1031 (c) 1054 (d) 108
9.108 9.108 9.108 6.023
3. The atomic weight of Cu is 63.546. There are only two naturally occurring isotopes of
copper 63Cu and 65Cu. The natural abundance of the 63Cu isotope must be approximately :
(a) 10% (b) 60% (c) 50% (d) 70%
4. Out of Molarity (M), Molality (m), Formality (F) and Mole fraction (x), those
independent of temperature are :
(a) M,m (b) F,x (c) m,x (d) M,x
5. The molality of a 1 L solution with x % H2SO4 is 9. The weight of solvent present in the
solution is 910 grams. The value of x is :
(a) 90 (b) 80.3 (c) 30.38 (d) 46.87
6. Density of ozone relative to oxygen is under the same temperature &pressure :
(a)1 (b) 2 (c) 1.5 (d) 2.5
7. Mole fraction of A in H2O is 0.2. The molality of A in H2O is :
(a) 13.8 (b) 15.5 (c) 14.5 (d) 16.8
8. The molarity of the solution containing 2.8% mass-volume solution of KOH/( Given
atomic mass of K = 39) i s :
(a) 0.1 M (b) 0.5 M (c) 0.2 M (d) 1 M
9. The molality of a sulphuric acid solution is 0.2 mol/kg. Calculate the total weight of the
solution :
(a) 1000 g (b) 1098.6 g (c) 980.4 g (d)1019.6 g
Select the Correct Alternatives (One or More Correct Answers)
1. "Suvarnabhasm", an ayuruvedic drug, is found to contain 400 ppm of colloidal gold.
Mass% of gold (atomic mass of Au = 197) will be :
(a) 0.040 % (b) 7.88% (c) 0.788% (d)4 × 10-4%
2. An antifreeze mixture consists of 40% ethylene glycol (C2H6O2) by weight in aqueous
solution. If the density of this solution is 1.05 g/mL, what is the molar concentration:
(a) 6.77 M (b) 6.45M (c) 0.017M (d) 16.9M
3. XeF6 fluorinates I2 to If7 and liberates Xenon(g). 210 mmol of XeF6 can yield a
maximum of ____ mmol of IF7 :
(a)420 (b) 180 (c) 210 (d) 245
4. When 100g of ethylene polymerises entirely to polythene, the weight of polythene
formed as per the equation nCH2 = CH2 → (CH2 -CH2)n is :
(a) (n/2)g (b) 100g (c) (100/n)g (d) 100n × g
5. 50g of ZnS are strongly heated in air to effect partial oxidation and the resultant mass
weight 44g. What is the ratio of ZnO to ZnS in the resultant mixture :
(a) 13.5 : 30.5 (b) 27 : 12.58 (c) 27 : 15.31 (d) 30.52 : 13.48
6. Iodobenzene (C6H5I) is prepared from aniline (C6H5NH2) in a two step process as shown
below
C6H5NH2 + HNO2+ HCl → C6H5N2+Cl- + 2H2O
C6H5N2 +Cl- + KI → C6H5I + N2 + KCl
In an actual preparation 9.30g of aniline was converted to 16.32g of iodobenzene. The
percentage yield of iodobenzene is :
(a) 8% (b) 50% (c) 75% (d) 80%
7. In an organic compound of molar mass greater than 100 containing only C, H and N, the
percentage of C is 6 times the percentage of H while the sum of the percentages of C and
H is 1.5 times the percentage of N. What is the least molar mass :
(a) 175 (b) 140 (c) 105 (d) 210
8. How many grams of urea on heating yield 1022 molecules of biuret by the reaction
2CO ( NH2 )2 → H2 N − CO − NH − CO − NH2 + NH3 ?
