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US3797552A - Multiple effect evaporators - Google Patents

Multiple effect evaporators Download PDF

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US3797552A
US3797552A US00299933A US3797552DA US3797552A US 3797552 A US3797552 A US 3797552A US 00299933 A US00299933 A US 00299933A US 3797552D A US3797552D A US 3797552DA US 3797552 A US3797552 A US 3797552A
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Prior art keywords
effect
vapor
effects
condensing side
tubes
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US00299933A
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K Frank
D Kays
J Kruse
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Aerojet Rocketdyne Inc
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Aerojet General Corp
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Assigned to MITSUI ENGINEERING AND SHIPBUILDING CO., LTD. reassignment MITSUI ENGINEERING AND SHIPBUILDING CO., LTD. SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ENVIROGENICS SYSTEMS COMPANY
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/26Multiple-effect evaporating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/06Evaporators with vertical tubes
    • B01D1/065Evaporators with vertical tubes by film evaporating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/06Flash distillation
    • B01D3/065Multiple-effect flash distillation (more than two traps)

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  • the tube bundles of adjacent effects are 159/28, 2 VH, 7 2 7 7 236 aligned along a central longitudinal portion of the shell and together form a substantially continuous bank of tubes with the tube bundle bank being inter- [56] References Cited UNITED STATES PATENTS rupted by traversely-located baffleswhich baffles pro- 3 30 6 3/1967 R b] d 159/13 vide walls between the respective tube bundles of adosen a acent ff ct 3.532.152 4/1968 Cartinhour 159/20 1 e e 5 3.6971383
  • each evaporator effect utilizes a falling film evaporator wherein the liquor forms a thin film on a heat transfer wall and flows by means of gravity down one side thereof. Hot vapor is applied to the opposite side of the heat transfer wall so that condensation of the vapor occurs on the one side and evaporation of the liquor occurs on the other. The hot vapor condensed on one surface of the wall transfers heat to the thin film of liquor on the opposite side thereof to thereby vaporize some of the liquor. The entriched liquor (concentrate) is then fed to the next subsequent effect, and hot vapor present in the subsequent evaporator effect operates on the liquor.
  • Prior multiple effect evaporation systems have utilized individual evaporators in separate tanks interconnected by a complex array of external piping carrying the various liquids and vapors from chamber to chamber. Insulation, structural support, and piping requirements have rendered such multiple effect systems costly and relatively inefficient to operate.
  • Another object of the present invention is to provide a multiple effect evaporator that makes more effective use of space.
  • Another object of the present invention is to provide a tortuous flow path for the vapor which is segregated from the liquor thereby aiding in the removal of brine droplets from vapor.
  • Another object of the present invention is to provide evaporator apparatus which effectively removes noncondensible material from the vapor to maximize the heat transfer capabilities of the heat transfer surfaces.
  • a multiple effect evaporator comprises a unitary housing comprising several serially interconnected evaporator effects separated from one another by internal barriers. Means is provided for introducing feed liquor into each subsequent effect so that a portion thereof vaporizes spontaneously, if previously superheated, thereby cooling the remainder of the liquor to the saturation temperature associated with the pressure in the effect.
  • the spontaneous vaporization of the liquor (sometimes called flashing) produces a temperature potential between the cooled liquor and the vapor from the previous stage to derive the heat transfer potential to effectuate evaporation of the liquor and condensation of the vapor from the previous effect.
  • the vapor from the liquor then flows into the next effect to condense therein and further vaporize liquor therein.
  • the vapor flow through each evaporator effect is substantially normal to the axis of the housing thereby exploiting the space within the housing to the maximum extent.
  • the tube bundles are so arranged and disposed that the vapor flow area within each bundle continuously decreases along the direction of the vapor flow so that the velocity of the vapor is maintained substantially high through all regions of each bundle.
  • the vapor flow between each evaporator effect is directed in such a manner that liquor droplets in the vapor impinge on the walls of the housing and are thereby removed from the vapor.
  • the multiple effect evaporator in accordance with the present invention is particularly useful in connection with the evaporator system described in the copending application of David D. Kays, now U.S. Pat. No. 3,672,960, entitled Multiple Effect Distillation Apparatus, and assigned to the same assignee as the present invention.
  • FIG. 1 is a plan view, partly in horizontal section of a multiple effect evaporator in accordance with the presently preferred embodiment of the present invention
  • FIG. 2 is a vertical transverse cross-section view of the evaporator taken at line 2-2 in FIG. 1;
  • FIG. 3 is a vertical transverse cross-section view of the evaporator taken at line 3-3 in FIG. 1.
  • the apparatus in accordance with the presently preferred embodiment of the present invention comprises a housing 10 having a substantially cylindrical portion 11 and an elongated rectangular portion 12 surmounting cylindrical portion 11.
  • Housing 10 contains a plurality of evaporator effects 13, I4, 15, l6, 17, I8, 19, 20, each having a bundle of evaporator tubes illustrated at 21, 22, 23, 24-and 25 for evaporator effects 13 through 17, respectively.
  • Each of the bundles comprises a plurality of evaporator tubes such as those described in the copending application of Ernest R. Roberts, now US. Pat. No. 3,664,928, entitled Dimpled Heat Transfer Walls for Distillation Apparatus, and assigned to the same assignee as the present invention.
  • Each tube bundle is preferably trapezoidal in crosssection, but it is to be understood that the tube bundles may be of any desirable shape.
  • the tubes are disposed in a vertical position normal to the axis of the cylindrical housing.
  • the brine or saline water is introduced through conduit 30 and is distributed into the tubes to flow in thin films down the interior wall surface of the tubes of bundle 21 to be heated by the steam condensing on the outside of the tubes of bundle 21 so that a portion of the liquid brine in the tubes is evaporated.
