WO2011074143A1 - Procédé de traitement de fibres de kératine - Google Patents
Procédé de traitement de fibres de kératine Download PDFInfo
- Publication number
- WO2011074143A1 WO2011074143A1 PCT/JP2009/071735 JP2009071735W WO2011074143A1 WO 2011074143 A1 WO2011074143 A1 WO 2011074143A1 JP 2009071735 W JP2009071735 W JP 2009071735W WO 2011074143 A1 WO2011074143 A1 WO 2011074143A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- keratin fibers
- composition
- group
- process according
- heating
- Prior art date
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- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical class [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 208000024963 hair loss Diseases 0.000 description 1
- 230000003676 hair loss Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000000832 lactitol Substances 0.000 description 1
- VQHSOMBJVWLPSR-JVCRWLNRSA-N lactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-JVCRWLNRSA-N 0.000 description 1
- 235000010448 lactitol Nutrition 0.000 description 1
- 229960003451 lactitol Drugs 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 229960001855 mannitol Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/24—Thermal properties
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/81—Preparation or application process involves irradiation
Definitions
- the present invention relates to a process for treating keratin fibers such as hair, as well as a composition and a kit to be used for the process.
- compositions and/or processes known as treatments for repairing damaged keratin fibers that have been proposed are still insufficient insofar as they are often temporary and do not achieve proper recovery of keratin fiber integrity.
- Saccharides or sugars are known as cosmetic agents in cosmetic products for keratin fibers.
- cosmetic agents for keratin fibers.
- an objective of the present invention is to provide a new treatment process for keratin fibers such as hair, using a saccharide or a derivative thereof, even with a relatively small amount thereof, which provides the keratin fibers with good cosmetic effects, in particular superior repairing or recovering effects, which can be effective against various stresses for a long time.
- composition comprising at least one saccharide or a derivative thereof
- composition contains neither a reducing agent nor a source of carbonate ions of the formula:
- X is a group selected from the group consisting of 0 " , OH, NH 2 , O- OH, and O-COO " .
- the above process may further comprise the step of rinsing the keratin fibers after the step of applying the composition onto the keratin fibers and/or after the step of heating the keratin fibers .
- Mechanical tension may be provided to the keratin fibers.
- the mechanical tension may be provided by using at least one
- reshaping means selected from the group consisting of a curler, a roller, a plate and an iron.
- the occlusive space may be formed by at least one coating means.
- the coating means may be rigid or flexible.
- the coating means may comprise at least one member selected from the group
- the keratin fibers may be heated at 45°C to 250°C during the step of heating the keratin fibers.
- the keratin fibers may be heated by at least one heater providing at least one selected from the group consisting of hot air, hot steam, high frequency induction heating, microwave heating, infra-red ray irradiation, laser, and flash lamp irradiation.
- the coating means and/or the reshaping means may comprise the heater.
- the saccharide may be selected from the group consisting of monosaccharides, oligosaccharides, polysaccharides, and mixtures thereof.
- the monosaccharide or a derivative thereof may be selected from the group consisting of glucose, fructose,
- the oligosaccharide or a derivative thereof may be selected from the group consisting of maltose, lactose, saccharose, cellobiose, trehalose, sucrose, flucto-oligosaccharide, dextrin, and mixtures thereof.
- the polysaccharide or a derivative thereof may be selected from alginic acid, guar gum, xanthan gum, gum arabic, arabinogalactan, carrageenan, agar, karaya gum, gum tragacanth, tara gum, pectin, locust bean gum, cardolan, jellan gum, dextran, pullulan, hyaluronic acid, cellulose and its derivatives, and mixtures thereof.
- the composition may comprise the saccharide in an amount of 0.001 to 50% by weight relative to the total weight of the composition.
- the pH of the composition may range from 4 to 11.
- compositions for treating keratin fibers to be heated in an occlusive space comprising at least one saccharide or derivative thereof,
- composition contains neither a reducing agent nor a source of carbonate ions of the formula:
- X is a group selected from the group consisting of Cf, OH, NH 2 , 0- OH, and O-COO " .
