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US3857960A - Toilet oil bar - Google Patents

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Publication number
US3857960A
US3857960A US00319593A US31959372A US3857960A US 3857960 A US3857960 A US 3857960A US 00319593 A US00319593 A US 00319593A US 31959372 A US31959372 A US 31959372A US 3857960 A US3857960 A US 3857960A
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United States
Prior art keywords
bar
oil
amide
weight
stearic acid
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Expired - Lifetime
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US00319593A
Inventor
L Mackles
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Bristol Myers Co
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Bristol Myers Co
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Priority to US00319593A priority Critical patent/US3857960A/en
Priority to CA175,748A priority patent/CA1020091A/en
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Publication of US3857960A publication Critical patent/US3857960A/en
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof

Definitions

  • This invention relates to a toilet bar or cake adapted to release oil when wet with water. More particularly, it concerns the incorporation of relatively large amounts of mineral oil in a toilet bar from which the subsequent release of oil can be effected when the bar is wet with warm water and applied to the skin. This will give an oily feel to the skin similar to that obtained from bath oils.
  • a solid toilet bar or cake may be prepared in which an oil, particularly mineral oil, is incorporated in amounts up to 85% by weight. This is made possible by means of certain amides specified more particularly below.
  • the bar looks and feels like a soap bar, but releases oil as an unstable emulsion when wet with warm water. Though no foam is developed, the white emulsion obtained resembles the lather developed by soap. No matter how the hands or body are rinsed after being rubbed with the mineral oil bar, the oil cannot be removed. The results are similar to those obtained when one uses a bath oil.
  • U.S. Pat. No. 2,085,693 discloses a cold cream preparation having a white mineral oil present in an amount of 54.5% by weight of the total preparation.
  • Other ingredients include white wax, paraffin, white ceresin, borax and 32% water.
  • U.S. Pat. No. 3,424,849 discloses a bath oil using light or heavy white mineral oil present in percentages as high as 60% for heavy white mineral oil as noted in Formulation 2 and as highas 47% for light white mineral oil as noted in Formulations 1 and 5 in columns 7 and 8. These formulations are noted to differ from other prior art formulations in that they employ octyl dodecanoate in the formulation.
  • U.S. Pat. No. 3,535,427 discloses a skin moisturizing composition having mineral oil present in a percentage of about 65 to 80% by weight and also includes acetylated lanolin alcohol and isopropyl myristate.
  • Cosmetic bars are also known in the prior art. These are exemplified by the following references: U.S. Pat. Nos. 1,006,736 to C. Ellis; 2,101,843 to F. Factor et al.; 2,303,932 to B. T. Guild; 2,465,340 to 11. Sharlit; 2,900,306 to J. N. Slater; 3,179,596 to R. E. Farrar et al.; and 3,598,746 to T. J. Kaniecki et al. In this group, U.S. Pat. No. 2,900,306 is of interest in that it discloses a deodorant stick using stearic acid and its salts and alkyl amine soaps as detergents and emulsifiers. However, the concept of incorporating large amounts of oil and particularly, mineral oil is not shown in this reference.
  • the oil and particularly mineral oil is solidified by heating the oil with either or mixtures of two amides.
  • the amides are:
  • the quantity of oil that may be incorporated in the bar of the present invention may amount up to 85% by weight based on the total weight of the bar. However, it is preferred that the oil be maintained in the range of from about to by weight based on the total weight of the bar.
  • the quantity of the amide component that can be employed in formulating the present oil bars may also vary somewhat. Ordinarily, it will comprise between about 5 to 30% by weight based on the total weight of the bar.
  • One or the other amides specified above may be employed alone as the amide component or they may both be used together in varying amounts to constitute the amide components.
  • the amide component comprises about 40% by weight of the amide component of the monoethanolamine stearic acid amide and 60% by weight of the amide component of N,N distearoyl ethylenediamine.
  • emulsifying agents of these characters that are useful herein, mention may be made of the following: among the non-ionics: diethanolamine stearic acid amide; sorbitan trioleate (Span polyoxyethylene sorbitan monolaurate (polysorbate 20) (Tween 20), polyoxyethylene sorbitan monooleate (polysorbate 80) (Tween 80); among the anionics: sodium lauryl sulfate; coconut oil fatty acid ester of 'sodium isethionate (lgepan AC-78); triethanolamine lauryl sulfate; sodium lauroyl lactylate, etc.
  • the quantity of emulsifying agent that may be employed can also vary somewhat. However, when present, the emulsifying agent will ordinarily comprise between about 1 and 10% by weight of the total weight of the bar.
  • the mineral oil, the amide component and if desired, the emulsifying agent are mixed and heated together.
  • the bars are formed as the mixture is cooled in a mold.
  • the bars are hard and firm.
  • Example 1 The same procedure described above in Example 1 is used to form an oil bar.
  • the perfume is added in the above Examples for organoleptic purposes. It may be dispensed with in which event another 0.5% by weight of the mineral oil is added to the composition.
  • a solid, hard and firm toilet oil bar having the appearance and feel of a soap bar; said oil bar releasing mineral oil when wet with warm water and applied to the skin, said bar containing mineral oil solidified with an amide component; said mineral oil constituting between about 70 percent to 85% by weight of said bar, and said amide component constituting between about 5 percent to 30% by weight of said bar and being selected from the group consisting of monoethanolamine stearic acid amide, N,N distearoyl ethylenediamine and mixtures thereof.
  • the oil bar of claim 1 including an emulsifying agent selected from the group consisting of diethanolamine stearic acid amide; sorbitan trioleate, polyoxyethylene (20) sorbitan monolaurate, polyoxyethylene (20) sorbitan monooleate; sodium lauryl sulfate; coconut oil fatty acid ester of sodium isethionate; triethanolamine lauryl sulfate and sodium lauroyl lactylate.
  • an emulsifying agent selected from the group consisting of diethanolamine stearic acid amide; sorbitan trioleate, polyoxyethylene (20) sorbitan monolaurate, polyoxyethylene (20) sorbitan monooleate; sodium lauryl sulfate; coconut oil fatty acid ester of sodium isethionate; triethanolamine lauryl sulfate and sodium lauroyl lactylate.
  • said amide component comprises a mixture of amides, about 40% by weight of said amide component being monoethanolamine stearic acid amide and about 60% by weight of said amide component being N,N distearoyl ethylenediamine.
  • the emulsifying agent component is a mixture of diethanolamine stearic acid amide and sodium lauroyl lactylate.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Veterinary Medicine (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

