WO2002053647A1 - Vibration-damping material - Google Patents
Vibration-damping material Download PDFInfo
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- WO2002053647A1 WO2002053647A1 PCT/JP2000/009369 JP0009369W WO02053647A1 WO 2002053647 A1 WO2002053647 A1 WO 2002053647A1 JP 0009369 W JP0009369 W JP 0009369W WO 02053647 A1 WO02053647 A1 WO 02053647A1
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- Prior art keywords
- vibration
- apparatuses
- damping material
- equipment
- damping
- Prior art date
Links
- 238000013016 damping Methods 0.000 title claims abstract description 40
- 239000000463 material Substances 0.000 title claims abstract description 33
- 239000000945 filler Substances 0.000 claims abstract description 21
- 239000002861 polymer material Substances 0.000 claims description 10
- 239000010445 mica Substances 0.000 claims description 8
- 229910052618 mica group Inorganic materials 0.000 claims description 8
- 235000012745 brilliant blue FCF Nutrition 0.000 claims 1
- 238000004891 communication Methods 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 4
- 238000012856 packing Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 229910052628 phlogopite Inorganic materials 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004709 Chlorinated polyethylene Substances 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 229920003049 isoprene rubber Polymers 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 241000255925 Diptera Species 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/016—Additives defined by their aspect ratio
Definitions
- the present invention relates to a vibration damping material applied to automobiles, home appliances, precision equipment, electronic equipment, office automation equipment, communication equipment, construction machinery, civil engineering buildings, various other machines, and equipment structures.
- the present inventors have focused on fillers that have been filled in conventional vibration damping materials, and as a result of intensive research, have found that the filler material, particularly the scaly filler material, has an improved aspect ratio. Density is closely related to the damping performance, and the required amount of flaky filler with a specific range of aspect ratio is filled to the specified range to improve the damping performance dramatically. I found that.
- the present invention has been completed based on this finding, and has as its object to propose a vibration damping material having excellent vibration damping performance as compared with a conventional vibration damping material.
- the present invention is scale-like filler is 1 ⁇ 3 g / cm 3 weight average Asupeku Ratio mosquito S 1 0 to 9 0 to polymeric material having viscoelastic properties
- the gist of the present invention is a vibration damping material characterized by being contained at a density.
- FIG. 1 is a graph showing the relationship between the loss factor and the density of the flaky filler in two types of vibration damping materials having different weight-average aspect ratios.
- the vibration damping material of the present invention is a material in which a flaky filler is contained in a polymer material having viscoelastic properties.
- the polymer material is not particularly limited as long as it has viscoelastic properties, What is necessary is just to determine suitably according to the above-mentioned use and use form.
- polyvinyl chloride chlorinated polyethylene, polyethylene, polypropylene, ethylene-butyl acetate copolymer, polymethyl methacrylate, polystyrene, polyurethane, polyvinylinoleanolone, styrene-butadiene acrylonitrile Copolymer, polyvinyl formal, epoxy resin, phenol resin, polyurethane resin, silicone resin, melamine resin, polyimide, acryl rubber (ACR), acrylonitrile-butadiene rubber (NBR), styrene-butadiene rubber (SBR), butadiene rubber (BR), natural rubber (NR), isoprene rubber (IR), chloroprene rubber (CR), silicon rubber (SR), or copolymers thereof.
- the polymer material can be used to improve the vibration damping performance of the polymer material while maintaining good mechanical properties (eg, tensile strength, flexural modulus, impact resistance, etc.). It has the function of improving.
- the scaly filler having such a function use one kind selected from mica flakes, sericite, dalaphyte, talc, glass flakes, aluminum flakes, or a combination of two or more kinds I can do it.
- mica flakes are preferred, and mica flakes include, for example, muscovite (mascopite), phlogopite (phlogopite), synthetic phlogopite, and the like. Only one of them may be used, or two or more thereof may be used.
- the weight average aspect ratio (weight 'average flake diameter, weight average flake thickness) of the scaly filler should be 10 to Must be in the range of 90.
- the weight-average aspect ratio of the flaky filler is less than 10, it is easy to mix in the polymer material and has the advantage of good dispersibility, but sufficient damping performance is improved by filling it. Can not expect.
- the weight-average aspect ratio exceeds 90, the damping performance is improved, but the bulk becomes bulky, so that it is difficult to fill the polymer material, and the scale-like filler is used as the whole polymer material.
