Safety Data Sheet according to Regulation (EC) No 1907/2006

REMA TIP TOP AG

TIP TOP SOLVENT CF-R4
Revision date: 18.03.2016 Revision No: 2,2
Product code: 00156-0009

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

TIP TOP SOLVENT CF-R4
Art.-No.
595 9118, 595 9125, 595 9132, 595 9156
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Cleaning agent
1.3. Details of the supplier of the safety data sheet
Company name: REMA TIP TOP AG
Street: Gruber Strasse 63
Place: D-85586 Poing
Telephone: +49 (0) 8121 / 707 - 0

Responsible Department: Responsible for the safety data sheet: sds@gbk-ingelheim.de

1.4. Emergency telephone INTERNATIONAL: +49 - (0) 6132 - 84463, GBK GmbH (24h - 7d/w - 365d/a)
number: England and Wales: NHS Direct - 0845 4647; Scotland: NHS 24 - 08454 24 24
24

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture according to 1272/2008/EC
Hazard categories:
Flammable liquid: Flam. Liq. 2
Serious eye damage/eye irritation: Eye Irrit. 2
Specific target organ toxicity - single exposure: STOT SE 3
Aspiration hazard: Asp. Tox. 1
Hazardous to the aquatic environment: Aquatic Chronic 2
Hazard Statements:
Highly flammable liquid and vapour.
May be fatal if swallowed and enters airways.
Causes serious eye irritation.
May cause drowsiness or dizziness.
Toxic to aquatic life with long lasting effects.
2.2. Label elements
Hazard components for labelling
Ethyl acetate
Hydrocarbons, C6-C7, n-alkanes, iso-alkanes, cyclic compounds, < 3% n-hexane
Signal word: Danger
Pictograms:

Hazard statements
H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P261 Avoid breathing vapour.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

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Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
TIP TOP SOLVENT CF-R4
Revision date: 18.03.2016 Revision No: 2,2
Product code: 00156-0009

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.

P331 Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P273 Avoid release to the environment.
Special labelling of certain mixtures
EUH066 Repeated exposure may cause skin dryness or cracking.
2.3. Other hazards
Vapours may form explosive mixture with air.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Preparation solved in petroleum spirit
Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
141-78-6 Ethyl acetate < 75 %
205-500-4 607-022-00-5 01-2119475103-46
Flam. Liq. 2, Eye Irrit. 2, STOT SE 3; H225 H319 H336 EUH066
92062-15-2 Hydrocarbons, C6-C7, n-alkanes, iso-alkanes, cyclic compounds, < 3% n-hexane [Solvent naphta < 35 %
(petroleum)]
926-605-8 01-2119486291-36
Flam. Liq. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H225 H336 H304 H411
Full text of H and EUH statements: see section 16.
Further Information
According to note P to the regulation (EC) no. 1272/2008, "Solvent naphta (petroleum)" is not to be
classified as "carcinogenic" or "mutagen" ingredient because a benzene content (EINECS No.
200-753-7) is below 0.1 % by weight.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information
Remove contaminated soaked clothing immediately.
In the event of persistent symptoms receive medical treatment.
Take away from danger area and lay down affected person .
After inhalation
Move to fresh air in case of accidental inhalation of vapours.
If you feel unwell, seek medical advice.
After contact with skin
Wash off with soap and plenty of water.
Consult a doctor if skin irritation persists.
After contact with eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Consult a physician.
After ingestion
Do not induce vomiting.
Never give anything by mouth to an unconscious person.
Summon a doctor immediately.
Induce vomiting only upon the advice of a physician.

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Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
TIP TOP SOLVENT CF-R4
Revision date: 18.03.2016 Revision No: 2,2
Product code: 00156-0009

4.2. Most important symptoms and effects, both acute and delayed
Causes serious eye irritation.
May be fatal if swallowed and enters airways.
May cause drowsiness or dizziness.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptoms.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media
Alcohol-resistant foam, dry chemical, carbon dioxide (CO2), water-spray.
Unsuitable extinguishing media
Full water jet.
5.2. Special hazards arising from the substance or mixture
Fire may produce:
Carbon monoxide and carbon dioxide
5.3. Advice for firefighters
Use breathing apparatus with independent air supply.
Protective suit.
Additional information
Vapours are heavier than air and spread along ground .
The vapour/air mixture is explosive, even in empty, uncleaned receptacles.
Cool containers at risk with water spray jet.
Fire residues and contaminated firefighting water must be disposed of in accordance with the local
regulations.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

In case of vapour formation use respirator.
Use only explosion-proof equipment.
Avoid contact with skin, eyes and clothing.
Ensure adequate ventilation.
Remove persons to safety.
Keep away sources of ignition.
6.2. Environmental precautions
Do not discharge into the drains/surface waters/ground water.
6.3. Methods and material for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Shovel into suitable container for disposal.
6.4. Reference to other sections
Observe protective instructions (see Sections 7 and 8).
Information for disposal see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Keep container tightly closed.
Vapours are heavier than air and spread along ground .
Use only in thoroughly ventilated areas.
Avoid contact with skin, eyes and clothing.
Advice on protection against fire and explosion
Do not smoke - volatile.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges .
Use only explosion-proof equipment.

