[go: up one dir, main page]

WO2010073623A1 - Procédé pour la formation d'un film de revêtement et fluide de revêtement - Google Patents

Procédé pour la formation d'un film de revêtement et fluide de revêtement Download PDF

Info

Publication number
WO2010073623A1
WO2010073623A1 PCT/JP2009/007124 JP2009007124W WO2010073623A1 WO 2010073623 A1 WO2010073623 A1 WO 2010073623A1 JP 2009007124 W JP2009007124 W JP 2009007124W WO 2010073623 A1 WO2010073623 A1 WO 2010073623A1
Authority
WO
WIPO (PCT)
Prior art keywords
hydrophobic
coating
fine particles
organic solvent
coating film
Prior art date
Application number
PCT/JP2009/007124
Other languages
English (en)
Japanese (ja)
Inventor
真子義邦
長谷川博
Original Assignee
株式会社カーメイト
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社カーメイト filed Critical 株式会社カーメイト
Publication of WO2010073623A1 publication Critical patent/WO2010073623A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23—Oxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60S—SERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
    • B60S1/00—Cleaning of vehicles
    • B60S1/02—Cleaning windscreens, windows or optical devices
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/213—SiO2
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/76—Hydrophobic and oleophobic coatings

Definitions

  • the present invention relates to a coating film forming method and a coating liquid used for forming the coating film, and in particular, exterior walls and roofs of buildings, bodies of aircraft, ships, vehicles, etc., glass, wheels, etc., side mirrors for passenger cars,
  • the present invention relates to a coating film forming method and a coating liquid applied to a heat exchanger, a parabolic antenna, an electric wire, and the like of an air conditioner.
  • JP 2003-206477 A and JP 2003-306670 A disclose a surface of a mirror or the like using a water repellent composition in which inorganic or organic fine particles hydrophobized are contained in an organic solvent. Discloses a method of forming a super water-repellent coating.
  • the presence of moisture on the surface of an object (mirror or the like) on which a film is formed has an adverse effect, and super water repellency cannot be realized in the formed film. Therefore, it is necessary to sufficiently remove moisture from the surface of the object and dry it before the film forming operation, and a complicated operation is required.
  • the film forming operation cannot be performed in an environment such as rain. *
  • the present invention has been made to solve the above-described problems, and an object of the present invention is to provide a film forming method and a coating liquid capable of forming a transparent and super-water-repellent coating film without requiring a complicated operation. Is to provide.
  • the coating film forming method of the present invention comprises a coating liquid in which fine particles having a hydrophobic surface and an average primary particle diameter of 100 nm or less are dispersed in an organic solvent containing a hydrophobic solvent in an amount of 65% by mass or more in the total organic solvent.
  • the coating liquid is applied to an object having a hydrophobic surface to form a film.
  • the object having a hydrophobic surface can be made hydrophobic by subjecting the surface of the hydrophilic object to a hydrophobic treatment.
  • the coating liquid it is preferable to use an aerosol method or a flow coating method, or to coat using a hydrophobic impregnated body.
  • the fine particles having a hydrophobic surface are preferably hydrophobic silica.
  • the coating liquid of the present invention is characterized in that fine particles having a hydrophobic surface and an average primary particle size of 100 nm or less are dispersed in an organic solvent containing a hydrophobic solvent in an amount of 65% by mass or more in the total organic solvent. . *
  • the fine particles having a hydrophobic surface are preferably hydrophobic silica.
  • a superhydrophobic film having transparency can be formed without performing a complicated operation.
