[go: up one dir, main page]

WO2006020642A3 - Desulfurization and novel process for same - Google Patents

Desulfurization and novel process for same Download PDF

Info

Publication number
WO2006020642A3
WO2006020642A3 PCT/US2005/028277 US2005028277W WO2006020642A3 WO 2006020642 A3 WO2006020642 A3 WO 2006020642A3 US 2005028277 W US2005028277 W US 2005028277W WO 2006020642 A3 WO2006020642 A3 WO 2006020642A3
Authority
WO
WIPO (PCT)
Prior art keywords
desulfurization
same
novel process
promoter
composition
Prior art date
Application number
PCT/US2005/028277
Other languages
French (fr)
Other versions
WO2006020642A2 (en
Inventor
Tushar V Choudhary
Glenn W Dodwell
Marvin M Johnson
Deborah K Just
Original Assignee
Conocophillips Co
Tushar V Choudhary
Glenn W Dodwell
Marvin M Johnson
Deborah K Just
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Conocophillips Co, Tushar V Choudhary, Glenn W Dodwell, Marvin M Johnson, Deborah K Just filed Critical Conocophillips Co
Priority to BRPI0514299A priority Critical patent/BRPI0514299B1/en
Priority to CN2005800342008A priority patent/CN101432398B/en
Priority to JP2007525741A priority patent/JP2008510035A/en
Priority to EP05784424A priority patent/EP1799794A4/en
Publication of WO2006020642A2 publication Critical patent/WO2006020642A2/en
Publication of WO2006020642A3 publication Critical patent/WO2006020642A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/306—Organic sulfur compounds, e.g. mercaptans
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

A composition comprising a metal oxide and a promoter, wherein at least a portion of the promoter is present as a reduced valence promoter, and methods of preparing such composition are disclosed. The thus-obtained composition is employed in a desulfurization zone to remove sulfur from a hydrocarbon stream.
PCT/US2005/028277 2004-08-10 2005-08-09 Desulfurization and novel process for same WO2006020642A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BRPI0514299A BRPI0514299B1 (en) 2004-08-10 2005-08-09 methods for producing compositions and processes for removing sulfur from a hydrocarbon stream
CN2005800342008A CN101432398B (en) 2004-08-10 2005-08-09 Desulfurization and novel process for same
JP2007525741A JP2008510035A (en) 2004-08-10 2005-08-09 Desulfurization and novel process for it
EP05784424A EP1799794A4 (en) 2004-08-10 2005-08-09 Desulfurization and novel process for same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/914,798 US20050020446A1 (en) 2003-07-23 2004-08-10 Desulfurization and novel process for same
US10/914,798 2004-08-10

Publications (2)

Publication Number Publication Date
WO2006020642A2 WO2006020642A2 (en) 2006-02-23
WO2006020642A3 true WO2006020642A3 (en) 2009-06-04

Family

ID=35908100

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/028277 WO2006020642A2 (en) 2004-08-10 2005-08-09 Desulfurization and novel process for same

Country Status (7)