- the present invention also relates to a kit for treating keratin fibers, comprising:
- At least one coating means to form an occlusive space
- At least one heater to heat the keratin fibers in the occlusive space
- composition comprising at least one saccharide or derivative thereof, wherein
- composition contains neither a reducing agent nor a source of carbonate ions of the formula:
- X is a group selected from the group consisting of 0 " , OH, NH 2 , 0- OH, and 0-COO " .
- cosmetic effects even using a saccharide or a derivative thereof, and in particular superior repairing or recovering effects, which can be effective against various stresses for a long time, by using a composition comprising a saccharide or a derivative thereof in association with a specific heating process for the keratin fibers.
- the above specific heating process is performed in a closed or occlusive environment, which limits the evaporation of water or moisture from the keratin fibers and maintains the keratin fibers at higher temperature preferably in the wet state. Accordingly, the keratin fibers can be evenly heated, and the saccharide or a derivative thereof can easily penetrate into or deposit onto the keratin fibers such that it can remain in or on the keratin fibers for a long time even after some stresses such as
- the process according to the present invention can exhibit good cosmetic effects by using even a relatively small amount of saccharide or derivative thereof as compared to a conventional process in which it is difficult for a saccharide or a derivative thereof to stay on or in the keratin fibers .
- composition used in the present invention must not contain any reducing agents such as thiol-compounds . Therefore, malodor derived from the reducing agents can be prevented. Furthermore, the composition used in the present invention must not contain any carbonate ion source as defined above. Therefore, cosmetic treatment is more effective, because ' there is no possibility of producing carbon dioxide which may form a foam that may inhibit the deposition or penetration of the saccharide or derivative thereof on or into the keratin fibers.
- composition used for the present invention comprises at least one saccharide or a derivative thereof.
- saccharide here means a polyalcohol composed of one or more glucidic units, and may have at least one carbonyl group.
- the derivative of a saccharide includes a sugar alcohol which is obtained by reducing one or more carbonyl groups of a saccharide, as well as a saccharide or a sugar alcohol in which the hydrogen atom or atoms in one or more hydroxy groups thereof has or have been replaced with at least one substituent such as an alkyl group, a hydroxyalkyl group, an alkoxy group, an acylgroup or a carbonyl group.
- the saccharide may be selected from the group consisting of monosaccharides, oligosaccharides, polysaccharides, and mixtures thereof .
- the monosaccharide may be selected from the group consisting of glucose, fructose, galactose, mannose, talose, sorbose, xylose, lyxose, fucose, arabinose, rhamnose, ribose, ribulose, xylulose, sorbitol, triose, pentose, hexose, ketose, glucosamine, and mixtures thereof.
- the oligosaccharide may be selected from the group consisting of maltose, lactose, saccharose, cellobiose, trehalose, sucrose, flucto-oligosaccharide, dextrin, and mixtures thereof.
- the preferred oligosaccharides may be composed of 2 to 10
- the polysaccharide may be selected from alginic acid, guar gum, xanthan gum, gum arabic, arabinogalactan, carrageenan, agar, karaya gum, gum tragacanth, tara gum, pectin, locust bean gum, cardolan, jellan gum, dextran, pullulan, hyaluronic acid, cellulose and its derivatives, and mixtures thereof.
- the derivative of a saccharide may be selected from the group consisting of erythritol, lactitol, maltitol, mannitol, sorbitol and xylitol, in which at least one hydrogen in the hydroxyl groups thereof may have been replaced with at least one substituent such as an alkyl group, a hydroxyalkyl group, an alkoxy group, an acylgroup or a carbonyl group.
- the above saccharides can exist in the form of L or D isomers.
- the saccharide or derivative thereof may be present in an amount ranging from 0.001% to 50% by weight, and preferably from 0.005% to 20% by weight, such as from 0.1% to 10% by weight, relative to the total weight of the composition.
