YU38504A - Postupak reagovanja ugljen monoksida sa reaktanom koji je podložan karbonilaciji i/ili njegovim estarskim derivatom - Google Patents
Postupak reagovanja ugljen monoksida sa reaktanom koji je podložan karbonilaciji i/ili njegovim estarskim derivatomInfo
- Publication number
- YU38504A YU38504A YU38504A YU38504A YU38504A YU 38504 A YU38504 A YU 38504A YU 38504 A YU38504 A YU 38504A YU 38504 A YU38504 A YU 38504A YU 38504 A YU38504 A YU 38504A
- Authority
- YU
- Yugoslavia
- Prior art keywords
- carbon monoxide
- ester derivative
- reacting carbon
- carbonylatable reactant
- gas
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title 1
- 229910002091 carbon monoxide Inorganic materials 0.000 title 1
- 150000002148 esters Chemical class 0.000 title 1
- 239000000376 reactant Substances 0.000 title 1
- 238000005810 carbonylation reaction Methods 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 3
- 230000006315 carbonylation Effects 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 1
- 230000001172 regenerating effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/573—Separation; Purification; Stabilisation; Use of additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Confectionery (AREA)
- Alcoholic Beverages (AREA)
- Dairy Products (AREA)
Abstract
Pronalazak se odnosi na postupak za regenerisanje jednog proizvoda karbonilacije iz tečne kompozicije iridijumom katalizovane reakcije karbonilacije, koji obuhvata izlaganje kompozicije isparavanju sa ili bez dovođenja toplote da bi se proizvela jedna gasna i jedna tečna frakcija, pri čemu gasna frakcija sadrži proizvod karbonilacije, a tečna frakcija ima koncentraciju vode od najmanje 0,5 mas.% da bi se stabilisao iridijumski katalizator.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB939306409A GB9306409D0 (en) | 1993-03-26 | 1993-03-26 | Process |
Publications (2)
Publication Number | Publication Date |
---|---|
YU38504A true YU38504A (sh) | 2004-07-15 |
YU49305B YU49305B (sh) | 2005-06-10 |
Family
ID=10732866
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
YU14594A YU49301B (sh) | 1993-03-26 | 1994-03-25 | Postupak za regenerisanje proizvoda karbonilacije |
YU38504A YU49305B (sh) | 1993-03-26 | 1994-03-25 | Postupak reagovanja ugljen monoksida sa reaktantom koji je podložan karbonilaciji i/ili njegovim estarskim derivatom |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
YU14594A YU49301B (sh) | 1993-03-26 | 1994-03-25 | Postupak za regenerisanje proizvoda karbonilacije |
Country Status (21)
Country | Link |
---|---|
US (2) | US5750007A (sh) |
EP (2) | EP0786447B1 (sh) |
JP (2) | JP4233122B2 (sh) |
KR (1) | KR100288997B1 (sh) |
CN (2) | CN1047588C (sh) |
BR (1) | BR9401281A (sh) |
CA (1) | CA2119609C (sh) |
DE (2) | DE69406167T2 (sh) |
ES (2) | ES2153138T3 (sh) |
FI (1) | FI941395A (sh) |
GB (1) | GB9306409D0 (sh) |
ID (1) | ID16946A (sh) |
IN (2) | IN188047B (sh) |
MY (1) | MY121550A (sh) |
NO (1) | NO300768B1 (sh) |
NZ (1) | NZ260174A (sh) |
RU (1) | RU2133731C1 (sh) |
SG (2) | SG46155A1 (sh) |
TW (1) | TW268939B (sh) |
UA (2) | UA41279C2 (sh) |
YU (2) | YU49301B (sh) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9306409D0 (en) * | 1993-03-26 | 1993-05-19 | Bp Chem Int Ltd | Process |
FR2703351A1 (fr) * | 1993-03-31 | 1994-10-07 | Rhone Poulenc Chimie | Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base de rhodium et d'iridium. |
EP0759022B1 (fr) * | 1994-05-13 | 2000-01-26 | Acetex Chimie | Procede de preparation d'acides carboxyliques ou des esters correspondants en presence d'un catalyseur a base d'iridium et d'iodures sous forme soluble |
GB9503385D0 (en) * | 1995-02-21 | 1995-04-12 | Bp Chem Int Ltd | Process |
US5696284A (en) * | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
ES2154421T3 (es) * | 1995-11-03 | 2001-04-01 | Ineos Acrylics Uk Ltd | Reacciones de carbonilacion. |