A toilet oil bar or cake adapted to release oil when wet with water. The oil bar is made by solidifying mineral oil with monoethanolamine stearic acid amide; N,N distearoyl ethylenediamine or mixtures thereof. The bar may also contain a non-ionic or anionic emulsifying agent to aid in the release of the oil.

Description

iter l States Patent [1 1 Maelrles [451 Dec. 31, 1974 [73] Assignee: Bristol-Myers Company, New York,
[22] Filed: Dec. 29, 1972 [21] Appl. N0.: 319,593
[52] 11.8. C1 424/365, 252/153, 424/358 [51] llnt. Cl A61k 7/00. [58] Field of Search 424/358, 365; 252/153 [56] References Cited UNITED STATES PATENTS 2,114,370 4/l938 Bickenaeuser 424/358 2,398,254 4/1946 Rosenthal 424/358 2,751,358
6/1956 Caviet 252/153 3,101,300 8/1963 Siegal et a1. 424/358 3,507,806 4/1970 Barker et al. 252/153 X FOREIGN PATENTS OR APPLICATIONS 708,585 4/1965 Canada 424/ 158 Primary Examiner-Frederick E. Waddell Attorney, Agent, or Firm-Irving Holtzman; George A. Mentis; David J. Mugford 57 ABSTRACT A toilet oil bar or cake adapted to release oil when wet with water. The oil bar is made by solidifying mineral oil with monoethanolamine stearic acid amide; N,N distearoyl ethylen'cdiamine or mixtures thereof. The bar may also contain a non-ionic or anionic emulsifying agent to aid in the release of the oil.
9 Claims, No Drawings TOILET 01L BAR This invention relates to a toilet bar or cake adapted to release oil when wet with water. More particularly, it concerns the incorporation of relatively large amounts of mineral oil in a toilet bar from which the subsequent release of oil can be effected when the bar is wet with warm water and applied to the skin. This will give an oily feel to the skin similar to that obtained from bath oils.
Attempts have been made in the past to add oils to soap bars. These, however, have never been successful in depositing oil on the skin largely because the oil that is so deposited is washed away by the emulsifying action of the soap.
It has now been found that a solid toilet bar or cake may be prepared in which an oil, particularly mineral oil, is incorporated in amounts up to 85% by weight. This is made possible by means of certain amides specified more particularly below. The bar looks and feels like a soap bar, but releases oil as an unstable emulsion when wet with warm water. Though no foam is developed, the white emulsion obtained resembles the lather developed by soap. No matter how the hands or body are rinsed after being rubbed with the mineral oil bar, the oil cannot be removed. The results are similar to those obtained when one uses a bath oil.
The prior art teaches the incorporation of large quantities of mineral oil in cosmetic formulations. However, nothing in this art suggests the use of the amides specified below in solidifying an oil, particularly mineral oil, in a bar as is characteristic of the present invention. Typical of this prior art are the references discussed below.
U.S. Pat. No. 2,085,693 discloses a cold cream preparation having a white mineral oil present in an amount of 54.5% by weight of the total preparation. Other ingredients include white wax, paraffin, white ceresin, borax and 32% water.
U.S. Pat. No. 3,424,849 discloses a bath oil using light or heavy white mineral oil present in percentages as high as 60% for heavy white mineral oil as noted in Formulation 2 and as highas 47% for light white mineral oil as noted in Formulations 1 and 5 in columns 7 and 8. These formulations are noted to differ from other prior art formulations in that they employ octyl dodecanoate in the formulation.
U.S. Pat. No. 3,535,427 discloses a skin moisturizing composition having mineral oil present in a percentage of about 65 to 80% by weight and also includes acetylated lanolin alcohol and isopropyl myristate.
Cosmetic bars are also known in the prior art. These are exemplified by the following references: U.S. Pat. Nos. 1,006,736 to C. Ellis; 2,101,843 to F. Factor et al.; 2,303,932 to B. T. Guild; 2,465,340 to 11. Sharlit; 2,900,306 to J. N. Slater; 3,179,596 to R. E. Farrar et al.; and 3,598,746 to T. J. Kaniecki et al. In this group, U.S. Pat. No. 2,900,306 is of interest in that it discloses a deodorant stick using stearic acid and its salts and alkyl amine soaps as detergents and emulsifiers. However, the concept of incorporating large amounts of oil and particularly, mineral oil is not shown in this reference.
In accordance with the present invention, the oil and particularly mineral oil, is solidified by heating the oil with either or mixtures of two amides. The amides are:
monoethanolamine stearic'acid amide or N,N distearoyl ethylenediamine or mixtures thereof.
The quantity of oil that may be incorporated in the bar of the present invention may amount up to 85% by weight based on the total weight of the bar. However, it is preferred that the oil be maintained in the range of from about to by weight based on the total weight of the bar.
