TW500695B - Colloidal dispersion of a cerium compound, process for preparing the same and process for predaring the same wherein the continuous phase is constituted by a water/water-miscible solvent mixture or by an organic solvent - Google Patents
Colloidal dispersion of a cerium compound, process for preparing the same and process for predaring the same wherein the continuous phase is constituted by a water/water-miscible solvent mixture or by an organic solvent Download PDFInfo
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- TW500695B TW500695B TW089124466A TW89124466A TW500695B TW 500695 B TW500695 B TW 500695B TW 089124466 A TW089124466 A TW 089124466A TW 89124466 A TW89124466 A TW 89124466A TW 500695 B TW500695 B TW 500695B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 16
- 238000001246 colloidal dispersion Methods 0.000 title claims abstract description 10
- 239000003960 organic solvent Substances 0.000 title claims description 6
- 239000011877 solvent mixture Substances 0.000 title claims 3
- 150000001785 cerium compounds Chemical class 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000006185 dispersion Substances 0.000 claims abstract description 53
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 239000002244 precipitate Substances 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 9
- 150000003839 salts Chemical class 0.000 claims abstract description 7
- 239000000919 ceramic Substances 0.000 claims abstract description 5
- 239000002537 cosmetic Substances 0.000 claims abstract description 4
- 239000000314 lubricant Substances 0.000 claims abstract description 4
- 229920006254 polymer film Polymers 0.000 claims abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 14
- 238000000108 ultra-filtration Methods 0.000 claims description 13
- -1 hydrazone salt Chemical class 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical group CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 4
- 229910052702 rhenium Inorganic materials 0.000 claims description 4
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 4
- 150000007857 hydrazones Chemical class 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 239000003518 caustics Substances 0.000 claims 2
- 241000272525 Anas platyrhynchos Species 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- 238000004821 distillation Methods 0.000 claims 1
- 229910000487 osmium oxide Inorganic materials 0.000 claims 1
- JIWAALDUIFCBLV-UHFFFAOYSA-N oxoosmium Chemical compound [Os]=O JIWAALDUIFCBLV-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 2