  • the coating liquid of the present invention is obtained by dispersing fine particles having a hydrophobic surface and an average primary particle diameter of 100 nm or less in an organic solvent.
  • this organic solvent needs to contain a hydrophobic solvent in an amount of 65% by mass or more in the total organic solvent, and preferably contains 75% by mass or more.
  • the effect of the present application cannot be exerted with an organic solvent having a hydrophobic solvent content of less than 65% by mass in the total organic solvent. Therefore, if water is present on the surface of the coating object, super water repellency is achieved. It cannot be expressed. *
  • the fine particles used in the present invention are required to have a hydrophobic surface and an average primary particle size of 100 nm or less.
  • the average primary particle diameter of the fine particles is preferably in the range of 1 to 100 nm, and more preferably in the range of 5 to 100 nm. This is because if the particle diameter of the fine particles exceeds 100 nm, light scattering occurs on the surface of the coating film, and transparency may not be maintained. That is, the coating film in which the fine particles are attached to the surface of glass or the like has irregularities having the same size and height as the fine particles.
  • the wavelength of visible light Mainly about 400 to 800 nm
  • the surface of the coating film is not scattered and light can be kept transparent. Therefore, when the object to which the coating composition of the present invention is applied is glass, a mirror, etc., the transparency is effectively utilized and it is particularly effective.
  • the shape of the fine particles is not limited to a spherical shape in a strict sense.
  • the crystal form or aggregated form may be substantially spherical, cylindrical, scaly, fibrous, indefinite, polyhedral, or the like.
  • Fine particles whose surface is hydrophobic are mainly composed of oxides such as silicon, titanium, aluminum, zirconium, antimony, tin, tungsten, zinc, iron, cerium, manganese, copper, magnesium, holmium, nickel, or carbon.
  • oxides such as silicon, titanium, aluminum, zirconium, antimony, tin, tungsten, zinc, iron, cerium, manganese, copper, magnesium, holmium, nickel, or carbon.
  • silicon oxide is particularly preferable. In this invention, these can be used individually or in mixture of 2 or more types.
  • the fine particles having a hydrophobic surface are preferably hydrophobic silica.
  • silica means not only those that exist strictly in the state of SiO 2 but also silicon oxide.
  • the fine particles whose surface is hydrophobic means those whose surface is hydrophobized.
  • the hydrophobic silica means one whose surface is hydrophobized.
  • the method for hydrophobizing the surface of the fine particles is not particularly limited as long as it can impart hydrophobicity to the surface of the fine particles, and is appropriately adopted.
  • the surface contains fluorine or an alkyl group.
  • the method for containing fluorine or an alkyl group on the surface of the fine particles include a method using an organometallic compound such as a silylating agent, a silane coupling agent, and alkylaluminum.
  • the silylating agent is a compound in which an alkyl group, an allyl group, a fluoroalkyl group containing fluorine, or the like is bonded to a hydrolyzable silyl group having affinity or reactivity with an inorganic material.
  • Examples of the hydrolyzable group bonded to silicon include an alkoxy group, a halogen, an acetoxy group, and the like. Usually, an alkoxy group such as a methoxy group and an ethoxy group, and chlorine are preferably used.
  • a trimethylsilylating agent, alkylsilanes, arylsilanes, fluoroalkylsilanes and the like can be mentioned.
  • the hydrophilic fine particles may be hydrophobized to make the surface hydrophobic.
  • the hydrophobizing treatment by dry means that the hydrophilic fine particles and the hydrophobizing agent are reacted in the gas phase.
  • the hydrophobizing agent monomethyltrichlorosilane, dimethyldichlorosilane, hexamethyldisilazane, silicone oil, or the like can be used.
  • silicon dioxide synthesized at high heat can be hydrophobized in a fluidized bed using dimethyldichlorosilane.