The quantity of the amide component that can be employed in formulating the present oil bars may also vary somewhat. Ordinarily, it will comprise between about 5 to 30% by weight based on the total weight of the bar. One or the other amides specified above may be employed alone as the amide component or they may both be used together in varying amounts to constitute the amide components. In a preferred form of this invention, the amide component comprises about 40% by weight of the amide component of the monoethanolamine stearic acid amide and 60% by weight of the amide component of N,N distearoyl ethylenediamine.
To facilitate the transferal of the oil from the bar to the skin and to help emulsify the oil to form a latherlike emulsion, it is advantageous to incorporate a nonionic or anionic emulsifying agent or mixtures thereof in the bar. By way of illustrating the emulsifying agents of these characters that are useful herein, mention may be made of the following: among the non-ionics: diethanolamine stearic acid amide; sorbitan trioleate (Span polyoxyethylene sorbitan monolaurate (polysorbate 20) (Tween 20), polyoxyethylene sorbitan monooleate (polysorbate 80) (Tween 80); among the anionics: sodium lauryl sulfate; coconut oil fatty acid ester of 'sodium isethionate (lgepan AC-78); triethanolamine lauryl sulfate; sodium lauroyl lactylate, etc. The quantity of emulsifying agent that may be employed can also vary somewhat. However, when present, the emulsifying agent will ordinarily comprise between about 1 and 10% by weight of the total weight of the bar.
As previously noted, in preparing the oil bars of this invention, the mineral oil, the amide component and if desired, the emulsifying agent are mixed and heated together. The bars are formed as the mixture is cooled in a mold. The bars are hard and firm.
The following Examples are given to further illustrate the present invention. It is understood, however, that the invention is not limited thereto.
EXAMPLE 1 Ingredient by Weigh! Mineral oil SUP -190 SSU Visc. 7 Monethanolamine stearic acid amide Diethanolarnine stearic acid amide N,N distearoyl ethylenediamine 1 Perfume val/0000 EXAMPLE 2 Ingredient by Weight Mineral oil USP- SSU Vise. 72.0
EXAMPLE 2-Continued ingredient by Weight Monoethanolamine stearic acid amide 8.0 Diethanolamine stearic acid amide 6.0 N,N distearoyl ethylenediamine li.5 Sodium lauroyl lactylate 2.0 Perfume 0.5
The same procedure described above in Example 1 is used to form an oil bar.
The perfume is added in the above Examples for organoleptic purposes. It may be dispensed with in which event another 0.5% by weight of the mineral oil is added to the composition.
Although the invention has been described with reference to specific forms thereof, it will be understood that many changes and modifications may be made without departing from the spirit of this invention.
What is claimed is:
l. A solid, hard and firm toilet oil bar having the appearance and feel of a soap bar; said oil bar releasing mineral oil when wet with warm water and applied to the skin, said bar containing mineral oil solidified with an amide component; said mineral oil constituting between about 70 percent to 85% by weight of said bar, and said amide component constituting between about 5 percent to 30% by weight of said bar and being selected from the group consisting of monoethanolamine stearic acid amide, N,N distearoyl ethylenediamine and mixtures thereof.
2. The oil bar of claim 1 including an emulsifying agent selected from the group consisting of diethanolamine stearic acid amide; sorbitan trioleate, polyoxyethylene (20) sorbitan monolaurate, polyoxyethylene (20) sorbitan monooleate; sodium lauryl sulfate; coconut oil fatty acid ester of sodium isethionate; triethanolamine lauryl sulfate and sodium lauroyl lactylate.
3. The oil bar of to claim 2 wherein said emulsifying agent component comprises from about 1 to about 10% by weight of said bar.
4. The oil bar of to claim 3 wherein said mineral oil comprises from about to about by weight of said bar.
5. The oil bar of to claim 4 in which said amide component comprises monoethanolamine stearic acid amide.
6. The oil bar of to claim 4 wherein said amide component comprises N,N distearoyl ethylenediamine.
7. The oil bar of to claim 4 wherein said amide component comprises a mixture of amides, about 40% by weight of said amide component being monoethanolamine stearic acid amide and about 60% by weight of said amide component being N,N distearoyl ethylenediamine.
8. The oil bar of to claim 7 wherein the emulsifying agent component is diethanolamine stearic acid amide.
9. The oil bar of to claim 7 wherein the emulsifying agent component is a mixture of diethanolamine stearic acid amide and sodium lauroyl lactylate.

