Safety Data Sheet according to Regulation (EC) No 1907/2006

Hitachi Europe GmbH

JP-K107, 1107K
Revision date: 08.03.2018 Revision No: 1,2
Product code: 00509-0067

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

JP-K107, 1107K
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Printing Ink
1.3. Details of the supplier of the safety data sheet
Company name: Hitachi Europe GmbH
Street: Niederkasseler Lohweg 191
Place: 40547 Duesseldorf, Germany
Telephone: +49 (0) 211-5283-0

Responsible Department: Responsible for the safety data sheet: sds@gbk-ingelheim.de

1.4. Emergency telephone INTERNATIONAL: +49 - (0) 6132 - 84463, GBK GmbH (24h - 7d/w - 365d/a)
number: In England and Wales: NHS 111 In Scotland: NHS 24 - dial 111

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture according to 1272/2008/EC
Hazard categories:
Flammable liquid: Flam. Liq. 2
Serious eye damage/eye irritation: Eye Irrit. 2
Specific target organ toxicity - single exposure: STOT SE 3
Hazard Statements:
Highly flammable liquid and vapour.
Causes serious eye irritation.
May cause drowsiness or dizziness.
2.2. Label elements
Hazard components for labelling
Butanone
Signal word: Danger
Pictograms:

Hazard statements
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 Keep container tightly closed.
P261 Avoid breathing vapours.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.

Print date: 08.03.2018 GB - EN Page 1 of 9

Safety Data Sheet according to Regulation (EC) No 1907/2006
Hitachi Europe GmbH
JP-K107, 1107K
Revision date: 08.03.2018 Revision No: 1,2
Product code: 00509-0067

Special labelling of certain mixtures

EUH066 Repeated exposure may cause skin dryness or cracking.
2.3. Other hazards
According to Regulation (EC) No 1907/2006 (REACH) none of the substances, contained in this
product are a PBT / vPvB substance.
Vapours may form explosive mixture with air.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Ink Jet printing ink in organic solvents.
Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
78-93-3 Butanone 80 - 90 %
201-159-0 606-002-00-3 01-2119457290-43
Flam. Liq. 2, Eye Irrit. 2, STOT SE 3; H225 H319 H336 EUH066
Full text of H and EUH statements: see section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information
Remove contaminated soaked clothing immediately.
Keep warm and calm injured person.
Take away from danger area and lay down affected person .
After inhalation
Move to fresh air in case of accidental inhalation of vapours or decomposition products.
Refer for medical treatment.
After contact with skin
Wash off with soap and plenty of water.
Consult a doctor if skin irritation persists.
After contact with eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Seek medical treatment by eye specialist.
After ingestion
Do not induce vomiting.
Rinse out mouth and give plenty of water to drink.
Never give anything by mouth to an unconscious person.
Summon a doctor immediately.
Induce vomiting only upon the advice of a physician.
4.2. Most important symptoms and effects, both acute and delayed
Causes serious eye irritation.
May cause drowsiness or dizziness.
Repeated exposure may cause skin dryness or cracking.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptoms.

SECTION 5: Firefighting measures

5.1. Extinguishing media

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Safety Data Sheet according to Regulation (EC) No 1907/2006
Hitachi Europe GmbH
JP-K107, 1107K
Revision date: 08.03.2018 Revision No: 1,2
Product code: 00509-0067

Suitable extinguishing media

Alcohol-resistant foam, dry chemical, carbon dioxide (CO2), water-spray.
Unsuitable extinguishing media
Full water jet.
5.2. Special hazards arising from the substance or mixture
Fire may produce:
carbon monoxide and carbon dioxide
5.3. Advice for firefighters
Use breathing apparatus with independent air supply.
Protective suit.
Additional information
Vapours are heavier than air and spread along ground .
The vapour/air mixture is explosive, even in empty, uncleaned receptacles.
Risk of bursting of the receptacle.
Cool containers at risk with water spray jet.
Fire residues and contaminated firefighting water must be disposed of in accordance with the local
regulations.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

In case of vapour formation use respirator.
Ensure adequate ventilation.
Use personal protective clothing.
Keep away sources of ignition.
6.2. Environmental precautions
Do not discharge into the drains/surface waters/ground water.
6.3. Methods and material for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Shovel into suitable container for disposal.
Clean contaminated surface thoroughly.
6.4. Reference to other sections
Observe protective instructions (see Sections 7 and 8).
Information for disposal see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Keep container tightly closed.
Do not breathe vapours.
Use only in thoroughly ventilated areas.
Avoid contact with skin, eyes and clothing.
Advice on protection against fire and explosion
Do not smoke - volatile.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges .
Use only explosion-proof equipment.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed in a dry, cool and well-ventilated place.
Pay attention to anti-explosion rules.
Advice on storage compatibility
Incompatible with oxidizing agents.

