WO2004052332A1 - Preparations de nettoyage contenant des sels d'acides gras - Google Patents
Preparations de nettoyage contenant des sels d'acides gras Download PDFInfo
- Publication number
- WO2004052332A1 WO2004052332A1 PCT/EP2003/050960 EP0350960W WO2004052332A1 WO 2004052332 A1 WO2004052332 A1 WO 2004052332A1 EP 0350960 W EP0350960 W EP 0350960W WO 2004052332 A1 WO2004052332 A1 WO 2004052332A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- use according
- cleaning
- skin
- acid salts
- fatty acid
- Prior art date
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- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 241000589636 Xanthomonas campestris Species 0.000 description 1
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
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- 125000002252 acyl group Chemical group 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 150000004347 all-trans-retinol derivatives Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-DVKNGEFBSA-N alpha-D-glucose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-DVKNGEFBSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 229940098323 ammonium cocoyl isethionate Drugs 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000003788 bath preparation Substances 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 229940000635 beta-alanine Drugs 0.000 description 1
- 235000010957 calcium stearoyl-2-lactylate Nutrition 0.000 description 1
- OEUVSBXAMBLPES-UHFFFAOYSA-L calcium stearoyl-2-lactylate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O.CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O OEUVSBXAMBLPES-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229940075510 carbopol 981 Drugs 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 229960004203 carnitine Drugs 0.000 description 1
- 150000001746 carotenes Chemical class 0.000 description 1
- 235000005473 carotenes Nutrition 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 229920006184 cellulose methylcellulose Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 150000001841 cholesterols Chemical class 0.000 description 1
- 235000017471 coenzyme Q10 Nutrition 0.000 description 1
- ACTIUHUUMQJHFO-UPTCCGCDSA-N coenzyme Q10 Chemical compound COC1=C(OC)C(=O)C(C\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UPTCCGCDSA-N 0.000 description 1
- 229940110767 coenzyme Q10 Drugs 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229960003624 creatine Drugs 0.000 description 1
- 239000006046 creatine Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 230000002354 daily effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical class OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 229940120503 dihydroxyacetone Drugs 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 229940079868 disodium laureth sulfosuccinate Drugs 0.000 description 1
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 description 1
- ZPRZNBBBOYYGJI-UHFFFAOYSA-L disodium;2-[1-[2-(carboxylatomethoxy)ethyl]-2-undecyl-4,5-dihydroimidazol-1-ium-1-yl]acetate;hydroxide Chemical compound [OH-].[Na+].[Na+].CCCCCCCCCCCC1=NCC[N+]1(CCOCC([O-])=O)CC([O-])=O ZPRZNBBBOYYGJI-UHFFFAOYSA-L 0.000 description 1
- YGAXLGGEEQLLKV-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-2-sulfonatobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)CC(C([O-])=O)S([O-])(=O)=O YGAXLGGEEQLLKV-UHFFFAOYSA-L 0.000 description 1
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- GZJITQIQRTXXLW-UHFFFAOYSA-N dodecanoic acid;tridecanoic acid Chemical compound CCCCCCCCCCCC(O)=O.CCCCCCCCCCCCC(O)=O GZJITQIQRTXXLW-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036074 healthy skin Effects 0.000 description 1
- GAFMQXDECDEWTD-UHFFFAOYSA-N heptadecanoic acid;hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCC(O)=O GAFMQXDECDEWTD-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 229930013032 isoflavonoid Natural products 0.000 description 1
- 150000003817 isoflavonoid derivatives Chemical class 0.000 description 1
- 235000012891 isoflavonoids Nutrition 0.000 description 1
- 150000003893 lactate salts Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940116335 lauramide Drugs 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N lauric acid amide propyl betaine Natural products CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 1
- 229940048848 lauryl glucoside Drugs 0.000 description 1
- 235000019136 lipoic acid Nutrition 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 235000021239 milk protein Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- DFOHESLHWMVRRC-UHFFFAOYSA-N nonadecanoic acid;octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCCC(O)=O DFOHESLHWMVRRC-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229940046947 oleth-10 phosphate Drugs 0.000 description 1
- NPKKRSHVJIQBKU-UHFFFAOYSA-N ornogenin Natural products CC(OC(=O)C=Cc1ccccc1)C2(O)CCC3(O)C4(O)CC=C5CC(O)CCC5(C)C4CC(OC(=O)C=Cc6ccccc6)C23C NPKKRSHVJIQBKU-UHFFFAOYSA-N 0.000 description 1
- 230000036542 oxidative stress Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001575 pathological effect Effects 0.000 description 1
