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US2856330A - Method of treating cotton fabrics - Google Patents

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US2856330A
US2856330A US467658A US46765854A US2856330A US 2856330 A US2856330 A US 2856330A US 467658 A US467658 A US 467658A US 46765854 A US46765854 A US 46765854A US 2856330 A US2856330 A US 2856330A
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fabrics
copper salt
milligram
water
molecules
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US467658A
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Harold N Vagenius
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/18—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing inorganic materials
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • A01N59/20—Copper
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/20—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing organic materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65—Salts of oxyacids of nitrogen

Definitions

  • This invention relates to methods of treating cotton fabrics for preventing or delaying the development of unpleasant odors and/or a rise in pH value when the treated fabrics are exposed to or impregnated with body secretions such as perspiration or urine.
  • the methods of this invention are particularly applicable to the treatment of diapers for the indicated purpose.
  • the methods of this ivention involve dipping or submerging cotton fabrics in dilute water solutions of copper salts.
  • such treatment of cotton fabrics ordinarily or often causes the fabrics to be tinted green, especially in the presence of small amounts of colloidal materials such as soaps, gums, starches, proteins such as albumen or casein and other colloidal material used in washing or treating fabrics and apt to remain in the fabrics after Washing or treatment therewith.
  • colloidal materials such as soaps, gums, starches, proteins such as albumen or casein and other colloidal material used in washing or treating fabrics and apt to remain in the fabrics after Washing or treatment therewith.
  • dipping or submerging cotton fabrics in dilute water solutions of copper salts often render the fabrics water repellent.
  • an object of the present invention to provide methods for treating cotton fabrics with dilute water solutions of copper salts without tinting the fabrics green or rendering the fabrics water repellent, even when the fabrics or the dipping solution of the copper salts contain colloidal materials such as soap.
  • cotton fabrics are immersed in water solutions of a water soluble copper salt such as copper sulfate, chloride, acetate or nitrate.
  • a water soluble copper salt such as copper sulfate, chloride, acetate or nitrate.
  • copper salt from about 0.05 to about 1 milligram molecules (an amount in milligrams numerically equal to the molecular weight) of copper salt are used for each 60 grams of cotton fabric.
  • This amount of copper salt is dissolved in from 100 cc. to 1000 cc. or more of water.
  • from about 2 to about 10 milligram molecules of disodium dihydrogcn pyrophosphate are added to the solution for each milligram molecule of copper salt.
  • dipping solution is kept acid, preferably at a pH of from about 3.0 to 3.5 to about 5 or 6.
  • the time of immersion may be from 1 or 2 minutes up to or minutes or longer, but is not critical.
  • the immersion may be carried out at room temperature or at elevated temperatures for instance
  • the above mentioned pH range is most suitably maintained by adding to the dipping solution appropriate amounts of acidic substances such as zinc or magnesium silicofluoride, acetic acid, lactic acid, hydrochloric acid, sulfuric acid and the like.
  • acidic substances such as zinc or magnesium silicofluoride, acetic acid, lactic acid, hydrochloric acid, sulfuric acid and the like.
  • disodium dihydrogen pyrophosphate equivalent amounts of tetrasodium pyrophosphate may be used, but then an additional amount of an acidic substance is added to neutralize one half of the sodium content of the tetrasodium pyrophosphate.
  • sodium pyrophosphate other alkali metal pyrophosphates may be used, such as the corresponding potassium pyrophosphates.
  • mixtures may be prepared comprising a finely divided copper salt and finely divided disodium dihydrogen pyrophosphate in a ratio of one molecule of copper salt to two Also, the pH of the to 10 molecules of said pyrophospnate. To insure proper acidity of the dipping solution, even in the presence of soaps, such mixtures may additionally comprise from one-half to two or more molecules of zinc or magnesium silicofluoride or equivalent acidic buffers for each molecule of said copper salt.
  • cotton fabrics are treated as described in the preceding paragraph, then rinsedwith water and dried, the fabrics are not rendered water repellent, nor are the fabrics tinted green, even when the fabrics (or the dipping solutions) contain even fairly large amounts of colloidal materials such as soaps, fats, oils, proteins such as albumen or casein, dirt or soil and the like.
  • cotton fabrics so treated contain copper substantively fixed thereon, Which copper is not removed by wetting or rinsing with water or expo-sure to body secretions such as perspiration or urine.
  • fabrics so treated do not develop unpleasant odors and/ or a rise in pH value and/ or formation of ammonia when the treated fabrics are exposed to or impregnated with body secretions such as perspiration and urine.
  • one 60 gram cotton diaper was first wetted with 150 to 180 cc. water having .2 gram of ordinary soap dissolved therein, thereafter immersed for from three to ten minutes in a copper salt solution containing disodium dihydrogen pyrophosphate, then removed from the copper salt solution, squeezed thoroughly, rinsed with water and dried.
  • the copper salts employed were the sulfate, chloride, acetate and nitrate.
  • the pH was adjusted downward-1y with an appropriate amount of zinc silicofluoride.
  • the exact amounts of copper salts, pyrophosphate, water and the pH are tabulated as follows:
  • a method of treating cotton fabrics which comprises immersing said fabrics in a dilute acidic aqueous solution of a water soluble copper salt selected from the group consisting of the sulfate, chloride, nitrate and acetate, said solution containing, for each 60 grams of fabric, from about to about 1000 cc. of Water, from about 0.05 to about 1 milligram molecules of a soluble copper salt, and from about 2 to about 10 milligram molecules of a di-alkali metal dihydrogen pyrophosphate for each milligram molecule of said copper salt said solution being maintained at a pH of from about 3 to about 6.
  • a water soluble copper salt selected from the group consisting of the sulfate, chloride, nitrate and acetate
  • a mixture comprising a water soluble copper salt selected from the group consisting of the sulfate, chloride, nitrate and acetate and disodium dihydrogen pyrophosphate in a ratio of one molecule of said copper salt to from two to ten molecules of said pyrophosphate.

