WO1989004862A1 - Detergent compositions containing cellulase granulates - Google Patents
Detergent compositions containing cellulase granulates Download PDFInfo
- Publication number
- WO1989004862A1 WO1989004862A1 PCT/DK1988/000189 DK8800189W WO8904862A1 WO 1989004862 A1 WO1989004862 A1 WO 1989004862A1 DK 8800189 W DK8800189 W DK 8800189W WO 8904862 A1 WO8904862 A1 WO 8904862A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cellulase
- granulates
- composition
- weight
- accordance
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 74
- 108010059892 Cellulase Proteins 0.000 title claims abstract description 63
- 229940106157 cellulase Drugs 0.000 title claims abstract description 56
- 239000008187 granular material Substances 0.000 title claims abstract description 48
- 239000003599 detergent Substances 0.000 title abstract description 25
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 38
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 18
- 239000004744 fabric Substances 0.000 claims abstract description 14
- 238000004140 cleaning Methods 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 18
- 239000004927 clay Substances 0.000 claims description 16
- 230000000694 effects Effects 0.000 claims description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
- 108010085318 carboxymethylcellulase Proteins 0.000 claims description 4
- 239000000391 magnesium silicate Substances 0.000 claims description 4
- 235000019792 magnesium silicate Nutrition 0.000 claims description 4
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 4
- 230000001580 bacterial effect Effects 0.000 claims description 3
- 230000002538 fungal effect Effects 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims 2
- 239000013543 active substance Substances 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 159000000007 calcium salts Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 description 23
- 125000000217 alkyl group Chemical group 0.000 description 18
- -1 alkyl sulphates Chemical class 0.000 description 17
- 239000004615 ingredient Substances 0.000 description 15
- 235000010216 calcium carbonate Nutrition 0.000 description 12
- 239000007844 bleaching agent Substances 0.000 description 9
- 108010084185 Cellulases Proteins 0.000 description 7
- 102000005575 Cellulases Human genes 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 108090000790 Enzymes Proteins 0.000 description 6
- 102000004190 Enzymes Human genes 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 229940088598 enzyme Drugs 0.000 description 6
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000004902 Softening Agent Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
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- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
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- 150000001875 compounds Chemical class 0.000 description 4
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- 239000002689 soil Substances 0.000 description 4
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- 229910019142 PO4 Inorganic materials 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical class [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001335 aliphatic alkanes Chemical group 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 235000012216 bentonite Nutrition 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000010410 dusting Methods 0.000 description 2
- 238000011534 incubation Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- HPAFOABSQZMTHE-UHFFFAOYSA-N phenyl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)C1=CC=CC=C1 HPAFOABSQZMTHE-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910021647 smectite Inorganic materials 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical class CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- AJJWBMVDEVRUCA-UHFFFAOYSA-N 4-dodec-2-enoxy-4-oxobutanoic acid Chemical compound CCCCCCCCCC=CCOC(=O)CCC(O)=O AJJWBMVDEVRUCA-UHFFFAOYSA-N 0.000 description 1
- LWYAUHJRUCQFCX-UHFFFAOYSA-N 4-dodecoxy-4-oxobutanoic acid Chemical compound CCCCCCCCCCCCOC(=O)CCC(O)=O LWYAUHJRUCQFCX-UHFFFAOYSA-N 0.000 description 1
- XGIPGWJHNHEEAL-UHFFFAOYSA-N 4-hexadecoxy-4-oxobutanoic acid Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCC(O)=O XGIPGWJHNHEEAL-UHFFFAOYSA-N 0.000 description 1
- LSWKXNPXIJXDHU-UHFFFAOYSA-N 4-oxo-4-tetradecoxybutanoic acid Chemical compound CCCCCCCCCCCCCCOC(=O)CCC(O)=O LSWKXNPXIJXDHU-UHFFFAOYSA-N 0.000 description 1
- JKTORXLUQLQJCM-UHFFFAOYSA-N 4-phosphonobutylphosphonic acid Chemical compound OP(O)(=O)CCCCP(O)(O)=O JKTORXLUQLQJCM-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000607534 Aeromonas Species 0.000 description 1
