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US3924031A - Method for metal coating diamonds so as to improve the interfacial bond strength - Google Patents

Method for metal coating diamonds so as to improve the interfacial bond strength Download PDF

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US3924031A
US3924031A US343806A US34380673A US3924031A US 3924031 A US3924031 A US 3924031A US 343806 A US343806 A US 343806A US 34380673 A US34380673 A US 34380673A US 3924031 A US3924031 A US 3924031A
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alloy
diamond
metal
layer
carbide
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US343806A
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Michael G Nicholas
Peter M Scott
Bruce I Dewar
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De Beers Industrial Diamond Division Pty Ltd
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De Beers Industrial Diamond Division Pty Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/14—Anti-slip materials; Abrasives
    • C09K3/1436—Composite particles, e.g. coated particles
    • C09K3/1445—Composite particles, e.g. coated particles the coating consisting exclusively of metals

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  • ABSTRACT A method of producing metal coated diamond particles in which the coatings are strongly bonded to the diamond particles characterised in that a layer of an alloy consisting of a major proportion of a metal such as copper, nickel or iron and a minor proportion of a carbide-forming metal such as titanium, chromium or vanadium is applied to the uncoated particles and then the coated particles are heat treated to a temperature of between 500C and a temperature just below the melting point of the alloy for a time sufficient to enable a bonding carbide layer to form at the alloy/- diamond interface, the steps being carried out in a non-oxidising atmosphere.
  • a layer of an alloy consisting of a major proportion of a metal such as copper, nickel or iron and a minor proportion of a carbide-forming metal such as titanium, chromium or vanadium is applied to the uncoated particles and then the coated particles are heat treated to a temperature of between 500C and a temperature just below the melting point of the alloy for a time sufficient to enable a bonding carbide layer to form
  • the invention further provides diamond particles having bonded thereto an alloy comprising a major proportion of nickel and a minor proportion of a carbide-forming metal such as titanium, chromium or vanadium, the bonding being achieved by means of a carbide layer, which is preferably continuous, at the alloy/diamond interface.
  • a carbide-forming metal such as titanium, chromium or vanadium
  • a method of producing a metal coated diamond particle including the steps of applying a layer of an alloy comprising a major proportion of a first metal and a'minor proportion of a carbide-forming metal to an uncoated particle and heat treating the particle at a temperature in the range of from 500C to a temperature just below the melting point of the alloy for a time sufficient to enable a bonding carbide layer to form at the alloy/- diamond interface, the steps being carried out in a nonoxidising atmosphere.
  • the bond strength of the alloy/- diamond interface is a function of the temperature'of heat treatment, the period of heat treatment and the concentration of carbide-forming metal in the alloy and that by suitably controlling these factors the bond strength can be maximised. Bond strengths in excess of kg/mm can be achieved.
  • carbide-forming metal in the alloy for a continuous carbide layer to be formed at the diamond/alloy interface.
  • the amount necessary to achieve this will vary with the depth of the alloy layer. For example it has been found that for alloy depths of about 1000 A, a carbide-forming metal content of between 10 and 30 percent by weight of the alloy produces a continuous layer of carbide at the diamond/alloy interface after the heat treatment.
  • the first metal may be any suitable metal for coating diamonds, for example copper, nickel or iron.
  • the carbide-forming metal is preferably a transition metal and preferably one selected from the group of titanium, vanadium and chromium.
  • the amount of alloy layer which is applied to the diamond particle will vary according to the particle and the application to which the coated particle is to be put. The choice of a particular amount for a particular situation is, however, well within the knowledge of one skilled in the art.
  • the particles may be in the form of large particles or grit such as RD, SD, or MD grit.
  • the coated grit is particularly suited for use in resin bond and metal bond wheels, saws and compacts.
  • the coated larger particles find application in crowns and single point tools.
  • the non-oxidising atmosphere may be provided by helium, argon, hydrogen, nitrogen or a vacuum of the order of 10' mm.Hg.
  • the layer of alloy may be applied to the diamond particles using known deposition techniques such as vacuum evaporation or sputtering techniques. These techniques are well known in the art and descriptions of them can be found in such references as Vacuum Deposition of Thin Films by L. Holland, Chapman and Hall, 1st Edition 1956.