- the filling amount of the flaky filler is not particularly limited, but the density after filling must be in the range of 1 to 3 gZcm 3 . If the packing density of the flaky filler is less than 1 g / cm 3 , it is not possible to expect a sufficient improvement in vibration damping performance. On the other hand, if the density is more than 3 g / cm 3 , mechanical properties such as tensile strength, flexural modulus, and impact resistance will be poor, which may cause adverse effects such as difficulty in molding. It is. '
- the vibration damping material of the present invention is obtained by mixing a scaly filler into the above polymer material at a predetermined ratio, kneading the mixture using a pan palley mixer, a roll, or the like, and further using a calendering method, an extrusion method, or the like. By shaping it into a shape appropriate for the purpose, it can be used as a vibration damping material for measures against vibration and noise of automobiles, bicycles, and OA equipment.
- the mica flakes with a weight average aspect ratio of 70 manufactured by Kuraray Mica Kuraray Co., Ltd.
- the mica flakes with a weight average aspect ratio of 23 were made to have different packing densities. (Eight types were prepared), and the mixture was put into a kneading roll set at 140 ° C together with chlorinated polyethylene and kneaded for 25 minutes.
- the obtained kneaded material was sandwiched between metal molds heated to 180 ° C. and heated for 180 seconds, and then pressed with a press machine at a pressure of 80 kg ⁇ f Z cm 2 for 30 seconds.
- the sheet was formed into a sheet having a thickness of 0.8 mm, and the obtained sheet was cut into a dimension of 67 mm ⁇ 9 mm to obtain eight kinds of test pieces.
- the packing density (g / cm 3 ) and the loss coefficient (77) were measured.
- Figure 1 shows the results. ' ⁇
- the loss coefficient ( ⁇ ) was determined by the central excitation method (Multi-Purpose FFT analyzer, CF-5220, manufactured by Ono Sokki Co., Ltd.).
- a flaky filler having a weight average aspect ratio of 0 to 90 is contained in a polymer material having viscoelastic properties at a density of 1 to 3 g / cm 3. As a result, it has superior damping performance compared to conventional damping materials.
- the vibration damping material of the present invention is applied to automobiles, home appliances, precision equipment, electronic equipment, OA equipment, communication equipment, construction machinery, civil engineering buildings, various other machines, equipment, and structures.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Vibration Prevention Devices (AREA)
Abstract
A vibration-damping material which is applicable to motor vehicles, domestic electrical appliances, precision apparatuses, electronic apparatuses, OA apparatuses, communication apparatuses, building machines, constructions and buildings, and other various machines, apparatuses, and structures. It is characterized by comprising a polymeric material having viscoelastic properties and a flaky filler having a weight-average aspect ratio of 10 to 90 contained in the polymeric material in an amount of 1 to 3 g per cm3. The vibration-damping material has excellent vibration-damping performance.
Description
系田 ¾ 制振材 技術分野 ' . Technical field of damping materials ''.
本発明は、 自動車、 家電製品、 精密機器、 電子機器、 O A機器、 通信機 器、 建設機械、 土木建築物、 その他種々の機械、 機器 構造物に適用され る制振材に関する。 背景技術 The present invention relates to a vibration damping material applied to automobiles, home appliances, precision equipment, electronic equipment, office automation equipment, communication equipment, construction machinery, civil engineering buildings, various other machines, and equipment structures. Background art
近年、 社会生活に欠かせない自動車から発生する ί辰動、 振動による騒音 は、 社会問題として大きくクローズアップされ、 法的規制がますます強化 される過程で、 その発生防止対策が強く求められようになった。 一方、 ド ライパーや乗客の側からは、 車内における振動、 振動による騒音の発生を 防止して、 ,自動車内における静粛性、 快適性を求める声も多い。 In recent years, noise caused by automobiles, which are indispensable for social life, has become a major social issue, and noise due to vibration has become a major social issue. Became. On the other hand, many drivers and passengers demand vibration and noise generated by vibrations in vehicles, and demand quietness and comfort in vehicles.
