WO2023003024A1 - 配線基板 - Google Patents
配線基板 Download PDFInfo
- Publication number
- WO2023003024A1 WO2023003024A1 PCT/JP2022/028241 JP2022028241W WO2023003024A1 WO 2023003024 A1 WO2023003024 A1 WO 2023003024A1 JP 2022028241 W JP2022028241 W JP 2022028241W WO 2023003024 A1 WO2023003024 A1 WO 2023003024A1
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- WIPO (PCT)
- Prior art keywords
- substrate
- region
- interlayer connection
- conductor layer
- wiring board
- Prior art date
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/11—Printed elements for providing electric connections to or between printed circuits
- H05K1/115—Via connections; Lands around holes or via connections
- H05K1/116—Lands, clearance holes or other lay-out details concerning the surrounding of a via
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/0296—Conductive pattern lay-out details not covered by sub groups H05K1/02 - H05K1/0295
- H05K1/0298—Multilayer circuits
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/09—Use of materials for the conductive, e.g. metallic pattern
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/4007—Surface contacts, e.g. bumps
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
- H05K1/036—Multilayers with layers of different types
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/01—Dielectrics
- H05K2201/0183—Dielectric layers
- H05K2201/0187—Dielectric layers with regions of different dielectrics in the same layer, e.g. in a printed capacitor for locally changing the dielectric properties
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/09372—Pads and lands
- H05K2201/09454—Inner lands, i.e. lands around via or plated through-hole in internal layer of multilayer PCB
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/09372—Pads and lands
- H05K2201/09481—Via in pad; Pad over filled via
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/095—Conductive through-holes or vias
- H05K2201/09509—Blind vias, i.e. vias having one side closed
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/095—Conductive through-holes or vias
- H05K2201/09563—Metal filled via
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/11—Treatments characterised by their effect, e.g. heating, cooling, roughening
- H05K2203/1131—Sintering, i.e. fusing of metal particles to achieve or improve electrical conductivity
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/0058—Laminating printed circuit boards onto other substrates, e.g. metallic substrates
- H05K3/0067—Laminating printed circuit boards onto other substrates, e.g. metallic substrates onto an inorganic, non-metallic substrate
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/12—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using thick film techniques, e.g. printing techniques to apply the conductive material or similar techniques for applying conductive paste or ink patterns
- H05K3/1283—After-treatment of the printed patterns, e.g. sintering or curing methods
- H05K3/1291—Firing or sintering at relative high temperatures for patterns on inorganic boards, e.g. co-firing of circuits on green ceramic sheets
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/20—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern by affixing prefabricated conductor pattern
- H05K3/207—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern by affixing prefabricated conductor pattern using a prefabricated paste pattern, ink pattern or powder pattern
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
- H05K3/4614—Manufacturing multilayer circuits by laminating two or more circuit boards the electrical connections between the circuit boards being made during lamination
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4688—Composite multilayer circuits, i.e. comprising insulating layers having different properties
- H05K3/4694—Partitioned multilayer circuits having adjacent regions with different properties, e.g. by adding or inserting locally circuit layers having a higher circuit density
Definitions
- the disclosed embodiments relate to wiring boards.
- a wiring board has been proposed in which a plurality of circuit parts made of organic resin are laminated on a ceramic board.
- the circuit section is provided with a plurality of connection conductors penetrating between the laminated layers.
- a wiring board is formed by laminating a first board, a surface conductor layer, and a second board in this order.
- the second substrate uses an organic material as an insulating base.
- the surface conductor layer is located on the surface of the first substrate.
- the second substrate has a plurality of interlayer connection conductors.
- the interlayer connection conductor extends in the thickness direction of the second substrate and has one end exposed to the surface of the second substrate.
- the surface conductor layer and the interlayer connection conductor are electrically connected.
- the insulating base of the second substrate has a first region and a second region. The first region is located on the surface conductor layer.
- the second region is located on the surface of the first substrate. The first region has a higher density than the second region.
- FIG. 1 is a cross-sectional view showing an example of a wiring board according to the first embodiment.
- FIG. 2 is a cross-sectional view showing an example of a wiring board according to the second embodiment.
- FIG. 3 is a cross-sectional view showing an example of a wiring board according to the third embodiment. 4 is an enlarged plan view of a part of the wiring substrate shown in FIG. 3.
