ZA200409576B - Standalone ignition subassembly for detonators. - Google Patents
Standalone ignition subassembly for detonators. Download PDFInfo
- Publication number
- ZA200409576B ZA200409576B ZA200409576A ZA200409576A ZA200409576B ZA 200409576 B ZA200409576 B ZA 200409576B ZA 200409576 A ZA200409576 A ZA 200409576A ZA 200409576 A ZA200409576 A ZA 200409576A ZA 200409576 B ZA200409576 B ZA 200409576B
- Authority
- ZA
- South Africa
- Prior art keywords
- subassembly
- ignition
- shell
- detonator
- standalone
- Prior art date
Links
- 238000000034 method Methods 0.000 claims description 14
- 239000003990 capacitor Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000002788 crimping Methods 0.000 claims description 2
- 238000005474 detonation Methods 0.000 claims description 2
- 239000002360 explosive Substances 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims 3
- 238000013016 damping Methods 0.000 claims 2
- 230000005540 biological transmission Effects 0.000 claims 1
- 238000005538 encapsulation Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 6
- UQMRAFJOBWOFNS-UHFFFAOYSA-N butyl 2-(2,4-dichlorophenoxy)acetate Chemical compound CCCCOC(=O)COC1=CC=C(Cl)C=C1Cl UQMRAFJOBWOFNS-UHFFFAOYSA-N 0.000 description 4
- 239000012212 insulator Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000001934 delay Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- NOVLQCYVQBNEEU-UHFFFAOYSA-I [K+].[Zr+4].[O-][Cl](=O)(=O)=O.[O-][Cl](=O)(=O)=O.[O-][Cl](=O)(=O)=O.[O-][Cl](=O)(=O)=O.[O-][Cl](=O)(=O)=O Chemical compound [K+].[Zr+4].[O-][Cl](=O)(=O)=O.[O-][Cl](=O)(=O)=O.[O-][Cl](=O)(=O)=O.[O-][Cl](=O)(=O)=O.[O-][Cl](=O)(=O)=O NOVLQCYVQBNEEU-UHFFFAOYSA-I 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000788 chromium alloy Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B3/00—Blasting cartridges, i.e. case and explosive
- F42B3/10—Initiators therefor
- F42B3/12—Bridge initiators
- F42B3/121—Initiators with incorporated integrated circuit
Landscapes
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- General Engineering & Computer Science (AREA)
- Air Bags (AREA)
Description
SPECIFICATION
STANDALONE IGNITION SUBASSEMBLY FOR DETONATORS
[001] The present invention relates to pyrotechnic detonators, and more particularly, to a standalone ignition subassembly designed for incorporation into detonators.
[0002] The efficient use of explosives in mining operations and the demolition of structures often requires that many charges be placed in a predetermined pattern and detonated in a timed sequence. In general, timed detonation can be accomplished by detonators that use pyrotechnic delays, sequential-type blasting machines, and electronically programmable detonators. Some examples of time-delayed detonators are described in U.S. Patent
Nos. 6,173,651, 6,085,659, 6,079,332, 5,602,360, 5,460,093, 5,435,248, 4,869,170, 4,819,560, 4,730,558, and 4,712,477, the disclosures of which are hereby incorporated by reference herein.
[0003] Such detonators are, however, generally tailored to a specific application, thus precluding the use of interchangeable detonators for a number of applications. Hitherto, it is believed that it has not been conceived to use an interchangeable, standalone ignition subassembly to initiate a veriety of detonators.
CONFIRMATION COPY
. © WO 03/100344 PCT/IB03/02057
[0004] A need exists to provide a standalone ignition subassembly that can be readily incorporated into a variety of detonator shells.
[0005] A separate need exists to provide an ignition subassembly that is protected against vibration and the environment, so as to permit convenient handling and transportation of the oo subassembly.
[0006] Fig. 1 is a side sectional view of an embodiment of the present invention.
[0007] Fig. 2 is a top sectional view of an alternate embodiment of the present invention. (0008] Fig. 3 is an exploded side and sectional view showing how an embodiment of the present invention such as that shown in
Figs. 1 or 2 fits into a loaded detonator shell.
[0009] Fig. 4 is a side view of an alternate embodiment of the present invention having an alternate outer surface to that of the embodiment shown in Fig. 3.