' また、 工場や住宅、 学校などの構造物についても、 より快適な生活を指 向するという思想の広がりにより、 構造物外部からの振動や騒音による被 害や、 構造物内部から発生する振動や振動による騒音が外部へ拡散するこ とによる被害が取り沙汰されるようになり、 その対策が求められている。 また、 振動の発生源となる産業機械、 器具、 あるいは振動による影響を 受け易い電子機器や精密機器、 家電製品、 O A機器、 通信機器についても、 使用者の振動対策製品についてのニーズが高まっている。 '' In addition, with regard to structures such as factories, houses, schools, etc., the spread of ideas toward more comfortable living has led to damage from vibrations and noise from outside the structures, and vibrations generated from inside the structures. Damage caused by the spread of noise due to vibrations has been reported, and countermeasures are required. In addition, there is a growing need for users to use vibration countermeasures for industrial machinery and equipment that are sources of vibration, or for electronic equipment, precision equipment, home appliances, OA equipment, and communication equipment that are easily affected by vibration. .
• 従来、 このような要求に応えるべく、 自動車、 家電製品、 電子機器、 精 密機器、 O A機器、 通信機器、 建設機械、 土木建築物、 その他種々の機械、 機器、 構造物には、 その振動対策として、 ゴム系、 プラスチック系、 ァス フアルト系といった粘弾性特性を有する材料 (制振材) を前記機械、 機器、 構造物などの適用箇所の大きさや形状に合わせて切断したり折り曲げたり して加工し、 これを適用箇所に貼り付けて、 当該機械、 機器、 構造物など に伝播する、 あるいは機械、 機器、 構造物などから発生する振動を吸収し
減衰させていた。 • Conventionally, to meet such demands, automobiles, home appliances, electronic equipment, precision equipment, OA equipment, communication equipment, construction machinery, civil engineering buildings, and various other machines, equipment, and structures have As a countermeasure, materials such as rubber, plastic, and asphalt that have viscoelastic properties (vibration damping material) are cut or bent according to the size and shape of the application location of the machine, equipment, structure, etc. And apply it to the applicable location to propagate to the machine, equipment, structure, etc., or absorb the vibration generated by the machine, equipment, structure, etc. Had been attenuated.
とこ,ろが、 従来の制振材にあっては、 制振性能が低く十分な騒音対策が なされていないのが現状であった。 そこで前述の粘弹性特性を有する材料 にマイ力や炭酸カルシゥムなどのフイラ一を充填して制振性能を高める試 みもなされていた。 At present, however, conventional damping materials have low damping performance and no adequate noise countermeasures have been taken. Therefore, attempts have been made to enhance the vibration damping performance by filling the above-mentioned material having the viscous property with a filler such as my force or calcium carbonate.
しかしながらこのような制振材にあっても、 その制振性能は十分に満足 できるものでは無かった。 However, even with such a damping material, its damping performance was not sufficiently satisfactory.
発明の開示 . DISCLOSURE OF THE INVENTION.
本発明者らは、 このような事情に鑑み、 従来の制振材に充填されていた 充填材に着目し、 鋭意研究を重ねた結果、 充填材、 特には鱗片状充填材の アスペク ト比と密度が制振性能と深く係わっており、 特定範囲のァスぺク ト比を有する鱗片状充填材を所要量充填して特定範囲の密度とすることで、 制振性能が飛躍的に向上することを見出した。 In view of such circumstances, the present inventors have focused on fillers that have been filled in conventional vibration damping materials, and as a result of intensive research, have found that the filler material, particularly the scaly filler material, has an improved aspect ratio. Density is closely related to the damping performance, and the required amount of flaky filler with a specific range of aspect ratio is filled to the specified range to improve the damping performance dramatically. I found that.
本発明は、 この知見に基づいて完成されたものであり、 従来の制振材に 比べて優れた制振性能を有する制振材を提案することを目的とするもので ある。 The present invention has been completed based on this finding, and has as its object to propose a vibration damping material having excellent vibration damping performance as compared with a conventional vibration damping material.
上記目的を達成するため、 本発明は、 粘弾性特性を有するポリマー材料 中に重量平均ァスぺク ト比カ S 1 0〜9 0である鱗片状充填材が 1〜 3 g / c m 3の密度で含まれていることを特徴とする制振材をその要旨とした。 図面の簡単な説明 To achieve the above object, the present invention is scale-like filler is 1~ 3 g / cm 3 weight average Asupeku Ratio mosquito S 1 0 to 9 0 to polymeric material having viscoelastic properties The gist of the present invention is a vibration damping material characterized by being contained at a density. BRIEF DESCRIPTION OF THE FIGURES
図 1は重量平均ァスぺク ト比が異なる 2種の制振材における損失係数と 鱗片状充填材の密度との関係を示すグラフである。 発明を実施するための最良の形態 FIG. 1 is a graph showing the relationship between the loss factor and the density of the flaky filler in two types of vibration damping materials having different weight-average aspect ratios. BEST MODE FOR CARRYING OUT THE INVENTION
以下、 本発明の制振材について詳しく説明する。 本発明の制振材は、 粘 弾性特性を有するポリ'マー材料中に鱗片状充填材が含まれているものであ る。 Hereinafter, the vibration damping material of the present invention will be described in detail. The vibration damping material of the present invention is a material in which a flaky filler is contained in a polymer material having viscoelastic properties.