- FIG. 5 is a cross-sectional view showing an example of a wiring board according to the fourth embodiment.
- FIG. 6 is a cross-sectional view showing an example of a wiring board according to the fifth embodiment.
- FIG. 7 is a cross-sectional view showing another example of the wiring board according to the embodiment.
- FIG. 1 is a cross-sectional view showing an example of a wiring board according to the first embodiment.
- FIG. 2 is a cross-sectional view showing an example of a wiring board according to the second embodiment.
- FIG. 3 is a cross-sectional view showing an example of a wiring board according
- FIG. 8 is a cross-sectional view showing another example of the wiring board according to the embodiment.
- 9A and 9B are explanatory views showing an example of a method for manufacturing a wiring board according to Sample 1.
- FIG. 10 is a plan view showing wiring substrates according to samples 1 to 6.
- FIG. 11 is a diagram showing evaluation results of wiring boards according to samples 1 to 6.
- FIG. 10 is a plan view showing wiring substrates according to samples 1 to 6.
- FIG. 1 is a cross-sectional view showing an example of a wiring board according to the first embodiment.
- the wiring substrate 1 has a first substrate 10 and a second substrate 20.
- the first substrate 10 has an insulating base material 11 and a surface conductor layer 12 .
- the insulating base material 11 is, for example, a ceramic base material made of ceramics.
- the insulating base material 11 may be, for example, alumina-based or glass-ceramic ceramics, dielectric materials such as cordierite, zirconia, barium titanate, strontium titanate, calcium titanate, aluminum titanate, and zirconate titanate. It may be lead (PZT) or the like.
- the insulating base material 11 may have, for example, a plurality of ceramics.
- the surface conductor layer 12 is located on the surface of the insulating base material 11 .
- the surface conductor layer 12 protrudes from the surface 101 of the first substrate 10 .
- the surface conductor layer 12 may be, for example, a wiring having a line shape, a pad having a circular shape, a square shape or other angular shape, or a solid power supply layer or ground layer. .
- the surface conductor layer 12 may be smaller than the area of the main surface of the first substrate 10, for example.
- FIG. 1 illustrates an example in which the surface conductor layer 12 protrudes from the surface 101 of the first substrate 10 by a thickness corresponding to the thickness of the surface conductor layer 12 .
- the surface conductor layer 12 may protrude from the surface 101 of the first substrate 10 in a small proportion with respect to the thickness of the surface conductor layer 12 .
- the surface conductor layer 12 may protrude from the surface 101 of the first substrate 10 by, for example, 1 ⁇ 3 or more of the average thickness of the surface conductor layer 12 .
- the surface conductor layer 12 is made of, for example, tungsten (W), molybdenum (Mo), a mixture of W—Mo, an alloy of W—Mo, an intermetallic compound of W—Mo, copper (Cu), silver (Ag), nickel. It may be a conductor such as (Ni). Moreover, the surface conductor layer 12 may contain ceramic powder or the like.
- the second substrate 20 is positioned on the first substrate 10.
- the second substrate 20 has an insulating base material 21 and a plurality of interlayer connection conductors 22 .
- the insulating base material 21 is, for example, a so-called organic base material having an organic material.
- the insulating base material 21 may be, for example, epoxy resin, acrylic resin, polycarbonate resin, polyimide resin, olefin resin, or polyphenylene resin.
- the insulating base material 21 may be made of, for example, polytetrafluoroethylene (PTFE) or other fluorine resin or polyphenylene ether resin.
- PTFE polytetrafluoroethylene
- the interlayer connection conductor 22 has one end 221 and the other end 222 and extends in the thickness direction of the second substrate 20 .
- One end 221 is positioned to be exposed on the surface 201 of the second substrate 20 .
- the other end 222 is electrically connected to the surface conductor layer 12 .
- the interlayer connection conductor 22 may contain, for example, copper powder, tin (Sn) powder, or bismuth (Bi) powder.
- the volume ratio of the metal components such as copper, tin and bismuth is preferably 60% or more and 90% or less. When the proportion of the metal component is within this range, the conductivity of the interlayer connection conductor 22 can be increased. Moreover, the adhesion of the interlayer connection conductor 22 to the insulating base material 21 and the surface conductor layer 12 can be enhanced.