Country Link
US (1) US20050020446A1 (en)
EP (1) EP1799794A4 (en)
JP (1) JP2008510035A (en)
CN (1) CN101432398B (en)
BR (1) BRPI0514299B1 (en)
RU (1) RU2393919C2 (en)
WO (1) WO2006020642A2 (en)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2531262A1 (en) * 2005-12-21 2007-06-21 Imperial Oil Resources Limited Very low sulfur heavy crude oil and process for the production thereof
JP4896766B2 (en) * 2006-02-24 2012-03-14 コスモ石油株式会社 Hydrocarbon desulfurization agent
BRPI0905900A2 (en) * 2008-02-08 2015-06-30 Vale Inco Ltd "Method for the manufacture of a pre-escorified metal oxide"
US8557019B2 (en) * 2008-02-08 2013-10-15 Vale Inco Limited Process for production of nickel and cobalt using metal hydroxide, metal oxide and/or metal carbonate
JP5518837B2 (en) * 2008-04-16 2014-06-11 ヴァーレ、カナダ、リミテッド Method for producing nickel and cobalt using metal hydroxide, metal oxide and / or metal carbonate
CN101618314B (en) * 2008-05-20 2013-03-06 中国石油化工股份有限公司 Desulfurizing adsorbent, preparation method and application thereof
CN101618313B (en) * 2008-06-30 2012-11-14 中国石油化工股份有限公司 Desulfurization adsorbent, preparation method and application thereof
WO2010075672A1 (en) * 2008-12-31 2010-07-08 中国石油化工股份有限公司 Desulfurizing adsorbent and preparation method and use thereof
JP5334630B2 (en) * 2009-03-06 2013-11-06 Ｊｘ日鉱日石エネルギー株式会社 Hydrocarbon oil desulfurization method and fuel cell system
JP5412584B2 (en) * 2009-10-30 2014-02-12 コリア エレクトリック パワー コーポレイション Zinc-based desulfurization agent molded by spray drying method and method for producing the same
EP3318872A1 (en) 2011-07-20 2018-05-09 The Regents of the University of California Dual-pore device
FR2984762B1 (en) * 2011-12-21 2014-04-25 IFP Energies Nouvelles CATALYTIC ADSORBENT FOR CAPTURING ARSENIC AND SELECTIVE HYDRODESULFURATION OF CATALYTIC CRACKING SPECIES
CA2818272C (en) * 2012-06-12 2017-11-14 China Petroleum & Chemical Corporation An alumina-based sulfur recovery catalyst and preparation method for the same
DE102013015117A1 (en) * 2013-09-12 2015-03-12 Johnson Matthey Catalysts (Germany) Gmbh Catalyst and method for nitrogen oxide reduction in an exhaust gas
CN104549489B (en) * 2013-10-29 2017-07-25 中国石油化工股份有限公司 A kind of desulfurization catalyst and method for its preparation and hydrocarbon oil desulfurization
DE102013113660A1 (en) * 2013-12-06 2015-06-11 Thyssenkrupp Ag Process and coke recovery plant for the treatment of sulfur-containing process residues from petroleum processing; Petroleum coke formed from sulfur-containing process residues
CN104148002B (en) * 2014-07-30 2017-07-11 迪普沃科技（深圳）有限公司 A kind of application of the Zr Ce O double-function catalyzing adsorbents and preparation method thereof with it in fuel desulfuration
CN105583001B (en) * 2014-10-20 2018-05-18 中国石油化工股份有限公司 A kind of method of desulphurization catalyst and preparation method thereof and desulfurization of hydrocarbon oil
US20170056860A1 (en) * 2015-08-28 2017-03-02 Lyondell Chemical Technology, L.P. Epoxidation processes and catalysts for use therein
CN106554832A (en) * 2015-09-24 2017-04-05 刘从荡 A kind of preparation method of concave-convex bar methane desulfurizing dessicant
CN105749863A (en) * 2016-04-06 2016-07-13 山东成泰化工有限公司 Compound desulfurizer and preparation method thereof
CN107474870B (en) * 2016-06-07 2019-11-15 中国石油化工股份有限公司 A kind of vulcanization method of adsorbent
CN108114756A (en) * 2016-11-29 2018-06-05 中国石油化工股份有限公司 A kind of sulfur-containing organic waste gas catalysis oxidation protective agent and its preparation method and application
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
US12025435B2 (en) 2017-02-12 2024-07-02 Magēmã Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil
US12071592B2 (en) 2017-02-12 2024-08-27 Magēmā Technology LLC Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil
US12281266B2 (en) 2017-02-12 2025-04-22 Magẽmã Technology LLC Heavy marine fuel oil composition
US10655074B2 (en) 2017-02-12 2020-05-19 Mag{hacek over (e)}m{hacek over (a)} Technology LLC Multi-stage process and device for reducing environmental contaminates in heavy marine fuel oil
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
CN108686642A (en) * 2018-05-09 2018-10-23 内蒙古包钢和发稀土有限公司 The preparation method of kaolinite soil matrix rare-earth desulfurization catalyst
CN109433219B (en) * 2018-10-31 2021-08-06 沈阳三聚凯特催化剂有限公司 Organic sulfur hydrogenation catalyst, preparation method and application thereof
CN109529860A (en) * 2018-12-04 2019-03-29 云南大学 A kind of X-Sn-Zr reducing catalyst and its preparation method and application
JP7295998B2 (en) * 2019-01-21 2023-06-21 日揮触媒化成株式会社 Desulfurizing agent precursor
JP7120936B2 (en) * 2019-01-21 2022-08-17 日揮触媒化成株式会社 Method for producing desulfurizing agent and method for producing desulfurizing agent precursor
CN114570413B (en) * 2020-12-02 2024-03-12 宁波中科远东催化工程技术有限公司 Material for desulfurization, preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4565800A (en) * 1985-06-24 1986-01-21 Philips Petroleum Company Hydrofining catalysts
US6683024B1 (en) * 2000-03-15 2004-01-27 Conocophillips Company Desulfurization and novel sorbents for same