  • Any hot vapor and non-condensible matter which are not condensed on the outer walls of the tubes of bundle 21 passes through suitable apertures in wall 31 (which forms the shorter base of the trapezoidal configuration) and is discharged through conduit 32.
  • suitable manifolds 33 may be provided for directing the remaining steam through conduit 32.
  • Condensed steam (condensate) which condenses on the outer surface of the tubes of. the tube bundles is collected and discharged through conduit 34.
  • the vapors collected in upper region of chamber 36 are directed over the top of wall 28 of the next effect 14.
  • the heating fluid for condensing on the outside surfaces of the tubes of each successive evaporator effect comprises the vapor developed in the previous effect.
  • the brine carried through conduit 137 of each effect may be pumped back through a suitable pump 38 into conduit 30 of the next effect for further evaporation in the next effect.
  • FIGS. 2 and 3 are-section views of two sequentially arranged effects l7 and 18 which share a common chamber 40 located between the outlet of tubes of effect 17 and the inlet to the tube bundle 25a of effect 18.
  • Brine from effect 16 (in chamber 39) is taken out through conduit 137 in chamber 39 and is pumped into inlet conduit associated with effect 17 via pump 38.
  • the brine flows through the tubes of bundle 25 of effect 17 and is heated by steam from chamber 39 of previous effect 16. Some of the heated brine evaporates, with the vapor passing into the lower region of chamber (FIG. 2), and the concentrate also collects in the lower region of chamber 40 (FIG. 2).
  • the brine collected in the lower region of chamber 40 is taken out via conduit 137 (FIG. 3) and pumped via pump 38a to conduit 30:; of next effect 18.
  • the vapor present in'lower region of chamber 40 passes through entrainment separator or filter (see both FIGS. 2 and 3) into the upper region of chamber 40 and from there passes over wall 28a (FIG. 3) to heat the brine flowing through the tubes in bundle 25a of effect l8.
  • Uncondensed vapor is discharged through conduit 32 from bundle 25 in effect 17 (FIG. 2), carrying with it non-condensible gas.
  • uncondensed vapor is removed from effect 18 via conduit 32a.
  • the vapor may, for example, be utilized in the preheating of the feed liquor or brine as described in the aforecondensate isremoved through conduit 34 in FIG. 3
  • conduit 32a As heretofore described.
  • each of the chambers 36, 37, 38, 39, 40, 41 and 42 occupies the area beneath the trapezoidal-shaped tube bundle as well as the area beneath the rectangular shaped demister filter 50, it will be appreciated that in horizontal section the lower region of each of the respective chambers has a rought L-shaped configuration.
  • the liquid passage between the legs of the L-shaped lower region is directly beneath the shorter side of the trapezoidal-shaped tube bundle and in the gap between adjacent and aligned walls 28 of alternate effects.
  • the upper region of the respective chambers is above the demister filter 50 and in horizontal section is rectangular in shape and in transverse cross-section view is seen to have an arcuate-shaped volume.
  • the pressure in such chamber 29, 2911 be lower than the pressure of the incoming brine from the lower portion of the previous effect.
  • the pressure in such chamber 29, 2911 be lower than the pressure of the incoming brine from the lower portion of the previous effect.
  • a restriction may be disposed at the entrance of each tube in bundle 25 so that de-pressurization, flashing and cooling take place as the brine enters the tube.
  • the cooled brine flows in a thin film down the interior wall surface of the tube and a temperature differential is established between the cooled brine within the tubes of the bundle and the vapor condensing on the outer surface of the tubes. Hence, the heat transfer effect is maintained and the system is self-sustaining.
  • the heated brine taken via conduit 137 and the heated condensate taken via conduit 34, and the steam taken via conduit 32 may be circulated through a preheater, such as described in the copending application of David D. Kays et al, Ser. No. 204,757, filed December 3, 1971 entitled Preheaters, which is a continuation of Ser. No. 10,223, filed Feb. 10, 1970, same title, now abandoned, both of which applications are assigned to the same assignee as the present invention.
  • the preheater described in the said Kays et a1 application utilizes the flashing principle wherein the heated liquid is flashed or spontaneously evaporated at a lower pressure in subsequent chambers to obtain partial vaporization of the liquid.
  • the present invention provides effective use of the space within the ellipsoidal or cylindrical housing, which results in a lesser overall length requirement for the containment of tube bundles, entrainment separators, pressureretaining bulkheads and vapor channelization than heretofore required in the prior art.
  • the overall length of the shell or housing is effectively shortened (see FIG. 1) by bunching the several tube bundles of the respective effects in a line along a central longitudinal portion of the shell and thereby forming a substantially continuous bank of tubes which tube bundle bank is interrupted at spaced intervalsby transversely-located baffles which baffles provide walls between the respective tube bundles of adjacent effects.
  • the tube bundles have been serially arranged in the direction of the'axis of the extended housing, thereby requiring that the vessel length be sufficient for vapor channelization and entrainment separation.
  • the space on each side of the tube bundle in housings of the prior art was not effectively utilized, and containment was both massive and costly.
  • the present invention provides increased efficiency of containment.
  • the tube bundles are so disposed and arranged that the vapor flow area continuously decreases along the direction of vapor flow.
  • the mass continuously decreases due to condensation of the vapor
  • the decreasing area of the vapor flow offsets the reduction of mass of the vapor so that the velocity of the vapor flow is high in all portions of the tube bundle.
  • This feature is of particular value in that it assures a higher velocity of vapor than would be expected if the area did not increase in the direction of flow.
  • the flow velocity across the tube bundle is maintained substantially constant even though the total flow decreases due to the condensation.
  • the high flow velocity in the bundle assures flow turbulence at the heat transfer surface of the tube bundles so that non-condensible materials present in the vapor flow may be removed.