- the ratio of the metal component contained in the interlayer connection conductor 22 may be determined as an area ratio of the cross section of the interlayer connection conductor 22 by, for example, an electron microscope equipped with an analyzer.
- the calculated area ratio may be regarded as the volume ratio.
- the amount of copper and the total amount of tin and bismuth should be the same. Also, it is preferable that the amounts of tin and bismuth are the same. Further, the interlayer connection conductor 22 may have the same material as the insulating base material 21, such as epoxy resin, as the remainder.
- the insulating base material 21 has a first region 211 and a second region 212 .
- the first region 211 is a portion of the insulating base material 21 located on the surface conductor layer 12 .
- the second region 212 is a portion of the insulating base material 21 located on the first substrate 10 other than the first region 211 .
- the first region 211 has a higher density than the second region 212 .
- a method of evaluating the density a method of obtaining the number of voids located in the first region 211 and the second region 212 or a ratio of the total area, a method of cutting out the first region 211 and the second region 212.
- There are methods to measure density There are methods to measure density. Among these methods, the method of obtaining the ratio of the total area of voids existing in a region per unit area is preferable. This is because a difference is likely to appear even in a minute area.
- the density of the first region 211 which is the insulating base material 21 located on the surface conductor layer 12, is located on the first substrate 10 where the surface conductor layer 12 is not located. It is higher than the density of the second region 212 which is the insulating base material 21 . For this reason, for example, in the wiring substrate 1 in which the plurality of interlayer connection conductors 22 are located in the insulating base material 21 of the second substrate 20, it is difficult for moisture to enter the interlayer connection conductors 22. FIG. Thereby, the wiring board 1 can reduce a decrease in insulation resistance.
- the density of the first region 211 may be 1.1 times or more the density of the second region 212 .
- Such a density can be calculated by the Archimedes method using a sample cut out from the wiring board 1 .
- the density may be obtained from the size and mass of the cut sample.
- the shape of the sample should preferably be a hexahedron.
- the degree of porosity of the insulating base material 21 may be used to evaluate the compactness of the first region 211 and the second region 212. It is easier to analyze the denseness of the first region 211 and the second region 212 from the porosity than from the density.
- the porosity is evaluated as follows. First, a photograph of the cross section of the wiring board 1 is taken, and the first region 211 and the second region 212 are defined in the photograph. Next, a region of a specific area is specified from each defined location. Next, the total area of voids seen in the cross section of each identified region is determined. The A1/A0 ratio is obtained when the specified area is A0 and the total area of voids is A1.
- the area to be analyzed may be appropriately set within a range of, for example, 10 ⁇ m ⁇ 10 ⁇ m to 100 ⁇ m ⁇ 100 ⁇ m depending on the thickness of the second substrate 20 and the interval between the interlayer connection conductors 22 .
- P1/P2 is preferably 0.95 or less.
- the first substrate 10 may have, for example, a conductor layer located inside the insulating base material 11 . Also, the first substrate 10 may have, for example, a plurality of insulating base materials 11 laminated in the thickness direction.
- the second substrate 20 may have a conductor layer located inside and/or on the surface of the insulating base material 21, for example.
- FIG. 2 is a cross-sectional view showing an example of a wiring board according to the second embodiment.
- the wiring board 1 may have a covering conductor layer 30 located on the surface conductor layer 12 .
- the thickness of the first region 211 of the insulating base material 21 becomes even smaller than that of the second region 212.
- the first region 211 may be denser than the second region 212 .
- the wiring board 1 can further reduce the decrease in insulation resistance.
- the thickness of the covering conductor layer 30 may be smaller than the thickness of the surface conductor layer 12 .
- the thickness of the covering conductor layer 30 may be, for example, 0.1 ⁇ m or more.
- the upper limit of the thickness of the covering conductor layer 30 may be, for example, the thickness of the surface conductor layer 12 .
- the thickness of the surface conductor layer 12 may be, for example, 0.2 ⁇ m or more and 20 ⁇ m or less.
- the thickness of the surface conductor layer 12 and the covering conductor layer 30 is the average thickness of each layer.
- the average thickness is the average value obtained by dividing the total thickness of each portion of the surface conductor layer 12 and the covering conductor layer 30 equally in one direction in the cross section of the wiring board 1 by the number of measurement points. is.
- the surface conductor layer 12 may be included in the second substrate 20 instead of the first substrate 10 .