  • the hydrophobization reaction is preferably performed at a temperature of 400 to 600 ° C.
  • the hydrophobizing treatment by wet means that the hydrophilic fine particles and the hydrophobizing agent are reacted in a solution. It should be noted that the degree of hydrophobicity of the fine particles having a hydrophobic surface is preferably designed as appropriate according to the material of the object to be coated and the type of organic solvent used. *
  • hydrophobic silica containing a methyl group on the silica surface examples include, for example, a trade name “Leolosil HM20S” (manufactured by Tokuyama Corporation, average primary particle size 12 nm), and a trade name “Leolosil HM30S” (produced by Tokuyama Corporation, average Primary particle diameter 7 nm), trade name “Leoroceal HM40S” (manufactured by Tokuyama Corporation, average primary particle diameter 7 nm), trade name “Leoroceal DM30S” (manufactured by Tokuyama Corporation, average primary particle diameter 7 nm), trade name “Leolosil” ZD30S "(manufactured by Tokuyama Co., Ltd., average primary particle diameter 7 nm) and the like can be obtained commercially.
  • a trade name “Leolosil HM20S” manufactured by Tokuyama Corporation, average primary particle size 12 nm
  • Leolosil HM30S produced by Tokuyama Corporation
  • the coating liquid of the present invention can further contain a coupling agent.
  • the coupling agent used in the present invention include silane coupling agents, titanate coupling agents, aluminate coupling agents, zirconia coupling agents and the like. These coupling agents may be used alone or in combination of two or more.
  • silane coupling agents include fluoroalkyl silanes (heptadecafluorodecyltrimethoxysilane, trifluoropropyltrimethoxysilane, etc.), alkyl silanes (decyltrimethoxysilane, etc.), and aluminate coupling agents. Examples thereof include alkyl acetoacetate aluminum diisopropylate. *
  • silane coupling agent trade name “TSL8233” (heptadecafluorodecyltrimethoxysilane, manufactured by Momentive), trade name “KBM-7103” (trifluoropropyltrimethoxysilane, manufactured by Shin-Etsu Chemical Co., Ltd.) ), Trade name “KBM-3103” (decyltrimethoxysilane, manufactured by Shin-Etsu Chemical Co., Ltd.) and the like can be obtained commercially.
  • TSL8233 heptadecafluorodecyltrimethoxysilane, manufactured by Momentive
  • KBM-7103 trifluoropropyltrimethoxysilane, manufactured by Shin-Etsu Chemical Co., Ltd.
  • trade name “KBM-3103” decyltrimethoxysilane, manufactured by Shin-Etsu Chemical Co., Ltd.
  • the titanate coupling agent the trade name “Plenact 38S” (manufactured by Ajinomoto Fine Techno Co., Ltd.), and as the aluminate coupling agent, the trade name “Plenact AL-M” (alkyl acetate aluminum diisopropylate).
  • a zirconia-based coupling agent a trade name “KENRIACT NZ01” (manufactured by Kenrich Co., Ltd.) and the like can be obtained commercially.
  • KENRIACT NZ01 a trade name “KENRIACT NZ01” (manufactured by Kenrich Co., Ltd.) and the like can be obtained commercially.
  • the amount of fine particles having hydrophobic surfaces is preferably in the range of 0.1% by mass or more and 15.0% by mass or less in the coating solution, and in the range of 1% by mass or more and 5% by mass or less. More preferably it is. This is because sufficient water repellency may not be obtained if the amount of fine particles added is less than 0.1% by mass, and transparency may be inferior if it exceeds 15.0% by mass. *
  • the coating liquid of the present invention is formed using an organic solvent containing a hydrophobic solvent of 65% by mass or more in the total organic solvent.
  • the organic solvent functions as a solvent for stably dispersing fine particles and the like.
  • organic solvent used in the present invention either a polar organic solvent or a nonpolar organic solvent can be used.
  • organic solvent preferably used in the present invention include methyl alcohol, ethyl alcohol, isopropyl alcohol, allyl alcohol, ethylene glycol, propylene glycol, 3-methoxy-3-methyl-1-butanol, and 1-methoxy-2-.