- 229910052684 Cerium Inorganic materials 0.000 abstract 4
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 4
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 229910000420 cerium oxide Inorganic materials 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- GNXDHCINGURTBP-UHFFFAOYSA-J C(C)(=O)[O-].[Re+4].C(C)(=O)[O-].C(C)(=O)[O-].C(C)(=O)[O-] Chemical compound C(C)(=O)[O-].[Re+4].C(C)(=O)[O-].C(C)(=O)[O-].C(C)(=O)[O-] GNXDHCINGURTBP-UHFFFAOYSA-J 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 230000002079 cooperative effect Effects 0.000 description 4
- 150000004714 phosphonium salts Chemical class 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- HXDLWJWIAHWIKI-UHFFFAOYSA-N 2-hydroxyethyl acetate Chemical class CC(=O)OCCO HXDLWJWIAHWIKI-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(iii) oxide Chemical compound O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 239000011833 salt mixture Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229910004664 Cerium(III) chloride Inorganic materials 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- XZQYTGKSBZGQMO-UHFFFAOYSA-I Rhenium(V) chloride Inorganic materials Cl[Re](Cl)(Cl)(Cl)Cl XZQYTGKSBZGQMO-UHFFFAOYSA-I 0.000 description 1
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- SMRRYUGQTFYZGD-UHFFFAOYSA-K diacetyloxythallanyl acetate Chemical compound [Tl+3].CC([O-])=O.CC([O-])=O.CC([O-])=O SMRRYUGQTFYZGD-UHFFFAOYSA-K 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- LYQGMALGKYWNIU-UHFFFAOYSA-K gadolinium(3+);triacetate Chemical compound [Gd+3].CC([O-])=O.CC([O-])=O.CC([O-])=O LYQGMALGKYWNIU-UHFFFAOYSA-K 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 238000002173 high-resolution transmission electron microscopy Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 150000003282 rhenium compounds Chemical class 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- UXMRNSHDSCDMLG-UHFFFAOYSA-J tetrachlororhenium Chemical compound Cl[Re](Cl)(Cl)Cl UXMRNSHDSCDMLG-UHFFFAOYSA-J 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052722 tritium Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0086—Preparation of sols by physical processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
- C01F17/224—Oxides or hydroxides of lanthanides
- C01F17/235—Cerium oxides or hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/50—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dermatology (AREA)
- Geology (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Nanotechnology (AREA)
- Dispersion Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Emergency Medicine (AREA)