  • any temperature in the above described range can be used.
  • the upper limit of the range preferably about 50 C below the melting point of the alloy.
  • the temperature is preferably maintained below the graphitization temperature of diamond.
  • a diamond particle having bonded thereto a layer of an alloy comprising a major proportion of nickel and a minor proportion of a carbide-forming metal, the bonding being achieved by means of a carbide layer at the alloy/diamond interface.
  • the bonding carbide layer is preferably a continuous layer.
  • the carbide forming metal is preferably chosen from those described above.
  • An outer layer of nickel or metal capable of alloying with nickel will preferably be provided on the outer surface of the alloy layer.
  • the choice of metal and the amount of it in the outer layer will depend on the application to which the coated particle will be put. One skilled in this art can, however, readily make these choices.
  • the outer layer can be deposited on the alloycoated particle using known deposition techniques such as electrolytic or electroless deposition techniques or the vacuum deposition techniques described above.
  • Nickel and copper based alloys were bonded to the diamond plaques.
  • the relevant alloy was made in a conventional manner and then swaged into an ingot of a desired diameter, e.g. 1.5 mm. The ingot was then cut into required lengths and a length placed on the diamond which in turn rested on a graphite anvil in a chamber consisting of a quartz tube clamped between water cooled top and bottom brass plates.
  • the chamber was evacuated by a rotary pump to 10' mm Hg or better pressure and maintained at this pressure during heating.
  • a silica piston entered the vacuum chamber through a Wilson seal in the top plate and was used to apply pressure to the samples on the anvils. The pressure applied was sufficient to provide intimate contact between the alloy and the diamond equivalent to coating.
  • the pressures used varied between about 3 to about 7.5 kg/rnm induction heating was then used to raise the temperature of the chamber to the desired temperature i.e., 700 or 800C. Excellent solid phase bonding between the alloy and the diamond resulted
  • the temperature was 800C, save for the Cu-Ti alloy in which the temperature was 700C.
  • Cu-Ti 0.54 wt Ti. Optimum time about 5 hours.
  • Bond strength 24.2 kg/mm 2.
  • Cu-Cr 0.22 wt Cr.
  • Optimum time about 1.5 to
  • EXAMPLE 2 40-50 mesh MD diamond grit was coated with a layer of nickeltitanium alloy (1 percent by weight titanium) using known vacuum sputtering techniques described in the Holland reference mentioned above. A layer amounting to 1 to 2 percent by weight of the uncoated particle was deposited. The coated particles were heat treated at a temperature of 800C for half an hour in a vacuum furnace mm/Hg).
  • a layer of nickel was then deposited on the treated grit using known electroless deposition techniques.
  • the nickel layer amounted to percent by weight of the alloy-coated particle.
  • pure nickel coated grit of the same size was prepared using the same electroless deposition techniques.
  • the nickel coating amounted to 20 percent by weight of the uncoated grit.
  • the two types of coated grit were incorporated in saws and sawing tests carried out. It was found that the saw containing the grit having the alloy layer showed twelve percent less wear than the other saw.
  • EXAMPLE 3 RD diamond grit was coated with a nickel-titanium alloy (1 percent by weight titanium) and a nickel outer coat using the same method as in Example 2, except that the nickel layer amounted to a 55 percent by weight of the alloy-coated grit.
  • RD grit was coated with a 55 percent pure nickel coating.
  • the two types of grit were incorporated in resin bond wheels. During grinding tests it was observed that the diamond grit was never pulled out of its coating in the case of the alloy coatings, whereas this did occur with the pure nickel coated particles. This test illustrates the strength of the diamond/alloy interfacial bond.
  • EXAMPLE 4 A layer of nickel-chromium alloy (10 percent by weight nickel) was deposited on diamond plaques using sputtering techniques. The coated plaques were heat treated at 800C for 2 hours. A nickel overlayer was electrolytically deposited on the alloy layer.
  • the diamond/alloy interfacial tensile strength or bond strength was found to be 10 kg/mm using the same apparatus as that described in Example 1.
  • a method of producing a metal coated diamond particle including the steps of applying to an uncoated diamond particle a layer which in the as-applied condition is an alloy comprising a major proportion of a metal selected from copper, nickel and iron and a minor proportion of a carbide-forming metal selected from titanium, chromium and vanadium sufficient to form a continuous carbide layer around the diamond particle, and heat treating the particle to a temperature in the -range of from 500C. to a temperature just below the melting point of the alloy for a time sufficient to produce a continuous bonding carbide layer at the alloy/diamond interface and an interface bond strength in excess of 10 kg/mm the steps being carried out in a non-oxidizing atmosphere.