US5831120A (en) * | 1996-11-19 | 1998-11-03 | Watson; Derrick John | Process for the production of acetic acid |
GB9626324D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
GB9626317D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
GB9626428D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
GB9816385D0 (en) | 1998-07-29 | 1998-09-23 | Bp Chem Int Ltd | Process |
GB9819079D0 (en) | 1998-09-03 | 1998-10-28 | Bp Chem Int Ltd | Carbonylation process |
GB9819606D0 (en) | 1998-09-08 | 1998-11-04 | Bp Chem Int Ltd | Carbonylation process |
US6552221B1 (en) | 1998-12-18 | 2003-04-22 | Millenium Petrochemicals, Inc. | Process control for acetic acid manufacture |
FR2795410B1 (fr) * | 1999-06-22 | 2002-12-27 | Acetex Chimie | Procede pour ameliorer la stabilite et/ou eviter la desactivation du catalyseur lors de la fabrication d'acide acetique et/ou d'acetate de methyle |
DE19946545B4 (de) | 1999-09-28 | 2006-05-04 | W.C. Heraeus Gmbh | Verfahren zur Herstellung von Tris(acetylacetonato)iridium(III) |
GB9926855D0 (en) * | 1999-11-12 | 2000-01-12 | Bp Chem Int Ltd | Process |
NL1013682C2 (nl) * | 1999-11-26 | 2001-05-30 | Purac Biochem Bv | Werkwijze en inrichting voor het zuiveren van een waterige oplossing van melkzuur. |
JP5069827B2 (ja) | 2001-02-28 | 2012-11-07 | 株式会社ダイセル | 反応制御方法および制御装置 |
JP4245298B2 (ja) | 2002-02-27 | 2009-03-25 | ダイセル化学工業株式会社 | 気体反応成分の供給制御方法および制御装置 |
GB0212974D0 (en) * | 2002-06-06 | 2002-07-17 | Bp Chem Int Ltd | Process |
GB0213485D0 (en) * | 2002-06-12 | 2002-07-24 | Bp Chem Int Ltd | Process |
CA2496839A1 (en) | 2004-07-19 | 2006-01-19 | Woodland Chemical Systems Inc. | Process for producing ethanol from synthesis gas rich in carbon monoxide |
CN100363321C (zh) * | 2005-12-29 | 2008-01-23 | 西南化工研究设计院 | 甲醇低压羰基合成醋酸工艺中的精馏方法 |
CA2682778C (en) * | 2006-04-05 | 2017-03-07 | Woodland Biofuels Inc. | System and method for converting biomass to ethanol via syngas |
DE102007014914B4 (de) | 2007-03-26 | 2013-09-12 | Heraeus Precious Metals Gmbh & Co. Kg | Katalytisch hochwirksame Edelmetall-Carboxylat-Verbindungen von Ir, Ru, Rh, Pd, Pt und Au |
US7902397B2 (en) * | 2007-10-11 | 2011-03-08 | Celanese International Corporation | Method and apparatus for making acetic acid with improved productivity |
EP2093209A1 (en) | 2008-02-19 | 2009-08-26 | BP Chemicals Limited | Process for the production of acetic acid |
US7820855B2 (en) | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
WO2012014393A1 (en) | 2010-07-26 | 2012-02-02 | Daicel Chemical Industries, Ltd. | Process for producing acetic acid |
CN103370300B (zh) * | 2010-12-15 | 2016-07-06 | 株式会社大赛璐 | 乙酸的制备方法 |
AR094541A1 (es) * | 2013-01-25 | 2015-08-12 | Daicel Corp | Procedimiento para producir ácido carboxílico |
US10464871B2 (en) | 2013-12-24 | 2019-11-05 | Bp P.L.C. | Process for the production of ethanol by hydrogenation of methyl acetate |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA837644A (en) * | 1970-03-24 | E. Paulik Frank | Production of carboxylic acids and esters | |
GB203385A (en) * | 1922-06-06 | 1923-09-06 | John Edward Thornton | Improved spindle for winding yarns |
SE364254B (sh) * | 1967-04-05 | 1974-02-18 | Monsanto Co | |
SE364255B (sh) * | 1967-04-05 | 1974-02-18 | Monsanto Co | |
US3772380A (en) * | 1970-03-12 | 1973-11-13 | Monsanto Co | Production of carboxylic acids and esters |
US3845121A (en) * | 1971-11-10 | 1974-10-29 | Monsanto Co | Process for separating carbonylation products from reaction mixture without catalyst decomposition |
US4102922A (en) * | 1974-12-30 | 1978-07-25 | Monsanto Company | Purification of carbonylation products |
US4008131A (en) * | 1975-12-11 | 1977-02-15 | Monsanto Company | Purification of acetic acid |
DE3149092A1 (de) * | 1981-12-11 | 1983-06-16 | Hoechst Ag, 6230 Frankfurt | Verfahren zur abtrennung des katalysatorsystems aus reaktionsgemischen von carbonylierungsreaktionen |