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hematology (AREA)
  • Epidemiology (AREA)
  • Materials Engineering (AREA)
  • Animal Behavior & Ethology (AREA)
  • Inorganic Chemistry (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

United States Patent METHOD OF TREATING COTTON FABRICS Harold N. Vagenius, Chicago, Ill.
No Drawing. Application Novemberfitl, 1954 Serial No. 467,658
4 Claims. (Cl. 167- 84) This inventionrelates to methods of treating cotton fabrics for preventing or delaying the development of unpleasant odors and/or a rise in pH value when the treated fabrics are exposed to or impregnated with body secretions such as perspiration or urine. The methods of this invention are particularly applicable to the treatment of diapers for the indicated purpose.
The methods of this ivention involve dipping or submerging cotton fabrics in dilute water solutions of copper salts. However, such treatment of cotton fabrics ordinarily or often causes the fabrics to be tinted green, especially in the presence of small amounts of colloidal materials such as soaps, gums, starches, proteins such as albumen or casein and other colloidal material used in washing or treating fabrics and apt to remain in the fabrics after Washing or treatment therewith. Further, dipping or submerging cotton fabrics in dilute water solutions of copper salts often render the fabrics water repellent.
It is, therefore, an object of the present invention to provide methods for treating cotton fabrics with dilute water solutions of copper salts without tinting the fabrics green or rendering the fabrics water repellent, even when the fabrics or the dipping solution of the copper salts contain colloidal materials such as soap.
According to the present invention, cotton fabrics are immersed in water solutions of a water soluble copper salt such as copper sulfate, chloride, acetate or nitrate. From about 0.05 to about 1 milligram molecules (an amount in milligrams numerically equal to the molecular weight) of copper salt are used for each 60 grams of cotton fabric. This amount of copper salt is dissolved in from 100 cc. to 1000 cc. or more of water. Further, from about 2 to about 10 milligram molecules of disodium dihydrogcn pyrophosphate are added to the solution for each milligram molecule of copper salt. dipping solution is kept acid, preferably at a pH of from about 3.0 to 3.5 to about 5 or 6. The time of immersion may be from 1 or 2 minutes up to or minutes or longer, but is not critical. The immersion may be carried out at room temperature or at elevated temperatures for instance 120 F., or 140 F. or 160 F.
The above mentioned pH range is most suitably maintained by adding to the dipping solution appropriate amounts of acidic substances such as zinc or magnesium silicofluoride, acetic acid, lactic acid, hydrochloric acid, sulfuric acid and the like. In place of the disodium dihydrogen pyrophosphate, equivalent amounts of tetrasodium pyrophosphate may be used, but then an additional amount of an acidic substance is added to neutralize one half of the sodium content of the tetrasodium pyrophosphate. In place of the sodium pyrophosphate, other alkali metal pyrophosphates may be used, such as the corresponding potassium pyrophosphates.
For convenience in making up the dipping solution, mixtures may be prepared comprising a finely divided copper salt and finely divided disodium dihydrogen pyrophosphate in a ratio of one molecule of copper salt to two Also, the pH of the to 10 molecules of said pyrophospnate. To insure proper acidity of the dipping solution, even in the presence of soaps, such mixtures may additionally comprise from one-half to two or more molecules of zinc or magnesium silicofluoride or equivalent acidic buffers for each molecule of said copper salt.