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  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

A method of producing metal coated diamond particles in which the coatings are strongly bonded to the diamond particles characterised in that a layer of an alloy consisting of a major proportion of a metal such as copper, nickel or iron and a minor proportion of a carbide-forming metal such as titanium, chromium or vanadium is applied to the uncoated particles and then the coated particles are heat treated to a temperature of between 500*C and a temperature just below the melting point of the alloy for a time sufficient to enable a bonding carbide layer to form at the alloy/diamond interface, the steps being carried out in a non-oxidising atmosphere. The invention further provides diamond particles having bonded thereto an alloy comprising a major proportion of nickel and a minor proportion of a carbide-forming metal such as titanium, chromium or vanadium, the bonding being achieved by means of a carbide layer, which is preferably continuous, at the alloy/diamond interface.

Description

United States Patent [19] Nicholas et al.
[ Dec. 2, 1975 METHOD FOR METAL COATING DIAMONDS SO AS TO IMPROVE THE INTERFACIAL BOND STRENGTH [73] Assignee: De Beers Industrial Diamond Division Limited, Johannesburg, South Africa [22] Filed: Mar. 22, 1973 [21] Appl. No.: 343,806
[30] Foreign Application Priority Data Mar. 22, 1972 United Kingdom...: 13426/72 Mar. 22, 1972 United Kingdom 13427/72 [52] U.S. Cl. 427/217; 51/295; 427/250; 427/294; 427/383; 427/399 [51] Int. Cl. B05D 7/00 [58] Field of Search 117/100 B, DIG. 11, 228, 117/118, 71 R; 51/295; 427/217, 250, 294,
[56] References Cited UNITED STATES PATENTS 3,356,473 12/1967 l-lull et a1. ll7/l00 B Kroder 51/295 Bickerdike et a1 117/71 R Primary Examiner-William D. Martin Assistant Examiner-Dennis C. Konopacki Attorney, Agent, or Firm-Young & Thompson [57] ABSTRACT A method of producing metal coated diamond particles in which the coatings are strongly bonded to the diamond particles characterised in that a layer of an alloy consisting of a major proportion of a metal such as copper, nickel or iron and a minor proportion of a carbide-forming metal such as titanium, chromium or vanadium is applied to the uncoated particles and then the coated particles are heat treated to a temperature of between 500C and a temperature just below the melting point of the alloy for a time sufficient to enable a bonding carbide layer to form at the alloy/- diamond interface, the steps being carried out in a non-oxidising atmosphere. The invention further provides diamond particles having bonded thereto an alloy comprising a major proportion of nickel and a minor proportion of a carbide-forming metal such as titanium, chromium or vanadium, the bonding being achieved by means of a carbide layer, which is preferably continuous, at the alloy/diamond interface.
1 Claim, No Drawings METHOD lFOlR METAL COATING DIAMONDS SO AS TO llMPROVE THE INTERFACIAL BOND STRENGTH This invention relates, to the metal coating of diamond.
Very extensive use is made of diamond in abrasive tools such as crowns, single point tools, resin and metal bond wheels, saws and compacts. Considerable amount of research has gone into improving the bonding properties of the diamond to the matrices of these tools as a poor bond at the diamond/matrix interface leads to dislodgment of the diamond from the matrix during the abrading operation. This research has led to the development of metal coated diamond particles which find application particularly in resin bond wheels. Such metal coated particles have been found to have retention properties in resin bond wheels which are superior to uncoated diamond particles. However, research continues in an effort to improve the bond strength of the metal/diamond interface, thereby to improve the retention properties of diamond in the matrices of abrasive tools.
It is an object of this invention to provide a method of bonding an alloy to diamond which provides a strong interfacial bond between the alloy and the diamond.
It is a further object of the invention to provide a novel metal coated diamond particle.
