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WO1998030194B1 - Compositions containing copolymers as a thickening agent - Google Patents

Compositions containing copolymers as a thickening agent

Info

Publication number
WO1998030194B1
WO1998030194B1 PCT/US1998/000595 US9800595W WO9830194B1 WO 1998030194 B1 WO1998030194 B1 WO 1998030194B1 US 9800595 W US9800595 W US 9800595W WO 9830194 B1 WO9830194 B1 WO 9830194B1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
oil
group
unsaturated carboxylic
functionality
Prior art date
Application number
PCT/US1998/000595
Other languages
French (fr)
Other versions
WO1998030194A2 (en
WO1998030194A3 (en
Filing date
Publication date
Priority claimed from US08/780,951 external-priority patent/US5736125A/en
Application filed filed Critical
Priority to BR9804762-0A priority Critical patent/BR9804762A/en
Priority to EP98901792A priority patent/EP0893984A1/en
Priority to JP10531232A priority patent/JP2000507273A/en
Priority to AU58229/98A priority patent/AU716399B2/en
Publication of WO1998030194A2 publication Critical patent/WO1998030194A2/en
Publication of WO1998030194A3 publication Critical patent/WO1998030194A3/en
Priority to NO984147A priority patent/NO984147L/en
Publication of WO1998030194B1 publication Critical patent/WO1998030194B1/en

Links

Abstract

The present invention is directed to compositions, particularly cosmetic compositions, in which the oil is thickened using at least one copolymer which has a hydrophobic funtionality sufficient to provide at least partial solubility and optionally stability in oil and a hydrophilic functionality sufficient to provide thickening of the oil. Use of such copolymers as thickening agents are advantageous in that they are soluble and stable in the oil phase. Further, sufficient thickening may be accomplished using very low amounts of these copolymers without the use of additional polymeric thickeners.

Claims

AMENDED CLAIMS[received by the International Bureau on 24 July 1998 (24.07.98); original claims 1 and 10 amended; remaining claims unchanged (2 pages)]
1. A composition comprising an oil and a polymeric thickener consisting essentially of at least one copolymer which has a hydrophobic functionality sufficient to provide at least partial solubility in oil and a hydrophilic functionality present in an amount effective to provide thickening of the oil, said hydrophilic functionality being provided by a constituent selected from the group consisting of C3-C6-α,β-ethylenically unsaturated carboxylic monoacid, C4-C6-α,β-ethylenically unsaturated carboxylic diacid, monoesters and monoamides of such carboxylic diacid.
2. The composition of claim 1 , wherein the hydrophobic functionality is provided by a constituent selected from the group consisting of C10-C22-acrylate, C10- C22-methacrylate, C10-C22-acrylamide, C10-C22-methacrylamide, C10-C22-vinyl ether, C10-C22-vinyl ester, siloxane, C10-C22-alpha olefin, fluorinated aliphatic side-chain of at least 6 carbons, styrene, and C^C^-alkyl-substituted styrene.
3. The composition of claim 2, wherein the hydrophobic functionality is provided by a constituent selected from the group consisting of C12-C22-acrylate, C12- C22-methacrylate, styrene, and C1-C24-alkyl-substituted styrene.
4. The composition of claim 1 , wherein the hydrophilic functionality is provided by a constituent selected from the group consisting of acrylic acid and methacrylic acid.
5. The composition of claim 1 , wherein the copolymer is selected from the group consisting of docosyl acrylate/styrene/acryiic acid and stearyl acry- late/methacrylic acid.
17
6. The composition of claim 1 , wherein the copolymer is present in an amount ranging from about 0.1 to about 12% by weight of the oil.
7. The composition of claim 1 , wherein the composition is neat and the copolymer is present in an amount of from about 2 to about 8% by weight of the oil.
8. The composition of claim 1 , wherein the composition is a water-in-oil emulsion and the copolymer is present in an amount of from about 0.5 to about 3.5% by weight of the oil.
9. The composition of claim 1 , wherein the composition is a cosmetic composition.
10. A process of thickening an oil comprising adding to the oil a polymeric thickener consisting essentially of at least one copolymer which has a hydrophobic functionality sufficient to provide at least partial solubility in oil and a hydrophilic functionality present in an amount effective to provide thickening of the oil, said hydrophobic functionality being provided by a constituent selected from the group consisting of C3-C5-α,β-ethylenically unsaturated carboxylic monoacid, C4-C6-α,β- ethylenically unsaturated carboxylic diacid, monoesters and monoamides of such carboxylic diacid.
11. The process of claim 10, wherein the hydrophobic functionality is provided by a constituent selected from the group consisting of C10-C22-acrylate, C10-
C22-methacrylate, C10-C22-acrylamide, C10-C22-methacrylamide, C10-C22-vinyl ether,
18 STATEMENT UNDER ARTICLE 19
Claims 1 and 10 have been amended to correct a typographical error. That C3-C6-α,β- ethylenically unsaturated carboxylic monoacid was intended is clear as the specification and claims both exemplify the unsaturated carboxylic monoacid by acrylic acid which is a C3-α,β-ethylenically unsaturated carboxylic monoacid. Further, acrylic acid is a preferred monomer and the examples use copolymers which contain acrylic acid.
Claim 10 has also been amended to change "hydrophobic" to "hydrophilic." This also is an obvious typographical error as any chemist knows that the selected group claimed is composed of hydrophilic members.
The specification will be amended under Article 34 such that page 4, line 8, will read "vided by C3-C6-α,β-ethylenically unsaturated carboxylic monoacid, C4-C6-".
19
PCT/US1998/000595 1997-01-10 1998-01-07 Compositions containing copolymers as a thickening agent WO1998030194A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BR9804762-0A BR9804762A (en) 1997-01-10 1998-01-07 Composition containing copolymers as a thickening agent.
EP98901792A EP0893984A1 (en) 1997-01-10 1998-01-07 Compositions containing copolymers as a thickening agent
JP10531232A JP2000507273A (en) 1997-01-10 1998-01-07 Composition containing copolymer as thickener
AU58229/98A AU716399B2 (en) 1997-01-10 1998-01-07 Compositions containing copolymers as a thickening agent
NO984147A NO984147L (en) 1997-01-10 1998-09-09 Compositions containing copolymers as thickeners

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/780,951 1997-01-10
US08/780,951 US5736125A (en) 1997-01-10 1997-01-10 Compositions containing copolymers as a thickening agent

Publications (3)

Publication Number Publication Date
WO1998030194A2 WO1998030194A2 (en) 1998-07-16
WO1998030194A3 WO1998030194A3 (en) 1998-08-13
WO1998030194B1 true WO1998030194B1 (en) 1998-10-01

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/000595 WO1998030194A2 (en) 1997-01-10 1998-01-07 Compositions containing copolymers as a thickening agent

Country Status (8)

Country Link
US (1) US5736125A (en)
EP (1) EP0893984A1 (en)
JP (1) JP2000507273A (en)
AU (1) AU716399B2 (en)
BR (1) BR9804762A (en)
CA (1) CA2248699A1 (en)
NO (1) NO984147L (en)
WO (1) WO1998030194A2 (en)

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