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2890178A (en) * 1953-10-14 1959-06-09 Exxon Research Engineering Co Hydrocarbon conversion catalysts
US2846363A (en) * 1954-09-29 1958-08-05 Pure Oil Co Catalysts for naphtha reforming
US2964463A (en) * 1956-12-10 1960-12-13 Pure Oil Co Upgrading hydrocarbon oils in the presence of hydrogen with a tungsten oxide, molybdenum oxide on silica-alumina catalyst composite
US3374183A (en) * 1961-03-30 1968-03-19 Ethyl Corp Copper oxide-alumina catalyst composition
US3104268A (en) * 1962-03-19 1963-09-17 Sinclair Research Inc Alkylation of aromatics with a zinc oxide, chromium oxide, copper oxide, silica-alumina catalyst
NL301436A (en) * 1962-12-12
GB1044333A (en) * 1963-04-01 1966-09-28 British Petroleum Co Hydrogenation process
GB1010574A (en) * 1963-04-23 1965-11-17 British Petroleum Co Production of hydrogen-containing gases
US3340012A (en) * 1963-12-19 1967-09-05 Universal Oil Prod Co Hydrogen production in a fluidized bed of attrition resistant catalyst
FR1413913A (en) * 1964-07-08 1965-10-15 Raffinage Cie Francaise Process and catalyst for the dehydrogenation of aliphatic hydrocarbons
US3349025A (en) * 1965-07-15 1967-10-24 Gulf Research Development Co Hydrocracking with a presulfided tungsten oxide composite catalyst from the group comprising of silver, zinc or thorium on a siliceous carrier
US3447893A (en) * 1966-02-04 1969-06-03 Ethyl Corp Oxidation catalysts
US3625867A (en) * 1967-06-02 1971-12-07 Takachika Yoshino Process for production of metal oxide-antimony oxide catalysts
US3501418A (en) * 1967-07-14 1970-03-17 Grace W R & Co Process for preparing cracking catalysts
US3524721A (en) * 1967-12-22 1970-08-18 Ethyl Corp Catalyst composition
CA1021354A (en) * 1972-04-20 1977-11-22 Alvin B. Stiles Methanol synthesis catalyst
US4752623A (en) * 1984-07-30 1988-06-21 The Dow Chemical Company Mixed alcohols production from syngas
US4596654A (en) * 1985-06-24 1986-06-24 Phillips Petroleum Company Hydrofining catalysts
US5045522A (en) * 1990-03-27 1991-09-03 Phillips Petroleum Company Absorption composition comprising zinc titanate for removal of hydrogen sulfide from fluid streams
KR930702472A (en) * 1990-11-07 1993-09-09 크리스토퍼 토마스 아일즈 Hydrodesulfurization
US6254766B1 (en) * 1999-08-25 2001-07-03 Phillips Petroleum Company Desulfurization and novel sorbents for same
US6676829B1 (en) * 1999-12-08 2004-01-13 Mobil Oil Corporation Process for removing sulfur from a hydrocarbon feed
US6274533B1 (en) * 1999-12-14 2001-08-14 Phillips Petroleum Company Desulfurization process and novel bimetallic sorbent systems for same
US6346190B1 (en) * 2000-03-21 2002-02-12 Phillips Petroleum Company Desulfurization and novel sorbents for same
JP4531939B2 (en) * 2000-03-31 2010-08-25 出光興産株式会社 Method for producing nickel-copper desulfurization agent
US7268097B2 (en) * 2000-03-31 2007-09-11 Idemitsu Kosan Co., Ltd. Desulfurizing agent for hydrocarbon derived from petroleum, method for producing hydrogen for use in fuel cell and method for producing nickel-based desulfurizing agent
JP4580071B2 (en) * 2000-03-31 2010-11-10 出光興産株式会社 Desulfurization agent for petroleum hydrocarbons and method for producing hydrogen for fuel cells
JP4580070B2 (en) * 2000-03-31 2010-11-10 出光興産株式会社 Desulfurization agent for petroleum hydrocarbons and method for producing hydrogen for fuel cells
JP4531917B2 (en) * 2000-03-31 2010-08-25 出光興産株式会社 Method for producing nickel-based desulfurization agent
JP4388665B2 (en) * 2000-03-31 2009-12-24 出光興産株式会社 Ni-Cu desulfurizing agent and method for producing hydrogen for fuel cell
US6429170B1 (en) * 2000-05-30 2002-08-06 Phillips Petroleum Company Sorbents for desulfurizing gasolines and diesel fuel
EP1334165A4 (en) * 2000-08-31 2004-11-03 Conoco Phillips Company Desulfurization and novel sorbents for same
DE60208420T2 (en) * 2001-10-25 2006-09-07 Bp Corporation North America Inc., Warrenville SULFUR REMOVAL PROCESS
US7105140B2 (en) * 2002-03-04 2006-09-12 Conocophillips Company Desulfurization compositions
US6878669B2 (en) * 2002-12-23 2005-04-12 Conocophillips Company Desulfurization and sorbent