- 229940086615 peg-6 cocamide Drugs 0.000 description 1
- GBOKETAUHCMAED-UHFFFAOYSA-N pentadecanoic acid;tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCC(O)=O GBOKETAUHCMAED-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 230000008832 photodamage Effects 0.000 description 1
- 235000011765 phytoene Nutrition 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 210000001732 sebaceous gland Anatomy 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000008257 shaving cream Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 230000008591 skin barrier function Effects 0.000 description 1
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940102544 sodium laureth-13 carboxylate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- 229940075560 sodium lauryl sulfoacetate Drugs 0.000 description 1
- 229940048109 sodium methyl cocoyl taurate Drugs 0.000 description 1
- BCISDMIQYBCHAT-UHFFFAOYSA-M sodium;2-(dodecanoylamino)ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCCS([O-])(=O)=O BCISDMIQYBCHAT-UHFFFAOYSA-M 0.000 description 1
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 1
- UAJTZZNRJCKXJN-UHFFFAOYSA-M sodium;2-dodecoxy-2-oxoethanesulfonate Chemical compound [Na+].CCCCCCCCCCCCOC(=O)CS([O-])(=O)=O UAJTZZNRJCKXJN-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 150000003445 sucroses Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 229960002663 thioctic acid Drugs 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical class OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- GAAKLDANOSASAM-UHFFFAOYSA-N undec-10-enoic acid;zinc Chemical compound [Zn].OC(=O)CCCCCCCCC=C GAAKLDANOSASAM-UHFFFAOYSA-N 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229940118257 zinc undecylenate Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/007—Soaps or soap mixtures with well defined chain length
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/225—Polymers
Definitions
- the present invention relates to the use of fatty acid salts to achieve or increase the selectivity of cosmetic or dermatological cleaning preparations.
- Known agents for cleaning and simultaneous care of the skin are e.g. B. oil-containing cleaning preparations or cleaning preparations with different moisturizers or skin moisturized, which are to re-grease or moisturize the skin during cleaning.
- B. oil-containing cleaning preparations or cleaning preparations with different moisturizers or skin moisturized which are to re-grease or moisturize the skin during cleaning.
- the prior art knows, for example, various types of oil bath preparations, shower oils, cleaning creams and the like.
- the content of one or more fatty acid salts is advantageously from 1.0 to 50% by weight and preferably from 5 to 40% by weight, in each case based on the total weight of the formulation.
- the soaps according to the invention are formed from the corresponding fatty acids by reaction with bases.
- the fatty acids lauric acid (dodecanecarboxylic acid), myristic acid (tetradecanecarboxylic acid), palmitic acid (hexadecanecarboxylic acid), stearic acid (octadecanecarboxylic acid) are advantageous according to the invention.
- one or more fatty acid salts are preferably selected from the group of the lauric, myristic and / or stearic acid salts.
- Bases preferred according to the invention are, for example, sodium hydroxide, potassium hydroxide and / or triethanolamine.
- advantageous preparations in which fatty acid salts are used according to the invention can contain one or more further surface-active compounds, in particular surfactants.
- acylglutamates for example sodium acylglutamate, di-TEA-palmitoylaspartate and sodium caprylic / capric glutamate,
- acyl peptides for example palmitoyl hydrolyzed milk protein, sodium cocoyl hydrolyzed soy protein and sodium / potassium cocoyl hydrolyzed collagen,
- sarcosinates for example myristoyl sarcosin, TEA-lauroyl sarcosinate, sodium lauroyl sarcosinate and sodium cocoyl sarcosinate,
- taurates for example sodium lauroyl taurate and sodium methyl cocoyl taurate
- Carboxylic acids and derivatives such as
- carboxylic acids for example lauric acid, aluminum stearate, magnesium alkanolate and zinc undecylenate,
- ester carboxylic acids for example calcium stearoyl lactylate, laureth-6 citrate and sodium PEG-4 lauramide carboxylate
- ether carboxylic acids for example sodium laureth-13 carboxylate and sodium PEG-6 cocamide carboxylate
- Phosphoric acid esters and salts such as DEA-Oleth-10 phosphate and Dilureth-4 phosphate,
- acyl isethionates e.g. Sodium / ammonium cocoyl isethionate
- alkylsulfonates for example sodium, sodium C 12-14 olefin - sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate,
- Sulfosuccinates for example dioctyl sodium sulfosuccinate, disodium laureth sulfosuccinate, disodium lauryl sulfosuccinate and disodium undecylenamido MEA sulfosuccinate
- sulfuric acid esters such as
- alkyl ether sulfate for example sodium, ammonium, magnesium, MIPA, TIPA laureth sulfate, sodium myreth sulfate and sodium C 12 .1 3 pareth sulfate,
- Alkyl sulfates for example sodium, ammonium and TEA lauryl sulfate.