  • Polar solvents such as alcohols such as propanol, ketones such as acetone and ethyl methyl ketone, ethers such as dimethyl ether, ethyl methyl ether, diethyl ether and dibutyl ether, esters such as ethyl acetate, hexane, n- Nonpolar solvents such as hexane, heptane, isooctane and the like can be mentioned.
  • Alcohols such as propanol
  • ketones such as acetone and ethyl methyl ketone
  • ethers such as dimethyl ether, ethyl methyl ether, diethyl ether and dibutyl ether
  • esters such as ethyl acetate, hexane, n-
  • Nonpolar solvents such as hexane, heptane, isooctane and the like can be mentioned.
  • the “hydrophobic solvent” means an organic solvent that does not substantially dissolve water.
  • the hydrophobic solvent used in the present invention include alkanes having 5 to 16 carbon atoms, alkenes, cycloalkanes, aromatics, and mixtures thereof, fluorine-based solvents, cyclic silicones (decamethylcyclohexane). Pentasiloxane, octamethylcyclotetrasiloxane, etc.), low-viscosity silicone oil (dimethylsilicone oil, etc.), and the like.
  • additives that are usually used in general coating liquids and the like can be added within a range that does not impair the effects of the present invention.
  • ultraviolet absorbers antioxidants, Coloring agents, fragrances, preservatives, acids, alkalis and the like can be added.
  • fine particles having a hydrophobic surface and an average primary particle size of 100 nm or less are dispersed in an organic solvent by a cavitation action.
  • fine particles are put in an organic solvent and dispersed by using an ultrasonic disperser or the like.
  • the fine particles dispersed by the cavitation action exhibit unexpected super water repellency, but this mechanism is not clear.
  • bubbles are instantaneously contracted and broken to disperse the hydrophobic fine particles in a good state or have some action on the fine particles themselves.
  • super-water repellency may be exhibited even when dispersed by a disperser such as a homogenizer, but adjustment is necessary in consideration of the transparency of the coating film to be formed.
  • a fine particle having a hydrophobic surface and, if necessary, a coating liquid in which a binder or a coupling agent is dispersed in a solvent are applied to the surface of an object to be coated such as glass or mirror, and then dried.
  • water repellency can be imparted to the object to be coated (coating object).
  • the fine particles adhere to the surface of the object to be coated and form irregularities.
  • the unevenness serves to reduce the contact point between the glass and the water droplet. Accordingly, it is possible to achieve super water repellency such that the contact angle of water drops is 150 ° to 175 °.
  • a component that forms a transparent body when dissolved in an organic solvent and dried serves as a binder.
  • the components used in the present invention to form a transparent body when dissolved in an organic solvent and dried are dimethyl, methylphenyl, methylhydrogen, amino-modified, epoxy-modified, epoxy polyether-modified, carboxyl-modified, carboxyl polyether Modified, alcohol-modified, alkyl-modified, alkyl-aralkyl-modified, alkyl-aralkyl polyether-modified, polyether-modified, fluorine-modified silicones and other silicones, phenylmethyl-based resins, methyl-based resins, resins such as modified resins, polyolefin-based Resins, vinyl resins, polyester resins, acrylic resins, epoxy resins, urethane resins, etc., anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants Surfactants such as polyvinyl pyrone
  • anionic surfactant examples include alkylbenzene sulfonic acid, ⁇ -olefin sulfonic acid, alkane sulfonic acid, alkyl sulfate, alkyl polyoxyethylene sulfate, alkyl phosphate, long chain fatty acid, ⁇ -sulfo fatty acid ester and salts thereof.
  • examples of the cationic surfactant include alkyl trimethyl ammonium salt, dialkyl dimethyl ammonium salt, and alkyl dimethyl benzyl ammonium salt.
  • Nonionic surfactants include alkyl polyoxyethylene ether, fatty acid diethanol amino acid, and the like.
  • amphoteric surfactants include dimethylalkylamine oxide, N-alkylbetaines, imidazoline derivatives, and the like. *
  • the surface of the object to be coated is hydrophobic, and when the surface is not hydrophobic, it is preferable to make it hydrophobic in advance.