When cotton fabrics are treated as described in the preceding paragraph, then rinsedwith water and dried, the fabrics are not rendered water repellent, nor are the fabrics tinted green, even when the fabrics (or the dipping solutions) contain even fairly large amounts of colloidal materials such as soaps, fats, oils, proteins such as albumen or casein, dirt or soil and the like. Further, cotton fabrics so treated contain copper substantively fixed thereon, Which copper is not removed by wetting or rinsing with water or expo-sure to body secretions such as perspiration or urine. Further, fabrics so treated do not develop unpleasant odors and/ or a rise in pH value and/ or formation of ammonia when the treated fabrics are exposed to or impregnated with body secretions such as perspiration and urine.
Examples of treatments of 60 gram cotton diapers according to the present invention are given hereinbelow.
For each of these examples, one 60 gram cotton diaper was first wetted with 150 to 180 cc. water having .2 gram of ordinary soap dissolved therein, thereafter immersed for from three to ten minutes in a copper salt solution containing disodium dihydrogen pyrophosphate, then removed from the copper salt solution, squeezed thoroughly, rinsed with water and dried. The copper salts employed were the sulfate, chloride, acetate and nitrate. The pH was adjusted downward-1y with an appropriate amount of zinc silicofluoride. The exact amounts of copper salts, pyrophosphate, water and the pH are tabulated as follows:
i Milligram i i Milligram Example No. Copper Molecules Water, Molecules pH Salt of copper cc. of pyrosalt phosphate Sulfate. 0.05 250 1 5. 0 0.1 250 .2 4. 5 0.1 .3 4. 5 0.1 250 .4 3. 5 0. .3 350 2. 0 3. 5 l. 0 450 5. 0 3. 5 1. 5 550 10.0 3. 5 0.1 250 0.3 3. 5 0.] 250 0.3 3. 5 10 Nitrate... 0.1 250 0.3 3. 5
An untreated diaper and each one of diapers Numbers 1 through 10 of the above table was impregnated with cc. urine and placed in a polyethylene bag, which was kept at room temperature for sixdays. The control (untreated) diaper developed an unpleasant sour odor within 24 hours followed shortly thereafter by a rise in pH and generation of ammonia. in the case of diapers of Examples 1 through 10, such odor and rise in pH value did not take place before four or five days, and generation of ammonia did not occur at all.
Many details may be varied without departing from the principles of this invention. It is therefore not my intention to limit the patent granted on this invention otherwise than necessitated by the scope of the appended claims.
'Iclairn:
1. A method of treating cotton fabrics which comprises immersing said fabrics in a dilute acidic aqueous solution of a water soluble copper salt selected from the group consisting of the sulfate, chloride, nitrate and acetate, said solution containing, for each 60 grams of fabric, from about to about 1000 cc. of Water, from about 0.05 to about 1 milligram molecules of a soluble copper salt, and from about 2 to about 10 milligram molecules of a di-alkali metal dihydrogen pyrophosphate for each milligram molecule of said copper salt said solution being maintained at a pH of from about 3 to about 6.
2. A method according to claim 1 in which said pyrophosphate is a sodium pyrophosphate.
3. A method according to claim 1 in which said copper salt is copper sulfate.
4. As a new composition of matter, a mixture comprising a water soluble copper salt selected from the group consisting of the sulfate, chloride, nitrate and acetate and disodium dihydrogen pyrophosphate in a ratio of one molecule of said copper salt to from two to ten molecules of said pyrophosphate.
References Cited in the file of this patent UNITED STATES PATENTS 22,362 Glynn Dec. 21, 1858 43,233 Stacey June 21, 1864 152,903 Gender July 14, 1874 1,903,041 Hall et a1. Mar. 28, 1933 1,960,627 Finlayson May 29, 1934 2,086,867 Hall July 13, 1937 2,241,580 Bishop May 13, 1941 2,580,286 Dorsett Dec. 25, 1951 2,643,969 Mahon June 30, 1953 FOREIGN PATENTS 453,348 France Apr. 2, 1913 OTHER REFERENCES 15 and Eng. Chem., April 1941, pp. 538-545.
Fullerton: Cotton Duck and Canvas, Rot-proofing, J. Text. Inst, 1942, p. A321.
Textile Colorist, January 1943, p. 30.
Goodman: Cosmetic Dermatology, McGraw Hil 20 Book Co., 1936, p. 45, entry Cupric Sulfas.