(a) 1.495 (b) 0.995 (c) 1.99 (d) 1.753
9. DNA has density 1.1 g/mL and its molecular weight is 6 × 103 g/mol. Average volume
occupied by its single molecule will be :
(a) 9.1 × 10-20 cc (b) 9.1 × 10-21 cc (c) 9.8 × 10-21 cc (d) 9.8 × 10-20 cc
10. For an infinitely dilute aqueous solution molarity will be equal to:
(a) formality (b) molarity (c) mole fraction (d) ppm
11. If 1 g of HCl and 1 g of MnO2 heated together the maximum weight of Cl2 gas evolved
will be :
MnO2 + 4HCl → MnCl2 + Cl2 + 2H2O :
(a) 2 g (b) 0.975 g (c) 0.486 g (d) 0.972 g
12. Na2SO4.xH2O has 50% H2O. Hence, x is :
(a) 4 (b) 5 (c) 6 (d) 8
13. In the following final results is …. 0.1 mol CH4 + 3.01 × 1023 molecules CH4 = x mol H
atom :
(a) 0 mol H atom (b) 0.2 mol H atom (c) 0.3 mol H atom (d) 0.4 mol H atom
14. A definite amount of gaseous hydrocarbon having (carbon atoms less than 5) was burnt
with sufficient amount of O2. The volume of all reactants was 600 mL, after the
explosion the volume of the products [CO2(g) and H2O(g)] was found to be 700 mL
under the similar conditions. The molecular formula of the compound is?
(a) C3H8 (b) C3H6 (c) C3H4 (d) C4H10
15. Solution containing 23g HCOOH is /are :
w
(a) 46g of 70% HCOOH (d solution = 1.40 g/mL)
v
(b) 50g of 10 M HCOOH (dsolution = 1 g/mL)
w
(c) 50g of 25 HCOOH
w
(d) 46 g of 5 M HCOOH (dsolution = 1 g/mL)
16. A sample of H2O2 solution labeled as "28 volume" has density of 265g/L. Mark the
correct option(s) representing concentration of some solution in other units:
w
(a) M H2O2 = 2.5 (b) % = 17
v
(c) mole fraction of H2O2 = 0.2 (d) m H2O2 = 13.88
Comprehension Based Questions
Comprehension 1:
Potash is any potassium mineral that is used for its potassium content. Most of the potash
produced in the United States goes into fertilizer. The major sources of potash are potassium
chloride (KCl) and potassium sulphate (K2SO4). Potash production is often reported as the
potassium oxide (K2O) equivalent or the amount of K2O that could be made from a given
mineral. KCl costs Rs. 50 per kg.
1. What with cost of K per mole of the KCl sample?
(a) Rs. 13.42 mol-1 (b) Rs 3.73 mol-1 (c) Rs 1.00 mol-1 (d) Rs. 2.00 mol-1
2. For what prices must K2SO4 be sold in order to supply the same amount of potassium as
in KCl?
(a) Rs 58.40 kg-1 (b) Rs 5.00 kg-1 (c) Rs 42.82kg-1 (d) Rs 25.00 kg-1
3. What mass (in kg of K2O contains the same number of moles of K atom as 1.00 Kg KCl?
(a) 0.158 kg (b) 0.315 kg (c) 1.262 kg (d) 0.631kg
Comprehension 2:
Calcium lactate is used in the food and beverage industries. It has also been used medicinally for
treatmentof various al allergies, for treatment of muscular leg cramps, and as an antidote for a
variety of poisons,including lead, arsenicals, and carbon tetrachloride. A 0.8274 g sample of
anhydrous calcium lactate isfound by analysis to contain 0.2732 g of C, 0.0382 g H, 0.1520 g Ca
and 0.3640 g O. Each moleof calcium lactate is found to contain one mole of calcium ions.
Calcium lactate can be crystallized fromwater as pentahydrate salt.