  • a method for making the surface of the coating object hydrophobic in advance it is not particularly limited before coating operation (if it is before coating operation, it may be just before, several hours, several days, or even longer time may elapse).
  • the surface of the object to be coated (coating object) is subjected to a hydrophobic treatment.
  • a hydrophobic treatment can be applied to the surface of the coating object by applying a water repellent or the like.
  • the glass surface is hydrophobized
  • the glass surface is polished with a glass cleaner to make the glass surface hydrophilic, and then sprayed with a glass coat G3 manufactured by Carmate Co., Ltd. Spread out and leave at room temperature for 24 hours. In this way, the glass surface can be made hydrophobic.
  • the above method can be appropriately applied and used.
  • a method for applying the coating liquid of the present invention is not particularly limited, and a general method can be adopted. Examples thereof include a flow coating method, a dip coating method, a spray coating method, a gravure coating method, a roll coating method, a bar coating method, and a screen printing method.
  • the impregnated body may be impregnated with a coating solution and applied.
  • use an impregnated body that is hydrophobic does not absorb water, for example, does not absorb water for 10 seconds when water is dropped onto an impregnated body placed horizontally. is required.
  • the above coating methods may be used in appropriate combination. *
  • the coating liquid of the present invention is applied to the object to be coated (object) by the above method and then dried.
  • the drying temperature is preferably 0 ° C. to 100 ° C.
  • the drying time is preferably 1 minute to 1 hour. . *
  • the coating liquid of the present invention can be applied to various coated objects.
  • coated objects to be coated include glass such as tempered glass, non-alkali glass and quartz glass, metals such as iron, aluminum, stainless steel and copper, plastics such as polyolefin resin, polyester resin, acrylic resin and polycarbonate. , Stones, concrete and the like. *
  • the coating liquid of the present invention can be coated on, for example, building window glass, exterior light glass, vehicle window glass, automobile side mirrors, sunglasses, window glass for various instruments, bathroom mirrors, etc. It can be used for exterior walls and roofs of buildings, fences, bodies, mirrors and wheels of automobiles, aircraft and ships.
  • a super-water-repellent film is formed on the coating surface formed by coating and drying the coating liquid of the present invention, preventing adhesion of water droplets, dust, etc., maintaining aesthetics and ensuring visibility. can do.
  • a super-water-repellent film is formed on the surface of parts that are subject to water droplets unnecessarily, such as heat exchangers in air conditioners, water droplets can be prevented, airflow resistance can be reduced, and A decrease in conductivity can be prevented.
  • a super water-repellent coating is formed on a parabolic antenna or an electric wire, condensation and icing can be prevented.
  • a transparent coating film can be formed, it can be preferably used for window glass, road mirrors, road signs, signboards and the like of high-rise houses.
  • Lerosil HM40S hydrophobic silica, solid content 100%, average primary particle diameter 7 nm, manufactured by Tokuyama Corporation “Leosileal DM30S”: hydrophobic silica, solid content 100%, average primary particle diameter 7 nm, manufactured by Tokuyama Corporation “Lerosil ZD30S”: Hydrophobic silica, solid content 100%, average primary particle size 7 nm, Tokuyama “TSL8233”: fluoroalkylsilane, heptadecafluorodecyltrimethoxysilane, Momentive “KBM-13”: methyl Trimethoxysilane, manufactured by Shin-Etsu Chemical Co., Ltd.
  • BM-22 Dimethyldimethoxysilane, manufactured by Shin-Etsu Chemical Co., Ltd.
  • KBE-103 Phenyltriethoxysilane, manufactured by Shin-Etsu Chemical Co., Ltd.
  • KBM-3103 Decyltrimethoxysilane, Shin-Etsu Chemical Co., Ltd.