- the covering conductor layer 30 may be, for example, a metallized film, which is a sintered body of a conductor paste film, or may be a plated film. If the covering conductor layer 30 is a plated film, a sintering process of heating may be performed after plating. The sintering treatment can be performed at a temperature of, for example, 600.degree. C. to 1000.degree. Further, for example, when the plated film is a base metal such as copper or nickel, the sintering process may be performed in a reducing atmosphere using nitrogen gas.
- FIG. 3 is a cross-sectional view showing an example of a wiring board according to the third embodiment.
- 4 is an enlarged plan view of a part of the wiring substrate shown in FIG. 3.
- FIG. 1 in the wiring substrate 1, the interlayer connection conductor 22 forming the second substrate 20 may have an inner region 22a and an outer region 22b.
- the inner region 22a is located inside the outer peripheral region 22b when the second substrate 20 is viewed from above.
- the inner region 22a is surrounded by the outer peripheral region 22b.
- the outer peripheral region 22b is positioned such that the resin component forms a belt shape in the longitudinal direction of the interlayer connection conductor 22 (the thickness direction of the second substrate 20).
- a region where the resin component is positioned in a belt shape in the longitudinal direction (thickness direction) of the interlayer connection conductor 22 is sometimes called a mixed region.
- the mixed region is a region in which the resin component and the metal shown below are mixed.
- the inner region 22a may contain less or almost no resin component compared to the outer region 22b.
- the strip shape means a long shape.
- the long shape is a shape having an aspect ratio of, for example, 2 or more. Specifically, when a cross section obtained by cutting or polishing the wiring board 1 is observed with an electron microscope and a photograph is taken, the shape of the resin component in the interlayer connection conductor 22 seen in the photograph is This is the case where the shape has the aspect ratio defined above.
- the interlayer connection conductor 22 has a lower porosity in the outer region 22b than in the inner region 22a, making it more difficult for moisture to enter the interlayer connection conductor 22.
- the wiring board 1 can further reduce the decrease in insulation resistance.
- the resin component present in the outer peripheral region 22b of the interlayer connection conductor 22 may be an organic resin component contained in the insulating base material 21 of the second substrate 20, for example.
- the resin component present in the outer peripheral region 22b is generated by, for example, laminating a raw sheet of the second substrate 20 (a state in which the conductive paste that is the material of the interlayer connection conductor 22 is filled) on the first substrate 10 and heating it.
- a mixed region may be formed in the outer peripheral region 22b in the longitudinal direction of the interlayer connection conductor 22, moving from the insulating base material 21 of the second substrate 20 when the pressure is applied.
- the width of the mixed region that is, the thickness of the outer peripheral region 22b along the radial direction of the interlayer connection conductor 22 is determined by the pressure, temperature, and time of pressurization and heating during lamination pressure bonding.
- the thickness of the outer peripheral region 22b along the radial direction of the interlayer connection conductor 22 may be, for example, 1/6 or more and 1/2 or less of the outer diameter of the interlayer connection conductor 22.
- the outer peripheral region 22b is preferably formed so as to surround the inner region 22a of the interlayer connection conductor.
- the resin component contained in the outer peripheral region 22b is extracted from the interlayer connection conductor 22, the resin component may have a cylindrical shape.
- the wiring board 1 can ensure the conductivity of the interlayer connection conductors 22 .
- FIG. 5 is a cross-sectional view showing an example of a wiring board according to the fourth embodiment. Also in FIG. 5, the interlayer connection conductor 22 is divided into an inner region 22a and an outer region 22b as in the case of FIG.
- the interlayer connection conductor 22 contains a metal component as described above.
- the interlayer connection conductors 22 contain particles of metal.
- the particulate metal is hereinafter sometimes referred to as metal particles.
- the outer peripheral region 22b has a higher percentage of metal particles than the inner region 22a located inside the outer peripheral region 22b.
- the region other than the portion of the metal particles is preferably filled with a resin component. Therefore, in the outer peripheral region 22b, the bond between the metal particles is weak due to the presence of a large amount of the resin component.
- the resin component has a lower elastic modulus than metal.