- composition used for the present invention contains neither a reducing agent nor a source of carbonate ions of the formula:
- X is a group selected from the group consisting of 0 “ , OH, NH 2 , 0- OH, and O-COO " .
- the pH of the composition may range from 4 to 11, preferably between 4.0 and 9.0, and more preferably between 6.0 to 8.0.
- the pH of the composition is not relatively high or low, damage to the keratin fibers by the composition can be reduced.
- an acidic or alkali agent (s) other than sources of ions of the invention may be used alone or in combination.
- the amount of the acidic or alkali agent (s) is not limited, but may be from 0.1 to 5% by weight relative to the total weight of the composition.
- the acidic agents mention may be made of any inorganic or organic acids which are commonly used in cosmetic products such as citric acid, lactic acid, phosphoric acid or hydrochloric acid (HC1) . HC1 is preferable.
- alkali agents mention may be made of any inorganic or organic basic agents which are commonly used in cosmetic products such as ammonia; alcanolamines such as mono-, di- and tri- ethanolamine, isopropanolamine; sodium and potassium hydroxides; urea, guanidine and their derivatives; basic amino acids such as lysine or arginine; and diamines such as those described in the structure below: R1 R3
- R denotes an alkylene such as propylene optionally
- Ri, R 2 , R3 and R 4 independently denote a hydrogen atom, an alkyl radical or a C1-C4 hydroxyalkyl radical, which may be exemplified by 1,3- propanediamine and derivatives thereof.
- monoethanolamine are preferred.
- the composition used for the present invention may also comprise one or more additional cosmetic agent (s).
- the amount of the additional cosmetic agent (s) is not limited, but may be from 0.1 to 10% by weight relative to the total weight of the composition.
- the cosmetic agent (s) may be selected from the group consisting of volatile or non volatile, linear or cyclic, amine-type or not, silicones, cationic, anionic, non ionic or amphoteric polymers, peptides and derivatives thereof, protein hydrolyzates, synthetic or natural waxes, and especially fatty alcohols, swelling agents and penetrating agents, as well as other active compounds, such as anionic, cationic, non ionic, amphoteric or zwitterionic surfactants, agents for combating hair loss, anti-dandruff agents, associative-type or not, natural or synthetic thickeners,
- suspending agents such as, but not limited to, benzyl alcohol, benzyl ether, benzyl ether, benzyl ether, benzyl ether, benzyl ether sulfate, benzyl ether sulfate, benzyl ether sulfate, benzyl ether sulfate, benzyl ether sulfate, benzyl ether sulfate, benzyl, sorbitol, sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, sulfate, sulfate, sulfate, sulfate, sulfonylurea sulfonylurea sulfonyl
- the vehicle for the composition used for the present invention is preferably an aqueous medium consisting of water and may
- cosmetically acceptable organic solvents which particularly include alcohols, such as ethyl alcohol, isopropyl alcohol, benzyl alcohol and phenylethyl alcohol, or polyols or polyol ethers, such as ethylene glycol monomethyl, monoethyl and monobutyl ethers, propylene glycol or ethers thereof, such as propylene glycol monomethylether,
- alcohols such as ethyl alcohol, isopropyl alcohol, benzyl alcohol and phenylethyl alcohol
- polyols or polyol ethers such as ethylene glycol monomethyl, monoethyl and monobutyl ethers, propylene glycol or ethers thereof, such as propylene glycol monomethylether
- butylene glycol dipropylene glycol as well as diethylene glycol alkyl ethers, such as diethylene glycol monoethylether or
- the water may be present in a concentration of from 10 to 90% by weight relative to the total weight of the composition.
- the organic solvent (s) may then be present in a concentration of from 0.1 to 20% by weight, and preferably from 1 to 10% by weight relative to the total weight of the composition.
- the composition used in the present invention may exist in any form such as a lotion, a gel, thickened or not, or a cream.