Claims (9)

1. A SOLID, HARD AND FIRM TOILET OIL BAR HAVING THE APPEARANCE AND FEEL OF A SOAP BAR; SAID OIL BAR RELEASING MINERAL OIL WHEN WET WITH WARM WATER AND APPLIED TO THE SKIN, SAID BAR CONTAINING MINERAL OIL SOLIDIFED WITH AN AMIDE COMPONENT; SAID MINERAL OIL CONSTITUTING BETWEEN ABOUT 70 PERCENT TO 85% BY WEIGHT OF SAID BAR, AND SAID AMIDE COMPONENT CONSTITUTING BETWEEN ABOUT 5 PERCENT TO 30% BY WEIGHT OF SAID BAR AND BEING SELECTED FROM THE GROUP CONSISTING OF MONOETHANOLAMINE STEARIC ACID AMIDE, N,N'' DISTEAROYL ETHYLENEDIAMINE AND MIXTURES THEREOF.
2. The oil bar of claim 1 including an emulsifying agent selected from the group consisting of diethanolamine stearic acid amide; sorbitan trioleate, polyoxyethylene (20) sorbitan monolaurate, polyoxyethylene (20) sorbitan monooleate; sodium lauryl sulfate; coconut oil fatty acid ester of sodium isethionate; triethanolamine lauryl sulfate and sodium lauroyl lactylate.
3. The oil bar of to claim 2 wherein said emulsifying agent component comprises from about 1 to about 10% by weight of said bar.
4. The oil bar of to claim 3 wherein said mineral oil comprises from about 70 to about 75% by weight of said bar.
5. The oil bar of to claim 4 in which said amide component comprises monoethanolamine stearic acid amide.
6. The oil bar of to claim 4 wherein said amide component comprises N,N distearoyl ethylenediamine.
7. The oil bar of to claim 4 wherein said amide component comprises a mixture of amides, about 40% by weight of said amide component being monoethanolamine stearic acid amide and about 60% by weight of said amide component being N,N distearoyl ethylenediamine.
8. The oil bar of to claim 7 wherein the emulsifying agent component is diethanolamine stearic acid amide.
9. The oil bar of to claim 7 wherein the emulsifying agent component is a mixture of diethanolamine stearic acid amide and sodium lauroyl lactylate.
US00319593A 1972-12-29 1972-12-29 Toilet oil bar Expired - Lifetime US3857960A (en)

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Cited By (25)

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US5490955A (en) * 1992-02-27 1996-02-13 Elizabeth Arden Company, Division Of Conopco, Inc. Cleansing compositions based on C10 -C16 acyl lactylate
US5496488A (en) * 1992-07-07 1996-03-05 The Procter & Gamble Company Cleansing bar composition containing petrolatum having a specific size range
WO1998027193A1 (en) * 1996-12-16 1998-06-25 The Procter & Gamble Company Personal cleansing bar composition containing sodium lauroyl lactylate
US5817609A (en) * 1997-01-08 1998-10-06 Lever Brothers Company, Division Of Conopco, Inc. Bar composition comprising low viscosity oils pre-thickened by non-antifoaming hydrophobic polymers
FR2811552A1 (en) * 2000-07-17 2002-01-18 Oreal COMPOSITION, IN PARTICULAR COSMETIC OR PHARMACEUTICAL, IN SOLID FORM
