BOARD OF INTERMEDIATE EDUCATION, KARACHI
H.S.C. Annual Examinations 2021
(MODEL QUESTION PAPER)
CHEMISTRY PAPER-I
Total Duration: 02 Hours Total Marks: 85
SECTION "A" (M.C.Qs) Marks: 43
Note: This section consists of 43 questions. Attempt all M.C.Qs. Each carries 01 marks.
Q1. Choose the correct answers for each from the given options:
1. Rain drops have spherical shape because a sphere has the least
Area Volume
Length Surface to volume ratio
2. The quantities relationship between the substances according to balance equation
describes:
Reversible reaction Stoichiometry
Limiting reactant Percentage compound
3. 870.0 have
Two significant figures Three significant figures
Four significant figures Five significant figures
4. The no. of orbitals in a shell can be determined by the formula
(2l+1) 2(2l+1)
n2 2n2
5. S-2 (Z=16) is isoelectronic with
+1 -1
11Na 9F
+1 +3
19K 13Al
6. The most of the radiations coming out from pitch blend were
Electron Proton
X-rays Neutron
1
7. The bonds present in ethene (C2H4) molecule
Five σbond and one bond Two σ bond and two bond
Three σ bonds and two bonds All σ bonds
8. Which molecule has linear structure:
CH4 NH3
BF3 C2H2
9. Ice floats on top of water because its density is
Lesser than density of water Equal to density of water
Greater than density of water All of them
10. Heat absorbed by a system when its volume does not change is equal to
Internal energy Work done by a system
Increase in internal energy Change in enthalpy of system
11. Which of the following is intensive property of system?
Density Energy
Volume Entropy
12. The product of pressure and volume, PV has the dimension
Pressure Volume
Energy Temperature
13. For the reaction 2NH3 N2+ 3H2 the relationship between Kc and Kp
Kc>Kp Kc<Kp
Kp=Kc Kc
Kp
2
14. Given the equilibrium the PCl5 PCl3 + Cl2 ∆H = +ve
concentration of Cl2 at equilibrium will be increased by
Lowering of temperature Adding PCl3 to the mixture
Adding PCl5 to mixture Increasing pressure
2
15. Which one of the following solution is basic
NH4Cl NaCl
Na2CO3 KCl
2
16. The oxidation number of Cr in Cr2O 7
+3 +6
+12 -2
17. The properties of solution which depends upon the no. of particles of solute are called
Colligative properties Intensive properties
Qualitative properties Physical properties
18. If the rate of reaction is independent of concentration of the reactant the reaction is of
Zero order 1st order
2nd order 3rd order
19. A catalyst is a substance which increase the rate of reaction of chemical reaction,
because
It increases the temperature It increases pressure
It changes the rate constant It lowers the activation energy
20. The branch of chemistry which deals with the study of reaction rates is known as
Photochemistry Chemical kinetics
Thermodynamics Electrochemistry
21. The penetration power of β-particle in air as compare to α-particle is
100 times 2 time
1000 times 200 times
22. A gas at zero kelvin:
Is super cooled freezes liquefies has zero volume
23. The molecular formula of vitamin C is C6H8O6, Its Emperical formula is:
C2H3O2 C3H4O3 CH2O CHO2
3
24. E+PV is called:
Entropy Enthalpy Free Energy Internal Energy
25. The quantum number values for 3p orbitals are:
n=2, l=1, n=3, l=0, n=2, l=2, n=3, l=1,
26. Orbitals having same energy are called:
Hybrid orbitals Degenerate orbitals
Valence orbitals Bonding orbitals
27. The net enthalpy change in a chemical reaction is same, whether it is brough about in
two or more different ways in one or several steps. It is known as:
Henry’s Law Hess’s Law
Joule’s Principle Law of Conservation of energy
28. Which of the following compound does not contain hydrogen bonding
CH4 H2O NH3 HF
29. In a chemical reaction equilibrium is said to have established when:
Concentration of Products and reactants Opposing reaction cease
are equal. Rate of forward reaction is twice as
Rate of Opposing reaction become equal compare to reverse reaction.