Claims (1)

1. A METHOD OF TREATING COTTON FABRICS WHICH COMPRISES IMMERSING SAID FABRICS IN A DILUTE ACIDIC AQUEOUS SOLUTION OF A WATER SOLUBLE COPPER SALT SELECTED FROM THE GROUP CONSISTING OF THE SULFATE, CHLORIDE, NITRATE AND ACETATE, SAID SOLUTION CONTAINING, FOR EACH 60 GRAMS OF FABRIC, FROM ABOUT 100 TO ABOUT 1000 CC. OF WATER, FROM ABOUT 0.05 TO ABOUT 1 MILLIGRAM MOLECULES OF A SOLUBLE COPPER SALT, AND FROM ABOUT 2 TO ABOUT 10 MILLIGRAM MOLECULES OF A DI-ALKALI METAL DIHYDROGEN PROPHOSPHATE FOR EACH MILLIGRAM MOLECULE OF SAID COPPER SALT SOLUTION BEING MAINTAINED AT A PH OF FROM ABOUT 3 TO ABOUT 6.
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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2904466A (en) * 1956-09-06 1959-09-15 Monsanto Chemicals Preservative composition comprising tetraalkali metal pyrophosphate, a polychlorophenate and a heavy metal salt
US3067745A (en) * 1959-08-12 1962-12-11 Johnson & Johnson Absorbent product
US3072534A (en) * 1958-02-21 1963-01-08 American Cyanamid Co Durable antibacterial textile finish for cellulosic fibers
US3101297A (en) * 1961-05-15 1963-08-20 Sir Properties Inc Diaper washing composition
US3379563A (en) * 1964-09-08 1968-04-23 Armour & Co Impregnated degradationresistant cloth
FR2490093A1 (en) * 1980-09-17 1982-03-19 Landstingens Inkopscentral ABSORBENT BODY GERMICIDE
EP0117613A2 (en) * 1983-01-24 1984-09-05 The Procter & Gamble Company Disposable absorbent article incorporating agents for the treatment and prophylaxis of diaper rash and diaper dermatitis
US4525410A (en) * 1982-08-24 1985-06-25 Kanebo, Ltd. Particle-packed fiber article having antibacterial property
EP0158092A1 (en) * 1984-03-06 1985-10-16 Henkel Kommanditgesellschaft auf Aktien Hygienic article
EP0159490A1 (en) * 1984-03-06 1985-10-30 Chemiefaser Lenzing Aktiengesellschaft Deodorizing and microbistatic fibre material
EP0163179A1 (en) * 1984-05-18 1985-12-04 Vereinigte Papierwerke AG Menstrual tampon
US4906462A (en) * 1986-11-14 1990-03-06 Nippon Zeon Co., Ltd. Deodorant composition and deodorant composite material
US4956183A (en) * 1986-08-07 1990-09-11 Nippon Zeon Co., Ltd. Composition comprising copper compound
US5492759A (en) * 1989-09-27 1996-02-20 Molnlycke Ab Fibres of increased specific surface area, a method for their manufacture, fluff pulp consisting of such fibres and the use of the fibres as absorption material
US5833970A (en) * 1977-01-24 1998-11-10 Cox; James P. Deodorant material and deodorizing method

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US22362A (en) * 1858-12-21 Improvement in medicated fabrics
US43233A (en) * 1864-06-21 Improved mode of preventing mildew in canvas, cloth
US152903A (en) * 1874-07-14 Improvement in treating textile fabrics to prevent mildew and decay
FR453348A (en) * 1912-01-17 1913-06-05 Oswald Silberrad Improvements in the preparation of flax and other fibers
US1903041A (en) * 1929-11-23 1933-03-28 John M Hopwood Water treatment
US1960627A (en) * 1932-10-28 1934-05-29 Sealth Corp Method for retarding the decay of fishing twine, nets, and allied equipment
US2086867A (en) * 1936-06-19 1937-07-13 Hall Lab Inc Laundering composition and process
US2241580A (en) * 1937-06-25 1941-05-13 Pennsylvania Salt Mfg Co Art of laundering and cleaning
US2580286A (en) * 1946-12-04 1951-12-25 Rowell R Dorsett Process of treating cellulosic and similar materials
US2643969A (en) * 1947-04-17 1953-06-30 Homemakers Products Corp Diaper