- 241000750142 Auricula Species 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000237379 Dolabella Species 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000223198 Humicola Species 0.000 description 1
- 241000223200 Humicola grisea var. thermoidea Species 0.000 description 1
- 241001480714 Humicola insolens Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000237852 Mollusca Species 0.000 description 1
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000006894 Primula auricula Nutrition 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 241000212342 Sium Species 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000003625 amylolytic effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical class O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- CMFFZBGFNICZIS-UHFFFAOYSA-N butanedioic acid;2,3-dihydroxybutanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)CCC(O)=O.OC(=O)C(O)C(O)C(O)=O CMFFZBGFNICZIS-UHFFFAOYSA-N 0.000 description 1
- HXDRSFFFXJISME-UHFFFAOYSA-N butanedioic acid;2,3-dihydroxybutanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)C(O)C(O)C(O)=O HXDRSFFFXJISME-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 229920003064 carboxyethyl cellulose Polymers 0.000 description 1
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- 125000002091 cationic group Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 210000000514 hepatopancreas Anatomy 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 230000007775 late Effects 0.000 description 1
- 230000002366 lipolytic effect Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- LUVMRKKWOQTAQD-UHFFFAOYSA-N n-acetyl-n-[6-(diacetylamino)hexyl]acetamide Chemical compound CC(=O)N(C(C)=O)CCCCCCN(C(C)=O)C(C)=O LUVMRKKWOQTAQD-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
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- 150000004965 peroxy acids Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
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- 229920000058 polyacrylate Polymers 0.000 description 1
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- 230000002797 proteolythic effect Effects 0.000 description 1
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- 230000003716 rejuvenation Effects 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- GSYPNDDXWAZDJB-MERQFXBCSA-M sodium 4-[(3R)-3,5,5-trimethylhexanoyl]oxybenzenesulfonate Chemical compound [Na+].C[C@@H](CC(=O)Oc1ccc(cc1)S([O-])(=O)=O)CC(C)(C)C GSYPNDDXWAZDJB-MERQFXBCSA-M 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
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- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- GKQFKSWGDUTIRB-UHFFFAOYSA-M sodium;4-(2-chlorooctanoyloxy)benzenesulfonate Chemical compound [Na+].CCCCCCC(Cl)C(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 GKQFKSWGDUTIRB-UHFFFAOYSA-M 0.000 description 1
- MEEQMYYIPMZWFF-UHFFFAOYSA-M sodium;4-decanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCCC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 MEEQMYYIPMZWFF-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 125000005017 substituted alkenyl group Chemical group 0.000 description 1
- 150000003457 sulfones Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
Definitions
- the amount of cellulase in the granules is determined by the total cellulase activity of the composition, which has to be in the limits set up hereinabove.
- Suitable anionic surfactants are water-soluble salts of alkyl benzene sulphonates, alkyl sulphates, alkyl polyethoxy ether sulphates, paraffin sulphonates, alpha- olefin sulphonates, alpha-sulphocarboxylates and their esters, alkyl glyceryl ether sulphonates, fatty acid monoglyceride sulphates and sulphonates, alkyl phenol polyethoxy either sulphates, 2-acyloxt-alkane-l- sulphonates, and beta-alkyloxy alkane sulphonates.
- alkyl benzene sulphonates have 9 to 15 carbon atoms in a linear or branched alkyl chain, especially from 11 to 13 carbon atoms.
- Suitable alkyl sulphates have from 10 to 22 carbon atoms in the alkyl chain, more especially from 12 to 18 carbon atoms.
- Suitable alkyl polyethoxy ether sulphates have from 10 to 18 carbon atoms in the alkyl chain and have an average of from 1 to 12 - CH CH.0- groups per molecule, especially from 10 to 16 carbon atoms in the alkyl chain aanndd aann aavvierage of from 1 to 6 -CH CH-0-groups per molecule.
- Suitable alpha-sulphocarboxy ⁇ lates contain from 6 to 20 carbon atoms; included herein are not only the salts of alpha-sulphonated fatty acids but also their esters made from alcohols containing 1 to 14 carbon atoms.
- Suitable alkyl glyceryl ether sulphates are ethers of alcohols having from 10 to 18 carbon atoms, more especially those derived from coconut oil and tallow.
- Suitable alkyl phenol polyethoxy ether sulphates have from 8 to 12 carbon atoms in the alkyl chain and an average of from 1 to 6 -CH 2 CH 2 0-groups per molecule.