- the wiring board 1 has an outer peripheral region 22b containing more resin components than the inner region 22a on the side where the wiring board 1 is in contact with the insulating base material 21 . For this reason, the wiring board 1 relaxes the stress caused by the difference in thermal expansion coefficient between the interlayer connection conductor 22 and the insulating base material 21 of the second substrate 20 located therearound. Easy to plan. Therefore, it is possible to suppress the occurrence of defects such as peeling between the interlayer connection conductor 22 and the surrounding insulating base material 21 . Thereby, the wiring board 1 can further reduce the decrease in insulation resistance.
- the aspect ratio of the shape appearing when the wiring board 1 is viewed in cross section is preferably 2 or less.
- the binding force within the metal is greater than that of an ingot-like one in which metals are integrated without gaps. become smaller.
- the metal positioned in the inner region 22a may have, for example, a shape in which metals are connected.
- a metal-linked conductor in the inner region 22a, for example, interfacial resistance between adjacent metal particles is reduced and electrical conductivity is increased.
- the inner region 22a may have voids within a range in which desired conductivity is obtained.
- FIG. 6 is a cross-sectional view showing an example of a wiring board according to the fifth embodiment.
- the interlayer connection conductor 22 of the wiring board 1 has a smaller diameter at a portion 24 near the surface 201 of the second substrate 20 than at a portion 23 located at the center in the thickness direction of the second substrate 20 .
- the peripheral surface 25 of the interlayer connection conductor 22 facing the insulating base material 21 of the second substrate 20 is partially rounded, the surface area of the interlayer connection conductor 22 is reduced and deformed against external pressure. difficult to do. Even if the organic resin second substrate 20 is, for example, largely deformed, the interlayer connection conductor 22 tends to remain in a small amount of deformation. Therefore, it is possible to improve the mounting reliability of the electrical elements electrically mounted on the interlayer connection conductors 22 .
- the diameter of the interlayer connection conductor 22 may gradually decrease from the vicinity of the center in the thickness direction of the second board 20 toward the ends. This makes it easier for the interlayer connection conductor 22 to have a mechanical effect such that the polyhedron becomes nearly spherical, so that the wiring board 1 is less likely to be deformed or broken.
- the organic resin of the insulating base material 21 penetrates deeply toward the center side in the radial direction of the interlayer connection conductor 22, for example. It may be in a state of being surrounded. Therefore, deformation of the interlayer connection conductor 22 can be further reduced. This makes it difficult for the interlayer connection conductors 22 to deform even when an electrical element is mounted on the surface 201 of the second substrate 20 with high pressure, for example.
- the interlayer connection conductor 22 may have a smaller diameter at a portion near the surface conductor layer 12 than at the center of the second substrate 20 in the thickness direction.
- FIG. 7 and 8 are cross-sectional views showing other examples of the wiring board according to the embodiment.
- the wiring board 1 may have a conductor layer 13 located inside the insulating base material 11 .
- the second substrate 20 has a conductor layer (for example, a conductor layer 26 (see FIG. 7) and a surface wiring layer 27 (see FIGS. 7 and 8)) located on the surface or inside the insulating base material 21.
- the thickness of the second substrate 20 may be in the range of 0.05 to 0.2 when the thickness of the first substrate 10 is 1, for example.
- the thickness of the second substrate 20 made of organic resin having a low elastic modulus is thinner than the thickness of the first substrate 10 made of ceramic, the first substrate 10 is resistant to the thermal expansion of the wiring substrate 1 and the load. Not easy to deform.
- the conductors of the second substrate 20 may be finer than the conductors of the first substrate 10 (especially the surface wiring layer 15 and the conductor layer 13), for example. This makes it easier to mount electrical elements having fine circuits on the second substrate 20 side, such as LSIs and other semiconductor elements.
- fine particularly means that the width of the conductor is small.
- the so-called signal lines are preferably narrower than the signal lines formed on the first substrate 10 . This can prevent the second substrate 20 from hardening and becoming difficult to deform.
- FIG. 1 is explanatory views showing an example of a method for manufacturing a wiring board according to Sample 1.
- FIG. 1 the first substrate 10 and the second substrate 20 were prepared.
- the first substrate 10 has a copper metallization film 120 on the surface of an insulating substrate 11 made of glass ceramic.
- the metallized film 120 protrudes from the surface of the insulating base material 11 by a thickness close to the thickness of the surface conductor layer 12 .
- the second substrate 20 has an uncured interlayer connection conductor 220 that penetrates the insulating base material 21 in the thickness direction.