- Quaternary surfactants contain at least one N atom that is covalently linked to 4 alkyl or aryl groups. Regardless of the pH value, this leads to a positive charge.
- Benzalkonium chloride, alkyl betaine, alkyl amidopropyl betaine and alkyl amidopropyl hydroxysultain are advantageous.
- acyl-dialkylethylenediamine for example sodium acylamphoacetate, disodium acylamphodipropionate, disodium alkylamphodiacetate, sodium acylamphohydroxypropylsulfonate, disodium acylamphodiacetate and sodium acylamphopropionate,
- N-alkylamino acids for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate.
- N-alkyl or N-alkenyl betaines with at least 12 carbon atoms such as.
- Nonionic surfactants to be used advantageously are I. alcohols,
- alkanolamides such as cocamides MEA / DEA / MIPA
- amine oxides such as cocoamidopropylamine oxide
- esters which are formed by esterification of carboxylic acids with ethylene oxide, glycerol, sorbitan or other alcohols, 5.
- ethers for example ethoxylated / propoxylated alcohols, ethoxylated / propoxylated esters, ethoxylated / propoxylated glycerol esters, ethoxylated / propoxylated cholesterols, ethoxylated / propoxylated Triglyceride esters, ethoxylated propoxylated lanolin, ethoxylated / propoxylated polysiloxanes, propoxylated POE ethers and alkyl polyglycosides such as lauryl glucoside, decyl glycoside and cocoglycoside. 6. sucrose esters, ether
- the cleaning preparations within the meaning of the present invention particularly advantageously contain one or more wash-active surfactants according to the invention from the group of surfactants which have an HLB value of more than 25, very particularly those which have an HLB value of more than 35.
- the content of one or more detergent surfactants in the cosmetic or dermatological cleaning preparation is in the range from 2.0 to 25% by weight, very particularly advantageously from 2.5 to 15% by weight. % is selected, based in each case on the total weight of the preparation.
- alkyl ether sulfate or a monoalkyl phosphate is used as further surface-active compounds.
- the preparations in which the fatty acid salts are used according to the invention contain one or more gel formers.
- Gel formers from the group of polyacrylates and / or acrylate copolymers are preferred according to the invention.
- one or more polyacrylates in a total concentration of 0.3 to 5.0% by weight, preferably in a concentration of 1.0 to 2.0% by weight, in each case based on the total weight of the preparation ,
- Polyacrylates which are advantageous according to the invention are polymers of acrylic acid, in particular those selected from the group of the so-called carbomers or carbopols (Carbopol® is actually a registered trademark of the BF Goodrich Company). Polyacrylates are compounds of the general structural formula whose molecular weight can be between approximately 400,000 and more than 4,000,000. The group of polyacrylates also includes acrylate-alkyl acrylate copolymers, for example those which are distinguished by the following structure:
- R ' represents a long-chain alkyl radical and x and y numbers which symbolize the respective stoichiometric proportion of the respective comonomers.
- Advantageous carbopoles are, for example, types 907, 910, 934, 940, 941, 951, 954, 980, 981, 1342, 1382, 2984 and 5984 or types ETD (Easy-to-disperse) 2001, 2020, 2050, where these compounds can be present individually or in any combination with one another.
- ETD Easy-to-disperse
- Carbopol 981, 1382 and ETD 2020 are particularly preferred.
- copolymers of CIO- 30 alkyl acrylates and one or more monomers of acrylic acid, methacrylic acid or their esters which are comparable to the acrylate-alkyl acrylate copolymers.
- the INCI names for such compounds are, for example, “Acrylates / C 10-30 Alkyl Acrylate Crosspolymer” or “Acrylates Copolymer”.