According to the invention, there is provided a method of producing a metal coated diamond particle including the steps of applying a layer of an alloy comprising a major proportion of a first metal and a'minor proportion of a carbide-forming metal to an uncoated particle and heat treating the particle at a temperature in the range of from 500C to a temperature just below the melting point of the alloy for a time sufficient to enable a bonding carbide layer to form at the alloy/- diamond interface, the steps being carried out in a nonoxidising atmosphere.
It has been found that the bond strength of the alloy/- diamond interface is a function of the temperature'of heat treatment, the period of heat treatment and the concentration of carbide-forming metal in the alloy and that by suitably controlling these factors the bond strength can be maximised. Bond strengths in excess of kg/mm can be achieved.
In order to achieve maximum bond strength it is preferred to provide sufficient carbide-forming metal in the alloy for a continuous carbide layer to be formed at the diamond/alloy interface. The amount necessary to achieve this will vary with the depth of the alloy layer. For example it has been found that for alloy depths of about 1000 A, a carbide-forming metal content of between 10 and 30 percent by weight of the alloy produces a continuous layer of carbide at the diamond/alloy interface after the heat treatment.
The first metal may be any suitable metal for coating diamonds, for example copper, nickel or iron.
The carbide-forming metal is preferably a transition metal and preferably one selected from the group of titanium, vanadium and chromium.
The amount of alloy layer which is applied to the diamond particle will vary according to the particle and the application to which the coated particle is to be put. The choice of a particular amount for a particular situation is, however, well within the knowledge of one skilled in the art.
The particles may be in the form of large particles or grit such as RD, SD, or MD grit. The coated grit is particularly suited for use in resin bond and metal bond wheels, saws and compacts. The coated larger particles find application in crowns and single point tools.
The non-oxidising atmosphere may be provided by helium, argon, hydrogen, nitrogen or a vacuum of the order of 10' mm.Hg.
The layer of alloy may be applied to the diamond particles using known deposition techniques such as vacuum evaporation or sputtering techniques. These techniques are well known in the art and descriptions of them can be found in such references as Vacuum Deposition of Thin Films by L. Holland, Chapman and Hall, 1st Edition 1956.
Any temperature in the above described range can be used. The upper limit of the range of preferably about 50 C below the melting point of the alloy. However, where high melting alloys are used, the temperature is preferably maintained below the graphitization temperature of diamond.
According to another aspect of the invention, there is .provided a diamond particle having bonded thereto a layer of an alloy comprising a major proportion of nickel and a minor proportion of a carbide-forming metal, the bonding being achieved by means of a carbide layer at the alloy/diamond interface. The bonding carbide layer is preferably a continuous layer.
The carbide forming metal is preferably chosen from those described above.
An outer layer of nickel or metal capable of alloying with nickel will preferably be provided on the outer surface of the alloy layer. The choice of metal and the amount of it in the outer layer will depend on the application to which the coated particle will be put. One skilled in this art can, however, readily make these choices. The outer layer can be deposited on the alloycoated particle using known deposition techniques such as electrolytic or electroless deposition techniques or the vacuum deposition techniques described above.
limitative examples.
EXAMPLE 1 in order to illustrate the maximisation of the bond strengths at the diamond/alloy interface certain experiments were carried out on diamond plaques.