- the insulating base material 21 was produced using a thermosetting epoxy resin as an organic material (resin component).
- the interlayer connection conductor 220 before curing contains 50 mol % copper powder, 25 mol % Sn powder, 25 mol % Bi powder, and the balance epoxy resin.
- a wiring board 1 (Sample 1: see FIG. 1) was obtained in which the interlayer connection conductors 22 of the second substrate 20 were positioned on the surface conductor layer 12 of the first substrate 10 .
- the insulating base material 21 (first region 211) of the second substrate 20 located on the surface conductor layer 12 of the first substrate 10 protruded from the surface conductor layer 12 is provided. is further pressurized than the second region 212 other than the first region 211 where the surface conductor layer 12 exists, so that it becomes denser.
- a nickel plating film is formed on the surface of the surface conductor layer 12 of the first substrate 10 used for the sample 1, and sintering is performed at a temperature of 700° C. in a nitrogen atmosphere to form a covering conductor layer 30 on the surface conductor layer 12.
- a wiring board 1 (Sample 2: see FIG. 2) was obtained.
- Wiring board 1 (Sample 3: see FIGS. 3 and 4) in which organic resin is positioned around interlayer connection conductors 22 was obtained by performing the same treatment as Sample 1, except that pressure and heating were performed for 30 seconds. rice field.
- the first substrate 10 had a copper metallized film 120 as the surface conductor layer 12 on the surface of the insulating base material 11 .
- the metallized film 120 had a surface conductor layer 12 protruding from the surface of the insulating base material 11 and protruded by a thickness close to the thickness of the surface conductor layer 12 .
- the first region 211 of the insulating base material 21 had a lower percentage of the total area of voids than the second region 212 with a difference of 0.5% or more. In this case, voids having a diameter of 0.1 ⁇ m or more were extracted.
- Sample 6 had the same ratio of the total area of voids in the portions corresponding to the first region and the second region of the insulating base material. In this case, if the numerical value of the ratio of the total area of voids is within 1%, it is regarded as the same.
- FIG. 10 is a plan view showing wiring substrates according to samples 1 to 6.
- the diameter of interlayer connection conductors 22 is 100 ⁇ m
- the interval between adjacent interlayer connection conductors 22 is 50 ⁇ m
- a total of 100 interlayer connection conductors 22 are arranged in 10 rows. It is located in the x10 column. These interlayer connection conductors 22 were connected in series.
- HAST test A high temperature and high humidity bias test (HAST test) was performed by applying a voltage of 5.5 V between adjacent interlayer connection conductors 22 for 168 hours under an environment of 130°C and 85% Rh. The rate of decrease in insulation resistance based on the value before the test was measured, and the results are shown in FIG. It should be noted that the value of the rate of decrease shown in FIG. 22-100).
- FIG. 11 shows the number of interlayer connection conductors 22 for which disconnection was confirmed by visual evaluation of the presence or absence of disconnection of the electrical elements mounted on the interlayer connection conductors 22 .
- FIG. 11 is a diagram showing evaluation results of wiring boards according to samples 1-6. As shown in FIG. 11, in all of the wiring substrates 1 according to Samples 1 to 5, the effect of reducing the decrease in insulation resistance as compared with the wiring substrate according to Sample 6 was confirmed.
- the wiring substrate according to the sample 6 has the effect of reducing disconnection of the electric elements mounted on the interlayer connection conductors 22 .
- the second substrate 20 uses an organic material as an insulating base material 21 .
- the surface conductor layer 12 is located on the surface of the first substrate 10 and protrudes from the surface.
- the second substrate 20 has a plurality of interlayer connection conductors 22 .
- the interlayer connection conductor 22 extends in the thickness direction of the second substrate 20 and has one end exposed on the surface of the second substrate 20 .
- the surface conductor layer 12 and the interlayer connection conductor 22 are electrically connected.
- the insulating base material 21 of the second substrate 20 has a first region 211 and a second region 212 .
- the first region 211 is located on the surface conductor layer 12 .
- a second region 212 is located on the surface of the first substrate 10 .
- the first region 211 has a higher density than the second region 212 .
- the wiring board 1 according to the embodiment it is possible to reduce the decrease in insulation resistance.
