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WO2008153016A1 - 水素分離膜、及び選択透過膜型反応器 - Google Patents

水素分離膜、及び選択透過膜型反応器 Download PDF

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Publication number
WO2008153016A1
WO2008153016A1 PCT/JP2008/060595 JP2008060595W WO2008153016A1 WO 2008153016 A1 WO2008153016 A1 WO 2008153016A1 JP 2008060595 W JP2008060595 W JP 2008060595W WO 2008153016 A1 WO2008153016 A1 WO 2008153016A1
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WIPO (PCT)
Prior art keywords
added metal
hydrogen separation
separation membrane
membrane
palladium
Prior art date
Application number
PCT/JP2008/060595
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English (en)
French (fr)
Inventor
Kenichi Noda
Original Assignee
Ngk Insulators, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ngk Insulators, Ltd. filed Critical Ngk Insulators, Ltd.
Priority to JP2009519253A priority Critical patent/JP5814506B2/ja
Priority to EP08765384.6A priority patent/EP2156883B1/en
Publication of WO2008153016A1 publication Critical patent/WO2008153016A1/ja
Priority to US12/622,546 priority patent/US8747766B2/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0223—Group 8, 9 or 10 metals
    • B01D71/02231—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D71/02232—Nickel
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    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/0257—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical annular shaped bed
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
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Abstract

　本発明の水素分離膜は、パラジウムと、他の異なる二種類の金属である添加金属Ａ及び添加金属Ｂとを少なくとも含むパラジウム合金からなり、前記添加金属Ａと前記添加金属Ｂのそれぞれは、パラジウムに対してそれぞれ全率固溶するものであるとともに、前記添加金属Ａと前記添加金属Ｂは、平衡状態図において３重点を有し、かつ、金属間化合物を形成しないものである。本発明の水素分離膜は、水素の透過性能に優れるとともに、耐久性にも優れている。
PCT/JP2008/060595 2007-06-11 2008-06-10 水素分離膜、及び選択透過膜型反応器 WO2008153016A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2009519253A JP5814506B2 (ja) 2007-06-11 2008-06-10 水素分離膜、及び選択透過膜型反応器
EP08765384.6A EP2156883B1 (en) 2007-06-11 2008-06-10 Method for producing hydrogen separation membrane and selectively permeable membrane reactor
US12/622,546 US8747766B2 (en) 2007-06-11 2009-11-20 Hydrogen separation membrane and permselective membrane reactor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-154326 2007-06-11
JP2007154326 2007-06-11

Related Child Applications (1)

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US12/622,546 Continuation US8747766B2 (en) 2007-06-11 2009-11-20 Hydrogen separation membrane and permselective membrane reactor

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WO2008153016A1 true WO2008153016A1 (ja) 2008-12-18

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PCT/JP2008/060595 WO2008153016A1 (ja) 2007-06-11 2008-06-10 水素分離膜、及び選択透過膜型反応器

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US (1) US8747766B2 (ja)
EP (2) EP2156883B1 (ja)
JP (1) JP5814506B2 (ja)
WO (1) WO2008153016A1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010201304A (ja) * 2009-03-02 2010-09-16 Ngk Insulators Ltd 水素分離装置および水素分離装置の運転方法
JP2012152701A (ja) * 2011-01-27 2012-08-16 National Institute Of Advanced Industrial Science & Technology 水素分離膜、その製造方法及び水素分離方法
JP2012200716A (ja) * 2011-03-28 2012-10-22 Jx Nippon Mining & Metals Corp 水素透過性モジュール及びこれを利用した水素分離方法
CN105903349A (zh) * 2016-06-07 2016-08-31 中国工程物理研究院核物理与化学研究所 一种用于氢同位素分离的大面积钯膜装置

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8101243B2 (en) * 2002-04-03 2012-01-24 Colorado School Of Mines Method of making sulfur-resistant composite metal membranes
US9044715B2 (en) * 2007-08-22 2015-06-02 Colorado School Of Mines Unsupported palladium alloy membranes and methods of making same
US9216390B2 (en) 2010-07-15 2015-12-22 Ohio State Innovation Foundation Systems, compositions, and methods for fluid purification
US8778058B2 (en) 2010-07-16 2014-07-15 Colorado School Of Mines Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same
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