Chris Fleming

Cross sections for electron capture by 60–120 keV protons and electron loss from 60–120 keV hydrogen atoms in collisions with molecular hydrogen, methane (CH4), acetylene (C2H2), ethylene (C2H4), ethane (C2H6), propylene (C3H6), and propane (C3H8) have been measured. We found that the capture and loss cross sections depend linearly on the number of carbon atoms and the number of hydrogen

Cross sections for electron capture by 60-120 keV protons and electron loss from 60-120 keV hydrogen atoms in collisions with molecular hydrogen, methane (CH4), acetylene (C2H2), ethylene (C2H4), ethane (C2H6), propylene (C3H6), and propane (C3H8) have been measured. We found that the capture and loss cross sections depend linearly on the number of carbon atoms and the number of hydrogen atoms in the target molecules, as predicted by the simple additivity rule. The success of the additivity rule allowed the extraction of effective electron capture and loss cross sections for atomic hydrogen and atomic carbon targets.

We provide an in-depth and thorough treatment of the validity of the rotating-wave approximation (RWA) in an open quantum system. We find that when it is introduced after tracing out the environment, all timescales of the open system are correctly reproduced, but the details of the quantum state may not be. The RWA made before the trace is more problematic: it results in incorrect values for environmentally-induced shifts to system frequencies, and the resulting theory has no Markovian limit. We point out that great care must be taken when coupling two open systems together under the RWA. Though the RWA can yield a master equation of Lindblad form similar to what one might get in the Markovian limit with white noise, the master equation for the two coupled systems is not a simple combination of the master equation for each system, as is possible in the Markovian limit. Such a naive combination yields inaccurate dynamics. To obtain the correct master equation for the composite system a proper consideration of the non-Markovian dynamics is required.

We revisit the model of a quantum Brownian oscillator linearly coupled to an environment of quantum oscillators at finite temperature. By introducing a compact and particularly well-suited formulation, we give a rather quick and direct derivation of the master equation and its solutions for general spectral functions and arbitrary temperatures. The flexibility of our approach allows for an immediate generalization to cases with an external force and with an arbitrary number of Brownian oscillators. More importantly, we point out an important mathematical subtlety concerning boundary-value problems for integro-differential equations which led to incorrect master equation coefficients and impacts on the description of nonlocal dissipation effects in all earlier derivations. Furthermore, we provide explicit, exact analytical results for the master equation coefficients and its solutions in a wide variety of cases, including ohmic, sub-ohmic and supra-ohmic environments with a finite cut-off.

The dependence of the dynamics of open quantum systems upon initial correlations between the system and environment is an utterly important yet poorly understood subject. For technical convenience most prior studies assume factorizable initial states where the system and its environments are uncorrelated, but these conditions are not very realistic and give rise to peculiar behaviors. One distinct feature is the rapid buildup or a sudden jolt of physical quantities immediately after the system is brought in contact with its environments. The ultimate cause of this is an initial imbalance between system-environment correlations and coupling. In this paper we demonstrate explicitly how to avoid these unphysical behaviors by proper adjustments of correlations and/or the coupling, for setups of both theoretical and experimental interest. We provide simple analytical results in terms of quantities that appear in linear (as opposed to affine) master equations derived for factorized initial states.

We revisit the model of a system made up of a Brownian quantum oscillator under the influence of an external classical force and linearly coupled to an environment made up of many quantum oscillators at zero or finite temperature. We show that the HPZ master equation for the reduced density matrix derived earlier [B.L. Hu, J.P. Paz, Y. Zhang, Phys. Rev. D 45, 2843 (1992)] with coefficients obtained from solutions of integro-differential equations can assume closed functional forms for a fairly general class of spectral densities of the environment at arbitrary temperature and coupling strength. As an illustration of these new results we solve the corresponding master equation and calculate, among other physical quantities, the uncertainty function whose late time behavior can be obtained fully. This produces a formula for investigating the standard quantum limit which is central to addressing many theoretical issues in macroscopic quantum phenomena and experimental concerns related to low temperature precision measurements. We find that any initial state always settles down to a Gaussian density matrix whose covariance is determined by the thermal reservoir and whose mean is determined by the external force. For more general spectra we show that the solution of the master equation can be reduced to solving for the motion of a classical parametric oscillator with parametric frequency determined by the unsolved for master equation coefficients. States in these systems experience evolution that is parametrically similar to the simpler evolution explicitly determined for in the case of Laurent-series spectra.