- the process for treating keratin fibers according to the present invention can be performed by
- keratin fibers such as hair are subjected to a specific heating process which is performed in an occlusive space.
- the heating process can be performed by any heating means which can be freely controlled to realize the temperature desired for the process.
- the heating process may preferably be performed by using a special heating device or devices that can form an occlusive space to restrict the evaporation of evaporable components such as water in the above-described composition from keratin fibers and keep a predetermined temperature in the heating device throughout the process.
- a special heating device or devices that can form an occlusive space to restrict the evaporation of evaporable components such as water in the above-described composition from keratin fibers and keep a predetermined temperature in the heating device throughout the process.
- the evaporable components such as water in the above-described composition evaporate from the keratin fibers, most of the heat energy applied to the keratin fibers will be consumed by the evaporation, and therefore the temperature of the keratin fibers cannot increase up to the predetermined temperature until all evaporable components in the composition evaporate.
- the above heating device may comprise a heat energy source being either in contact with keratin fibers or apart from keratin fibers, and at least one means to form an occlusive space surrounding the keratin fibers.
- the heat energy source is used to heat keratin fibers.
- the heat energy source may be at least one heater providing at least one selected from the group consisting of hot air, hot steam, high frequency induction heating, microwave heating, infrared ray irradiation, laser, and flash lamp irradiation.
- the occlusive space may be formed by at least one coating means.
- a plurality of coating means may be used.
- the coating means may be rigid or flexible.
- the coating means may comprise at least one member selected from the group consisting of a film and a sheet.
- the material of the film or the sheet is not limited.
- the film or the sheet may comprise a thermoplastic or thermosetting resin, a paper, a textile, a bonnet, a metal foil such as aluminum foil, and the like.
- the film or sheet may be set on a heating rod, a heating bar or a heating plate which is covered by keratin fibers.
- the coating means may
- the film or sheet which includes a heater may be set on a rod, a bar, or a plate which is covered by keratin fibers.
- the occlusive conditions can restrict the evaporation of
- evaporable components such as water in the above-described
- composition applied to keratin fibers and therefore the
- the temperature of the keratin fibers can be increased higher than that obtainable by a conventional heating process or device for the keratin fibers in open conditions. Furthermore, the keratin fibers can be heated effectively, and the keratin fibers can be heated evenly.
- the occlusive space may comprise apertures, the surface area of which is less than 5%, preferably less than 3% and more particularly less than 0.5% of the total surface area of the coating means.
- the total surface area of the coating means comprises the surface area of, when it is present, an opening means for the coating means.
- the apertures may be passages, holes or orifices, which may allow an exchange of air between the occlusive space and the exterior thereof, especially when the reaction such as forming vapor inside the occlusive space is too great.
- a person skilled in the art could form the apertures such that the diffusion of heat in the occlusive space is not impaired.
- the keratin fibers can be heated at 45°C to 250°C, preferably 60°C to 200°C, more preferably 60°C to 150°C, more preferably 60°C to 90°C, during the step of heating the keratin fibers.
- the heating process may be performed for an appropriate time which is required to treat keratin fibers.
- the time length for the heating process is not limited, but it may be from 1 minute to 2 hours, preferably 1 minute to 1 hour, and more preferably 1 minute to 30 minutes.
- the time for heating may be from 5 to 20 minutes, preferably 10 to 15 minutes.
- the keratin fibers may be rinsed after the step of applying the composition onto the keratin fibers and/or after the step of heating the keratin fibers.
- the keratin fiber may be subjected to mechanical tension which is typically used for permanent
- mechanical tension is applied to keratin fibers may be performed as follows.
- keratin fibers are subjected to mechanical tension for deformation.
- the mechanical tension can be applied to the keratin fibers by any means to deform the keratin fibers to an intended shape.
- the mechanical tension may be provided by at least one reshaping means selected from the group consisting of a curler, a roller, a clip, a plate and an iron.