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4565800A (en) * 1985-06-24 1986-01-21 Philips Petroleum Company Hydrofining catalysts
US6683024B1 (en) * 2000-03-15 2004-01-27 Conocophillips Company Desulfurization and novel sorbents for same

Also Published As

Publication number Publication date
CN101432398B (en) 2012-03-28
RU2007108545A (en) 2008-09-20
RU2393919C2 (en) 2010-07-10
EP1799794A2 (en) 2007-06-27
WO2006020642A2 (en) 2006-02-23
JP2008510035A (en) 2008-04-03
US20050020446A1 (en) 2005-01-27
EP1799794A4 (en) 2010-06-09
CN101432398A (en) 2009-05-13
BRPI0514299B1 (en) 2016-03-29
BRPI0514299A (en) 2008-06-10

Similar Documents

Publication Publication Date Title
WO2006020642A3 (en) Desulfurization and novel process for same
WO2005010124A3 (en) Desulfurization and novel process for same
WO2004029022A3 (en) Catalytic method of producing mercaptans from thioethers
WO2005021684A3 (en) Desulfurization and novel methods for same
PL354251A1 (en) Sorbent composition, process for producing same and use in desulfurization
WO2006053135A3 (en) Desulfurization and novel process for same
WO2012082684A3 (en) Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction
DE60034359D1 (en) SORBING COMPOSITION, METHOD FOR THE PRODUCTION THEREOF AND ITS USE IN DRAINING
WO2004033659A3 (en) Novel tumor suppressor gene and compositions and methods for making and using the same
AU5993298A (en) Process for the presulphurization of catalysts
WO2006131371A8 (en) Method for reducing and/or refining a metal-containing slag
GEP20084323B (en) Paving binders (variants) and manufacturing methods
WO2006071693A3 (en) Injectable non-aqueous suspension
MY152091A (en) Removal of heavy metals from hydrocarbon gases
WO2006113413A3 (en) Method of reusing flexible mold and microstructure precursor composition
AR041800A1 (en) DESULFURATION AND NEW COMPOSITIONS FOR THE SAME
WO2009039019A3 (en) A catalyst composition useful in the catalytic reduction of sulfur compound contained in a gas stream and a method of making and using such composition
WO2001066671A8 (en) Process for removing sulfur compounds from gas and liquid hydrocarbon streams
WO2006026087A3 (en) Process for the removal of heavy metal from gases, and compositions therefor and therewith
WO2005055747A3 (en) Catalysts comprising ultrafine particles
WO2003068693A3 (en) Processes for treating iron-containing waste streams
GB2387840B (en) Process for the utilization of vanadium from chromium ore as vanadium (V) oxide
WO2004066923A3 (en) Compositions and methods for improving recovery after general anesthesia
WO2005098054A8 (en) Method in connection with steel production
PL1761484T3 (en) Method of improving the crushing strength and reducing the dust formation and the caking tendency of urea, and urea composition

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200580034200.8

Country of ref document: CN

AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KM KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NG NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU LV MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2007525741

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2005784424

Country of ref document: EP

Ref document number: 2007108545

Country of ref document: RU

WWP Wipo information: published in national office

Ref document number: 2005784424

Country of ref document: EP

ENP Entry into the national phase

Ref document number: PI0514299

Country of ref document: BR