  • the reduction of area of the vapor flow is preferably achieved through the use of trapezoidally shaped tube bundles as illustrated in the drawings, although other configurations may be used.
  • the trapezoidal shape is preferred because it permits efficient use of tube sheet material as several trapezoids may be cut from a single rectangular strip of tube sheet material.
  • a multiple effect evaporator comprising: a horizontally-disposed, elongated shell having a substantially curved portion and closed at its opposite ends and containing a plurality of contiguously juxtapositioned, transversely-oriented effects, each of the effects having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, with a bundle of tubes vertically-disposed in the condensing side of each effect with the lower ends of the interiors of'the several tubes of the bundle of each effect opening into a concentrate reservoir in a lower region of the evaporating side, means for withdrawing concentrate from the concentrate reservoir of an effect and delivering the withdrawn concentrate exteriorly of the shell to the upper ends of the interiors of the several tubes of the bundle of the next adjacent effect with respect to liquor flow, means for withdrawing the condensate from the condensing side of each effect, means
  • a multiple effect evaporator comprising: a horizontally-disposed, elongated shell having a substantially curved portion and closed at its opposite ends and containing a plurality of contiguously juxtapositioned, transversely-oriented effects, each of the effects having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, with a bundle of tubes vertically-disposed in the condensing side of each effect with the lower ends of the interiors of the several tubes of the bundle of each effect opening into a concentrate reservoir in a lower region of the evaporating side, means for withdrawing concentrate from the concentrate reservoir of an effect and delivering the withdrawn concentrate exteriorly of the shell to the upper ends of the interiors of the several tubes of the bundle of the next adjacent effect with respect to liquor flow, means for withdrawing the condensate from the condensing side of each effect, means for removing unconden
  • a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising:
  • a horizontally-disposed elongated shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated shell with a bundle of tubes vertically-disposed in the condensing side of each effect, and a baffle arrangement for directing vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the shell and in opposite directions in adjacent effects and with the flow path of the vapor across the respective tube bundles decreasing in horizontal section in direction of vapor flow thereacross.
  • a multiple effect evaporator in accordance with claim 9 wherein the breadth of each of the several bundles converges in horizontal section in the direction of vapor flow thereacross, said convergence of successive bundles occurring in opposite directions in adjacent effects.
  • a multiple effect evaporator in accordance with claim 10 wherein the several tube bundles are each trapezoidal in horizontal cross section with the smaller bases of the trapezoids of adjacent effects facing in opposite directions.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

A multiple effect evaporator according to the present disclosure comprises a housing divided into a plurality of evaporator effects each effect having a bundle of heat transfer tubes disposed therein. The bundles are arranged so that the vapor flow is transverse or normal to the axis of the housing and in opposite directions in adjacent effects. Preferably, the bundles are arranged in such a configuration, e.g. a trapezoid, that the area of vapor flow in the bundles decreases in the direction of vapor flow. In one embodiment of the evaporator of the invention the tube bundles of adjacent effects are aligned along a central longitudinal portion of the shell and together form a substantially continuous bank of tubes with the tube bundle bank being interrupted by traversely-located baffles which baffles provide walls between the respective tube bundles of adjacent effects.

Description

United States Patent 1 91 I I 1 1 3,797,552
Frank et al. Mar. 19, 1974 MULTIPLE EFFECT EVAPORATORS [75] Inventors: Kurt F. Frank, Pomona; David D. Kays, Claremont; John W. Kruse,
Primary Examiner-Jack Sofer Attorney, Agent, or Firm-Edward O. Ansell; T. Reid Jr., La Canada, all of Calif. Anders [73] Assignee: Aerojet General Corporation, El [57] ABSTRACT Monte Cahf' A multiple effect evaporator according to the present [22] Fil d; O 24, 1972 disclosure comprises a housing divided into a plurality of evaporator effects each effect having a bundle of [21] Appl' 3 heat transfer tubes disposed therein. The bundles are R l d Us} A li ti D t arranged so that the vapor flow is transverse or normal to the axis of the housing and in opposite directions in 63 Continuation of Ser. No. 10,231. Feb. 10. 1970, 1 7 ad acent effects. Preferably, the bundles are arranged abandoned.
a in such a configuration, e.g. a trapezoid, that the area 52 us. c1. 159/17 C, 202/174 of vapor flow in the bundles decreases in the direction 51 1m. 01. Bld 1/26, 1301a 3/02 of vapor In one embodiment Of the evaporator of 53 Field f Search H 159/13, 13 A, 7 27 20, the invention the tube bundles of adjacent effects are 159/28, 2 VH, 7 2 7 7 236 aligned along a central longitudinal portion of the shell and together form a substantially continuous bank of tubes with the tube bundle bank being inter- [56] References Cited UNITED STATES PATENTS rupted by traversely-located baffleswhich baffles pro- 3 30 6 3/1967 R b] d 159/13 vide walls between the respective tube bundles of adosen a acent ff ct 3.532.152 4/1968 Cartinhour 159/20 1 e e 5 3.6971383 /1972 Weaver 202/174 12 Claims, 3 Drawing Figures STEAM IN VAPOR VAPOR 1 1 BRINE F] -P| VAPOR VAPOR Z6 LTER P 2 121 RFMOVAL u m F/az 501 311211 3/4 :51? g 137 BRINE I "BRINE 1 I Z -11- 37 I57 '39 4 I l 1 .25 2531 3 T 2s 50: a r 5061 TUBE BUNDLE r 42 1 I 1i ft 9 L 20 42 l .2 42 Q 28 Q Z/ i i 4 t .1 33: 1 O I, I 24, B WE Lll \BRINE gt. Z8 22 mm {M k 3O /0 a 2% 137 5%. I 1 18111112 1 a/ 12 *w i i l VAPOR I l 52 50-FILTER \32 50 2 32 2 VAPOR H I vAPoR LTER E I 3 7 32b ivAPoR This application is a continuation of pending application r al Nol9 .fi Februa y- .10. lQYQQQW.
abandoned.