- Particularly advantageous are those available under the trade names Pemulen TR1 and Pemulen TR2 and Carbopol Aqua-SF 1 polymer from NOVEON. According to the invention, it is advantageous to choose one or more polyacrylates from the group of acrylate-alkyl acrylate copolymers.
- polyacrylates and cellulose derivatives it is preferred to use a combination of polyacrylates and cellulose derivatives as the polymeric thickener.
- the preparation according to the invention advantageously contains the cellulose derivatives in a total concentration of 0.1 to 1.0% by weight, preferably in a total concentration of 0.2 to 0.5% by weight, based in each case on the total weight of the preparation.
- Preferred cellulose derivatives in the sense of the present invention are hydroxyalkyl celluloses. It is particularly preferred if one or more hydroxyalkyl celluloses are selected, such as. B. carboxymethyl cellulose and other cellulose ethers, hydroxyethyl and propyl cellulose and hydroxypropyl methyl cellulose.
- xanthan (CAS No. 11138-66-2), also known as xanthan gum, which is an anionic heteropolysaccharide which is generally formed from corn sugar by fermentation and is isolated as the potassium salt. It is produced by Xanthomonas campestris and some other species under aerobic conditions with a molecular weight of 2x106 to 24x106.
- compositions within the meaning of the present invention further advantageously contain water and optionally the additives customary in cosmetics, e.g. B. preservatives, preservation aids, bactericides, perfumes, dyes, pigments that have a coloring effect, solubilizers, moisturizing and / or moisturizing substances, fillers that improve the feeling on the skin, fats, oils, waxes or other common components of a cosmetic or dermatological formulation.
- the additives customary in cosmetics e.g. B. preservatives, preservation aids, bactericides, perfumes, dyes, pigments that have a coloring effect, solubilizers, moisturizing and / or moisturizing substances, fillers that improve the feeling on the skin, fats, oils, waxes or other common components of a cosmetic or dermatological formulation.
- the water phase of the preparations can advantageously comprise customary cosmetic auxiliaries, such as, for example, alcohols, in particular those with a low C number, preferably ethanol and / or isopropanol, diols or polyols with a low C number and their ethers, preferably propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether, propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl - or - monoethyl ether and analog products, polymers, foam stabilizers, electrolytes, dihydroxyacetone and in particular one or more thickeners, which or which can advantageously be selected from the group consisting of silicon dioxide, aluminum silicates, polysaccharides or their derivatives, e.g.
- customary cosmetic auxiliaries such as, for example, alcohols, in particular those with a low C number, preferably ethanol and / or isopropan
- Moisturizers are substances or mixtures of substances that give cosmetic or dermatological preparations the property of reducing the release of moisture from the horny layer (also called trans-epidermal water joss (TEWL)) and / or hydrating the skin after application or distribution on the skin surface To influence the horny layer positively.
- TEWL trans-epidermal water joss
- moisturizers for the purposes of the present invention are, for example, glycerol, lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, biosaccaride gum-1, glycine soya, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid and urea. It is also particularly advantageous to use polymeric moisturizers from the group of water-soluble and / or water-swellable and / or water-gelable polysaccharides.
- antioxidants are used as additives or active ingredients.
- the preparations advantageously contain one or more antioxidants. All of the antioxidants suitable or customary for cosmetic and / or dermatological applications can be used as inexpensive, but nevertheless optional, antioxidants.
- Water-soluble antioxidants such as vitamins, e.g. B. ascorbic acid and its derivatives.
- Preferred antioxidants are also vitamin E and its derivatives and vitamin A and its derivatives.
- the amount of the antioxidants (one or more compounds) in the preparations is preferably 0.001 to 30% by weight, particularly preferably 0.05 to 20% by weight, in particular 0.1 to 10% by weight, based on the total weight the preparation.
- vitamin E and / or its derivatives represent the antioxidant (s)
- vitamin A or vitamin A derivatives or carotenes or their derivatives represent the antioxidant or antioxidants, it is advantageous to add their respective concentrations in the range from 0.001 to 10% by weight, based on the total weight of the formulation choose.
- the cosmetic preparations according to the present invention contain cosmetic or dermatological active ingredients, preferred active ingredients being antioxidants which can protect the skin and / or the hair from oxidative stress.
- active ingredients in the sense of the present invention are natural active ingredients and / or their derivatives, such as.
- the preparation according to the invention advantageously contains one or more conditioners.