ポリマ一材料としては粘弾性特性を有するものであれば特に限定されず、
上述の用途や使用形態に応じて適宜決定すればよい。 具体的にはポリ塩化 ビュル、 .塩素化ポリエチレン、 ポリエチレン、 ポリプロ ピレン、 エチレン 一酢酸ビュル共重合体、 ポリメタクリル酸メチル、 ポリスチレン、 ポリウ レタン、 ポリ ビニノレアノレコーノレ、 スチレン一ブタジエンーァク リ ロニ ト リ ル共重合体、 ポリビニルホルマール、 エポキシ樹脂、 フヱノール樹脂、 ュ リァ樹脂、 シリコン樹脂、 メラミン樹脂、 ポリイミ ド、 ァクリルゴム (A C R ) 、 アクリロニトリル一ブタジエンゴム (N B R ) 、 スチレン一ブタ ジェンゴム (S B R ) 、 ブタジエンゴム (B R ) 、 天然ゴム (N R ) 、 ィ ソプレンゴム ( I R ) 、 ク ロロプレンゴム ( C R ) 、 シリ コンゴム ( S R ) の中から選ばれた 1種、 若しくはこれらの共重合体を挙げることがで さる。 The polymer material is not particularly limited as long as it has viscoelastic properties, What is necessary is just to determine suitably according to the above-mentioned use and use form. Specifically, polyvinyl chloride, chlorinated polyethylene, polyethylene, polypropylene, ethylene-butyl acetate copolymer, polymethyl methacrylate, polystyrene, polyurethane, polyvinylinoleanolone, styrene-butadiene acrylonitrile Copolymer, polyvinyl formal, epoxy resin, phenol resin, polyurethane resin, silicone resin, melamine resin, polyimide, acryl rubber (ACR), acrylonitrile-butadiene rubber (NBR), styrene-butadiene rubber (SBR), butadiene rubber (BR), natural rubber (NR), isoprene rubber (IR), chloroprene rubber (CR), silicon rubber (SR), or copolymers thereof.
鱗片状充填材としては、 これを充填することで良好な機械的物性 (例え ば引張強さ、 曲げ弾性率、 耐衝撃性など) を保ちながら、 前記ポリマー材 料の持つの制振性能をより向上させるという機能を持つものである。 この ような機能を持つ鱗片状充填材には、 マイカフレーク、 セリサイ ト、 ダラ ファイ ト、 タルク、 ガラスフレーク、 アルミニウムフレークから選ばれる 1種、 若しくはこれらを 2種以上を組み合わせたものを使用することがで きる。 上記鱗片状充填材の中でもマイカフレークが好ましく、 マイカフレ ークとしては、 例えば白雲母 (マスコパイ ト) 、 金雲母 (フロゴパイ ト) , 合成フ口ゴパイ トなどを挙げることができ、 それらのマイカフレークのう ちの 1種のみを使用してもまたは 2種以上を使用してもよい。 As a scaly filler, the polymer material can be used to improve the vibration damping performance of the polymer material while maintaining good mechanical properties (eg, tensile strength, flexural modulus, impact resistance, etc.). It has the function of improving. As the scaly filler having such a function, use one kind selected from mica flakes, sericite, dalaphyte, talc, glass flakes, aluminum flakes, or a combination of two or more kinds I can do it. Among the above scaly fillers, mica flakes are preferred, and mica flakes include, for example, muscovite (mascopite), phlogopite (phlogopite), synthetic phlogopite, and the like. Only one of them may be used, or two or more thereof may be used.