GB8319184D0 (en) * | 1983-07-15 | 1983-08-17 | Bp Chem Int Ltd | Carboxylic acids |
US5026908A (en) * | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
JPH0615489B2 (ja) * | 1985-12-20 | 1994-03-02 | ダイセル化学工業株式会社 | 酢酸と無水酢酸の同時製造法 |
CA1299195C (en) * | 1986-06-16 | 1992-04-21 | G. Paull Torrence | Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol |
DE3806304A1 (de) * | 1988-02-27 | 1989-09-07 | Basf Ag | Verfahren zur reinigung von aldehyde, acetale und/oder ungesaettigte verbindungen enthaltenden carbonsaeureestern |
GB8904125D0 (en) * | 1989-02-23 | 1989-04-05 | British Petroleum Co Plc | Process for preparing carboxylic acids |
CA2035426A1 (en) * | 1990-02-09 | 1991-08-10 | David W. Smith | Catalytic carbonylation process |
GB9106298D0 (en) * | 1991-03-25 | 1991-05-08 | Bp Chem Int Ltd | Process |
GB9120902D0 (en) * | 1991-10-02 | 1991-11-13 | Bp Chem Int Ltd | Purification process |
GB9211671D0 (en) * | 1992-06-02 | 1992-07-15 | Bp Chem Int Ltd | Process |
GB9306409D0 (en) * | 1993-03-26 | 1993-05-19 | Bp Chem Int Ltd | Process |
ES2113623T3 (es) * | 1993-03-31 | 1998-05-01 | Acetex Chimie | Procedimiento de preparacion de acidos carboxilicos o de los esteres correspondientes en presencia de un catalizador a base de iridio. |
US5374774A (en) * | 1994-03-11 | 1994-12-20 | Hoechst Celanese Corporation | Control system for an acetic acid manufacturing process |
US5599976A (en) * | 1995-04-07 | 1997-02-04 | Hoechst Celanese Corporation | Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process |
-
1993
- 1993-03-26 GB GB939306409A patent/GB9306409D0/en active Pending
-
1994
- 1994-01-20 TW TW083100476A patent/TW268939B/zh not_active IP Right Cessation
- 1994-03-09 DE DE69406167T patent/DE69406167T2/de not_active Expired - Lifetime
- 1994-03-09 ES ES97104832T patent/ES2153138T3/es not_active Expired - Lifetime
- 1994-03-09 SG SG1995001788A patent/SG46155A1/en unknown
- 1994-03-09 EP EP97104832A patent/EP0786447B1/en not_active Expired - Lifetime
- 1994-03-09 SG SG1997002700A patent/SG70019A1/en unknown
- 1994-03-09 DE DE69426467T patent/DE69426467T2/de not_active Expired - Lifetime
- 1994-03-09 EP EP94301645A patent/EP0616997B1/en not_active Expired - Lifetime
- 1994-03-09 ES ES94301645T patent/ES2108376T3/es not_active Expired - Lifetime
- 1994-03-09 IN IN280DE1994 patent/IN188047B/en unknown
- 1994-03-22 CA CA002119609A patent/CA2119609C/en not_active Expired - Lifetime
- 1994-03-22 MY MYPI95003063A patent/MY121550A/en unknown
- 1994-03-24 NZ NZ260174A patent/NZ260174A/en unknown
- 1994-03-24 BR BR9401281A patent/BR9401281A/pt not_active IP Right Cessation
- 1994-03-24 RU RU94009853A patent/RU2133731C1/ru active
- 1994-03-24 ID IDP970887A patent/ID16946A/id unknown
- 1994-03-25 FI FI941395A patent/FI941395A/fi unknown
- 1994-03-25 YU YU14594A patent/YU49301B/sh unknown
- 1994-03-25 YU YU38504A patent/YU49305B/sh unknown
- 1994-03-25 NO NO941115A patent/NO300768B1/no not_active IP Right Cessation
- 1994-03-25 UA UA94005144A patent/UA41279C2/uk unknown
- 1994-03-26 CN CN94103438A patent/CN1047588C/zh not_active Expired - Fee Related
- 1994-03-26 KR KR1019940006140A patent/KR100288997B1/ko not_active IP Right Cessation
- 1994-03-28 JP JP05699394A patent/JP4233122B2/ja not_active Expired - Fee Related
-
1995
- 1995-05-31 US US08/454,620 patent/US5750007A/en not_active Expired - Lifetime
- 1995-09-01 UA UA95094007A patent/UA43843C2/uk unknown
-
1996
- 1996-02-08 CN CN96102586A patent/CN1073543C/zh not_active Expired - Lifetime
-
1997
- 1997-10-23 US US08/956,567 patent/US5874610A/en not_active Expired - Lifetime
-
2001
- 2001-09-07 IN IN934DE2001 patent/IN191080B/en unknown
-
2008
- 2008-10-25 JP JP2008274991A patent/JP2009073846A/ja active Pending
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