- Conditioners preferred according to the invention are, for example, all compounds which are in the International Cosme ⁇ c Ingredient Dictionary and Handbook (Volume 4, publisher: RC Pepe, JA Wenninger, GN McEwen, The Cosmetic, Toiletry, and Fragrance Association, 9th edition, 2002) under Section 4 under the keywords Hair Conditioning Agents, Humectants, Skin-Conditioning Agents, Skin-Conditioning Agents-Emollient, Skin-Conditioning Agents-Humactant, Skin-Conditioning Agents-Miscellaneous, Skin-Conditioning Agents-Occiusive and Skin Protectans are listed as well as all of them in EP 0934956 (p.11-13) under water soluble conditioning agent and oil soluble conditioning agent listed connections.
- Further conditioners which are advantageous according to the invention are, for example, the compounds named polyquaternium according to the international nomenclature for cosmetic ingredients (INCI).
- polyquaternium-1 to polyquaternium-56 but also the polyethylene glycols and polyproylene glycols which are advantageous according to the invention.
- the preparations in which the fatty acid salts are advantageously used according to the invention have a pH of greater than 7 and preferably a pH of greater than 8.
- the cleaning preparations in which the fatty acid salts are used according to the invention are advantageously used in liquid or semi-liquid form.
- Liquid means preparations according to the invention which have a viscosity of 1500 to 5000 mPas.
- “Semi-liquid” means preparations according to the invention which have a viscosity of greater than 5000 mPas. The viscosity values of the preparations and individual substances listed in the context of the preceding document were determined with the aid of a Viscotester VT 02 viscometer from Haake.
- the cleaning compositions containing fatty acid salts used according to the invention can be composed as usual and can be used for cosmetic and / or dermatological body cleaning such as cleaning the skin and / or hair, as a make-up removal product for decorative cosmetics and for facial cleaning.
- the cleaning preparations in which the fatty acid salts are used according to the invention are advantageously used for cleaning oily and / or impure skin / scalp.
- the compositions comprising fatty acid salts used according to the invention are applied to the skin and / or the hair in a sufficient amount in the manner customary for cosmetics.
- the preparations in which the fatty acid salts are advantageously used according to the invention can be used as the impregnation medium for an insoluble substrate, for example a nonwoven or cloth, the substrate also being able to be in the form of a substrate which appears to be dry or as a substrate which appears to be moist.
- the preparations in which the fatty acid salts are advantageously used according to the invention can be used as a shampoo, shower gel, foam bath or tub bath and as a hand wash lotion or shaving cream. According to the invention, they can advantageously be stored in double-chamber packaging or foam dispensers (mechanical pump dispensers (pump foamers) or aerosol cans).
- the preparations in which the fatty acid salts are advantageously used according to the invention can be used for cleaning and washing clothes and textiles (“detergents”) and for cleaning everyday objects (for example dishes, table and cupboard surfaces, cars).
- the selectivity is that dirt and impurities are removed from the textiles and objects of daily life with high selectivity and the skin's own lipids, which are essential for preventing the skin from drying out, are protected.