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US22362A (en) * 1858-12-21 Improvement in medicated fabrics
US43233A (en) * 1864-06-21 Improved mode of preventing mildew in canvas, cloth
US152903A (en) * 1874-07-14 Improvement in treating textile fabrics to prevent mildew and decay
FR453348A (en) * 1912-01-17 1913-06-05 Oswald Silberrad Improvements in the preparation of flax and other fibers
US1903041A (en) * 1929-11-23 1933-03-28 John M Hopwood Water treatment
US1960627A (en) * 1932-10-28 1934-05-29 Sealth Corp Method for retarding the decay of fishing twine, nets, and allied equipment
US2086867A (en) * 1936-06-19 1937-07-13 Hall Lab Inc Laundering composition and process
US2241580A (en) * 1937-06-25 1941-05-13 Pennsylvania Salt Mfg Co Art of laundering and cleaning
US2580286A (en) * 1946-12-04 1951-12-25 Rowell R Dorsett Process of treating cellulosic and similar materials
US2643969A (en) * 1947-04-17 1953-06-30 Homemakers Products Corp Diaper

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2904466A (en) * 1956-09-06 1959-09-15 Monsanto Chemicals Preservative composition comprising tetraalkali metal pyrophosphate, a polychlorophenate and a heavy metal salt
US3072534A (en) * 1958-02-21 1963-01-08 American Cyanamid Co Durable antibacterial textile finish for cellulosic fibers
US3067745A (en) * 1959-08-12 1962-12-11 Johnson & Johnson Absorbent product
US3101297A (en) * 1961-05-15 1963-08-20 Sir Properties Inc Diaper washing composition
US3379563A (en) * 1964-09-08 1968-04-23 Armour & Co Impregnated degradationresistant cloth
US5833970A (en) * 1977-01-24 1998-11-10 Cox; James P. Deodorant material and deodorizing method
DE3135410A1 (en) * 1980-09-17 1982-06-24 Landstingens inköpscentral LIC, ekonomisk förening, 17141 Solna CLIMATE-KILLING ABSORBENT BODY
US4385632A (en) * 1980-09-17 1983-05-31 Landstingens Inkopscentral Germicidal absorbent body
FR2490093A1 (en) * 1980-09-17 1982-03-19 Landstingens Inkopscentral ABSORBENT BODY GERMICIDE
US4525410A (en) * 1982-08-24 1985-06-25 Kanebo, Ltd. Particle-packed fiber article having antibacterial property
EP0117613A2 (en) * 1983-01-24 1984-09-05 The Procter & Gamble Company Disposable absorbent article incorporating agents for the treatment and prophylaxis of diaper rash and diaper dermatitis
EP0117613A3 (en) * 1983-01-24 1986-12-30 The Procter & Gamble Company Disposable absorbent article incorporating agents for the treatment and prophylaxis of diaper rash and diaper dermatitis
US4556560A (en) * 1983-01-24 1985-12-03 The Procter & Gamble Company Methods for the treatment and prophylaxis of diaper rash and diaper dermatitis
EP0158092A1 (en) * 1984-03-06 1985-10-16 Henkel Kommanditgesellschaft auf Aktien Hygienic article
US4637820A (en) * 1984-03-06 1987-01-20 Lenzing Aktiengesellschaft Copper-modified carboxyalkyl-cellulose fiber
US4675014A (en) * 1984-03-06 1987-06-23 Henkel Kommanditgesellschaft Auf Aktien Microbistatic and deodorizing catamenial and hygienic devices
EP0159490A1 (en) * 1984-03-06 1985-10-30 Chemiefaser Lenzing Aktiengesellschaft Deodorizing and microbistatic fibre material
EP0163179A1 (en) * 1984-05-18 1985-12-04 Vereinigte Papierwerke AG Menstrual tampon
US4661101A (en) * 1984-05-18 1987-04-28 Vereinigte Papierwerke, Schickedanz & Co. Layered catamenial device
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