1. Simplest formula of the calcium lactate is :
(a) CaO6C6H10 (b) CaO3C3H5 (c) CaO2C3H3 (d) CaO2C3H5
2. Formula weight of calcium lactate is :
(a) 129 g mol-1 (b) 111 g mol-1 (c) 218 g mol-1 (d) 113 g mol-1
3. How many grams of calcium lactate pentahydrate would be recovered from 1 g of
anhydrous salt:
(a) 141g (b) 1.00 g (c) 1.27g (d) 1.51g
Comprehension 3:
NaBr, used to produce AgBr for use in photography can be self prepared as follows:
Fe + Br2 → FeBr2 ... (i )
FeBr2 + Br2 → Fe3Br8 ... (ii )
Fe3Br8 + Na 2CO3 → NaBr + CO2 + Fe3O4 ... (iii )
How much Fe in kg is consumed to produces 2.06 × 103 Kg NaBr … (iv)
1. Mass of iron required to produces 2.06 × 103 kg NaBr
(a) 420g (b) 420kg (c) 4.2 × 105 kg (d) 4.2 × 108g
2. If the yield of (ii) is 60% & (iii) reaction is 70% then mass of iron required to produces
2.06 × 103 kg NaBr
(a) 105 kg (b) 105 g (c) 103 kg (d) none
3. If yield of (iii) reaction is 90% then mole of CO2 formed when 2.06 × 103 kg NaBr is
formed
(a) 20 (b) 10 (c) 40 (d) none
Comprehension 4:
A monobasic acid of weight 15.5 g is heated with excess of oxygen & evolved gases when
passed through KOH solution increased its weight by 22 g and when passed through anhydrous
CaCl2, increased its weight by 13.5 g. When the same mass of this organic acid is reacted with
excess of silver nitrate solution form 41.75 g silver salt of the acid which on ignition gave the
residue of weight 27 g.
1. The molecular formula of the organic acid is
(a) C2H6 (b) C2H5O2 (c) C2H6O2 (d) C2H4O
2. The molar masses of the acid & its silver salt respectively are:
(a) 60, 168 (b) 167, 60 (c) 60, 167 (d) 168, 60
Comprehension 5:
342g of 20% by mass of Ba(OH)2 solution (sp. gr. 0.57) is reacted with 200 mL of 2M HNO3
according to given balanced reaction :
Ba ( OH )2 + 2HNO3 → Ba ( NO3 )2 + 2H2O
1. The nature of the final solution is :
(a) acidic (b) neutral (c) basic (d) can't say
2. Find the molarity of the iron in resulting solution by which nature of the above solution is
identified is
(a) 0.5 M (b) 0.8 M (c) 0.4 M (d) 1 M
Conceptual Subjective
1. A crystalline hydrated salt on being rendered anhydrous, loses 45.6% of its weight. The
percentage composition of anhydrous salt is : Al = 10.5%, K = 15.1%, S = 24.8% and I =
49.6%. Find the empirical formula of the anhydrous and crystalline salt :
2. A1.85 g sample of mixture of CuCl2 and CuBr2 was dissolved i n water and mixed
thoroughly with 1.8 g portion of AgCl. After reaction, the solid which now contain AgCl
and AgBr was filtered, dried and weighed to be 2.052 g. What was the % by weight of
CuBr2 in the mixture?
3. A mixture of CuSO4.5H2O and MgSO4.7H2O was heated until all the water was driven-
off. If 5.0 g of mixture gave 3 g of anhydrous salts, what was the percentage by mass of
CuSO4.5H2O in the original mixture :
ASSIGNMENT- 1( Abhimanyu-Batch)
Answer Key
Select the Correct Alternative (Only One Correct Answer)
1. (c) 2. (d) 3. (d) 4. (c) 5. (d)
6. (c) 7. (a) 8. (b) 9. (d)
Select the Correct Alternatives (One or More Correct Answers)
1. (a) 2. (a) 3. (b) 4. (b) 5. (d)
6. (d) 7. (b) 8. (c) 9. (b) 10. (b)
11. (c) 12. (d) 13. (a) 14. (a) 15. (a,b)
16. (a,c,d)
Comprehension Based Questions
Comprehension 1:
1. (b) 2. (c) 3. (d)
Comprehension 2:
1. (a) 2. (c) 3. (a)
Comprehension 3:
1. (b) 2. (c) 3. (b)
Comprehension 4:
1. (c) 2. (a)
Comprehension 5:
1. (c) 2. (a)
Conceptual Subjective
1. (KAlS2O8, KAlS2O8.12H2O) 2. (34.18) 3. (74.4)