  • “KBM-7103” trifluoropropyltrimethoxysilane, “SR2405” manufactured by Shin-Etsu Chemical Co., Ltd., silicone resin solution, “Unidyne TG-658” manufactured by Dow Corning Toray, fluorinated water and oil repellent, Daikin Industries “TSF404” manufactured by Co., Ltd .: cyclic silicone (octamethylcyclotetrasiloxane), “TSF405” manufactured by Momentive: cyclic silicone (decamethylcyclopentasiloxane), “KF995” manufactured by Momentive: cyclic silicone (decamethylcyclopentasiloxane) “KF96-1.5cst” manufactured by Shin-Etsu Chemical Co., Ltd .: dimethyl silicone oil, IPA manufactured by Shin-Etsu Chemical Co., Ltd .: alcohol solvent (isopropyl alcohol) ethanol: alcohol solvent (ethyl alcohol) nonane: petroleum solvent (Nonan
  • Example 1 Hydrophobic silica having a hydrophobic surface and a particle diameter of about 7 nm (trade name “Leolosil HM30S”, solid content 100%, manufactured by Tokuyama Corporation) 2.0 mass% is obtained by isooctane 80.0.
  • a hydrophobic silica dispersion is prepared by placing in a solvent comprising 1% by mass and 18.0% by mass of isopropyl alcohol (hereinafter also referred to as “IPA”) and dispersing for 1 hour at a frequency of 44 kHz using an ultrasonic disperser. did.
  • IPA isopropyl alcohol
  • the glass substrate (sample glass) having a water-repellent film was prepared by naturally drying at 25 ° C. for 15 minutes to form a film.
  • the surface of the slide glass plate was previously subjected to the following hydrophobization treatment, and coating was performed under two types of coating conditions (DRY, WET). That is, i) DRY: the glass substrate surface was dried, and ii) WET: the glass substrate surface was coated with water droplets.
  • the glass substrate surface is polished with a professional glass water spot cleaner P1 (manufactured by Carmate Co., Ltd.) to make the glass surface hydrophilic.
  • P1 professional glass water spot cleaner
  • the product was spray-coated and spread evenly, and then allowed to stand at room temperature (25 ° C.) for 24 hours.
  • the temperature of the glass substrate at the time of coating, the temperature of the coating liquid, and the water temperature at the time of WET were all adjusted to 25 ° C.
  • the initial finish was visually evaluated. Moreover, based on the said measuring method etc., the initial water droplet contact angle was measured as super-water-repellent evaluation. The results are shown in Table 1. However, in the evaluation of super water repellency, an evaluation criterion “ ⁇ ” or higher was regarded as an acceptable level, and in the evaluation of finish (transparency), an evaluation criterion “ ⁇ ” or larger was regarded as an acceptable level. *
  • Examples 2 to 30, Comparative Examples 1 to 21 A hydrophobic silica dispersion (coating solution) was prepared in the same manner as in Example 1 except that the composition of the coating solution was changed as shown in Tables 1 to 9.
  • the glass substrate As shown in Tables 1 to 9, the glass surface was hydrophobized (or not hydrophobized), and a coating solution was applied thereto to prepare a sample glass. About the obtained sample glass, the same measurement and evaluation as Example 1 were performed. The results are shown in Tables 1 to 9.
  • the impregnated body for example, non-woven fabric
  • the coating liquid is impregnated with the coating liquid so that the impregnation ratios shown in Tables 1 to 9 are obtained. It apply
  • coating was performed by directly spraying on a glass substrate fixed at an inclination of 30 degrees.
  • coating was performed by allowing the liquid to flow on a glass substrate fixed at an inclination of 30 degrees.
  • the coating composition of the present invention can be effectively used in places where it is necessary to impart super water repellency to buildings, automobiles, aircraft, ships and the like.
  • a film having super water repellency can be formed without complicated steps even in the presence of moisture, it can be used particularly effectively even in a portion that requires application in the rain.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Combustion & Propulsion (AREA)
  • Surface Treatment Of Glass (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Paints Or Removers (AREA)