当該制振材の制振性能および機械的性質をより良好なものとするために は、 鱗片状充填材の重量平均アスペク ト比 (重量'平均フレーク径 重量平 均フレーク厚) は、 1 0〜9 0の範囲とする必要がある。 鱗片状充填材の 重量平均アスペク ト比が 1 0を下回る場合、 ポリマー材料中に混合し易く、 かつ分散性がよいという利点はあるものの、 これを充填したことによる十 分な制振性能の向上を期待することができない。 一方、 重量平均ァスぺク ト比が 9 0を上回る場合には制振性能は向上するものの嵩高とな,,るため、 ポリマー材料への充填が難しく、 かつ鱗片状充填材をポリマー材料全体に
均一に分散できなくなり、 '制振材全体にわたって制振性能が均一に向上す るという効果が得られないという不具合が生じることになるからである。' この鱗片状充填材の充填量としては特に限定されないが、 充填後の密度 が 1〜3 gZc m3の範囲とする必要がある。 鱗片状充填材の充填密度が 1 g/c m3を下回ると、 十分な制振性能の向上を期待することができない。 一方、 密度が 3 g/c m3を上回る場合には、 引張強さ、 曲げ弾性率、 耐衝 擊性など機械的性質が不良となり、 さらには成形困難となるなどの弊害を 招く恐れがあるからである。 ' In order to improve the damping performance and mechanical properties of the damping material, the weight average aspect ratio (weight 'average flake diameter, weight average flake thickness) of the scaly filler should be 10 to Must be in the range of 90. When the weight-average aspect ratio of the flaky filler is less than 10, it is easy to mix in the polymer material and has the advantage of good dispersibility, but sufficient damping performance is improved by filling it. Can not expect. On the other hand, if the weight-average aspect ratio exceeds 90, the damping performance is improved, but the bulk becomes bulky, so that it is difficult to fill the polymer material, and the scale-like filler is used as the whole polymer material. To This is because it becomes impossible to uniformly disperse, and a problem arises in that the effect of uniformly improving the damping performance over the entire damping material cannot be obtained. 'The filling amount of the flaky filler is not particularly limited, but the density after filling must be in the range of 1 to 3 gZcm 3 . If the packing density of the flaky filler is less than 1 g / cm 3 , it is not possible to expect a sufficient improvement in vibration damping performance. On the other hand, if the density is more than 3 g / cm 3 , mechanical properties such as tensile strength, flexural modulus, and impact resistance will be poor, which may cause adverse effects such as difficulty in molding. It is. '
本発明の制振材は、 上記ポリマー材料に鱗片状充填材を所定割合で配合 し、 これをパンパリーミキサーやロール等を用いて混練し、 さらにカレン ダ一法や押し出し法などにより、 用途、 目的に応じた形状に成形すること で、 自動車や自転車、 OA機器などの振動、 騒音対策用の制振材とするこ とができる。 , 実施例 , 重量平均アスペク ト比が 7 0のマイカフレーク (クラライ トマイカ ク ラレ株式会社製) と、 重量平均アスペク ト比が 23のマイカフレーク (灰 化マイ力) をそれぞれ充填密度が異なるように (各 8種類となるように) 調合し、 1 40°Cに設定した混練ロールに塩素化ポリエチレンとともに投 入し 2 5分間混練した。 The vibration damping material of the present invention is obtained by mixing a scaly filler into the above polymer material at a predetermined ratio, kneading the mixture using a pan palley mixer, a roll, or the like, and further using a calendering method, an extrusion method, or the like. By shaping it into a shape appropriate for the purpose, it can be used as a vibration damping material for measures against vibration and noise of automobiles, bicycles, and OA equipment. The mica flakes with a weight average aspect ratio of 70 (manufactured by Kuraray Mica Kuraray Co., Ltd.) and the mica flakes with a weight average aspect ratio of 23 (ashing strength) were made to have different packing densities. (Eight types were prepared), and the mixture was put into a kneading roll set at 140 ° C together with chlorinated polyethylene and kneaded for 25 minutes.
次いで、 得られた混練物を 1 8 0°Cに加熱した金型間に挟んで 1 8 0秒 間加熱し、 この後プレス機で 8 0 k g · f Z c m2 の圧力で 3 0秒間加圧し. 0. 8 mmの厚さにシート化し、 得られたシートを 6 7 mmX 9 mmの寸 法に切断して、 8種類の試験片を得た。 得られた試験片 (制振シート) について、 それぞれ充填密度 (g/c m3) と損失係数 (77) とを測定した。 その結果を図 1に示す。 ' · Next, the obtained kneaded material was sandwiched between metal molds heated to 180 ° C. and heated for 180 seconds, and then pressed with a press machine at a pressure of 80 kg · f Z cm 2 for 30 seconds. The sheet was formed into a sheet having a thickness of 0.8 mm, and the obtained sheet was cut into a dimension of 67 mm × 9 mm to obtain eight kinds of test pieces. With respect to the obtained test pieces (damping sheets), the packing density (g / cm 3 ) and the loss coefficient (77) were measured. Figure 1 shows the results. '·
尚、 損失係数 ( η ) は、 中央加振法 (Multi-Purpose FFTアナライサ、 、 CF - 5 220、 株式会社小野測器製) によって求めた。 The loss coefficient (η) was determined by the central excitation method (Multi-Purpose FFT analyzer, CF-5220, manufactured by Ono Sokki Co., Ltd.).