This invention relates to distillation apparatus, and particularly to multiple effect distillation evaporators wherein the liquor concentrate evaporated in one effeet is fed to a subsequent effect in series. I
Multiple effectevaporators are characterized by the use of several evaporator effects serially arranged so that the feed liquor is operated on by each evaporator effect sequentially. Ordinarily, each evaporator effect utilizes a falling film evaporator wherein the liquor forms a thin film on a heat transfer wall and flows by means of gravity down one side thereof. Hot vapor is applied to the opposite side of the heat transfer wall so that condensation of the vapor occurs on the one side and evaporation of the liquor occurs on the other. The hot vapor condensed on one surface of the wall transfers heat to the thin film of liquor on the opposite side thereof to thereby vaporize some of the liquor. The entriched liquor (concentrate) is then fed to the next subsequent effect, and hot vapor present in the subsequent evaporator effect operates on the liquor.
Prior multiple effect evaporation systems have utilized individual evaporators in separate tanks interconnected by a complex array of external piping carrying the various liquids and vapors from chamber to chamber. Insulation, structural support, and piping requirements have rendered such multiple effect systems costly and relatively inefficient to operate.
It is an object of the present invention to provide a multiple effect evaporator which more effectively distills liquor than previous evaporators.
Another object of the present invention is to provide a multiple effect evaporator that makes more effective use of space.
Another object of the present invention is to provide a tortuous flow path for the vapor which is segregated from the liquor thereby aiding in the removal of brine droplets from vapor.
Another object of the present invention is to provide evaporator apparatus which effectively removes noncondensible material from the vapor to maximize the heat transfer capabilities of the heat transfer surfaces.
In accordance with the present invention, a multiple effect evaporator comprises a unitary housing comprising several serially interconnected evaporator effects separated from one another by internal barriers. Means is provided for introducing feed liquor into each subsequent effect so that a portion thereof vaporizes spontaneously, if previously superheated, thereby cooling the remainder of the liquor to the saturation temperature associated with the pressure in the effect. The spontaneous vaporization of the liquor (sometimes called flashing) produces a temperature potential between the cooled liquor and the vapor from the previous stage to derive the heat transfer potential to effectuate evaporation of the liquor and condensation of the vapor from the previous effect. The vapor from the liquor then flows into the next effect to condense therein and further vaporize liquor therein.
According to one feature of the present invention, the vapor flow through each evaporator effect is substantially normal to the axis of the housing thereby exploiting the space within the housing to the maximum extent.
According to another feature of the present invention, the tube bundles are so arranged and disposed that the vapor flow area within each bundle continuously decreases along the direction of the vapor flow so that the velocity of the vapor is maintained substantially high through all regions of each bundle.
According to another feature of the present invention, the vapor flow between each evaporator effect is directed in such a manner that liquor droplets in the vapor impinge on the walls of the housing and are thereby removed from the vapor.
According to another feature of the present invention, the heated products of each evaporator effect may be utilized to preheat the feedliquor.
The multiple effect evaporator in accordance with the present invention is particularly useful in connection with the evaporator system described in the copending application of David D. Kays, now U.S. Pat. No. 3,672,960, entitled Multiple Effect Distillation Apparatus, and assigned to the same assignee as the present invention.
The above and other features of this invention will be more fully understood from the following detailed description and from the accompanying drawings, in which:
FIG. 1 is a plan view, partly in horizontal section of a multiple effect evaporator in accordance with the presently preferred embodiment of the present invention;
FIG. 2 is a vertical transverse cross-section view of the evaporator taken at line 2-2 in FIG. 1; and
FIG. 3 is a vertical transverse cross-section view of the evaporator taken at line 3-3 in FIG. 1.
The apparatus in accordance with the presently preferred embodiment of the present invention comprises a housing 10 having a substantially cylindrical portion 11 and an elongated rectangular portion 12 surmounting cylindrical portion 11. Housing 10 contains a plurality of evaporator effects 13, I4, 15, l6, 17, I8, 19, 20, each having a bundle of evaporator tubes illustrated at 21, 22, 23, 24-and 25 for evaporator effects 13 through 17, respectively. Each of the bundles comprises a plurality of evaporator tubes such as those described in the copending application of Ernest R. Roberts, now US. Pat. No. 3,664,928, entitled Dimpled Heat Transfer Walls for Distillation Apparatus, and assigned to the same assignee as the present invention. Each tube bundle is preferably trapezoidal in crosssection, but it is to be understood that the tube bundles may be of any desirable shape. The tubes are disposed in a vertical position normal to the axis of the cylindrical housing.
Steam is introduced into the system through conduit 26 so that steam enters chamber'27 of first evaporator effect 13. The steam passes over the upper edge of wall 28 (which defines the longer base of the trapezoidal configuration) to condense on the outside surface of the tubes in bundle 21 and heat the same. As readily seen in FIG. 2 the wall 28 extends to the bottom inside surface of the housing 10 and, thus, provides a liquid barrier between the adjacent effects. Liquor to be evaporated is introduced into the region or chest 29 above the tubes in the bundle by means of conduit 30. The brine or saline water is introduced through conduit 30 and is distributed into the tubes to flow in thin films down the interior wall surface of the tubes of bundle 21 to be heated by the steam condensing on the outside of the tubes of bundle 21 so that a portion of the liquid brine in the tubes is evaporated. Any hot vapor and non-condensible matter which are not condensed on the outer walls of the tubes of bundle 21 passes through suitable apertures in wall 31 (which forms the shorter base of the trapezoidal configuration) and is discharged through conduit 32. As illustrated particularly in FIGS. 2 and 3, suitable manifolds 33 may be provided for directing the remaining steam through conduit 32. Condensed steam (condensate) which condenses on the outer surface of the tubes of. the tube bundles is collected and discharged through conduit 34.