Abstract

L'invention porte sur un procédé pour la formation d'un film de revêtement, par lequel un film de revêtement transparent et hautement hydrofuge peut être formé sans travail pénible. Le procédé comprend : l'utilisation d'un fluide de revêtement préparé par la dispersion de fines particules, dont les surfaces sont hydrophobes et qui ont un diamètre moyen des particulaires primaires inférieur ou égal à 100 nm, dans un solvant organique qui contient un solvant hydrophobe à hauteur de 65 % en masse ou plus par rapport au solvant organique ; l'application du fluide de revêtement sur un substrat, dont la surface est hydrophobe ; et la formation ainsi d'un film de revêtement. L'application du fluide de revêtement peut être effectuée par un procédé par aérosol, un procédé d'application par arrosage, un procédé utilisant un article hydrophobe et apte à être imprégné par un fluide, ou d'autres procédés.
PCT/JP2009/007124 2008-12-26 2009-12-22 Procédé pour la formation d'un film de revêtement et fluide de revêtement WO2010073623A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2008333291A JP4790003B2 (ja) 2008-12-26 2008-12-26 コーティング膜形成方法およびコーティング液
JP2008-333291 2008-12-26

Publications (1)

Publication Number Publication Date
WO2010073623A1 true WO2010073623A1 (fr) 2010-07-01

Family

ID=42287270

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2009/007124 WO2010073623A1 (fr) 2008-12-26 2009-12-22 Procédé pour la formation d'un film de revêtement et fluide de revêtement

Country Status (2)

Country Link
JP (1) JP4790003B2 (fr)
WO (1) WO2010073623A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9217094B2 (en) 2011-07-28 2015-12-22 The Board Of Trustees Of The University Of Illinois Superhydrophobic compositions
US9364859B2 (en) 2011-07-28 2016-06-14 Kimberly-Clark Worldwide, Inc. Superhydrophobic surfaces
US9803100B2 (en) 2013-04-30 2017-10-31 Kimberly-Clark Worldwide, Inc. Non-fluorinated water-based superhydrophobic surfaces
US10005917B2 (en) 2013-04-30 2018-06-26 Kimberly-Clark Worldwide, Inc. Non-fluorinated water-based superhydrophobic compositions
US10533096B2 (en) 2015-02-27 2020-01-14 Kimberly-Clark Worldwide, Inc. Non-fluorinated water-based superhydrophobic compositions
WO2022009689A1 (fr) 2020-07-09 2022-01-13 ダイキン工業株式会社 Particule fine organique
US11596975B2 (en) 2017-02-14 2023-03-07 Mitsubishi Electric Corporation Water repellent coating film and product provided with same
WO2024113486A1 (fr) * 2022-11-30 2024-06-06 苏州大学 Microplaque super-hydrophobe pour culture cellulaire tridimensionnelle, puce microfluidique multi-organe et son utilisation
WO2024113488A1 (fr) * 2022-11-30 2024-06-06 苏州大学 Mini-modèle de mammifère pour la détection de l'effet, de la toxicité et de la pharmacocinétique d'un médicament et son utilisation

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2942380B1 (fr) 2013-01-07 2018-01-31 Mitsubishi Electric Corporation Composition de revêtement, procédé de production associé et article revêtu article
JP5701441B1 (ja) * 2014-09-01 2015-04-15 エムケイテック株式会社 撥水剤組成物
JP6732540B2 (ja) * 2015-05-29 2020-07-29 三洋化成工業株式会社 樹脂粒子及び樹脂粒子分散液の製造方法
JP6498091B2 (ja) * 2015-09-25 2019-04-10 Ｊｘ金属株式会社 表面処理金属箔、積層体、プリント配線板、半導体パッケージ、電子機器
EP3467061B1 (fr) 2016-06-02 2021-12-08 M. Technique Co., Ltd. Composition d'agent bloquant les ultraviolets et/ou le proche infrarouge pour matériau transparent
JP6995477B2 (ja) * 2016-12-28 2022-01-14 日華化学株式会社 撥水剤組成物、撥水性繊維製品及び撥水性繊維製品の製造方法
JP6849475B2 (ja) * 2017-02-22 2021-03-24 株式会社ソフト９９コーポレーション 撥水処理剤
WO2021181549A1 (fr) * 2020-03-11 2021-09-16 三菱電機株式会社 Film de revêtement hydrofuge et produit sur lequel est formé ledit film de revêtement hydrofuge, procédé pour la récupération dudit film de revêtement hydrofuge et procédé pour la détection d'une détérioration dudit film de revêtement hydrofuge
TWI805995B (zh) * 2021-01-28 2023-06-21 旭諾生物科技股份有限公司 用於口罩的抗菌液

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003206477A (ja) * 2002-01-10 2003-07-22 Toyo Riken Kk 超撥水剤組成物