Nickel and copper based alloys were bonded to the diamond plaques. In each case, the relevant alloy was made in a conventional manner and then swaged into an ingot of a desired diameter, e.g. 1.5 mm. The ingot was then cut into required lengths and a length placed on the diamond which in turn rested on a graphite anvil in a chamber consisting of a quartz tube clamped between water cooled top and bottom brass plates. The chamber was evacuated by a rotary pump to 10' mm Hg or better pressure and maintained at this pressure during heating. A silica piston entered the vacuum chamber through a Wilson seal in the top plate and was used to apply pressure to the samples on the anvils. The pressure applied was sufficient to provide intimate contact between the alloy and the diamond equivalent to coating. The pressures used varied between about 3 to about 7.5 kg/rnm induction heating was then used to raise the temperature of the chamber to the desired temperature i.e., 700 or 800C. Excellent solid phase bonding between the alloy and the diamond resulted in each case.
Using this method optimum conditions have been determined for a number of nickel and copper based alloys.
In all cases, the temperature was 800C, save for the Cu-Ti alloy in which the temperature was 700C.
1. Cu-Ti: 0.54 wt Ti. Optimum time about 5 hours.
Bond strength 24.2 kg/mm 2. Cu-Cr: 0.22 wt Cr. Optimum time about 1.5 to
2.0 hours. Bond strength 21.4 kglmm 3. Nichrome V (80% by weight nickel and 20% by weight chromium): Optimum time about 2 hours. Bond strength 14.2 kg/mm 4. Ni-Ti: 1 wt Ti. Optimum time about 0.5 hours.
Bond strength 28.3 kg/mm 5. Ni-V: 0.83 wt V. Optimum time about 2 hours.
Bond strength 26.2 kglmm The bond strengths i.e. interfacial tensile strengths,
were measured in a standard manner using a shearing jig to which was attached a Hounsfield tensometer.
EXAMPLE 2 40-50 mesh MD diamond grit was coated with a layer of nickeltitanium alloy (1 percent by weight titanium) using known vacuum sputtering techniques described in the Holland reference mentioned above. A layer amounting to 1 to 2 percent by weight of the uncoated particle was deposited. The coated particles were heat treated at a temperature of 800C for half an hour in a vacuum furnace mm/Hg).
A layer of nickel was then deposited on the treated grit using known electroless deposition techniques. The nickel layer amounted to percent by weight of the alloy-coated particle.
For purposes of comparison, pure nickel coated grit of the same size was prepared using the same electroless deposition techniques. The nickel coating amounted to 20 percent by weight of the uncoated grit.
The two types of coated grit were incorporated in saws and sawing tests carried out. It was found that the saw containing the grit having the alloy layer showed twelve percent less wear than the other saw.
EXAMPLE 3 RD diamond grit was coated with a nickel-titanium alloy (1 percent by weight titanium) and a nickel outer coat using the same method as in Example 2, except that the nickel layer amounted to a 55 percent by weight of the alloy-coated grit.
Similarly, RD grit was coated with a 55 percent pure nickel coating. The two types of grit were incorporated in resin bond wheels. During grinding tests it was observed that the diamond grit was never pulled out of its coating in the case of the alloy coatings, whereas this did occur with the pure nickel coated particles. This test illustrates the strength of the diamond/alloy interfacial bond.
EXAMPLE 4 A layer of nickel-chromium alloy (10 percent by weight nickel) was deposited on diamond plaques using sputtering techniques. The coated plaques were heat treated at 800C for 2 hours. A nickel overlayer was electrolytically deposited on the alloy layer.
The diamond/alloy interfacial tensile strength or bond strength was found to be 10 kg/mm using the same apparatus as that described in Example 1.
We claim:
1. A method of producing a metal coated diamond particle including the steps of applying to an uncoated diamond particle a layer which in the as-applied condition is an alloy comprising a major proportion of a metal selected from copper, nickel and iron and a minor proportion of a carbide-forming metal selected from titanium, chromium and vanadium sufficient to form a continuous carbide layer around the diamond particle, and heat treating the particle to a temperature in the -range of from 500C. to a temperature just below the melting point of the alloy for a time sufficient to produce a continuous bonding carbide layer at the alloy/diamond interface and an interface bond strength in excess of 10 kg/mm the steps being carried out in a non-oxidizing atmosphere.
US343806A 1972-03-22 1973-03-22 Method for metal coating diamonds so as to improve the interfacial bond strength Expired - Lifetime US3924031A (en)