As the thin film of brine or liquor flows down the interior surface of the tubes of the respective tube bundles, it is heated by the condensing steam and some of the liquor is evaporated. The vapors produced from the liquor flow out through the lower end of the tubes (which are sealed in apertures in barrier-tube sheet 35 of the housing) and into the lower region of chamber 36 of the next effect (chamber 40 in FIG. 2, chamber 41 in FIG. 3). Likewise, the concentrated brine (concentrate) is collected in the lower region of the chamber 36 and is removed through conduit 137. As more readily seen in FIGS. 2 and 3, the lower region of each chamber 36, 37, 38, 39, 40, 41 and 42 is separated by a horizontally-disposed elongated liquid-vapor filter 50 from the upper region of the respective chamber. The vapors collected in upper region of chamber 36 are directed over the top of wall 28 of the next effect 14. Thus, the heating fluid for condensing on the outside surfaces of the tubes of each successive evaporator effect comprises the vapor developed in the previous effect. The brine carried through conduit 137 of each effect may be pumped back through a suitable pump 38 into conduit 30 of the next effect for further evaporation in the next effect.
With reference to FIGS. 2 and 3, the operation of the apparatus in accordance with the present invention is more fully explained. FIGS. 2 and 3 are-section views of two sequentially arranged effects l7 and 18 which share a common chamber 40 located between the outlet of tubes of effect 17 and the inlet to the tube bundle 25a of effect 18. Brine from effect 16 (in chamber 39) is taken out through conduit 137 in chamber 39 and is pumped into inlet conduit associated with effect 17 via pump 38. The brine flows through the tubes of bundle 25 of effect 17 and is heated by steam from chamber 39 of previous effect 16. Some of the heated brine evaporates, with the vapor passing into the lower region of chamber (FIG. 2), and the concentrate also collects in the lower region of chamber 40 (FIG. 2). The brine collected in the lower region of chamber 40 is taken out via conduit 137 (FIG. 3) and pumped via pump 38a to conduit 30:; of next effect 18.,The vapor present in'lower region of chamber 40 passes through entrainment separator or filter (see both FIGS. 2 and 3) into the upper region of chamber 40 and from there passes over wall 28a (FIG. 3) to heat the brine flowing through the tubes in bundle 25a of effect l8. Uncondensed vapor is discharged through conduit 32 from bundle 25 in effect 17 (FIG. 2), carrying with it non-condensible gas. Similarly, uncondensed vapor is removed from effect 18 via conduit 32a. The vapor may, for example, be utilized in the preheating of the feed liquor or brine as described in the aforecondensate isremoved through conduit 34 in FIG. 3
and uncondensed vapor is carried out through conduit 32a, as heretofore described.
Remembering that the lower region of each of the chambers 36, 37, 38, 39, 40, 41 and 42 occupies the area beneath the trapezoidal-shaped tube bundle as well as the area beneath the rectangular shaped demister filter 50, it will be appreciated that in horizontal section the lower region of each of the respective chambers has a rought L-shaped configuration. The liquid passage between the legs of the L-shaped lower region is directly beneath the shorter side of the trapezoidal-shaped tube bundle and in the gap between adjacent and aligned walls 28 of alternate effects. The upper region of the respective chambers is above the demister filter 50 and in horizontal section is rectangular in shape and in transverse cross-section view is seen to have an arcuate-shaped volume.
It is preferred that when the brine enters chamber 29, 29a of each subsequent effect, that the pressure in such chamber 29, 2911 be lower than the pressure of the incoming brine from the lower portion of the previous effect. Thus, as the brine enters each chamber 29, it is flashed or spontaneously evaporated so that some of the brine is cooled to the saturation temperature associated with the pressure in the region 29. If desired, a restriction (not shown) may be disposed at the entrance of each tube in bundle 25 so that de-pressurization, flashing and cooling take place as the brine enters the tube. The cooled brine flows in a thin film down the interior wall surface of the tube and a temperature differential is established between the cooled brine within the tubes of the bundle and the vapor condensing on the outer surface of the tubes. Hence, the heat transfer effect is maintained and the system is self-sustaining.
The heated brine taken via conduit 137 and the heated condensate taken via conduit 34, and the steam taken via conduit 32 may be circulated through a preheater, such as described in the copending application of David D. Kays et al, Ser. No. 204,757, filed December 3, 1971 entitled Preheaters, which is a continuation of Ser. No. 10,223, filed Feb. 10, 1970, same title, now abandoned, both of which applications are assigned to the same assignee as the present invention. The preheater described in the said Kays et a1 application utilizes the flashing principle wherein the heated liquid is flashed or spontaneously evaporated at a lower pressure in subsequent chambers to obtain partial vaporization of the liquid. The vapors then transfer heat to feed liquor thereby raising the temperature of the feed liquor prior to introduction into the first effect of the multiple effect evaporator. Further discussion of theoperation of the overall system may be found in the aforesaid Kays U.S. Pat. No. 3,672,960.
The present invention provides effective use of the space within the ellipsoidal or cylindrical housing, which results in a lesser overall length requirement for the containment of tube bundles, entrainment separators, pressureretaining bulkheads and vapor channelization than heretofore required in the prior art. The overall length of the shell or housing is effectively shortened (see FIG. 1) by bunching the several tube bundles of the respective effects in a line along a central longitudinal portion of the shell and thereby forming a substantially continuous bank of tubes which tube bundle bank is interrupted at spaced intervalsby transversely-located baffles which baffles provide walls between the respective tube bundles of adjacent effects. Heretofore, the tube bundles have been serially arranged in the direction of the'axis of the extended housing, thereby requiring that the vessel length be sufficient for vapor channelization and entrainment separation. Hence, the space on each side of the tube bundle in housings of the prior art was not effectively utilized, and containment was both massive and costly. By directing the vapor in the direction transverse or normal to the axis of the multiple effect housing, the present invention provides increased efficiency of containment.