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003206477A (ja) * 2002-01-10 2003-07-22 Toyo Riken Kk 超撥水剤組成物

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9217094B2 (en) 2011-07-28 2015-12-22 The Board Of Trustees Of The University Of Illinois Superhydrophobic compositions
US9364859B2 (en) 2011-07-28 2016-06-14 Kimberly-Clark Worldwide, Inc. Superhydrophobic surfaces
US9803100B2 (en) 2013-04-30 2017-10-31 Kimberly-Clark Worldwide, Inc. Non-fluorinated water-based superhydrophobic surfaces
US10005917B2 (en) 2013-04-30 2018-06-26 Kimberly-Clark Worldwide, Inc. Non-fluorinated water-based superhydrophobic compositions
US10533096B2 (en) 2015-02-27 2020-01-14 Kimberly-Clark Worldwide, Inc. Non-fluorinated water-based superhydrophobic compositions
US11596975B2 (en) 2017-02-14 2023-03-07 Mitsubishi Electric Corporation Water repellent coating film and product provided with same
WO2022009689A1 (fr) 2020-07-09 2022-01-13 ダイキン工業株式会社 Particule fine organique
KR20230013069A (ko) 2020-07-09 2023-01-26 다이킨 고교 가부시키가이샤 유기 미립자
WO2024113486A1 (fr) * 2022-11-30 2024-06-06 苏州大学 Microplaque super-hydrophobe pour culture cellulaire tridimensionnelle, puce microfluidique multi-organe et son utilisation
WO2024113488A1 (fr) * 2022-11-30 2024-06-06 苏州大学 Mini-modèle de mammifère pour la détection de l'effet, de la toxicité et de la pharmacocinétique d'un médicament et son utilisation

Also Published As

Publication number Publication date
JP4790003B2 (ja) 2011-10-12
JP2010155727A (ja) 2010-07-15

Similar Documents

Publication Publication Date Title
JP4790003B2 (ja) コーティング膜形成方法およびコーティング液
JP6305462B2 (ja) スルホネート官能コーティング及び方法
JP4198598B2 (ja) 超撥水性基体
RU2519258C2 (ru) Покрытие на основе двуокиси кремния для повышенной гидрофильности
US7344783B2 (en) Durable hydrophobic surface coatings using silicone resins
JP2002080830A (ja) 親水性部材およびその製造方法
JP6713319B2 (ja) 撥水性被膜付基材およびその製造方法
JP2012187529A (ja) 撥水性部材及びその製造方法、並びに空調機室外機
JP5553297B2 (ja) コーティング組成物
JP4060333B2 (ja) 撥水剤とその使用
JPH09202651A (ja) 親水性被膜及びその形成法
JP2008069365A (ja) 撥水剤とその使用
JP2009161579A (ja) コーティング組成物
JP2005350502A (ja) 超撥水性被膜被覆物品、その製造方法及び超撥水性被膜形成用塗工材料
JP2009018946A (ja) 透明超撥水性膜の形成方法及び透明超撥水性膜を有するガラス基材
JP2004149700A (ja) コーティング組成物と、その製造方法、ならびに、このコーティング組成物で被覆された被覆体
JP4963896B2 (ja) 撥水処理剤および撥水処理方法
JP2000026756A (ja) コーティング組成物、基材表面のコーティング方法、表面にコーティングされた基材
EP3394175A1 (fr) Composition, procédé de fabrication de composition, et article
JP2005218980A (ja) コーティング組成物の塗工方法、及び、コーティング組成物含浸体
CN117343806B (zh) 一种洗车液及其制备方法
JP4020602B2 (ja) 浴室用防曇鏡およびその製造方法
JP4093987B2 (ja) 表面処理された基材の製造方法
JPH1110077A (ja) 防汚性自動車及び自動車車体用表面処理剤
WO2025089219A1 (fr) Stratifié et procédé de fabrication de stratifié

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 09834431

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 09834431

Country of ref document: EP

Kind code of ref document: A1