[0010] Fig. 5 is a side sectional view of an alternate embodiment of the present invention incorporating an off-the- shelf capacitor, with this embodiment inserted in a loaded shell and crimped in place with a plug. 2
AMENDED SHEET
(oo) Fig. 6 is a side sectional view of another alternate : _ embodiment similar to that shown in Fig. 5, with the off-the- shelf cepacitor in a different configuration.
DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT! (oor2] Referring to Figs. 1 and 2, an ignition subassembly 8 of an embodiment of the present invention, and an alternate embodiment B’, are shown. As shown in Fig. 3, such a subassembly is placed inside of a shell 40 that may contain a primary charge 36 and a base charge 38 loaded into its closed end. {A detonator shell is typically a metal cylinder 6 to 8 mm. in diameter and from 60-100 mm. in length). Subassembly 8 can then be secured in place in the shell 40, such as by placing an elastomeric plug or the like (see elastomeric plug 46 and crimp 47 in Figs. 5 and 6) in the open end of the shell and crimping the shell 40 to the plug, or other suitable method.
Subassembly 8 may have a body portion 32 formed of an ' The present description incorporates by reference in full the disclosures of the following copending applications filed herewith: “DETONATOR UTILIZING FEATURES OF AUTOMOTIVE AIRBAG
INITIATORS, ” by John J. Walsh, David MM. Forman, Abrar A.
Tirmizi, and Gloria Vawter (Express Mail No. EU124494852US), “DETONRTOR WITH AN IGNITION ELEMENT HAVING A TRANSISTOR-TYPE
SEALED FEEDTHROUGH,” by David M. Forman and John H. Oldham (Express Mail fo. EU124495272US), and “DETONATOR WITH ONBOARD
ELECTRONICS MECHRNICRLLY CONNECTED TO IGHITION ELEMENT” (Express mail No. EU1Z4495€22US), each of which zpplications is assigned
Ic the éssignee cf the present suplication.
encapsulation 31 and may have ridges 57 protruding out from the outer surface of body portion 32, so as to snugly hold subassembly 8 within the shell 40. Such ridges 57 or other protuberances such as nubs 57' shown in Fig. 4 are preferably formed to dampen vibrations to which the detonator may be subjected, generally in eccordance with the teachings of U.S.
Patent No. 6,078,332.
[0013] The material for encapsulation 31 is preferably chosen to af*ord economical material and manufacturing costs, desirable electrical isolation and vibration and environmental protection for the encapsulated circuitry (including desirable modulus of elasticity, et cetera, as generally taught in U.S. Patent No. 6,079,332), adequate physical integrity and holding and securing of the subassembly’s components, and a lack of chemical volatility with other materials comprising the detonator. At least three processes may be used, including insert molding with thermoplastics, hot-melt molding (similar to glue-gun technology), and reactive injection molding (RIM, a 2-part mix and injection with low temperatures and pressures). Insert molding is a preferable technique, and preferred encapsulation materials for use in that technique are polypropylene, polyurethane, or polyethylene, although polystyrene, polyester, polyamide, and polyolefin can also pe considered depending on the epplicaticn. The preferrsd encapsulation marsriels for use in the notmelt technique are polyamides, but polypropylene, polyurethane, polyester, polyolefin, EVA, acrylic, end silicone can also be considered cepending on the sppliication.
The preferred encepsulation materials for use in the RIM technique are poyurethane-based materials.” Some relevant teachings : — regarding encapsulation are also set forth in U.S.
Patent Nos. £,079,332 and 4,869,170. . [00It] Although a standalone ignition subassembly according to the present invention may include any kind of suitable ignition element (e.g., matchhead-type) as long as it is hermetically sealed and protected from the environment, a header-based, or automotive airbag initiator-style, ignition element 28 is employed in the preferred embodiments shown in the Figures.
As will be appreciated, such an ignition element lends itself to hermetic sealing because it includes an integral, rigid charge can and header that hermetically seals the charge in an enclosure.
U.S.