The tube bundles are so disposed and arranged that the vapor flow area continuously decreases along the direction of vapor flow. Thus, as vapor condenses on the tube of the tube bundle, the mass continuously decreases (due to condensation of the vapor), and the decreasing area of the vapor flow offsets the reduction of mass of the vapor so that the velocity of the vapor flow is high in all portions of the tube bundle. This feature is of particular value in that it assures a higher velocity of vapor than would be expected if the area did not increase in the direction of flow. Hence, the flow velocity across the tube bundle is maintained substantially constant even though the total flow decreases due to the condensation. The high flow velocity in the bundle assures flow turbulence at the heat transfer surface of the tube bundles so that non-condensible materials present in the vapor flow may be removed. The reduction of area of the vapor flow is preferably achieved through the use of trapezoidally shaped tube bundles as illustrated in the drawings, although other configurations may be used. The trapezoidal shape is preferred because it permits efficient use of tube sheet material as several trapezoids may be cut from a single rectangular strip of tube sheet material.
The vapor flow between evaporator effects is directed from the exit of the tubes (below barrier 35 of the housing) to the entrance of the next tube bundle above wall 28 of the subsequent effect through several turns in the path. Minute droplets of brine in the vapor tend to impinge and condense on wall ll of housing as well as in entrainment separator 50, thereby assuring removal of brine from the vapor. The curvilinear shape to wall 11 of housing 10, which aids in directing the flow, minimizes vapor flow resistance.
The vertical tube evaporator described herein operates as a multiple effect evaporator in that hot vapor is introduced into the first effect and a heat rejection apparatus (not shown) is associated with the vapor outlet of the last effect. The heat rejection device (not shown) aids in the continuous removal of non-condensible material and also establishes a temperature and pressure profile for maintaining the operation of all the effects and of the feed heating stages.
This invention is not to be limited by the embodiment shown in the drawings and described in the description, which is given by way of example and not of limitation.
We claim: .1. A multiple effect evaporator comprising: a horizontally-disposed, elongated shell having a substantially curved portion and closed at its opposite ends and containing a plurality of contiguously juxtapositioned, transversely-oriented effects, each of the effects having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, with a bundle of tubes vertically-disposed in the condensing side of each effect with the lower ends of the interiors of'the several tubes of the bundle of each effect opening into a concentrate reservoir in a lower region of the evaporating side, means for withdrawing concentrate from the concentrate reservoir of an effect and delivering the withdrawn concentrate exteriorly of the shell to the upper ends of the interiors of the several tubes of the bundle of the next adjacent effect with respect to liquor flow, means for withdrawing the condensate from the condensing side of each effect, means for removing uncondensed hot vapor and non-condensibles from the condensing section of each effect and wherein the breadth of each of the several bundles converges in horizontal section in the direction of vapor flow thereacross, said convergences of successive bundles occurring in opposite directions and said bundles being baffled to produce said convergence and to impart a vapor flow substantially perpendicular to the longitudinal axis of the shell.
2. A multiple effect evaporator comprising: a horizontally-disposed, elongated shell having a substantially curved portion and closed at its opposite ends and containing a plurality of contiguously juxtapositioned, transversely-oriented effects, each of the effects having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, with a bundle of tubes vertically-disposed in the condensing side of each effect with the lower ends of the interiors of the several tubes of the bundle of each effect opening into a concentrate reservoir in a lower region of the evaporating side, means for withdrawing concentrate from the concentrate reservoir of an effect and delivering the withdrawn concentrate exteriorly of the shell to the upper ends of the interiors of the several tubes of the bundle of the next adjacent effect with respect to liquor flow, means for withdrawing the condensate from the condensing side of each effect, means for removing uncondensed hot vapor and non-condensibles from the condensing section of each effect and wherein the breadth of each of the several bundles converges in horizontal section in the direction of vapor flow thereacross, said convergences of successive bundles occurring in opposite directions and said bundles being baffled to produce said convergence and to impart a vapor flow substantially perpendicular to the longitudinal axis of the shell, and wherein the several tube bundles are each trapezoidal in horizontal cross section with the smaller bases of the trapezoids of adjacent effects facing in opposite directions and with the opposing larger bases of the respective trapezoids being parallel to the longitudinal axis of the shell.
33. in a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising:
a horizontally-disposed, elongated shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tube bundles being aligned along a central longitudinal portion of the shell and together forming a substantially continuous 'bank of tubes with the tube bundle bank being interrupted by a traversely-located baffles which baffles provide walls between the respective tube bundles of adjacent effects, said baffles being disposed to direct vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the shell.
4. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising:
a horizontally-disposed, elongated shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tube bundles being aligned along a central longitudinal portion of the shell and together forming a substantially-continuous bank of tubes with the tube bundle bank being traversed at spaced intervals by a baffling arrangement which provides walls between the respective tube bundles of adjacent effects, said baffling arrangement being disposed to directvapor flow across the several bundles substantially perpendicular to the longitudinal axis of the shell and in opposite directions in adjacent effects.
5. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising:
a horizontally-disposed, elongated shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tube bundles being aligned along a central longitudinal portion of the shell and together forming a substantially-continuous bank of tubes with the tube bundle bank being traversed at spaced intervals by a baffling arrangement which provides walls between the respective tube bundles of adjacent effects, said baffling arrangement being disposed to direct vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the shell and in oposite directions in adjacent effects and with the flow path of the vapor across the respective tube bundles decreasing in horizontal section in direction of vapor flow there across.