FR2819398A1 (en) * 2001-01-17 2002-07-19 Oreal Composition useful in cosmetics, especially foundation sticks, comprises lipophilic liquid and low molecular weight polymer
US6716420B2 (en) 2001-10-05 2004-04-06 L′Oreal Methods of use and of making a mascara comprising at least one coloring agent and at least one heteropolymer
US6835399B2 (en) 2000-12-12 2004-12-28 L'ORéAL S.A. Cosmetic composition comprising a polymer blend
US6869594B2 (en) 2000-01-24 2005-03-22 L'ORéAL S.A. Transfer-free mascara composition comprising at least one volatile solvent and at least one polymer
US6881400B2 (en) 2000-12-12 2005-04-19 L'oreal S.A. Use of at least one polyamide polymer in a mascara composition for increasing the adhesion of and/or expressly loading make-up deposited on eyelashes
US6960339B1 (en) 1999-07-15 2005-11-01 L'oreal S.A. Compositions structured with at least one polymer and methods of using the same
US6979469B2 (en) 2000-12-12 2005-12-27 L'Oréal, S.A. Use of polyamide polymer in a mascara composition comprising at least one inert filler
US7008629B2 (en) 2002-07-22 2006-03-07 L'ORéAL S.A. Compositions comprising at least one heteropolymer and fibers, and methods of using the same
US7025953B2 (en) 2001-01-17 2006-04-11 L'oreal S.A. Nail polish composition comprising a polymer
US7030985B2 (en) 2000-12-12 2006-04-18 L'oréal Colored transparent or translucent cosmetic composition
US7052681B2 (en) 2001-01-17 2006-05-30 L'ORéAL S.A. Cosmetic composition containing a polymer and a fluoro oil
US7144582B1 (en) 1999-07-15 2006-12-05 L'ORéAL S.A. Compositions structured with at least one polymer and methods of using the same
US7276547B2 (en) 2000-12-12 2007-10-02 L'oreal S.A. Compositions comprising heteropolymers and at least one oil-soluble polymers chosen from alkyl celluloses and alkylated guar gums
US7314612B2 (en) 2000-12-12 2008-01-01 L'oreal S.A. Cosmetic compositions containing at least one heteropolymer and at least one gelling agent and methods of using the same
US20080119570A1 (en) * 2002-06-11 2008-05-22 Hernando Brieva Stable Cosmetic Emulsion With Polyamide Gelling Agent
US7410636B2 (en) 2000-12-12 2008-08-12 L'oreal S.A. Cosmetic composition comprising a polymer and fibres
US7491749B2 (en) 2000-12-12 2009-02-17 L'oreal At least one polyamide polymer in a cosmetic composition comprising at least one solid substance having a melting point of 45 degrees C. or greater
US7749524B2 (en) 2003-07-11 2010-07-06 L'oreal S.A. Cosmetic compositions comprising a structuring agent, silicone powder and swelling agent
US8080257B2 (en) 2000-12-12 2011-12-20 L'oreal S.A. Cosmetic compositions containing at least one hetero polymer and at least one film-forming silicone resin and methods of using
US8449870B2 (en) 2002-06-11 2013-05-28 Color Access, Inc. Stable cosmetic emulsion with polyamide gelling agent

