The document appears to be a chemistry exam with multiple choice and long answer questions covering various chemistry topics such as atomic structure, chemical reactions, organic chemistry, and industrial processes.
The document appears to be a chemistry exam with multiple choice and long answer questions covering various chemistry topics such as atomic structure, chemical reactions, organic chemistry, and industrial processes.
The document appears to be a chemistry exam with multiple choice and long answer questions covering various chemistry topics such as atomic structure, chemical reactions, organic chemistry, and industrial processes.
The document appears to be a chemistry exam with multiple choice and long answer questions covering various chemistry topics such as atomic structure, chemical reactions, organic chemistry, and industrial processes.
Circle the best alternative to the following questions.
1. Which of the following is also called alpha particles?
a) 2He1 b) He++ c)He+ d) Li+ 2. The oxidation number of oxygen in KO2 is a) +1/2 b)-1/2 c)+1 d)-1 3. 6 g of an element X combine with 16g of another element Y to give 0.5 mol of compound XY. The molecular mass of XY is a) 11 b) 22 c) 44 d) 8 4. Which of the following has highest ionization potential? a) Mg b) Si c) Al d) P 5. Bauxite is an ore of a) Cu b) Al c) Na d)Fe 6. The brown ring test , during qualitative analysis is performed to detect a) Br- b) SO4- - c)NO2- d)NO3- 7. Which of the following is deliquescent? a) CaF2 b) CaCl2 c)NaCl d)KI 8. Caustic soda can be manufactured by a) Solvay-ammonia soda process b) Castner-kellne process c) Down’s process d) Contact process 9. Carbon monoxide is a) Neutral ocide b) Acidic oxide c) Amphoteric ixide d) Basuc oxide 10. IUPAC name of urea is a) Diaminoketone b) 1-Aminoethanamide c) 1-Aminomethanamide d) Aminoacetamide
11. The secondary prefix is used to identify the
a) Nature of bonding b) Number of carbon present in long chain
c) Functional group present in compound d) Substituent present in compound
Group-B [8*5= 40] 1. Define Avogadro’s hypothesis. How would you apply Avogadro’s hypothesis to show the molecular weight of gas is twice of its vapour density? An oxide of nitrogen contains same of its own volume of nitrogen and its vapour density is 54. Determine its molecular formula. [1+2+2] OR
Define coefficient of viscosity. How coefficient of viscosity is related to viscous
force? Why is glycerine more viscous than water? [1+1+1]
Also differentiate between isotropic and anisotropic substances with suitable
examples. [2]
2. X, Y and Z represent element of atomic number 1, 6 and 17 respectively. [1.5+1.5+2]
a) Write the electronic configuration and electronic structure of X, Y and Z. b) What are the values of n, l and m for the outermost electron of Y. c) Write the formula and the lewis structure of covalent compound formed between i) X and Y ii) X and Z 3. 20g of 40% pure CaCO3 if reacted with 5g of HCl to produce CaCl2 , H2O and CO2 a) Find which one is limiting reactant and why? [1.5] b) Calculate the number molecules of reactant left over unreacted. [1] c) How many number of water molecules are produced? [1] d) Calculate the volume of CO2 produced at 27̊C and 0.5 atm pressures? [1.5] 4. Define oxidation and reduction in terms of electronic concept.[1] Given equation is Zn + HNO3 Zn(NO3)2 + N2O + H2O i) Explain with electronic concept which substance is oxidized and which one is reduced.[1] ii) Balance the equation by ion electron or O.N method. [3]
OR
Define law of mass action and equilibrium constant. What is the relation between KP and Kc for following reactions? [1+1+1]
PCl5 (g) PCl3 (g) + Cl2 (g)
What happens when pressure is increased in this equilibrium reaction? [2]
5. Write any two name and formula of ores of each which are applied for: [2+3] i) a. froth floatation b. Leaching ii) What do you mean by leaching? Give reactions involved during leaching of silver ore. 6. Write balanced chemical reactions for the laboratory method of preparation of: [2+1+2] a. Hydrogen sulphide b. sulphur dioxide
What happens when a moist red flower is introduced into a gas jar containing SO2 gas? Give reactions for each to show:
a. SO2 as an oxidizing agent b. H2S as an reducing agent
7. Explain solubility and stability of compounds of alkaline earth metals. :[3+2]
Also mention any two uses of bleaching powder and Epsom salt.
8. What is meant by homologous series? Mention any four characteristics of it and
write down the structural formula and IUPAC name of the third member following homologous series: [1+2+2] a. Alkanal b. alkanol c. Alkanoic acid d. Alkene
Group-C [ 3*8=24] 9. Derive an ideal equation PV=nRT where symbol have their usual meaning. How did Charle’s law give the concept of absolute scale temperature? Plot temperature- volume relationship indicating absolute zero. [3+1+1] The rate of diffusion of a saturated hydrocarbon (CnH2n+2) gas is 1.206 times that of SO2 gas under identical conditions. Find the molecular mass and the molecular formula of this gas. [3] 10. One of the main raw materials for the preparation of nitrogen fertilizers, dyes and drugs is nitric acid, which is obtained by Ostwald’s process. a. Write the principle, process and draw a flow sheet diagram for the manufacture of nitric acid by Ostwald’s process. [3+2] b. Give a one examples of nitrogen fertilizers and how can we prepared it from nitric acid? [1] c. Write the action of aquaregia on gold.[1] d. Why conc.HNO3 is stored in dark brown bottle? [1] OR
Describe the principle involved in the manufacture of sodium carbonate by Solvay-
Ammonia process. Sketch a well-labelled diagram for it. Also mention the function of limestone in the manufacture process. Why do alkali metals impart characteristic colors to flame? How would you convert washing soda into soda ash? Give any two uses of sodium carbonate. [2+2+1+1+1+1]
11. a) What do you mean by foreign element? How would detect nitrogen and halogen in the given organic compound?[1+2+1] b) Write the IUPAC name of following compound:[2] a. (CH3)2C(Br)-CH(NH2)-COOH b. CH3-C(CH3)2-C(OCH3)(OH)-CO-CH3
c.
d. c) Write the structure of following organic compounds:[1] a. 4-hydroxypentanal b. 2-chloro-2,3-dimethylpentane Also define octane number and cetane number [1]