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Abstract
Description
図1は、第1実施形態に係る配線基板の一例を示す断面図である。
図2は、第2実施形態に係る配線基板の一例を示す断面図である。図2に示すように、配線基板1は、表面導体層12上に位置する被覆導体層30を有してもよい。
図3は、第3実施形態に係る配線基板の一例を示す断面図である。図4は、図3に示す配線基板の一部を拡大視した平面図である。図3、図4に示すように、配線基板1において、第2基板20を構成する層間接続導体22は、内側領域22aと、外周領域22bとを有してもよい。ここで、内側領域22aは、第2基板20を平面視したときに、外周領域22bの内側に位置している。言い換えると、内側領域22aは、外周領域22bに囲まれている。外周領域22bは、樹脂成分が層間接続導体22の長手方向(第2基板20の厚み方向)に帯状を成すように位置している。樹脂成分が層間接続導体22の長手方向(厚み方向)に帯状を成すように位置している領域のことを混在領域という場合がある。混在領域とは、樹脂成分と下記に示す金属とが混在した領域のことである。また、内側領域22aは、外周領域22bに比べて、樹脂成分が少ないかまたはほとんど含まれていない場合がある。帯状とは、言い換えると、長尺状のことである。ここで長尺状とは、アスペクト比が、例えば、2以上の形状である。具体的には、配線基板1を切断、あるいは研磨して得られた断面を、電子顕微鏡により観察し、写真を撮影したときに、その写真に見られる層間接続導体22中の樹脂成分の形状が上記で規定したアスペクト比を有する形状となっている場合である。
図5は、第4実施形態に係る配線基板の一例を示す断面図である。図5においても、層間接続導体22を、図3の場合と同様に、内側領域22a、外周領域22bとに分けて説明する。
図6は、第5実施形態に係る配線基板の一例を示す断面図である。図6に示すように、配線基板1の層間接続導体22は、第2基板20の厚み方向の中央に位置する部分23の径よりも第2基板20の表面201に近い部分24の径が小さくてもよい。
図7、図8は、実施形態に係る配線基板の他の一例を示す断面図である。
以下に示す試料1~6に係る配線基板1を作製し、特性を評価した。
図9は、試料1に係る配線基板の製造方法の一例を示す説明図である。まず、第1基板10および第2基板20を準備した。第1基板10は、ガラスセラミック製の絶縁基材11の表面に銅のメタライズ膜120を有している。メタライズ膜120は、絶縁基材11の表面から表面導体層12の厚みに近い厚さだけ突出させている。
試料1に用いた第1基板10の表面導体層12の表面にニッケルメッキ膜を形成して、窒素雰囲気中、温度700℃でシンター処理を行うことにより、表面導体層12上に被覆導体層30を有する配線基板1(試料2:図2参照)を得た。
加圧加熱を30秒間行うことを除き、試料1と同様に処理を行うことにより、層間接続導体22の周囲に有機樹脂が位置する配線基板1(試料3:図3、図4参照)を得た。
第2基板20の絶縁基材21となる有機材料(樹脂成分)中に含ませる硬化剤(アミン系)を試料1の場合の1.2倍としたことを除き、試料1と同様に処理を行うことにより、内側領域22aよりも粒子状の金属の割合が高い外周領域22bを有する配線基板1(試料4:図5参照)を得た。
試料4の第2基板20に用いた絶縁基材21の材料よりも硬い生のシートを用いることを除き、試料4と同様に処理を行うことにより、硬化前の層間接続導体220が変形し、第2基板20の厚み方向の中央に位置する部分の径よりも第2基板20の表面に近い部分の径が小さい層間接続導体22を有する配線基板1(試料5:図6参照)を得た。試料4の第2基板20に用いた絶縁基材21の材料よりも硬い生のシートとしては、用いた有機材料のガラス転移温度が試料4に用いた有機材料に比べて20℃高い有機材料を用いた。
絶縁基材11の表面にメタライズ膜120を有さない第1基板10を使用することを除き、試料1と同様に処理を行うことにより、密度が一様の絶縁基材21を有する配線基板(比較例)を得た。試料6は、絶縁基材の第1領域および第2領域に相当する部分におけるボイドの総面積の割合が同じであった。この場合、ボイドの総面積の割合の数値として1%以内である場合に同じとした。
図10は、試料1~6に係る配線基板を示す平面図である。図10に示すように、試料1~6に係る配線基板1Aは、層間接続導体22の直径を100μm、隣り合う層間接続導体22の間隔を50μmとし、計100個の層間接続導体22が10行×10列に位置している。これらの層間接続導体22を、直列に接続した。
10 第1基板
11,21 絶縁基材
12 表面導体層
20 第2基板
22 層間接続導体
22a 内側領域
22b 外周領域
30 被覆導体層
211 第1領域
212 第2領域
Claims (6)
- 第1基板と、
表面導体層と、
有機材料を絶縁基材とする第2基板と
がこの順に積層されており、
前記表面導体層は、前記第1基板の表面上に位置し、