図 1から、 重量平均ァスぺク ト比カ 2 3のマイカフレークを充填した試
験片については、 充填密度 (gZc m3) が高くなるにつれて損失係数 ( η ) も徐々にではあるが高くなることが確認された。 From Fig. 1, it was found that mica flakes with a weight average For the test piece, it was confirmed that the loss factor (η) gradually increased as the packing density (gZc m 3 ) increased.
一方、 重量平均ァスぺク ト比カ S 7 0のマイ力フレークを充填した試験片 にあっては、 充填密度 (g / c m3) が高くなるにつれて上昇する損失係数 ( ) の上昇度合いが重量平均アスペク ト比が 2 3のものに比べて大きく、 重量平均アスペク ト比が高く、 なおかつ充填密度 ( g / c m3) が大きな試 験片がより高い損失係数 (7? ) 、 すなわち優れた制振性能を有することが 解った。 ' 発明の効果 On the other hand, in the test piece filled with the my-force flake having a weight-average aspect ratio of S70, the degree of increase in the loss factor () that increases as the packing density (g / cm 3 ) increases increases. larger than that of the weight average aspect ratio is 2 3, high weight average aspect ratio, yet packing density (g / cm 3) higher loss factor larger test pieces (7?), i.e. good It was found that it had damping performance. ' The invention's effect
本発明の制振材は、 粘弾性特性を有するポリマー材料中に重量平均ァス ぺク ト比カ 0〜9 0である鱗片状充填材が 1〜 3 g / c m3の密度で含ま れているので、 従来の制振材に比べて優れた制振性能を有する。 産業上の利用可能性 In the vibration damping material of the present invention, a flaky filler having a weight average aspect ratio of 0 to 90 is contained in a polymer material having viscoelastic properties at a density of 1 to 3 g / cm 3. As a result, it has superior damping performance compared to conventional damping materials. Industrial applicability
本発明の制振材は、 自動車、 家電製品、 精密機器、 電子機器、 OA機器、 通信機器、 建設機械、 土木建築物、 その他種々の機械、 機器、 構造物に適 用される。
The vibration damping material of the present invention is applied to automobiles, home appliances, precision equipment, electronic equipment, OA equipment, communication equipment, construction machinery, civil engineering buildings, various other machines, equipment, and structures.
Claims
1. 粘弾性特性を有するポリマー材料中に重量平均ァスぺク ト比カ S'l 0 〜90である鱗片状フイラ一が 1〜3 g/ c m3の密度で含まれていること を特徴とする制振材。 1. The polymer material having viscoelastic properties is characterized in that a flaky filler having a weight average aspect ratio of S'l 0 to 90 is contained at a density of 1 to 3 g / cm 3. And damping material.
2. 鱗片状フイラ一がマイカフレークであることを特徴とする請求項 1 記載の制振材。
2. The damping material according to claim 1, wherein the scaly filler is mica flake.
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WO2004056644A1 (en) * | 2002-12-23 | 2004-07-08 | Graham William Pickering | Flexible training wheel assembly |
JP2005281393A (en) * | 2004-03-29 | 2005-10-13 | Kimoto & Co Ltd | Vibration deadening coating and vibration deadening member using the same |
WO2007026653A1 (en) | 2005-08-29 | 2007-03-08 | Mitsubishi Gas Chemical Company, Inc. | Damping material and method for production thereof |
JP2010235891A (en) * | 2009-03-31 | 2010-10-21 | Cci Corp | Vibration-damping composition |
JP2011084690A (en) * | 2009-10-19 | 2011-04-28 | Cci Corp | Damping resin composition |
JP2021191971A (en) * | 2020-05-19 | 2021-12-16 | テーエムデー フリクション サービシス ゲーエムベーハー | Damping for brake pad, and damping material for intermediate layer |
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