Patent Nos. 6,274,252, 5,709,724, 5,639,986, 5,602,359, 5,596,163, 5,404,263, 5,140,906, and 3,971,220 are also hereby incorporated by reference herein for their disclosure concerning the construction of ignition elements based on a glass-to-metral sealed header feedthrough. (0015] As shown ir Figs. 1 énd 2, ignition element 28 (and 28’) irc lucdes a header assembly wits a sealed electrical feedthrough, comprising an eyelet 10 (preferebly stainless steel), insulator glass 14 (preferably a glass such as a sodasilicate, e.g., 9010, thet is chosen to form & ccmpression seal with the eyelet and center pin, or less preferebly a matched sezl), a center pin 18 (preferably en iron nickel elloy), a ground pin 20, and an igniter wire 12 (preferably a low energy igniter wire with a diameter of 10 to 20 microns). The ignition element 28 further preferably includes a charge can 26 that is preferably metallic and hermetically sealed to the eyelet at circumferential through-weld 16, with an ignition charge contained between the can 26 and upper surface of the header, in tight contact with igniter wire 12. An insulator cup 27 may preferably be attached around the can 26 so that, except for female connectors 52 that protrude from the input end of the subassembly, the entire cuter surface of ignition subassembly 8 consists of insulating material, thus providing electrical isolation and vibration and environmental protection to the components within.
Pins are inserted and crimped within female connectors 52.
006] In the depicted embodiment, a circuit board 24 and slectronic components 25 may be provided within ignition subassembly 8, to provide a means of triggering ignition of the .gnition element based on the processing of an electrical .gnition signal received by connectors 52, which are :lactrically connected to a blasting machine or the like that .0WErs the detonator.
Such slescironic components are well-known and preferably include means for imparting a programmable period cf delay to the ignition, means for ESD and RF protection, et cetera. Circuit board 24 and electronic components 25 are preferably encapsulsted together in encepsuletion 31, end connected to pins 18 and 20 at contacts 22 through soldering or . other suitable connection. Referring to Fig. 2, as is well- ynown in encapsulated automotive airbag initiators, retention of the ignition element 28 to the encapsulation 31 may be enhanced by providing a lip 17 at the bottom of the eyelet 10’. The insulator cup 27’ may also be held within the encapsulation 31 to facilitate its retention as well, and the can may also have 2 lip (not shown) as another retention feature.
[0017] Figs. 5 and 6 illustrate two alternate configurations for the electronics encapsulated within the alternate ignition subassemblies 8a and 8b. In these configurations, an off-the- shelf cylindrical capacitor 42 is contained within the encapsulation 31, either between the input leads 48 and circuit board 24a as shown in Fig. 5, or between the circuit board 24a and the ignition element 28 as shown in Fig. 6. As shown in
Fig. 5, in order to accommodate the capacitor 42 within the diameter of the encapsulation 31 (which is determined by the inner diameter of the type of detonator shell with which the ignition subassembly is to be compatible), thin, flat flexible jumpers 44 cen be provided, &nd the &xis of the capacitor 42 slightly offset from the axis of the subassembly Ba. Similarl: és shown in Fig. 6, flexible jumper 60 can traverse the length of cepacitor 42, and the leeds to capecitor 42 cen be soldered to the circuit board 24 at through-mounts (as can one or both o the eads of flexible jumper 60).
[0018] By way of example, in an embodiment like that shown in .
Figs. 1 and 2, it has been found that a nickel/chromium alloy, 13 micron diameter, 0.7mm long igniter wire, and a 50 mg ignition charge of zirconium potassium perchlorate having a neight of 1.0mm and a diameter of 4.8mm, is capable of reliably detonating all commonly used primary charges. Preferably, a minimum suitable charge is approximately 30 mg for a configuration of this size, as a4 smaller charge may result in an insufficient charge thickness. A preferred all-fire voltage is 6 volts, and in this embodiment, may be delivered with a 100 microfarad capacitor included in the electronic components 25. (0019) It should be noted that although the Figures depict embodiments including electronic components that receive, process, and deliver an ignition signal, such an ignition signal may alternately be received, processed, and delivered Dy a number of other well-known non-electronic or partly-electronic ms=ans, such as through the use of a shock tube to deliver an ignition signal to a piezoelectric device, column fuse delays, etl cetera. It is noted that this detailed dascription of
© WO 03/100344 PCT/1B03/02057 certain embodiments herein does not imply that such alternate embodiments are not within the scope of the invention.