6.'ln a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising:
a horizontally-disposed, elongated cylindrical shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the cylindrical shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tube bundles being aligned along a central longitudinal portion of the cylindrical shell and together forming a substantially continuous bank of tubes with the tube bundle bank being interrupted by transversely-located baffles which provide walls between the respective tube bundles of adjacent effects, said baffles being disposed to direct vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the cylindrical shell and in opposite directions in adjacent effects.
7. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effects with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising:
a horizontally-disposed, elongated cylindrical shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the cylindrical shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tube bundles being aligned along a central longitudinal portion of the cylindrical shell and together forming a substantiallycontinuous bank of tubes with the tube bundle bank being interrupted by traversely-located baffles which provide walls between the respective tube bundles of adjacent effects, said baffles being disposed to direct vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the cylindrical shell and in opposite directions in adjacent effects and with the flow path of the vapor through the respective tube bundles decreasing in horizontal section in the. direction of vapor flow thereacross.
8. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate anda hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect, the improvement comprising:
a horizontally-disposed elongated shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated shell with a bundle of tubes vertically-disposed on the condensing side of each effect, said tubes each presenting a solid, perforation-free heat transfer wall separating the evaporating and condensing side of the effect, a baffle arrangement for directing vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the shell and in opposite directions in adjacent effects and means for withdrawing uncondensed vapors from the condensing side of each effect without passage across the heat transfer walls defined by said tubes.
9. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising:
a horizontally-disposed elongated shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated shell with a bundle of tubes vertically-disposed in the condensing side of each effect, and a baffle arrangement for directing vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the shell and in opposite directions in adjacent effects and with the flow path of the vapor across the respective tube bundles decreasing in horizontal section in direction of vapor flow thereacross.
10. A multiple effect evaporator in accordance with claim 9 wherein the breadth of each of the several bundles converges in horizontal section in the direction of vapor flow thereacross, said convergence of successive bundles occurring in opposite directions in adjacent effects.
11. A multiple effect evaporator in accordance with claim 10 wherein the several tube bundles are each trapezoidal in horizontal cross section with the smaller bases of the trapezoids of adjacent effects facing in opposite directions.
12. In multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect, the improvement comprising:
a horizontally-disposed elongated cylindrical shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated cylindrical shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tubes each presenting a solid, perforation-free heat transfer wall separating the evaporating and condensing side of the effect, a baffle arrangement for directing vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the cylindrical shell and in opposite directions in adjacent effects and means for withdrawing uncondensed vapors from the condensing side of each effect without passage across the heat transfer walls defined by said tubes.

Claims (12)

1. A multiple effect evaporator comprising: a horizontallydisposed, elongated shell having a substantially curved portion and closed at its opposite ends and containing a plurality of contiguously juxtapositioned, transversely-oriented effects, each of the effects having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, with a bundle of tubes verticallydisposed in the condensing side of each effect with the lower ends of the interiors of the several tubes of the bundle of each effect opening into a concentrate reservoir in a lower region of the evaporating side, means for withdrawing concentrate from the concentrate reservoir of an effect and delivering the withdrawn concentrate exteriorly of the shell to the upper ends of the interiors of the several tubes of the bundle of the next adjacent effect with respect to liquor flow, means for withdrawing the condensate from the condensing side of each effect, means for removing uncondensed hot vapor and non-condensibles from the condensing section of each effect and Wherein the breadth of each of the several bundles converges in horizontal section in the direction of vapor flow thereacross, said convergences of successive bundles occurring in opposite directions and said bundles being baffled to produce said convergence and to impart a vapor flow substantially perpendicular to the longitudinal axis of the shell.
2. A multiple effect evaporator comprising: a horizontally-disposed, elongated shell having a substantially curved portion and closed at its opposite ends and containing a plurality of contiguously juxtapositioned, transversely-oriented effects, each of the effects having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, with a bundle of tubes vertically-disposed in the condensing side of each effect with the lower ends of the interiors of the several tubes of the bundle of each effect opening into a concentrate reservoir in a lower region of the evaporating side, means for withdrawing concentrate from the concentrate reservoir of an effect and delivering the withdrawn concentrate exteriorly of the shell to the upper ends of the interiors of the several tubes of the bundle of the next adjacent effect with respect to liquor flow, means for withdrawing the condensate from the condensing side of each effect, means for removing uncondensed hot vapor and non-condensibles from the condensing section of each effect and wherein the breadth of each of the several bundles converges in horizontal section in the direction of vapor flow thereacross, said convergences of successive bundles occurring in opposite directions and said bundles being baffled to produce said convergence and to impart a vapor flow substantially perpendicular to the longitudinal axis of the shell, and wherein the several tube bundles are each trapezoidal in horizontal cross section with the smaller bases of the trapezoids of adjacent effects facing in opposite directions and with the opposing larger bases of the respective trapezoids being parallel to the longitudinal axis of the shell.
3. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising: a horizontally-disposed, elongated shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tube bundles being aligned along a central longitudinal portion of the shell and together forming a substantially continuous bank of tubes with the tube bundle bank being interrupted by a traversely-located baffles which baffles provide walls between the respective tube bundles of adjacent effects, said baffles being disposed to direct vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the shell.
4. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect aNd means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising: a horizontally-disposed, elongated shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tube bundles being aligned along a central longitudinal portion of the shell and together forming a substantially-continuous bank of tubes with the tube bundle bank being traversed at spaced intervals by a baffling arrangement which provides walls between the respective tube bundles of adjacent effects, said baffling arrangement being disposed to direct vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the shell and in opposite directions in adjacent effects.
5. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising: a horizontally-disposed, elongated shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tube bundles being aligned along a central longitudinal portion of the shell and together forming a substantially-continuous bank of tubes with the tube bundle bank being traversed at spaced intervals by a baffling arrangement which provides walls between the respective tube bundles of adjacent effects, said baffling arrangement being disposed to direct vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the shell and in oposite directions in adjacent effects and with the flow path of the vapor across the respective tube bundles decreasing in horizontal section in direction of vapor flow thereacross.
6. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising: a horizontally-disposed, elongated cylindrical shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the cylindrical shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tube bundles being aligned along a central longitudinal portion of the cylindrical shell and together forming a substantially continuous bank of tubes with the tube bundle bank being interrupted by transversely-located baffles which provide walls between the respective tube bundles of adjacent effects, said baffles being disposed to direct vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the cylindrical shell and in opposite directions in adjacent effects.
7. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effects with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising: a horizontally-disposed, elongated cylindrical shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the cylindrical shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tube bundles being aligned along a central longitudinal portion of the cylindrical shell and together forming a substantially-continuous bank of tubes with the tube bundle bank being interrupted by traversely-located baffles which provide walls between the respective tube bundles of adjacent effects, said baffles being disposed to direct vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the cylindrical shell and in opposite directions in adjacent effects and with the flow path of the vapor through the respective tube bundles decreasing in horizontal section in the direction of vapor flow thereacross.
8. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect, the improvement comprising: a horizontally-disposed elongated shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated shell with a bundle of tubes vertically-disposed on the condensing side of each effect, said tubes each presenting a solid, perforation-free heat transfer wall separating the evaporating and condensing side of the effect, a baffle arrangement for directing vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the shell and in opposite directions in adjacent effects and means for withdrawing uncondensed vapors from the condensing side of each effect without passage across the heat transfer walls defined by said tubes.
9. In a multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect and means for withdrawing uncondensed vapor from the condensing side of each effect, the improvement comprising: a horizontally-disposed elongated shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated shell with a bundle of tubes vertically-disposed in the condensing side of each effect, and a baffle arrangement for directing vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the shell and in opposite directions in adjacent effects and with the flow path of the vapor across the respective tube bundles decreasing in horizontal section in direction of vapor flow thereacross.
10. A multiple effect evaporator in accordance with claim 9 wherein the breadth of each of the several bundles converges in horizontal seCtion in the direction of vapor flow thereacross, said convergence of successive bundles occurring in opposite directions in adjacent effects.
11. A multiple effect evaporator in accordance with claim 10 wherein the several tube bundles are each trapezoidal in horizontal cross section with the smaller bases of the trapezoids of adjacent effects facing in opposite directions.
12. In multiple effect evaporator having a number of effects with each effect having a condensing side and an evaporating side to form a concentrate and a hot vapor which vapor is condensed on the condensing side of the next lower pressure subsequent effect, thus providing a condensate, and having provision for transferring concentrate from a prior effect to the vertical tubes of next adjacent effect with respect to liquor flow and having means for removing condensate from the condensing side of each effect, the improvement comprising: a horizontally-disposed elongated cylindrical shell closed at its opposite ends with a plurality of effects being contiguously juxtapositioned and transversely-oriented in the elongated cylindrical shell with a bundle of tubes vertically-disposed in the condensing side of each effect, said tubes each presenting a solid, perforation-free heat transfer wall separating the evaporating and condensing side of the effect, a baffle arrangement for directing vapor flow across the several bundles substantially perpendicular to the longitudinal axis of the cylindrical shell and in opposite directions in adjacent effects and means for withdrawing uncondensed vapors from the condensing side of each effect without passage across the heat transfer walls defined by said tubes.
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4981555A (en) * 1988-10-12 1991-01-01 Metallgesellschaft Ag Process and apparatus for concentrating a solution
US5423952A (en) * 1992-07-22 1995-06-13 T & G Technologies, Inc. Structure for multiple-effect distillation
US8486223B2 (en) 2003-07-04 2013-07-16 Jiangsu Sinorgchem Technology Co., Ltd. Falling film evaporator
US20090048465A1 (en) * 2003-07-04 2009-02-19 Jiangsu Sinorgchem Technology Co., Ltd. Process for preparing 4-aminodiphenylamine
US7989662B2 (en) 2003-07-04 2011-08-02 Jiangsu Sinorgchem Technology Co., Ltd. Process for preparing 4-aminodiphenylamine
US20110226606A1 (en) * 2003-07-04 2011-09-22 Jiangsu Sinorgchem Technology Co., Ltd. Falling film evaporator
US20070227675A1 (en) * 2003-07-04 2007-10-04 Sinorgchem Co. Process for preparing 4-aminodiphenylamine
US8686188B2 (en) 2003-07-04 2014-04-01 Jiangsu Sinorgchem Technology Co., Ltd. Process for preparing 4-aminodiphenylamine
US9029603B2 (en) 2003-07-04 2015-05-12 Jiangsu Sinorgchem Technology Co., Ltd. Process for preparing alkylated p-phenylenediamines
US8535538B1 (en) 2009-01-27 2013-09-17 Fairmount Brine Processing, LLC Brine water recycle process
US9302259B2 (en) 2010-05-24 2016-04-05 Jiangsu Sinorgchem Technology Co., Ltd. Solid base catalyst and method for making and using the same
US20180306519A1 (en) * 2015-10-21 2018-10-25 Technip France Device for the exchange of heat between a first fluid intended to be vaporized and a second fluid intended to be cooled and/or condensed, and associated installation and method
US11686531B2 (en) * 2015-10-21 2023-06-27 Technip Energies France Device for the exchange of heat between a first fluid intended to be vaporized and a second fluid intended to be cooled and/or condensed, and associated installation and method
US11045779B2 (en) 2017-10-26 2021-06-29 Alfa Laval Olmi S.P.A Shell-and-tube equipment with distribution device

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