- the reshaping means may comprise at least one heater as described above. If the keratin fibers are rolled around a curler, this rolling-up may be performed on the entire length of the keratin fibers or, for example, on half the length of the keratin fibers. Depending on, for example, the desired hairstyle shape and amount of curls, the rolling-up may be performed with more or less thick locks .
- the above-described composition is applied to the keratin fibers.
- the application of the composition may be performed by any means, such as a brush and a comb.
- the keratin fibers to which the mechanical tension has been applied should be treated with the composition. It may be possible that the keratin fibers are left as they are for a certain amount of time, if necessary.
- the heat energy is applied to the keratin fibers under occlusive conditions as described above.
- This process for permanent deformation of keratin fibers may be performed without any step of oxidizing the keratin fibers.
- the time required for the process according to the present invention can be shorter than that for a conventional process which needs an oxidizing step. Furthermore, damage to the keratin fibers by the oxidizing step can be avoided.
- the keratin fibers may be rinsed after the step of applying the composition onto the keratin fibers and/or after the step of heating the keratin fibers.
- One embodiment of the hair treatment process according to the present invention may be a process for reshaping or permanent deforming keratin fibers, in particular hair, comprising:
- the temperature can be set, adjusted and
- thermo-measurement probe such as Digital Surface Sensor Module, reference MT-144, sold by Sakaguchi E.H VOC Corp (Japan), set on the keratin fibers.
- the probe is set on a single keratin fiber.
- the probe is set on the part of the keratin fibers which directly contacts with the occlusive space, and more preferably, the probe is set on the part of the keratin fibers which directly contacts with the occlusive space and forms the curl end of the keratin fibers, if a curler is used.
- the temperature is measured at atmospheric pressure of 101325 Pa.
- the temperature of the keratin fibers may be constant with a fluctuation of ⁇ 2 or 3°C over the head, if the keratin fibers are hair, of an individual, and the probe may be set on any type of keratin fibers.
- keratin fibers are hair, according to the present
- the constant temperature with a fluctuation of ⁇ 2 or 3°C can be obtained for any type of hair, and the temperature of the hair can be controlled to be constant ⁇ 2 or 3°C during the heating of the hair at a certain temperature.
- the hair style becomes uniform and homogeneous for the entirety of the hair, and a more excellent hair style can be finally obtained.
- the coating means may comprise one or more thermal insulating materials, and more advantageously, the coating means may consist of the material (s).
- thermal insulating material means any material which has an electric conductivity of 0 to 1 W/m°C (PVC: 0.17 W/m°C) .
- the heating means may be adjusted such that the temperature measured on the keratin fibers is 50 °C or more, more preferably 55°C to less than 150°C, and further more preferably less than 100°C. It is preferable that the heating is performed by heating via electrical resistance.
- the coating means is impermeable with regard to the composition used in the step b) .
- At least one of the reshaping or mechanical tensioning means and at least one of the covering means may include a heater.
- occlusive space means that when the coating means is placed on the reshaping or mechanical tensioning means, or vice versa, they together form a closed structure in which heat can diffuse, but heat cannot diffuse out of or is difficult to diffuse out of the closed structure.
- the coating means and the reshaping or mechanical tensioning means can form the occlusive space when they are set on the head, if the keratin fibers are hair.
- the occlusive space may form a condensation cage in which water and a component or components in the composition used in the step b) may evaporate from the keratin fibers, adhere to the wall of the coating means, and drop onto the keratin fibers. This cycle may be repeated during the heating of the keratin fibers.
- the keratin fibers can be always kept wet, and drying and deteriorating of the keratin fibers will be prevented.
- occlusive space is an important characteristic ⁇ of the present invention, because the keratin fibers in the occlusive space can be kept wet and the temperature of the keratin fibers can be constant.
- the process of the present invention may comprise an additional step of tightening the coating means on the head of an individual, if the keratin fibers are hair, by an elastic cord, an extensible band, or a stretch.
- the amount of a cosmetic component or components in the composition is advantageously reduced as compared to the processes in the prior art.
