ZA200603717B - Exhaust gas catalyst - Google Patents
Exhaust gas catalyst Download PDFInfo
- Publication number
- ZA200603717B ZA200603717B ZA200603717A ZA200603717A ZA200603717B ZA 200603717 B ZA200603717 B ZA 200603717B ZA 200603717 A ZA200603717 A ZA 200603717A ZA 200603717 A ZA200603717 A ZA 200603717A ZA 200603717 B ZA200603717 B ZA 200603717B
- Authority
- ZA
- South Africa
- Prior art keywords
- amount
- rare earth
- group
- earth metal
- tio
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims description 76
- 238000000034 method Methods 0.000 claims description 38
- 230000008569 process Effects 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 30
- 229910052691 Erbium Inorganic materials 0.000 claims description 24
- 229910052720 vanadium Inorganic materials 0.000 claims description 24
- 229910052771 Terbium Inorganic materials 0.000 claims description 22
- 238000002360 preparation method Methods 0.000 claims description 22
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 21
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 18
- 229910052772 Samarium Inorganic materials 0.000 claims description 17
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 16
- 150000002910 rare earth metals Chemical class 0.000 claims description 16
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 13
- 239000002002 slurry Substances 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 12
- 229910052684 Cerium Inorganic materials 0.000 claims description 10
- 229910052779 Neodymium Inorganic materials 0.000 claims description 10
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical group [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 10
- 229910052727 yttrium Inorganic materials 0.000 claims description 10
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 150000003681 vanadium Chemical class 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 2
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 32
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 27
- 230000000694 effects Effects 0.000 description 25
- 239000010936 titanium Substances 0.000 description 19
- 239000000243 solution Substances 0.000 description 17
- 230000032683 aging Effects 0.000 description 16
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 238000003756 stirring Methods 0.000 description 13
- 239000007789 gas Substances 0.000 description 11
- 239000012071 phase Substances 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
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- 238000001354 calcination Methods 0.000 description 5
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- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 4
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- -1 coppe=r Chemical compound 0.000 description 4
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- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 3
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- 230000010757 Reduction Activity Effects 0.000 description 2
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- 238000004458 analytical method Methods 0.000 description 2
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- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
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- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
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- 241000196324 Embryophyta Species 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 101000798940 Gallus gallus Target of Myb protein 1 Proteins 0.000 description 1
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- 240000000037 Prosopis spicigera Species 0.000 description 1
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- 229910052776 Thorium Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