前記第2基板は、複数の層間接続導体を有し、
前記層間接続導体は、前記第2基板の厚み方向に延び、一端が前記第2基板の表面に露出しており、
前記表面導体層と前記層間接続導体とは電気的に接続されており、
前記第2基板の前記絶縁基材は、第1領域と、第2領域とを有し、
前記第1領域は、前記表面導体層上に位置し、
前記第2領域は、前記第1基板の表面上に位置し、
前記第1領域は、前記第2領域よりも密度が高い
配線基板。 - 前記表面導体層の表面上に位置する被覆導体層を有する
請求項1に記載の配線基板。 - 前記層間接続導体が、樹脂成分を含んでおり、
該樹脂成分は、前記層間接続導体の外周領域に前記第2基板の厚み向に帯状を成すように位置している
請求項1または2に記載の配線基板。 - 前記層間接続導体は、金属粒子を含んでおり、
前記層間接続導体は、前記第2基板を平面視したときに、前記層間接続導体の外縁を含む外周領域と、前記層間接続導体の中心軸を通り前記外周領域の内側に位置する内側領域と、を有しており、
前記外周領域における前記金属粒子の体積割合は、前記内側領域における前記金属粒子の体積割合よりも高い
請求項3に記載の配線基板。 - 前記層間接続導体は、前記第2基板の厚み方向の中央に位置する部分の径よりも前記第2基板の表面に近い部分の径が小さい
請求項1~4のいずれか1つに記載の配線基板。 - 前記層間接続導体は、前記第2基板の厚み方向の中央に位置する部分の径よりも前記表面導体層に近い部分の径が小さい
請求項5に記載の配線基板。
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US18/578,489 US20240389226A1 (en) | 2021-07-20 | 2022-07-20 | Wiring board |
JP2023536782A JPWO2023003024A1 (ja) | 2021-07-20 | 2022-07-20 | |
CN202280048987.7A CN117643183A (zh) | 2021-07-20 | 2022-07-20 | 布线基板 |
EP22845957.4A EP4376562A1 (en) | 2021-07-20 | 2022-07-20 | Wiring substrate |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH07170046A (ja) * | 1993-09-22 | 1995-07-04 | Matsushita Electric Ind Co Ltd | プリント配線板及びその製造方法 |
JP2004296504A (ja) * | 2003-03-25 | 2004-10-21 | Toshiba Corp | 配線部材およびその製造方法 |
JP2005285802A (ja) * | 2004-03-26 | 2005-10-13 | Kyocera Corp | 配線基板及びその製造方法 |
JP2019207977A (ja) | 2018-05-30 | 2019-12-05 | 京セラ株式会社 | 配線基板 |
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JP2003008233A (ja) * | 2001-06-19 | 2003-01-10 | Nitto Denko Corp | 多層配線基板 |
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- 2022-07-20 JP JP2023536782A patent/JPWO2023003024A1/ja active Pending
- 2022-07-20 WO PCT/JP2022/028241 patent/WO2023003024A1/ja active Application Filing
- 2022-07-20 US US18/578,489 patent/US20240389226A1/en active Pending
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH07170046A (ja) * | 1993-09-22 | 1995-07-04 | Matsushita Electric Ind Co Ltd | プリント配線板及びその製造方法 |
JP2004296504A (ja) * | 2003-03-25 | 2004-10-21 | Toshiba Corp | 配線部材およびその製造方法 |
JP2005285802A (ja) * | 2004-03-26 | 2005-10-13 | Kyocera Corp | 配線基板及びその製造方法 |
JP2019207977A (ja) | 2018-05-30 | 2019-12-05 | 京セラ株式会社 | 配線基板 |
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