[go: up one dir, main page]

Gustafsson et al., 2001 - Google Patents

Coordination of (β-N-sulfonylaminoalkyl) phosphines and their analogous arsines to Pd II and Pt II. Application of the Pd-complexes as chiral catalysts in asymmetric …

Gustafsson et al., 2001

Document ID
9066380976110313651
Author
Gustafsson M
Bergqvist K
Frejd T
Publication year
Publication venue
Journal of the Chemical Society, Perkin Transactions 1

External Links

Snippet

Optically active ligands 2 and 3 were synthesised from phenylglycine and the coordination of ligand 2 to PdCl2 (CH3CN) 2 and PtCl2 (C6H5CN) 2 was studied with 1H, 31P and 15N– 1H-HMQC NMR spectroscopy. The results indicated P, O rather than P, N bidentate …
Continue reading at pubs.rsc.org (other versions)

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • C07F15/008Rhodium compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C-Si linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • C07F17/02Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00Asymmetric syntheses
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS

Similar Documents

Publication Publication Date Title
Kuriyama et al. Hemilabile amidomonophosphine ligand− rhodium (I) complex-catalyzed asymmetric 1, 4-addition of arylboronic acids to cycloalkenones
Ohta et al. An anionic Dinuclear BINAP− ruthenium (II) complex: crystal structure of [NH2Et2][{RuCl ((R)-p-MeO-BINAP)} 2 (μ-cl) 3] and its use in asymmetric hydrogenation
Naziruddin et al. Synthesis of rhodium (i) complexes bearing bidentate NH, NR-NHC/phosphine ligands
Albert et al. Resolution of benzylcyclohexylphenylphosphine by palladium (II)− amine metallacycles. A new ligand for asymmetric hydrovinylation
EP1206427B1 (en) Chiral ligands, transition-metal complexes thereof and uses thereof in asymmetric reactions
CN108774263B (en) A kind of synthetic method of allyl phosphine oxide compound
Steenwinkel et al. Hypercoordinate aryltrialkylsilanes and-stannanes and their use in the synthesis of homodinuclear organometallic complexes with a 1, 4-phenylene bridge
Arena et al. Structural control in palladium (II)-catalyzed enantioselective allylic alkylation by new chiral phosphine-phosphite and pyridine-phosphite ligands
Gu et al. Synthesis and structural studies on the chiral phosphine-NHC rhodium and palladium complexes for their performances in the metal-catalyzed reactions
Darcel et al. Direct use of chiral or achiral organophosphorus boranes as pro-ligands for transition metal catalyzed reactions
Cadierno et al. Efficient Synthetic Routes to Terminal γ-Keto− Alkynes and Unsaturated Cyclic Carbene Complexes Based on Regio-and Diastereoselective Nucleophilic Additions of Enolates on Ruthenium (II) Indenyl Allenylidenes
Carmona et al. Chiral phosphinooxazoline− ruthenium (II) and− osmium (II) complexes as catalysts in diels− alder reactions
Carmona et al. Chiral Brønsted Acid Catalysts. Activation of Methyl 3, 3, 3-Trifluoropyruvate by Hydroxymethylpyridine-Containing Half-Sandwich Complexes
Gustafsson et al. Coordination of (β-N-sulfonylaminoalkyl) phosphines and their analogous arsines to Pd II and Pt II. Application of the Pd-complexes as chiral catalysts in asymmetric hydrosilylation of 1, 3-dienes
Esteruelas et al. Synthesis of Novel Organometallic Compounds Containing η1-Carbon Polycyclic Ligands: Condensation of Propargyl Alcohol with the Allenylidene Ligand of [Ru (η5-C5H5)(CC CPh2)(CO)(PPri3)] BF4
Ogasawara et al. Kinetic resolution of planar-chiral ferrocenylphosphine derivatives by molybdenum-catalyzed asymmetric ring-closing metathesis and their application in asymmetric catalysis
Holz et al. Synthesis of Chiral 2, 5‐Bis (oxymethyl)‐Functionalized Bis (phospholanes) and Their Application in Rh‐and Ru‐Catalyzed Enantioselective Hydrogenations
Demir et al. Synthesis of rhodium complexes derived from benzimidazolin-2-ylidene ligands and first used for the addition of arylboron to benzonitriles
CN115490724B (en) Organophosphine compounds based on cyclophane skeleton and uses thereof
Bolm et al. Crystal structure of a new chiral Pd (0)/diphosphine complex and its use in enantioselective allylic alkylations
Aarif et al. Synthesis and X-ray Crystallographic Characterization of (μ-(Diphenylphosphino) phenyl-C 2, P) palladium Bromide. A Novel Tetranuclear Metalated Compound
Vazquez-Garcia et al. Versatile Behavior of the Schiff Base Ligand 2, 5-Me2C6H3C (H) N (2, 4, 6-Me3C6H2) toward Cyclometalation Reactions: C (sp2, phenyl)− H vs C (sp3, methyl)− H Activation
Mino et al. Palladium-catalyzed asymmetric allylic alkylation using chiral hydrazone ligands with ferrocene skeleton
Son et al. Synthesis of planar chiral tricarbonylcyclopentadienylmanganese complexes using a Mn (CO) 3+ transfer reactionElectronic supplementary information (ESI) available: characterization of 2b, 2c, 4, 6, 7, 8 and 9, and a typical procedure for Pd-catalyzed allylic alkylation. See http://www. rsc. org/suppdata/cc/b1/b102693n
JP3789508B2 (en) Optically active asymmetric diphosphine and method for obtaining optically active substance in the presence of the compound