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- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- SJIMNYNTHDVHGF-UHFFFAOYSA-N acetic acid;erbium;tetrahydrate Chemical compound O.O.O.O.[Er].CC(O)=O.CC(O)=O.CC(O)=O SJIMNYNTHDVHGF-UHFFFAOYSA-N 0.000 description 1
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- 229910052782 aluminium Inorganic materials 0.000 description 1
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
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- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
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- 239000004202 carbamide Substances 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
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- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
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- XAYGUHUYDMLJJV-UHFFFAOYSA-Z decaazanium;dioxido(dioxo)tungsten;hydron;trioxotungsten Chemical compound [H+].[H+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O XAYGUHUYDMLJJV-UHFFFAOYSA-Z 0.000 description 1
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- YBYGDBANBWOYIF-UHFFFAOYSA-N erbium(3+);trinitrate Chemical compound [Er+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O YBYGDBANBWOYIF-UHFFFAOYSA-N 0.000 description 1
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- 239000003546 flue gas Substances 0.000 description 1
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- UDKYUQZDRMRDOR-UHFFFAOYSA-N tungsten Chemical compound [W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W] UDKYUQZDRMRDOR-UHFFFAOYSA-N 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
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- 229910052725 zinc Inorganic materials 0.000 description 1
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Classifications
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
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- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
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- B01D2258/01—Engine exhaust gases
- B01D2258/012—Diesel engines and lean burn gasoline engines
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0183103A AT412846B (de) | 2003-11-13 | 2003-11-13 | Abgaskatalysatorzusammensetzung |
Publications (1)
Publication Number | Publication Date |
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ZA200603717B true ZA200603717B (en) | 2007-11-28 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200603717A ZA200603717B (en) | 2003-11-13 | 2004-11-12 | Exhaust gas catalyst |
Country Status (13)
Country | Link |
---|---|
US (1) | US8716172B2 (de) |
EP (2) | EP1682266B1 (de) |
KR (1) | KR101121184B1 (de) |
CN (1) | CN1917955B (de) |
AT (2) | AT412846B (de) |
BR (1) | BRPI0416597B1 (de) |
CA (1) | CA2545332C (de) |
DE (1) | DE602004030609D1 (de) |
DK (1) | DK1682266T3 (de) |
ES (1) | ES2358020T3 (de) |
MX (1) | MXPA06005460A (de) |
WO (1) | WO2005046864A1 (de) |
ZA (1) | ZA200603717B (de) |
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CN101632922B (zh) * | 2008-07-25 | 2013-09-25 | 中国科学院福建物质结构研究所 | 高可见光催化活性钒钆氧复合氧化物催化剂及其制备方法和用途 |
TWI478767B (zh) * | 2009-04-23 | 2015-04-01 | Treibacher Ind Ag | 用於使廢氣進行選擇性催化還原反應之催化劑組成物 |
US8545796B2 (en) * | 2009-07-31 | 2013-10-01 | Cristal Usa Inc. | Silica-stabilized ultrafine anatase titania, vanadia catalysts, and methods of production thereof |
BR112012026077B1 (pt) | 2010-04-16 | 2024-01-16 | Treibacher Industrie Ag | Composições catalisadoras para redução catalítica seletiva de gases de escapamento, e seu processo de preparação |
JP5490074B2 (ja) * | 2010-12-28 | 2014-05-14 | トヨタ自動車株式会社 | 三酸化硫黄分解用触媒、及び水素生成方法 |
JP5497688B2 (ja) | 2011-05-25 | 2014-05-21 | トヨタ自動車株式会社 | 三酸化硫黄分解用触媒、及び水素生成方法 |
RU2015110285A (ru) * | 2012-08-24 | 2016-10-20 | КРИСТАЛ ЮЭсЭй ИНК. | Материалы носителя катализатора, катализаторы, способы их получения и применения |