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Safety Data Sheet according to Regulation (EC) No 1907/2006
Hitachi Europe GmbH
JP-K107, 1107K
Revision date: 08.03.2018 Revision No: 1,2
Product code: 00509-0067

Further information on storage conditions

Keep away from food, drink and animal feeding stuffs.
7.3. Specific end use(s)
Printing Ink

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

78-93-3 Butan-2-one (methyl ethyl ketone) 200 600 TWA (8 h) WEL

300 899 STEL (15 min) WEL
1333-86-4 Carbon black - 3.5 TWA (8 h) WEL
- 7 STEL (15 min) WEL

Biological Monitoring Guidance Values (EH40)

CAS No Substance Parameter Value Test material Sampling time

78-93-3 Butan-2-one butan-2-one 70 µmol/L urine Post shift

8.2. Exposure controls

Appropriate engineering controls
Ensure adequate ventilation, especially in confined areas.
Protective and hygiene measures
Do not inhale vapours.
Avoid contact with eyes and skin.
Wash hands before breaks and immediately after handling the product .
When using do not eat, drink or smoke.
Take off immediately all contaminated clothing.
Eye/face protection
Tightly fitting goggles (EN 166).
Eye wash bottle with pure water (EN 15154).
Hand protection
Protective gloves resistant to chemicals made off viton , minimum coat thickness 0.7 mm, permeation
resistance (wear duration) approx. 10 minutes, i.e. protective glove < Vitoject 890> made by
www.kcl.de.
This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN
374 carried out under lab conditions.
Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the
recommendations given by the manufacturer of protective gloves.
Skin protection
Long sleeved clothing (EN 368).
Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment (gas filter type A) (EN 14387).

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: Liquid
Colour: Black
Odour: Solvent-like

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Safety Data Sheet according to Regulation (EC) No 1907/2006
Hitachi Europe GmbH
JP-K107, 1107K
Revision date: 08.03.2018 Revision No: 1,2
Product code: 00509-0067

Changes in the physical state

Initial boiling point and boiling range: 80 °C *)
Flash point: - 6,8 °C Closed cup
Lower explosion limits: 1,8 vol. % *)
Upper explosion limits: 11,5 vol. % *)
Ignition temperature: 470 °C
Vapour pressure: 105 hPa *)
Density (at 20 °C): 0,86 g/cm³
Water solubility: 290 g/L *)
(at 20 °C)
Partition coefficient: (n-octanol/water) Log Pow: 0,29 *)
Solvent content: < 90 %
9.2. Other information
*) Butanone

SECTION 10: Stability and reactivity

10.1. Reactivity
No decomposition if stored and applied as directed.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Reactions with oxidizing agents.
10.4. Conditions to avoid
Vapour/air mixtures are explosive at intensive warming.
Heating can release vapours which can be ignited.
10.5. Incompatible materials
Oxidizing agents (strong).
10.6. Hazardous decomposition products
Carbon monoxide and carbon dioxide

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity
Based on available data, the classification criteria are not met.
No toxicological data available.
Butanone
LD50/oral/rat: 2737 mg/kg
LD50/dermal/rabbit: 6480 mg/kg
Irritation and corrosivity
Causes serious eye irritation.
Skin corrosion/irritation: Based on available data, the classification criteria are not met.
Sensitising effects
Based on available data, the classification criteria are not met.
STOT-single exposure
May cause drowsiness or dizziness. (Butanone)
Severe effects after repeated or prolonged exposure
Repeated exposure may cause skin dryness or cracking.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.

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Safety Data Sheet according to Regulation (EC) No 1907/2006
Hitachi Europe GmbH
JP-K107, 1107K
Revision date: 08.03.2018 Revision No: 1,2
Product code: 00509-0067

Aspiration hazard
Based on available data, the classification criteria are not met.
Additional information on tests
Classification in compliance with the assessment procedure specified in the Regulation (EC) no
1272/2008.
Practical experience
Other observations
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.