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Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
TIP TOP SOLVENT CF-R4
Revision date: 18.03.2016 Revision No: 2,2
Product code: 00156-0009

7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage rooms and vessels
Keep container tightly closed in a dry, cool and well-ventilated place.
Pay attention to anti-explosion rules.
Advice on storage compatibility
Incompatible with strong acids and oxidizing agents.
Further information on storage conditions
Keep away from food, drink and animal feeding stuffs.
7.3. Specific end use(s)
Cleaning agent

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

141-78-6 Ethyl acetate 200 - TWA (8 h) WEL

400 - STEL (15 min) WEL

8.2. Exposure controls

Appropriate engineering controls
Ensure adequate ventilation, especially in confined areas.
Protective and hygiene measures
Do not inhale vapours.
Wash hands before breaks and immediately after handling the product .
When using do not eat, drink or smoke.
Treat subsequently with skin cream.
Remove and wash contaminated clothes before re-use.
Eye/face protection
Tightly fitting goggles (EN 166).
Eye wash bottle with pure water (EN 15154).
Hand protection
Splash protection:
Protective gloves resistant to chemicals made off butyl , minimum coat thickness 0,7 mm, permeation
resistance (wear duration) approx. 120 minutes, i.e. protective glove <Butoject 898> made by
www.kcl.de.
Protective gloves resistant to chemicals made off nitrile , minimum coat thickness 0.4 mm, permeation
resistance (wear duration) approx. 30 minutes, i.e. protective glove < Camatril Velours 730> made by
www.kcl.de.
This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN
374 carried out under lab conditions.
Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the
recommendations given by the manufacturer of protective gloves.
Skin protection
Solvent-resistant apron (EN 467).
Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment (gas filter type A) (EN 14387).

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: Liquid
Colour: Colourless
Odour: Solvent-like

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Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
TIP TOP SOLVENT CF-R4
Revision date: 18.03.2016 Revision No: 2,2
Product code: 00156-0009

Changes in the physical state

Melting point: < - 20 °C
Initial boiling point and boiling range: > 76 °C
Flash point: - 10 °C
Explosive properties The product is considered non-explosive; nevertheless explosive vapour/air
mixture can be generated.
Lower explosion limits: 2,1 vol. %
Upper explosion limits: 11,5 vol. %
Ignition temperature: 460 °C
Oxidizing properties Non oxidizing.
Vapour pressure: 100 hPa
(at 20 °C)
Density (at 20 °C): 0,85 g/cm³
Water solubility: Immiscible
(at 20 °C)
Viscosity / kinematic: < 20,5 mm²/s
(at 40 °C)
Flow time: < 30 s 3 DIN/ISO 2431
Solvent content: 100 %
9.2. Other information
No data available.

SECTION 10: Stability and reactivity

10.1. Reactivity
No decomposition if stored and applied as directed.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Reactions with acids.
Reactions with oxidizing agents.
10.4. Conditions to avoid
To avoid thermal decomposition, do not overheat.
Vapour/air mixtures are explosive at intensive warming.
Heating can release vapours which can be ignited.
10.5. Incompatible materials
Acids and oxidizing agents.
10.6. Hazardous decomposition products
Carbon monoxide and carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity
Based on available data, the classification criteria are not met.
No toxicological data available.
Ethyl acetate
LD50/oral/rat: 5620 mg/kg
LD50/dermal/rabbit: > 18000 mg/kg
LC50/inhalation/rat: 56 mg/l/4 h
Irritation and corrosivity
Causes serious eye irritation.
Skin corrosion/irritation: Based on available data, the classification criteria are not met.
Sensitising effects
Based on available data, the classification criteria are not met.

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Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
TIP TOP SOLVENT CF-R4
Revision date: 18.03.2016 Revision No: 2,2
Product code: 00156-0009

STOT-single exposure
May cause drowsiness or dizziness. (Ethyl acetate ), (Hydrocarbons, C6-C7, n-alkanes, iso-alkanes,
cyclic compounds, < 3% n-hexane [Solvent naphta (petroleum)])
Severe effects after repeated or prolonged exposure
Repeated exposure may cause skin dryness or cracking.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
Aspiration hazard
May be fatal if swallowed and enters airways.
Additional information on tests
Classification in compliance with the assessment procedure specified in the Regulation (EC) no
1272/2008.
Practical experience
Other observations
Inhalation of high vapour concentration may cause symptoms like headache, dizziness, tiredness,
nausea and vomiting.
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties
of the product.