- Cationic co-surfactants which can be used herein, include water-soluble quaternary ammonium compounds of the - 10 -
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BR888807805A BR8807805A (pt) | 1987-11-19 | 1988-11-18 | Composicoes detergentes contendo granulados de celulase |
| KR1019890701353A KR950013920B1 (ko) | 1987-11-19 | 1988-11-18 | 셀룰라아제 과립을 함유하는 세제 조성물 |
| AT89900022T ATE84818T1 (de) | 1987-11-19 | 1988-11-18 | Cellulosegranulate enthaltende waschmittelzusammensetzungen. |
| DE8989900022T DE3877768T2 (de) | 1987-11-19 | 1988-11-18 | Cellulosegranulate enthaltende waschmittelzusammensetzungen. |
| DK110890A DK164708C (da) | 1987-11-19 | 1990-05-04 | Detergentkompositioner indeholdende cellulasegranulater og cellulasegranulater til anvendelse heri |
| FI902446A FI92496C (fi) | 1987-11-19 | 1990-05-17 | Sellulaasigranulaatteja sisältävät pesuainekoostumukset |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB878727081A GB8727081D0 (en) | 1987-11-19 | 1987-11-19 | Granular detergent compositions |
| GB8727081 | 1987-11-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1989004862A1 true WO1989004862A1 (en) | 1989-06-01 |
Family
ID=10627204
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/DK1988/000189 WO1989004862A1 (en) | 1987-11-19 | 1988-11-18 | Detergent compositions containing cellulase granulates |
Country Status (19)
| Country | Link |
|---|---|
| EP (1) | EP0383828B1 (fi) |
| JP (1) | JP2735663B2 (fi) |
| KR (1) | KR950013920B1 (fi) |
| CN (2) | CN1026124C (fi) |
| AT (1) | ATE84818T1 (fi) |
| AU (1) | AU634705B2 (fi) |
| BR (1) | BR8807805A (fi) |
| CA (1) | CA1336894C (fi) |
| DE (1) | DE3877768T2 (fi) |
| DK (1) | DK164708C (fi) |
| FI (1) | FI92496C (fi) |
| GB (1) | GB8727081D0 (fi) |
| HK (1) | HK143896A (fi) |
| IE (1) | IE61734B1 (fi) |
| IN (1) | IN183413B (fi) |
| MX (1) | MX169695B (fi) |
| MY (1) | MY103481A (fi) |
| NZ (1) | NZ227025A (fi) |
| WO (1) | WO1989004862A1 (fi) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0495258A1 (en) * | 1991-01-16 | 1992-07-22 | The Procter & Gamble Company | Detergent compositions with high activity cellulase and softening clays |
| EP0579230A3 (de) * | 1992-07-17 | 1995-04-19 | Benckiser Gmbh Joh A | Maschinenschonendes Geschirrspülmittel. |
| US5443750A (en) * | 1991-01-16 | 1995-08-22 | The Procter & Gamble Company | Detergent compositions with high activity cellulase and softening clays |
| US5520838A (en) * | 1991-01-16 | 1996-05-28 | The Procter & Gamble Company | Compact detergent compositions with high activity cellulase |
| WO2003062363A1 (de) * | 2002-01-23 | 2003-07-31 | Henkel Kommanditgesellschaft Auf Aktien | Kombination von cellulasen und spezieller cellulose in waschmitteln |
| WO2022248316A1 (en) * | 2021-05-25 | 2022-12-01 | Unilever Ip Holdings B.V. | Laundry method |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6723549B2 (en) | 1995-10-17 | 2004-04-20 | Ab Enzymes Oy | Cellulases, the genes encoding them and uses thereof |
| US6184019B1 (en) | 1995-10-17 | 2001-02-06 | Röhm Enzyme Finland OY | Cellulases, the genes encoding them and uses thereof |
| GB0124307D0 (en) | 2001-10-10 | 2001-11-28 | Unilever Plc | Detergent compositions |
| GB0124308D0 (en) | 2001-10-10 | 2001-11-28 | Unilever Plc | Detergent compositions |
| CN103816884B (zh) * | 2014-02-24 | 2015-09-09 | 钟春燕 | 一种负载二氧化钛的纳米活性碳纤维制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0170360A1 (en) * | 1984-05-29 | 1986-02-05 | Novo Nordisk A/S | Enzyme containing granulates suitable for use as detergent additives |
| EP0177165A2 (en) * | 1984-08-29 | 1986-04-09 | Unilever Plc | Detergent composition |
| GB2167758A (en) * | 1984-10-12 | 1986-06-04 | Showa Denko Kk | Enzyme-granulating method and granular composition containing enzyme |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ230842A (en) * | 1988-10-21 | 1992-05-26 | Colgate Palmolive Co | Nonionic heavy duty particulate detergent containing protease, amylase and cellulase |
-
1987
- 1987-11-19 GB GB878727081A patent/GB8727081D0/en active Pending
-
1988