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US3101300A (en) * 1960-06-30 1963-08-20 Bristol Myers Co Clear mineral oil in water emulsion for hair application
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US6979469B2 (en) 2000-12-12 2005-12-27 L'Oréal, S.A. Use of polyamide polymer in a mascara composition comprising at least one inert filler
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US7011823B2 (en) 2000-12-12 2006-03-14 L'oreal S.A. Method of making a mascara composition comprising a polyamide polymer and at least one inert filler
US7351418B2 (en) 2000-12-12 2008-04-01 L'oreal S.A. Cosmetic composition comprising a polymer blend
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US7052681B2 (en) 2001-01-17 2006-05-30 L'ORéAL S.A. Cosmetic composition containing a polymer and a fluoro oil
US7025953B2 (en) 2001-01-17 2006-04-11 L'oreal S.A. Nail polish composition comprising a polymer
US7008619B2 (en) 2001-10-05 2006-03-07 L'oreal S.A. Methods of use and of making a mascara comprising at least one coloring agent and at least one polyamide polymer chosen from the ethylenediamine/stearyl dimer tallate copolymer
US6716420B2 (en) 2001-10-05 2004-04-06 L′Oreal Methods of use and of making a mascara comprising at least one coloring agent and at least one heteropolymer
US20080119570A1 (en) * 2002-06-11 2008-05-22 Hernando Brieva Stable Cosmetic Emulsion With Polyamide Gelling Agent
US8333956B2 (en) 2002-06-11 2012-12-18 Color Access, Inc. Stable cosmetic emulsion with polyamide gelling agent
US8449870B2 (en) 2002-06-11 2013-05-28 Color Access, Inc. Stable cosmetic emulsion with polyamide gelling agent
US7008629B2 (en) 2002-07-22 2006-03-07 L'ORéAL S.A. Compositions comprising at least one heteropolymer and fibers, and methods of using the same
US7749524B2 (en) 2003-07-11 2010-07-06 L'oreal S.A. Cosmetic compositions comprising a structuring agent, silicone powder and swelling agent

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