SECTION 12: Ecological information

12.1. Toxicity
Ecological data are not available.
Toxic to aquatic life with long lasting effects.
Hydrocarbons, C6-C7, n-alkanes, iso-alkanes, cyclic compounds, < 3% n-hexane
LC50/EC50/EC50 : 1 - 10 mg/l
Ethyl acetate
LC50/EC50/EC50 : > 100 mg/l
12.2. Persistence and degradability
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
According to Regulation (EC) No 1907/2006 (REACH) none of the substances, contained in this
product are a PBT / vPvB substance.
12.6. Other adverse effects
Hazardous water pollutant.
Further information
Do not flush into surface water or sanitary sewer system.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal
Where possible recycling is preferred to disposal.
Can be incinerated, when in compliance with local regulations.
Waste disposal number of waste from residues/unused products
080117 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS;
wastes from MFSU and removal of paint and varnish; wastes from paint or varnish removal containing
organic solvents or other hazardous substances
Classified as hazardous waste.
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal.

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Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
TIP TOP SOLVENT CF-R4
Revision date: 18.03.2016 Revision No: 2,2
Product code: 00156-0009

Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be
taken for reuse.
Packaging that cannot be cleaned should be disposed of like the product.

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: UN 1263
14.2. UN proper shipping name: Paint related material
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Classification code: F1
Limited quantity: 5 L / 30 kg
Excepted quantity: E2
Transport category: 2
Hazard No: 33
Tunnel restriction code: D/E
Inland waterways transport (ADN)
14.1. UN number: UN 1263
14.2. UN proper shipping name: Paint related material
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Classification code: F1
Limited quantity: 5 L / 30 kg
Excepted quantity: E2
Marine transport (IMDG)
14.1. UN number: UN 1263
14.2. UN proper shipping name: Paint related material (Solvent naphtha (petroleum))
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Marine pollutant: Yes

Limited quantity: 5 L / 30 kg
Excepted quantity: E2
EmS: F-E, S-E
Air transport (ICAO)
14.1. UN number: UN 1263
14.2. UN proper shipping name: Paint related material
14.3. Transport hazard class(es): 3
14.4. Packing group: II

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Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
TIP TOP SOLVENT CF-R4
Revision date: 18.03.2016 Revision No: 2,2
Product code: 00156-0009

Hazard label: 3

Limited quantity Passenger: Y341 / 1 L

Passenger LQ: Y341
Excepted quantity: E2
IATA-packing instructions - Passenger: 353
IATA-max. quantity - Passenger: 5L
IATA-packing instructions - Cargo: 364
IATA-max. quantity - Cargo: 60 L
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: yes

14.6. Special precautions for user

Handle in accordance with good industrial hygiene and safety practice.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
The transport takes place only in approved and appropriate packaging.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
2004/42/EC (VOC): 100 %
National regulatory information
Employment restrictions: Observe restrictions to employment for juvenils according to the 'juvenile
work protection guideline' (94/33/EC). Observe employment restrictions
under the Maternity Protection Directive (92/85/EEC) for expectant or
nursing mothers.
Water contaminating class (D): 2 - water contaminating
15.2. Chemical safety assessment
For this substance a chemical safety assessment has not been carried out.

SECTION 16: Other information

Abbreviations and acronyms
ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route
RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses
ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure
IMDG = International Maritime Code for Dangerous Goods
IATA/ICAO = International Air Transport Association / International Civil Aviation Organization
MARPOL = International Convention for the Prevention of Pollution from Ships
IBC-Code = International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
REACH = Registration, Evaluation, Authorization and Restriction of Chemicals
CAS = Chemical Abstract Service
EN = European norm
ISO = International Organization for Standardization
DIN = Deutsche Industrie Norm
PBT = Persistent Bioaccumulative and Toxic
vPvB = Very Persistent and very Bio-accumulative

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Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
TIP TOP SOLVENT CF-R4
Revision date: 18.03.2016 Revision No: 2,2
Product code: 00156-0009

LD = Lethal dose
LC = Lethal concentration
EC = Effect concentration
IC = Median immobilisation concentration or median inhibitory concentration

Relevant H and EUH statements (number and full text)

H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
EUH066 Repeated exposure may cause skin dryness or cracking.
Further Information
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the
product (in this sense consult information on use and on product), but to liberation of major amounts in
case of accidents and irregularities.
The information describes exclusively the safety requirements for the product(s) and is based on the
present level of our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the
legal warranty regulations.
(n.a. = not applicable; n.d. = not determined)

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

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