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GB1342672A GB1388172A (en) 1972-03-22 1972-03-22 Metal coating of diamonds
GB1342772 1972-03-22

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CH (1) CH577566A5 (en)
FR (1) FR2177031B1 (en)
GB (1) GB1388172A (en)
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US4062660A (en) * 1973-04-16 1977-12-13 Nicholas Michael G Method of producing nickel coated diamond particles
US4063907A (en) * 1975-07-28 1977-12-20 General Electric Company Modifying the surface of diamond particles
US4074471A (en) * 1974-10-15 1978-02-21 Carnegie-Mellon University Process for nucleating diamonds
US4142869A (en) * 1973-12-29 1979-03-06 Vereschagin Leonid F Compact-grained diamond material
US4338365A (en) * 1980-12-31 1982-07-06 Mobil Oil Corporation Boilable pouch for foods
US4399167A (en) * 1978-03-09 1983-08-16 Pipkin Noel J Metal coating of abrasive particles
US4689276A (en) * 1983-03-15 1987-08-25 Varian Associates Diamond bonded electronic circuit
US4943488A (en) * 1986-10-20 1990-07-24 Norton Company Low pressure bonding of PCD bodies and method for drill bits and the like
US4951427A (en) * 1989-05-30 1990-08-28 General Electric Company Refractory metal oxide coated abrasives and grinding wheels made therefrom
US5024680A (en) * 1988-11-07 1991-06-18 Norton Company Multiple metal coated superabrasive grit and methods for their manufacture
US5030276A (en) * 1986-10-20 1991-07-09 Norton Company Low pressure bonding of PCD bodies and method
US5068126A (en) * 1988-03-04 1991-11-26 Sharp Kabushiki Kaisha Process for producing graphite electrodes
US5090969A (en) * 1987-10-21 1992-02-25 Takeo Oki Coated abrasive grains and a manufacturing method therefor
US5104422A (en) * 1989-05-30 1992-04-14 General Electric Company Refractory metal oxide coated abrasives and grinding wheels made therefrom
US5116568A (en) * 1986-10-20 1992-05-26 Norton Company Method for low pressure bonding of PCD bodies
US5126207A (en) * 1990-07-20 1992-06-30 Norton Company Diamond having multiple coatings and methods for their manufacture
US5169508A (en) * 1988-03-04 1992-12-08 Sharp Kabushiki Kaisha Graphite electrode
EP0520776A2 (en) * 1991-06-27 1992-12-30 General Electric Company Method of applying metal coatings on diamond
EP0533443A1 (en) * 1991-09-20 1993-03-24 General Electric Company Dual coated diamond pellets
US5230718A (en) * 1987-10-21 1993-07-27 Takeo Oki Coated abrasive grains and a manufacturing method therefor
US5232469A (en) * 1992-03-25 1993-08-03 General Electric Company Multi-layer metal coated diamond abrasives with an electrolessly deposited metal layer
US5250086A (en) * 1992-03-25 1993-10-05 General Electric Company Multi-layer metal coated diamond abrasives for sintered metal bonded tools
US5804321A (en) * 1993-07-30 1998-09-08 The United States Of America As Represented By The Secretary Of The Navy Diamond brazed to a metal
US6162497A (en) * 1991-07-17 2000-12-19 Materials Innovation, Inc. Manufacturing particles and articles having engineered properties
US6302186B1 (en) * 1999-11-01 2001-10-16 Jeneric/Pentron, Inc. Plunger for a pressing furnace
US20040157089A1 (en) * 2002-09-23 2004-08-12 Gunter Kneringer Heat sink formed of diamond-containing composite material with a multilayer coating
US20050108948A1 (en) * 2002-09-24 2005-05-26 Chien-Min Sung Molten braze-coated superabrasive particles and associated methods
US20060059785A1 (en) * 2002-09-24 2006-03-23 Chien-Min Sung Methods of maximizing retention of superabrasive particles in a metal matrix
US20070020457A1 (en) * 2005-07-21 2007-01-25 3M Innovative Properties Company Composite particle comprising an abrasive grit
US20120177925A1 (en) * 2011-01-11 2012-07-12 Omg Electronic Chemicals, Llc Electroless plating bath composition and method of plating particulate matter
CN104789931A (en) * 2015-04-29 2015-07-22 富耐克超硬材料股份有限公司 Titanizing process for superhard material micro powder
US20160281264A1 (en) * 2013-12-11 2016-09-29 Beijing Polystar Hitech Co., Ltd. A method of preparing a monocrystalline diamond abrasive grain
US20160279761A1 (en) * 2015-03-25 2016-09-29 Baker Hughes Incorporated Polycrystalline diamond, methods of forming same, cutting elements, and earth-boring tools
CN113106449A (en) * 2021-04-30 2021-07-13 华侨大学 Preparation method and preparation device for coating chromium powder on surfaces of diamond particles
CN114561565A (en) * 2022-02-12 2022-05-31 太原理工大学 Preparation method of diamond particle reinforced high-entropy alloy composite material
CN115011917A (en) * 2022-05-18 2022-09-06 湖南工业职业技术学院 Diamond particle surface modification method based on vacuum thermal evaporation
CN117210780A (en) * 2023-11-07 2023-12-12 成都成高阀门股份有限公司 High-wear-resistance supersonic speed flame-sprayed chromium carbide-based coating and preparation method thereof

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GB1353832A (en) * 1971-08-03 1974-05-22 Degussa Sulphonium compounds of alpha-hydroxy-gamma-alkyl-mercapto butyric acid
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US3663191A (en) * 1970-07-23 1972-05-16 Dentsply Int Inc Diamond tool and method of making the same

Cited By (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4062660A (en) * 1973-04-16 1977-12-13 Nicholas Michael G Method of producing nickel coated diamond particles
US4142869A (en) * 1973-12-29 1979-03-06 Vereschagin Leonid F Compact-grained diamond material
US4074471A (en) * 1974-10-15 1978-02-21 Carnegie-Mellon University Process for nucleating diamonds
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CA984240A (en) 1976-02-24
AU466277B2 (en) 1975-10-23
FR2177031B1 (en) 1977-07-29
FR2177031A1 (en) 1973-11-02
GB1388172A (en) 1975-03-26
JPS5738523B2 (en) 1982-08-16
IE37578L (en) 1973-09-22
SE412379B (en) 1980-03-03
CH577566A5 (en) 1976-07-15
AU5335173A (en) 1974-09-19
JPS4918787A (en) 1974-02-19
IE37578B1 (en) 1977-08-31

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