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Abstract
La présente invention concerne des compositions de nettoyage contenant des sels d'acides gras, permettant d'améliorer l'état de la peau de façon notable, notamment de réduire la rugosité de la peau. Les compositions selon l'invention sont caractérisées par la sélectivité de l'effet de nettoyage.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10257984.9 | 2002-12-12 | ||
DE10257984A DE10257984A1 (de) | 2002-12-12 | 2002-12-12 | Verwendung von Fettsäuresalzen zum Erzielen oder Erhöhen der Selektivität von Reinigungszubereitungen |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004052332A1 true WO2004052332A1 (fr) | 2004-06-24 |
Family
ID=32336219
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/050960 WO2004052332A1 (fr) | 2002-12-12 | 2003-12-08 | Preparations de nettoyage contenant des sels d'acides gras |
Country Status (2)
Country | Link |
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DE (1) | DE10257984A1 (fr) |
WO (1) | WO2004052332A1 (fr) |
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EP0106193A2 (fr) * | 1982-09-20 | 1984-04-25 | Union Carbide Corporation | Composition liquide pour le nettoyage de la peau |
EP0203750A2 (fr) * | 1985-05-13 | 1986-12-03 | The Procter & Gamble Company | Composition ultra-douce pour la purification de la peau |
JPH06256165A (ja) * | 1993-03-05 | 1994-09-13 | Noevir Co Ltd | 液体洗浄料 |
JPH07138127A (ja) * | 1993-11-12 | 1995-05-30 | Kose Corp | パック化粧料 |
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JP2001031560A (ja) * | 1999-07-15 | 2001-02-06 | Sakamoto Yakuhin Kogyo Co Ltd | 皮膚洗浄料 |
WO2001041729A1 (fr) * | 1999-12-06 | 2001-06-14 | Unilever Plc | Liquides stables a forte teneur en glycerol contenant des monoesters d'acide sulfosuccinique |
JP2002322498A (ja) * | 2001-04-27 | 2002-11-08 | Mandom Corp | 洗浄剤組成物 |
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EP0115252A3 (fr) * | 1982-12-29 | 1985-12-27 | Ciba-Geigy Ag | Mélanges de sels polymères d'ammonium quaternaire, de tensioactifs et d'acides gras, leur préparation et leur utilisation dans des compositions cosmétiques |
JP2567277B2 (ja) * | 1988-10-27 | 1996-12-25 | 川研ファインケミカル株式会社 | 液体洗浄剤組成物 |
US5234619A (en) * | 1989-05-05 | 1993-08-10 | Lever Brothers Company, Division Of Conopco, Inc. | Aqueous based personal washing cleanser |
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CA2131174C (fr) * | 1992-03-25 | 1999-01-12 | Michel Joseph Giret | Compositions de nettoyage |
EG20886A (en) * | 1993-06-18 | 2000-05-31 | Procter & Gamble | Personal cleansing system comprising a plolymeric diamon-mesh bath sponge and a liquid cleanser with moisturizer |
EP0796084B1 (fr) * | 1994-12-06 | 1999-05-06 | The Procter & Gamble Company | Demaquillant liquide pour la peau stable en conservation avec un ester d'acide gras d'ethylene glycol cristallin; liquide et polymere formant gel |
EP0728475A3 (fr) * | 1995-02-21 | 1997-03-19 | Kao Corp | Nettoyant épidermique |
JP3620140B2 (ja) * | 1996-02-26 | 2005-02-16 | 株式会社ツムラ | 皮膚用液体洗浄剤組成物 |
DE19649102A1 (de) * | 1996-11-27 | 1998-05-28 | Henkel Kgaa | Reinigungsmittel |
DE19735518C1 (de) * | 1997-08-16 | 1999-03-11 | Friedrun Geier | Abspülbare Emulsionen zur Verwendung als talglösende Zubereitungen |
JP2000192078A (ja) * | 1998-12-25 | 2000-07-11 | Lion Corp | 液体洗浄剤組成物 |
DE19916036A1 (de) * | 1999-04-09 | 2000-10-12 | Cognis Deutschland Gmbh | Handwaschpasten |
JP2001213763A (ja) * | 2000-02-03 | 2001-08-07 | Kanebo Ltd | 皮膚洗浄料 |
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2002
- 2002-12-12 DE DE10257984A patent/DE10257984A1/de not_active Withdrawn
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2003
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EP0106193A2 (fr) * | 1982-09-20 | 1984-04-25 | Union Carbide Corporation | Composition liquide pour le nettoyage de la peau |
EP0203750A2 (fr) * | 1985-05-13 | 1986-12-03 | The Procter & Gamble Company | Composition ultra-douce pour la purification de la peau |
JPH06256165A (ja) * | 1993-03-05 | 1994-09-13 | Noevir Co Ltd | 液体洗浄料 |
JPH07138127A (ja) * | 1993-11-12 | 1995-05-30 | Kose Corp | パック化粧料 |
JPH11189788A (ja) * | 1997-12-26 | 1999-07-13 | Nof Corp | 透明ゲル状洗浄剤組成物 |
JP2001031560A (ja) * | 1999-07-15 | 2001-02-06 | Sakamoto Yakuhin Kogyo Co Ltd | 皮膚洗浄料 |
WO2001041729A1 (fr) * | 1999-12-06 | 2001-06-14 | Unilever Plc | Liquides stables a forte teneur en glycerol contenant des monoesters d'acide sulfosuccinique |
JP2002322498A (ja) * | 2001-04-27 | 2002-11-08 | Mandom Corp | 洗浄剤組成物 |
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Also Published As
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DE10257984A1 (de) | 2004-06-24 |
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