- the amount of the cosmetic component (s) may be 0.3 to 3wt% of the composition .
- a coating means may be placed on each hair curler as the reshaping or mechanically tensioning means, if the keratin fibers are hair.
- each of the hair curlers if two or more hair curlers are used, may be covered individually by a coating means. It is advantageous to cover each hair curler because leaking to the scalp of the composition which has been applied onto keratin fibers in the step b) can be prevented.
- a coating means may cover all hair curlers, if two or more hair curlers are used.
- the coating means may cover the entirety of the head if the keratin fibers are hair.
- the occlusive space formed in the step d) may be maintained during the step e) .
- the coating means may be removed only after the step e) or after the stop of the heating in the step e) .
- the composition may be applied to keratin fibers before applying mechanical tension to the keratin fibers. It may be possible that the keratin fibers are left as they are for a certain amount of time, if necessary, before and/or after
- the keratin fibers may be fixed by oxidation after being taken out from the coating means.
- the present invention also relates to a composition for treating keratin fibers to be heated in an occlusive space, comprising at least one saccharide or derivative thereof,
- composition contains neither a reducing agent nor a source of carbonate ions of the formula:
- X is a group selected from the group consisting of 0 " , OH, NH 2 , 0- OH, and 0-COO " .
- This composition may not need to be used in combination with an oxidizing agent which is used in a conventional permanent
- the composition may be used in one step, whereas two steps (reducing step and oxidizing step) are necessary in the conventional permanent deformation of keratin fibers.
- This composition may have the same technical features as those of the composition described above.
- the present invention also relates to a kit for treating keratin fibers, comprising:
- At least one reshaping means to provide the keratin fibers with mechanical tension
- At least one coating means to form an occlusive space, and at least one heater to heat the keratin fibers in the occlusive space;
- composition comprising at least one saccharide or derivative
- composition contains neither a reducing agent nor a source of carbonate ions of the formula:
- X is a group selected from the group consisting of 0 “ , OH, NH 2 , 0-OH, and O-COO " .
- the coating means and the heater, as well as the composition in the kit, may be the same as those described above.
- composition 1 A hair treatment composition (referred to as "Composition 1") having the following composition shown in Table 1 was prepared (active ingredients in wt %) .
- Composition 1 was applied to a lg natural Japanese hair swatch for 20 minutes. Then, the hair was wrapped by a plastic film and covered by a flexible heating film (FTH-050 from Tokyo
- the hair was heated in occlusive conditions for 10 minutes at 80°C. After the heating step, the hair was rinsed and dried. The hair was soft and smooth.
- Composition 1 was applied to a lg natural Japanese hair swatch which was the same as that used in Example 1 for 20 minutes.
- composition 2 A hair treatment composition (referred to as "Composition 2 " ) having the following composition shown in Table 2 was prepared (active ingredients in wt %) .
- Composition 2 was applied to a lg natural Japanese hair swatch previously wrapped on a 1.7 cm heating perm-roller for 15 minutes. Then, the perm-roller was covered by a plastic film and plugged into a Digital Perm Machine (Oohiro, model ODIS-2) . After the heating process at 90°C for 15 minutes, the hair was rinsed, removed from the perm-roller and dried.
- ODIS-2 Digital Perm Machine
- Composition 2 was applied to a lg natural Japanese hair swatch which was the same as that used in Example 2 for 15 minutes.
- composition 3 A hair treatment composition having the following composition shown in Table 3 was prepared (active ingredients in wt %).
- Composition 3 was applied to a Ig natural Japanese hair swatch previously wrapped on a 1.7 cm heating perm-roller for 15 minutes. Then, the perm-roller was covered by a plastic film and plugged into a Digital Perm Machine (Oohiro, model ODIS-2) . After the heating process at 90°C for 15 minutes, the hair was removed from the perm-roller, rinsed and dried.
- ODIS-2 Digital Perm Machine
- Composition 3 was applied to a lg natural Japanese hair swatch which was the same as that used in Example 2 for 15 minutes.