[0020] A preferred embodiment of a standalone ignition subassembly designed for ready incorporation into pyrotechnic detonators, and many of its attendant advantages, has thus been disclosed. It will be apparent, however, that various changes may be made in the form, construction, and arrangement of the parts without departing from the spirit and scope of the invention, the form hereinbefore described being merely a preferred or exemplary embodiment thereof. Therefore, the invention is not to be restricted or limited except in accordance with the following claims. "Comprises/comprising"” when used in this specification is taken to specify the presence of stated features, integers, steps or components but does not preclude the presence or addition of one or more other features, integers, steps or components or groups thereof. 9
AMENDED SHEET
Claims (1)
- hat is claimed is:. bh stendalone icnition subsssembpy for use in a detonator that includes a shell and a detonetor charge within seid shell, said ignition subassembly having a substantially oo cylindrical body with an initietor end and a trigger end, and comprising: a) 8 body portion having an outer diameter selected to closely match the inner diameter of a standard detonator shell; b) 2 hermetically sealed ignition element at said initiator end; and, c) a trigger means for causing said ignition element to ignite in response to an ignition signal, at least a portion of said trigger means being at said trigger end. The subassembly of claim 1, wherein said ignition element includes an ignition charge having an explosive energy sufficient to cause the detonation of a selected range of detonator charges when said ignition subassembly is secured in the detonator shell and said ignition element is ignited. The subassembly of claim 1, wherein said ignition element includss a charge enclosure that is hermetically sealed and substentially filled with &n ignition charge.4. The subassembly of claim 3, wherein said ignition element includes a glass-to-metal header having a sealed feedthrough, and further includes a metallic can around said ignition charge.5. Tre subassembly of claim 1, wherein said body portion includes e polymer encapsulating at least a portion of said trigger means.6. The subassembly of claim 1, wherein said trigger means includes electronics for processing said ignition signal.7. The subassembly of claim 6, wherein said electronics include a circuit board having electrical components.8. The subassembly of claim 7, wherein said electronics ’ further include an off-the-shelf cylindrical capacitor that is substantially aligned with said circuit board.9. The subassembly of claim 6, wherein said body portion includes a polymer encapsulating said circuit board and electrical components.10. The subassembly of claim 8, wherein said trigger means includes one or more electrical leads protruding out through said polymer at said trigger end.11. The subassembly of claim 1, wherein said detonator charge comprises a primary cherge and 2 bese cnarge.12. The subassembly of claim 10, wherein said one or more electrical leads includes a female adapter formed to securely receive the end of a pin or straight wire.13. The subassembly of claim 1, wherein said body portion includes a vibration damping feature to reduce the transmission of vibrations from said shell into said trigger means and ignition element when said standalone ignition subassembly is secured within the shell.4. The subassembly of claim 13, wherein said vibration damping feature includes one or more protuberances made of a poylmer and formed in the shape of nubs or ridges distributed on the outer surface of said body portion.5. The subassembly of claim 14, wherein said protuberances are distributed on the outer surface of said body portion in a circular, longitudinal, or spiral pattern.6. A method of making a standalone ignition subassembly for use with a detonator shell having a standard inner shell diameter and a detonator charge within said shell, comprising the following steps: :a) providing s hermetically sealed ignition element including a charge enclosure thst is hermetically sealed 5nd substantielly filled with an ignition cherge;b) providing e substancielly cylindrical body portion having first and second ends, and an outer diameter selected to closely match the detonator shell’s standard inner shell diameter:~) attaching said ignition element to the first end of said hody portion; and,d) providing a trigger means for causing said ignition : element to ignite in response to an ignition signal, and locating at least a portion of said trigger means at said second end of said body portion.The method of claim 16, wherein step