KR101284214B1 (ko) | 2012-10-04 | 2013-07-08 | 한국과학기술연구원 | 질소산화물 분해 촉매 및 그 제조 방법 |
EP2719454A1 (de) | 2012-10-11 | 2014-04-16 | Treibacher Industrie AG | Thermostabiler SCR Katalysator auf Vanadiumoxidbasis und Verfahren zu dessen Herstellung |
CN102989467B (zh) * | 2012-12-13 | 2015-08-26 | 中国科学院生态环境研究中心 | 一种氧化钛负载型钒酸铁催化剂、制备方法及其用途 |
CN103263912B (zh) * | 2013-05-27 | 2015-02-04 | 四川中自尾气净化有限公司 | 一种柴油车尾气净化催化剂及其制备方法 |
CN104549218B (zh) * | 2013-10-28 | 2017-12-15 | 中国石油化工股份有限公司 | 用于低碳烷烃脱氢制烯烃的催化剂及其制备方法 |
CN103736497B (zh) * | 2014-01-22 | 2016-01-27 | 无锡威孚力达催化净化器有限责任公司 | 高效处理柴油机尾气中氮氧化物的钒基scr催化剂及其制备方法 |
WO2016188989A1 (en) | 2015-05-26 | 2016-12-01 | Treibacher Industrie Ag | Process for the preparation of titania/metal vanadate based catalyst compositions |
CN109937087A (zh) * | 2016-07-26 | 2019-06-25 | 巴斯夫公司 | 负载型催化剂、整料选择性催化还原(scr)催化剂、其制备方法和氮氧化物脱除方法 |
EP3482824A1 (de) * | 2017-11-14 | 2019-05-15 | Umicore Ag & Co. Kg | Scr-katalysator |
CN108940299A (zh) * | 2018-01-08 | 2018-12-07 | 南京东南工业装备股份有限公司 | 一种柴油机尾气NOx净化钒钛基催化剂及制备方法 |
KR102041127B1 (ko) * | 2018-03-27 | 2019-11-27 | 한밭대학교 산학협력단 | 이산화티탄 결정상을 가지는 단일상의 수소저장용 산화물 및 이의 제조방법 |
CN108435196A (zh) * | 2018-05-02 | 2018-08-24 | 河北国创环境科技有限公司 | 一种内燃机尾气净化用scr脱硝催化剂及制备方法 |
KR102084504B1 (ko) * | 2018-07-19 | 2020-04-23 | 한국과학기술연구원 | 고온용 선택적 질소산화물 환원용 촉매 |
EP3829751A1 (de) * | 2018-07-30 | 2021-06-09 | BASF Corporation | Vanadiumbasierter katalysator zur selektiven katalytischen reduktion |
CN110773191B (zh) * | 2019-09-18 | 2022-09-13 | 上海瀚昱环保材料有限公司 | 脱二噁英协同脱硝的催化剂及其制备方法 |
CN111558394A (zh) * | 2020-05-20 | 2020-08-21 | 佛山科学技术学院 | 一种二氧化钛介孔薄膜材料、制备方法及应用 |
KR102447605B1 (ko) * | 2020-08-28 | 2022-09-28 | 한국에너지기술연구원 | 질소산화물 환원용 촉매, 이의 제조방법, 및 이의 용도 |
CN112717916B (zh) * | 2020-12-30 | 2023-04-28 | 江苏安纳泰环保科技有限公司 | 一种稀土单原子负载二维片状氧化钛复合光催化材料及其制备方法和应用 |
CN114917898B (zh) * | 2022-05-23 | 2024-03-15 | 大唐南京环保科技有限责任公司 | 一种适用于高温烟气的平板式脱硝催化剂及其制备方法和应用 |
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-
2003
- 2003-11-13 AT AT0183103A patent/AT412846B/de not_active IP Right Cessation
-
2004
- 2004-11-12 BR BRPI0416597-7A patent/BRPI0416597B1/pt not_active IP Right Cessation
- 2004-11-12 ES ES04797861T patent/ES2358020T3/es not_active Expired - Lifetime
- 2004-11-12 DK DK04797861.4T patent/DK1682266T3/da active
- 2004-11-12 EP EP04797861A patent/EP1682266B1/de not_active Expired - Lifetime
- 2004-11-12 DE DE602004030609T patent/DE602004030609D1/de not_active Expired - Lifetime
- 2004-11-12 CN CN2004800382797A patent/CN1917955B/zh not_active Expired - Fee Related
- 2004-11-12 CA CA2545332A patent/CA2545332C/en not_active Expired - Fee Related
- 2004-11-12 KR KR1020067009363A patent/KR101121184B1/ko not_active Expired - Fee Related
- 2004-11-12 AT AT04797861T patent/ATE491514T1/de active
- 2004-11-12 EP EP09008903A patent/EP2153895A1/de not_active Withdrawn
- 2004-11-12 US US10/595,795 patent/US8716172B2/en active Active
- 2004-11-12 ZA ZA200603717A patent/ZA200603717B/en unknown
- 2004-11-12 MX MXPA06005460A patent/MXPA06005460A/es active IP Right Grant
- 2004-11-12 WO PCT/EP2004/012860 patent/WO2005046864A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
CN1917955A (zh) | 2007-02-21 |
WO2005046864A1 (en) | 2005-05-26 |
ATA18312003A (de) | 2005-01-15 |
ES2358020T3 (es) | 2011-05-04 |
CA2545332C (en) | 2012-01-17 |
DK1682266T3 (da) | 2011-03-14 |
BRPI0416597B1 (pt) | 2014-05-20 |
DE602004030609D1 (de) | 2011-01-27 |
KR20070004536A (ko) | 2007-01-09 |
BRPI0416597A (pt) | 2007-01-30 |
US8716172B2 (en) | 2014-05-06 |
CN1917955B (zh) | 2011-03-09 |
MXPA06005460A (es) | 2007-01-26 |
US20070129241A1 (en) | 2007-06-07 |
EP1682266A1 (de) | 2006-07-26 |
HK1103675A1 (en) | 2007-12-28 |
EP1682266B1 (de) | 2010-12-15 |
EP2153895A1 (de) | 2010-02-17 |
AT412846B (de) | 2005-08-25 |
KR101121184B1 (ko) | 2012-03-23 |
CA2545332A1 (en) | 2005-05-26 |
ATE491514T1 (de) | 2011-01-15 |
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