- 1988-11-17 IN IN1001DE1988 patent/IN183413B/en unknown
- 1988-11-18 AT AT89900022T patent/ATE84818T1/de not_active IP Right Cessation
- 1988-11-18 JP JP1500029A patent/JP2735663B2/ja not_active Expired - Lifetime
- 1988-11-18 EP EP89900022A patent/EP0383828B1/en not_active Expired - Lifetime
- 1988-11-18 IE IE346588A patent/IE61734B1/en not_active IP Right Cessation
- 1988-11-18 BR BR888807805A patent/BR8807805A/pt not_active IP Right Cessation
- 1988-11-18 WO PCT/DK1988/000189 patent/WO1989004862A1/en active IP Right Grant
- 1988-11-18 CA CA000583568A patent/CA1336894C/en not_active Expired - Fee Related
- 1988-11-18 KR KR1019890701353A patent/KR950013920B1/ko not_active Expired - Fee Related
- 1988-11-18 AU AU26117/88A patent/AU634705B2/en not_active Ceased
- 1988-11-18 DE DE8989900022T patent/DE3877768T2/de not_active Expired - Fee Related
- 1988-11-19 MY MYPI88001320A patent/MY103481A/en unknown
- 1988-11-19 CN CN88108833A patent/CN1026124C/zh not_active Expired - Fee Related
- 1988-11-21 MX MX013871A patent/MX169695B/es unknown
- 1988-11-21 NZ NZ227025A patent/NZ227025A/en unknown
-
1990
- 1990-05-04 DK DK110890A patent/DK164708C/da not_active IP Right Cessation
- 1990-05-17 FI FI902446A patent/FI92496C/fi not_active IP Right Cessation
-
1994
- 1994-01-07 CN CN94100297A patent/CN1092101A/zh active Pending
-
1996
- 1996-08-01 HK HK143896A patent/HK143896A/en not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0170360A1 (en) * | 1984-05-29 | 1986-02-05 | Novo Nordisk A/S | Enzyme containing granulates suitable for use as detergent additives |
| EP0177165A2 (en) * | 1984-08-29 | 1986-04-09 | Unilever Plc | Detergent composition |
| GB2167758A (en) * | 1984-10-12 | 1986-06-04 | Showa Denko Kk | Enzyme-granulating method and granular composition containing enzyme |
Non-Patent Citations (1)
| Title |
|---|
| Chemical Abstracts, volume 105, no. 26, December 1986, (Columbus, Ohio, US), see page 119 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0495258A1 (en) * | 1991-01-16 | 1992-07-22 | The Procter & Gamble Company | Detergent compositions with high activity cellulase and softening clays |
| WO1992013057A1 (en) * | 1991-01-16 | 1992-08-06 | The Procter & Gamble Company | Compact detergent compositions with high activity cellulase |
| US5443750A (en) * | 1991-01-16 | 1995-08-22 | The Procter & Gamble Company | Detergent compositions with high activity cellulase and softening clays |
| US5520838A (en) * | 1991-01-16 | 1996-05-28 | The Procter & Gamble Company | Compact detergent compositions with high activity cellulase |
| EP0579230A3 (de) * | 1992-07-17 | 1995-04-19 | Benckiser Gmbh Joh A | Maschinenschonendes Geschirrspülmittel. |
| WO2003062363A1 (de) * | 2002-01-23 | 2003-07-31 | Henkel Kommanditgesellschaft Auf Aktien | Kombination von cellulasen und spezieller cellulose in waschmitteln |
| WO2022248316A1 (en) * | 2021-05-25 | 2022-12-01 | Unilever Ip Holdings B.V. | Laundry method |
Also Published As
| Publication number | Publication date |
|---|---|
| FI92496C (fi) | 1994-11-25 |
| CN1036402A (zh) | 1989-10-18 |
| EP0383828A1 (en) | 1990-08-29 |
| IN183413B (fi) | 1999-12-25 |
| IE61734B1 (en) | 1994-11-30 |
| EP0383828B1 (en) | 1993-01-20 |
| KR890701719A (ko) | 1989-12-21 |
| DK164708B (da) | 1992-08-03 |
| FI92496B (fi) | 1994-08-15 |
| DE3877768T2 (de) | 1993-05-27 |
| JPH03503775A (ja) | 1991-08-22 |
| JP2735663B2 (ja) | 1998-04-02 |
| AU2611788A (en) | 1989-06-14 |
| IE883465L (en) | 1989-05-19 |
| BR8807805A (pt) | 1990-10-23 |
| ATE84818T1 (de) | 1993-02-15 |
| DK110890D0 (da) | 1990-05-04 |
| CN1026124C (zh) | 1994-10-05 |
| CA1336894C (en) | 1995-09-05 |
| DE3877768D1 (de) | 1993-03-04 |
| HK143896A (en) | 1996-08-09 |
| DK110890A (da) | 1990-05-04 |
| DK164708C (da) | 1992-12-21 |
| NZ227025A (en) | 1992-08-26 |
| AU634705B2 (en) | 1993-03-04 |
| MX169695B (es) | 1993-07-19 |
| GB8727081D0 (en) | 1987-12-23 |
| KR950013920B1 (ko) | 1995-11-18 |
| CN1092101A (zh) | 1994-09-14 |
| MY103481A (en) | 1993-06-30 |
| FI902446A0 (fi) | 1990-05-17 |
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