Gu et al., 2014 - Google Patents
Synthesis and structural studies on the chiral phosphine-NHC rhodium and palladium complexes for their performances in the metal-catalyzed reactionsGu et al., 2014
- Document ID
- 18301886629991475321
- Author
- Gu P
- Xu Q
- Shi M
- Publication year
- Publication venue
- Tetrahedron
External Links
Snippet
Diverse chiral rhodium and palladium complexes ligated with phosphine-functionalized N- heterocyclic carbene ligands based on 1, 1′-binaphthyl backbone have been synthesized. The structures of these phosphine-NHC rhodium and palladium complexes have been …
- 239000010948 rhodium 0 title abstract description 35
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Gu et al. | Synthesis and structural studies on the chiral phosphine-NHC rhodium and palladium complexes for their performances in the metal-catalyzed reactions | |
| Ogasawara et al. | 2, 2 ‘-Bis (diphenylphosphino)-1, 1 ‘-biphenyl: New Entry of Bidentate Triarylphosphine Ligand to Transition Metal Catalysts | |
| Li et al. | Chiral 1, 2-cyclohexane-bridged bis-NHC palladium catalysts for asymmetric Suzuki–Miyaura coupling: synthesis, characterization, and steric effects on enantiocontrol | |
| Zhang et al. | Synthesis of planar chiral [2.2] paracyclophane monophosphine ligands and their application in the umpolung allylation of aldehydes | |
| Fu et al. | Biscarbene palladium (II) complexes. Reactivity of saturated versus unsaturated N-heterocyclic carbenes | |
| Tamura et al. | Design and synthesis of chiral 1, 10-phenanthroline ligand, and application in palladium catalyzed asymmetric 1, 4-addition reactions | |
| Shigeng et al. | Synthesis, structure, and catalytic activity of palladium complexes with new chiral cyclohexane-1, 2-based di-NHC-ligands | |
| Kleman et al. | Chiral Rh phosphine–phosphite catalysts immobilized on ionic resins for the enantioselective hydrogenation of olefins in water | |
| Ezzaher et al. | Diiron chelate complexes relevant to the active site of the iron-only hydrogenase | |
| Guo et al. | Palladium, iridium and ruthenium complexes with acyclic imino-N-heterocyclic carbenes and their application in aqua-phase Suzuki–Miyaura cross-coupling reaction and transfer hydrogenation | |
| Allouch et al. | Ferrocenyl (P, N)-diphosphines incorporating pyrrolyl, imidazolyl or benzazaphospholyl moieties: Synthesis, coordination to group 10 metals and performances in palladium-catalyzed arylation reactions | |
| Griebel et al. | Bisbiphenyl Phosphines: Structure and Synthesis of Gold (I) Alkene π-Complexes with Variable Phosphine Donicity and Enhanced Stability | |
| Lee et al. | Synthesis of novel planar chiral ferrocene and cyclopentadienyl manganese tricarbonyl derivatives and their use as chiral ligands in the palladium-catalyzed asymmetric allylic alkylation | |
| Chen et al. | Synthesis, structure, and catalytic activity of a new chiral NHC–iridium (III) complex | |
| Cao et al. | Nickel-catalyzed direct stereoselective α-allylation of ketones with non-conjugated dienes | |
| Lai et al. | Bis-chelate N-heterocyclic tetracarbene Ru (II) complexes: Synthesis, structure, and catalytic activity toward transfer hydrogenation of ketones | |
| Suslov et al. | Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines | |
| Abdellah et al. | Resolution of the atropochiral biminap ligand and applications in asymmetric catalysis | |
| Chapp et al. | Platinum-catalyzed asymmetric alkylation of bis (isitylphosphino) ethane: stereoselectivity reversal in successive formation of two P− C bonds | |
| Jansat et al. | Chiral S, S-donor ligands in palladium-catalysed allylic alkylation | |
| Aydemir et al. | Aminophosphine–palladium (II) complexes: Synthsesis, structure and applications in Suzuki and Heck cross-coupling reactions | |
| Zurawinski et al. | Palladium complexes of a chiral P, C-chelating phosphino-(sulfinylmethyl) phosphonium ylide ligand | |
| Keller et al. | Azetidines as ligands in the Pd (II) complexes series | |
| Demir et al. | Synthesis and catalytic properties of novel ruthenium N-heterocyclic-carbene complexes | |
| Aydemir et al. | Synthesis and characterization of new bis (diphenylphosphino) aniline ligands and their complexes: X-ray crystal structure of palladium (II) and platinum (II) complexes, and application of palladium (II) complexes as pre-catalysts in Heck and Suzuki cross-coupling reactions |