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Abstract
La présente invention concerne un procédé de traitement de fibres de kératine qui comprend les étapes consistant à : appliquer sur les fibres de kératine, une composition contenant au moins un saccharide ou un dérivé de saccharide; placer ensuite les fibres de kératine dans un espace occlusif; puis chauffer les fibres de kératine. La composition ne contient pas d'agent réducteur ni de source d'ions carbonate de formule:...- dans la formule X représente un groupe sélectionné dans le groupe formé par O-, OH, NH2, O- OH et O-COO-. La présente invention concerne également la composition elle-même et une trousse à utiliser pour le procédé décrit ci-avant.
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PCT/JP2009/071735 WO2011074143A1 (fr) | 2009-12-18 | 2009-12-18 | Procédé de traitement de fibres de kératine |
JP2012528138A JP2013514264A (ja) | 2009-12-18 | 2009-12-18 | ケラチン繊維を処理する方法 |
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PCT/JP2009/071735 WO2011074143A1 (fr) | 2009-12-18 | 2009-12-18 | Procédé de traitement de fibres de kératine |
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KR20210031546A (ko) * | 2015-08-04 | 2021-03-19 | 오지 홀딩스 가부시키가이샤 | 화장료 |
US9833398B2 (en) | 2016-01-11 | 2017-12-05 | The Procter & Gamble Company | Method of treating a skin condition and compositions therefor |
CN107184418A (zh) * | 2017-04-06 | 2017-09-22 | 山东省药学科学院 | 一种含普鲁兰多糖的护发素 |
US11110049B2 (en) | 2017-06-23 | 2021-09-07 | The Procter & Gamble Company | Composition and method for improving the appearance of skin |
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US10874600B2 (en) | 2018-06-18 | 2020-12-29 | The Procter & Gamble Company | Method for degrading bilirubin in skin |
FR3083110A1 (fr) * | 2018-06-29 | 2020-01-03 | L'oreal | Procede de mise en forme des cheveux comprenant une etape d’application d’une composition comprenant un sucre ou derive de sucre, une etape de mise en forme et un long temps de pause |
WO2020002524A1 (fr) * | 2018-06-29 | 2020-01-02 | L'oreal | Procédé de mise en forme des cheveux comprenant une étape d'application d'une composition comprenant un sucre ou un dérivé de sucre et une étape de mise en forme des cheveux avec une longue durée d'application |
US11622963B2 (en) | 2018-07-03 | 2023-04-11 | The Procter & Gamble Company | Method of treating a skin condition |
FR3094230A1 (fr) * | 2019-04-01 | 2020-10-02 | Societe Limousine D'application Biologique | Utilisation capillaire de l’association de galactomannanes obtenus a partir de caesalpinia spinosa et de galactanes sulfates reticules obtenus a partir de kappaphycus alvarezii |
GB2589948B (en) * | 2019-09-06 | 2022-01-26 | Henkel Ag & Co Kgaa | Styling composition for temporarily shaping keratinous fibers and its use |
GB2589948A (en) * | 2019-09-06 | 2021-06-16 | Henkel Ag & Co Kgaa | Styling composition for temporarily shaping keratinous fibers and its use |
US11571379B2 (en) | 2020-01-24 | 2023-02-07 | The Procter & Gamble Company | Skin care composition |
US10959933B1 (en) | 2020-06-01 | 2021-03-30 | The Procter & Gamble Company | Low pH skin care composition and methods of using the same |
US11583488B2 (en) | 2020-06-01 | 2023-02-21 | The Procter & Gamble Company | Method of improving penetration of a vitamin B3 compound into skin |
US11911498B2 (en) | 2020-06-01 | 2024-02-27 | The Procter & Gamble Company | Low pH skin care composition and methods of using the same |
US12036302B2 (en) | 2020-12-14 | 2024-07-16 | The Procter & Gamble Company | Method of treating oxidative stress in skin and compositions therefor |
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