d) includes the step of providing electronics for processing said ignition signal.The method of claim 17, wherein step b} includes the step of encapsulating said electronics.A method of making a decounator, comprising the following steps: sz) selecting a standard deroneter shell heving e detonetor charge end & precelécmined inner dlemeter;© WO 03/100344 PCT/1B03/02057 b) providing a standalone iginition subassembly having a hermetically sealed ignition element and a cylindrical body portion with an outer diameter selected to closely match said predetermined inner diameter of said detonator shell; c) pushing said standalone ignition subassembly into said -shell; and, d) securing said standalone iginition subassembly within said shell.20. The method of claim 19, wherein step d) includes the step of inserting a body plug into said shell and crimping said shell to said body plug.21. The standalone ignition subassembly including any new and inventive integer or combination of integers, substantially as herein described.22. The standalone ignition subassembly according to the invention, as hereinbefore generally described.23. The standalone ignition subassembly as specifically described with reference to or as illustrated in the accompanying drawings. 14 AMENDED SHEET° WO 03/100344 PCT/IB03/0205724. The method according to the invention for making a : standalone ignition subassembly, substantially as hereinbefore described and exemplified.25. The method for making a standalone subassembly including any new and inventive integer or combination of integers, substantially as herein described.26. The method according to the invention for making a detonator, substantially as hereinbefore described and exemplified.27. The method for making a detonator including any new and inventive integer or combination of integers, substantially as herein described. AMENDED SHEET
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/158,529 US20030221577A1 (en) | 2002-05-29 | 2002-05-29 | Standalone ignition subassembly for detonators |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200409576B true ZA200409576B (en) | 2005-10-12 |
Family
ID=29582705
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200409576A ZA200409576B (en) | 2002-05-29 | 2004-11-26 | Standalone ignition subassembly for detonators. |
Country Status (5)
Country | Link |
---|---|
US (1) | US20030221577A1 (en) |
EP (1) | EP1509743A1 (en) |
AU (1) | AU2003232382A1 (en) |
WO (1) | WO2003100344A1 (en) |
ZA (1) | ZA200409576B (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7107908B2 (en) * | 2003-07-15 | 2006-09-19 | Special Devices, Inc. | Firing-readiness diagnostic of a pyrotechnic device such as an electronic detonator |
EP2583052B1 (en) * | 2010-06-18 | 2016-11-16 | Battelle Memorial Institute | Non-energetics based detonator |
US12203350B2 (en) | 2013-07-18 | 2025-01-21 | DynaEnergetics Europe GmbH | Detonator positioning device |
CN110260729B (en) * | 2019-07-04 | 2024-04-19 | 广西金建华民用爆破器材有限公司 | Electronic detonator assembly production line |
CN111238318A (en) * | 2020-02-21 | 2020-06-05 | 北京凯米迈克科技有限公司 | Reinforced electronic ignition part and electronic detonator thereof |
CN113375612B (en) * | 2021-06-10 | 2022-06-10 | 南京理工大学 | Device and method for testing critical boost size of explosive based on 3D inkjet charge |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3533389A1 (en) * | 1984-11-02 | 1986-06-05 | Dynamit Nobel Ag, 5210 Troisdorf | Electronic explosive time fuze |
CA1332960C (en) * | 1988-09-29 | 1994-11-08 | Kenichi Aiko | Electronic delayed detonator |
US5140906A (en) * | 1991-11-05 | 1992-08-25 | Ici Americas, Inc. | Airbag igniter having double glass seal |
US6274252B1 (en) * | 1994-08-04 | 2001-08-14 | Coors Ceramics Company | Hermetic glass-to-metal seal useful in headers for airbags |
CN1074830C (en) * | 1995-12-06 | 2001-11-14 | 澳瑞凯炸药技术有限公司 | Electronic explosives initiating device |
US5912428A (en) * | 1997-06-19 | 1999-06-15 | The Ensign-Bickford Company | Electronic circuitry for timing and delay circuits |
-
2002
- 2002-05-29 US US10/158,529 patent/US20030221577A1/en not_active Abandoned
-
2003
- 2003-05-28 AU AU2003232382A patent/AU2003232382A1/en not_active Abandoned
- 2003-05-28 EP EP03755251A patent/EP1509743A1/en not_active Withdrawn
- 2003-05-28 WO PCT/IB2003/002057 patent/WO2003100344A1/en not_active Application Discontinuation
-
2004
- 2004-11-26 ZA ZA200409576A patent/ZA200409576B/en unknown
Also Published As
Publication number | Publication date |
---|---|
AU2003232382A1 (en) | 2003-12-12 |
WO2003100344A1 (en) | 2003-12-04 |
US20030221577A1 (en) | 2003-12-04 |
EP1509743A1 (en) | 2005-03-02 |
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