30. Which of the following molecules has the largest bond angle:
H2O NH3 CH4 BeCl2
31. The value of R (general gas constant) in S.I Unit is
8.3143 8.3143 0.0821 0.0821 N.m/K.mole
N.m/K.mole N.m/ .mole N.m/ .mole
32. Bohr’s Atomic model is contradicted by:
Planck’s Chadwick Heisenberg Faraday’s Law
Quantum Experiment uncertainty
Theory Principle
4
33. The ⁄ value of electron is :
1.758x108 0.000550 ⁄ 1.008 ⁄ 9.11x10-28 ⁄
⁄
34. The reaction which involves both oxidation and reduction is called:
Addition Redox Elimination Substitution
reaction reaction reaction reaction.
35. The rate of reaction
Increases as the reaction proceeds Remain the same as the reaction
Decreases as the reaction proceeds proceed
May decreases or increases as the reaction
proceed
36. For gaseous system, the value of Kp and Kc are same when:
Reaction occurs at S.T.P reaction is exothermic
Reaction is endothermic No. of moles of products are equal to No. of
moles of reactant.
37. Heat absorbed or released during a chemical process at constant pressure is equal to:
38. Which of the following molecules has two :
CH4 C2H4 N2 O2
39. No two electrons in an atom can have a same set of four quantum number is called
Newton’s first law Pauli Exclusion Principle
Hund’s Rule Aufbau rule
40. Alpha rays are
Neutron Electron Proton Helium Nuclei
41. The surface tension of liquid is independent of:
Temperature Intermolecular forces
Nature of Liquid Amount of Liquid
5
42. The tendency of liquid to cling together is called:
Surface Cohesion Adhesion Viscosity
Tension
43. The No of waves travel per one centimeter distance is :
Wavelength wave no. wave function frequency
Section ‘B’ (Short Answer Questions)
Note: Attempt any five part questions. (Marks = 25)
Q2. (i) 1.367g of an organic compound containing C, H and O was combusted in a stream of
air yield 3.002g CO2 and 1.64g H2O. what is the empirical formula.
(ii) Define the following.
* Significant figure * System * Viscosity * Gay-Lussac Law
(iii) State Boyle’s Law, Charles’s law and prove them in term of Kinetic Molecular Theory.
(iv) Write down the electronic configuration for ground sates of each of the following.
* Cl (Z = 17) * Ca+2 (Z = 20) * Fe (Z = 26) * N-3 (Z = 7)
(v) Differentiate between the following (write only two differences for each).
* Sigma and Pi bond * Hydration and Hydrolysis
(vi)The ratio of rates of diffusion of two gasses A and B is 1.5:1. If the relative molecular
mass of gas A is 16, find out the relative molecular mass of gas B.
(vii) State First Law of Thermodynamic. In a certain process, 500 J of work is done on a
system which gives off 200 J of heat. What is the value of change in Internal energy
for the process.
(viii) Explain the effects of surface area and concentration of reactant on the rate of
reaction.
(ix) Define Dipole moment. Why dipole moment of CO2 and CCl4 is zero.
(x) Predict the effect of increase in temperature and pressure on the following system at
equilibrium state (only predict the direction)
* N2 + 3H2↔2NH3 + Heat * N2 + O2 + Heat ↔2NO
6
SECTION "C" (DETAILED-ANSWER QUESTIONS) (Max Marks: 17)
Note: Attempt any one questions from this section.
Q3 (a) Write the postulates of Bohr’s atomic. Derive the formula for the radius of nth orbit of
hydrogen atom by using Bohr’s atomic model. (9)
(b) Write the postulates of electron pair repulsion theory. Explain the shape of the H2O and
NH3 on the basis of electron pair repulsion theory. (8)
Q4 (a) Define oxidation and reduction. Balance the given equations by ION electron method.
(9)
* Cl2+OH-1 Cl-1 + Cl + H2O (Basic)
* Mn +S MnO2+ S (Acidic)
(b) Explain Arrhenius theory of ionization in detail. Also define indicator with two examples.
(8)
Q5 (a) what are cathode rays? Give the properties of cathode rays and conclusion drawn about
the structure of the atom from this experiment. Also define the construction of discharge
tube. (9)
(b) How Kc is used to predict the extent of a reversible reaction ? Calculate the number of
moles of Cl2 produced at equilibrium when one mole of PCl5 is heated at 250 in
vessel having a capacity of 10dm3 (Kc=0.041) (8)
PCl5 ↔ PCl3 + Cl2