SECTION 12: Ecological information

12.1. Toxicity
Ecological data are not available.
12.2. Persistence and degradability
Butanone
Readily biodegradable.
12.3. Bioaccumulative potential
Butanone
Low bio-accumulation can be estimated because of low log Po/w. (Log Pow: 0,29)
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
According to Regulation (EC) No 1907/2006 (REACH) none of the substances, contained in this
product are a PBT / vPvB substance.
12.6. Other adverse effects
Low hazard to waters.
Further information
Do not flush into surface water or sanitary sewer system.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal
Where possible recycling is preferred to disposal.
Can be incinerated, when in compliance with local regulations.
Waste disposal number of waste from residues/unused products
080312 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS;
wastes from MFSU of printing inks; waste ink containing hazardous substances; hazardous waste
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal.
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be
taken for reuse.
Contaminated packagings are to be treated like the product itself.

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: UN 1210
14.2. UN proper shipping name: Printing ink
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

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Safety Data Sheet according to Regulation (EC) No 1907/2006
Hitachi Europe GmbH
JP-K107, 1107K
Revision date: 08.03.2018 Revision No: 1,2
Product code: 00509-0067

Classification code: F1
Limited quantity: 5 L / 30 kg
Excepted quantity: E2
Transport category: 2
Hazard No: 33
Tunnel restriction code: D/E
Inland waterways transport (ADN)
14.1. UN number: UN 1210
14.2. UN proper shipping name: Printing ink
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Classification code: F1
Limited quantity: 5 L / 30 kg
Excepted quantity: E2
Marine transport (IMDG)
14.1. UN number: UN 1210
14.2. UN proper shipping name: Printing ink
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Marine pollutant: No
Limited quantity: 5 L / 30 kg
Excepted quantity: E2
EmS: F-E, S-D
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: UN 1210
14.2. UN proper shipping name: Printing ink
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Limited quantity Passenger: 1L

Passenger LQ: Y341
Excepted quantity: E2
IATA-packing instructions - Passenger: 353
IATA-max. quantity - Passenger: 5L
IATA-packing instructions - Cargo: 364
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Safety Data Sheet according to Regulation (EC) No 1907/2006
Hitachi Europe GmbH
JP-K107, 1107K
Revision date: 08.03.2018 Revision No: 1,2
Product code: 00509-0067

IATA-max. quantity - Cargo: 60 L

14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: no
14.6. Special precautions for user
Handle in accordance with good industrial hygiene and safety practice.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
The transport takes place only in approved and appropriate packaging.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
Information according to 2012/18/EU P5c FLAMMABLE LIQUIDS
(SEVESO III):
2004/42/EC (VOC): 75 - 85%
National regulatory information
Water contaminating class (D): 1 - slightly water contaminating
Additional information
Content of RoHS Directive material Cd < 100ppm; Pb, Hg, Hexavalent Cr, PBB, PBDE < 1000ppm.
15.2. Chemical safety assessment
For this substance a chemical safety assessment has not been carried out.

SECTION 16: Other information

Abbreviations and acronyms
ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route
RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses
ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure
IMDG = International Maritime Code for Dangerous Goods
IATA/ICAO = International Air Transport Association / International Civil Aviation Organization
MARPOL = International Convention for the Prevention of Pollution from Ships
IBC-Code = International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
REACH = Registration, Evaluation, Authorization and Restriction of Chemicals
CAS = Chemical Abstract Service
EN = European norm
ISO = International Organization for Standardization
DIN = Deutsche Industrie Norm
PBT = Persistent Bioaccumulative and Toxic
vPvB = Very Persistent and very Bio-accumulative

LD = Lethal dose
LC = Lethal concentration
EC = Effect concentration
IC = Median immobilisation concentration or median inhibitory concentration

Relevant H and EUH statements (number and full text)

H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
EUH066 Repeated exposure may cause skin dryness or cracking.
Further Information
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the
product (in this sense consult information on use and on product), but to liberation of major amounts in
case of accidents and irregularities.

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Safety Data Sheet according to Regulation (EC) No 1907/2006
Hitachi Europe GmbH
JP-K107, 1107K
Revision date: 08.03.2018 Revision No: 1,2
Product code: 00509-0067

The information describes exclusively the safety requirements for the product(s) and is based on the
present level of our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the
legal warranty regulations.
(n.a. = not applicable; n.d. = not determined)

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

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