- Physics & Mathematics (AREA)
- Colloid Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Cosmetics (AREA)
Description
500695 A7
I I I I I I I -II. <請先閲讀背面之注意事填寫本頁) · · 本發明有關含鈽m之鈽化合物之膠體分散液。 鋅落膠更特別是四價銻溶膠爲已 ^ # ^ ^ + 、 其在例如陶瓷工業 成發先,豆領域中具有相當重要性。 杏：建^ ^ ^ ^ …、而，此寺應用需要相 田/辰、μ且純（轉。但轉製備方法尤其需使用離子 父換樹脂。最希望具有獲得此溶膠之更簡易路捏。 之^=目㈣使„單路徑克服此困難點及產生足夠濃 取終，本發明提供_㈣化合物之㈣分散液， 爲其氧化飾濃度至少50克/升，其鈽含量相對於飾總含量 馬至少〇.5%，其導電度至多5ms/em，其阳在4至8範 圍且係由平均粒徑至多15奈米之顆粒所構成。 Μ明亦提供―種製備㈣體分散液之方法，其特徵爲 使至少一種鈽m鹽與鹼在可使H+/Ce比例大於^之量之酸 存在下反應，接著使前述反應之沉澱物再分散於水中。 本發明之方法並不複雜，因其主要包括使鹽與鹼反應且 可利用簡單裝置進行。其自鈽ΠΙ開始，其部分可見於本 發明之分散液中，且此分散液具有所需之純度特徵。 經濟部智慧財產局員工消費合作社印製 本發明進一步特徵、細節及優點將由下列説明及用以説 明本發明之各種非限制性實例更加了解。 整個說明書中，鈽化合物之”膠體分散液”或，，溶膠π音 指由氧化鈽及/或水合氧化物（氫氧化物）爲主之膠體尺寸 細固體顆粒於含水液相中之懸浮液所構成之任何系統，該 顆粒亦可含有殘留之键結或吸附離子如硝酸根離子、乙酸 根離子、檸檬酸根離子或銨離子。需注意此分散液中，錦 .4 ** 本紙張尺度翻中國國家標準（CNS)A4規格（210 X 297公爱) 500695
五、發明說明（2) 可完全成膠體或同時成離子·及膠體態。 第一特徵中，本發明分散液之濃度至少50克/升。尤其 疋土 V 100克/升且又更好至少丨50克/升。濃度以氧化錦
Ce〇2 *里 >辰度表示。其係於空氣中乾燥及鍛燒既定容積之 分散液後測定。 分散液之第二特徵爲鈽III之量。其量至少0.5%。更好 土 V l/o又更好至少I·5 %。通常至多5 0%。又更佳，至 夕爲10 /〇。其以鈽Ιπ總原子比表示。分散液亦可包括鈽 I V態之鈽。 本發明分散液之第三特徵爲其純度。純度係藉分散液之 4 1¾ f生而//、]畺。導電性至多5 mS/cm 。可低於此値且較好 至^ 2 mS/cm ’更好至多1 mS/Cm 。又更佳，可低於〇 3 mS/cm 〇 再者’本發明分散液之pH亦高，例如在4至8之範 圍。該等PH接近中性，引起本發明分散液之有趣應用。 構成本發明溶膠之膠體顆粒爲細顆粒。因此平均直徑至 多15奈米，尤其在2奈米至15奈米間，更佳在2奈米至 6奈米間。直徑係使用HRTEM分析（高解析傳送電子顯微 鏡）之光度計解析而測量。 杈佳％化中，本發明分散液就硝酸根陰離子而言特別 純。更精確而言，分散液中硝酸根陰離子量，以膠體顆粒 重量之硝酸根陰離子量測量，小於8〇 ppm。 最後，本發明分散液亦可爲水性分散液，連續相爲水或 連續相可由水/水相容溶劑構成之分散液或有機溶劑之分 (請先閱讀背面之注 裝 意事填寫本頁) 訂；！丨‘-----#- 經濟部智慧財產局員工消費合作社印製
500695 五 經濟部智慧財產局員工消費合作社印製 A7 B7 發明說明（3) 散液。 一 · 更尤其’有機溶劑可爲水相容溶劑。可引述之溶劑實例 爲醇類如甲醇或乙醇、二醇類如乙二醇、二醇之乙酸酯衍 生物如乙二醇單乙酸酯、二醇醚、多元醇或酮類。 現在説明製備本發明分散液之方法。 該方法包括第一步驟爲使鈽ΙΠ鹽與鹼在酸存在下反 應。 該驗可爲氫氧化物類產物。可引述鹼及鹼土及銨氫氧化 物。亦可使用二級、三級或四級胺。然而，胺及氨較佳因 其可降低驗或驗土族陽離子污染之危險。 更特別引述之鈽III鹽爲ΙΠ乙酸鹽、氣化物及硝酸鹽， 及此乙酸鹽/氣化物混合物之該等鹽混合物。 本發明特別之特徵中，該鈽鹽係在酸存在下與驗反應。 可使用之酸包含無機及/或有機酸，更尤其爲對應於反 應中所用之鈽ΠΙ鹽者。因此，可引述有乙酸或鹽酸。 反應中存在或使用之酸量爲可使H+/Ce莫耳比例大於1 者’較好大於1·5 ，更好至少爲2。此量爲與鹼開始反應 時存在之量。 該鹼可於連續反應中與鈽鹽反應，意指同時添加反應物 至反應介質中。該反應可在空氣中、空氣與氮之大氣中或 於氮氣中進行。 反應介質之pH —般在7.5至9.5之範圍。 反應後獲得沉澱物。此沉澱物可藉任何已知方法自液體 中分離’例如離心。獲得之沉澱物接著可製成水懸浮液而 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） (請先閱讀背面之注意事'Pt填寫本頁) 裝 500695 A7 經濟部智慧財產局員工消費合作社印製 五、發明說明（4 ) 產生本發明之分散液。 - 有利地，反應之沉澱物可經洗滌。此洗滌可藉添加水至 沉/殿物中接著攪摔後，藉例如離心自液體介質中分離固體 而進行。此操作若需要可重複操作數次。 本發明變化中，作成水懸浮液所得之分散液可藉超離過 遽純化。 右需要，分散液可藉例如超過濾濃縮。 洗滌及超過濾可於空氣中、空氣與氮之大氣中，或氮中 進行。發生該等操作之大氣在鈽ΙΠ轉化成鈽Iv中扮演重 要角色。 於溶劑介質中而非水中之部分或完全分散液之例中，分 散欣可藉添加有機溶劑至水性分散液中接著蒸餾除水或以 超過濾膜逐漸去除水而製備水性分散液。 本發明分散液可使用於各種應用中。尤其可引述觸媒， 更特別是汽車後燃機，其中使用本發明分散液製備觸媒。 此分散液亦可用於潤滑劑、陶瓷及用以製造發光體化合 物。此分散液亦可使用其抗_uv性冑，例如製備聚:㈣ (例如丙晞酸或聚碳酸類）或用於化妝品組 口切，兀具疋製 備防UV乳霜。最後，其可使用作爲抗腐蝕劑之基質。 現在説明實例。該等實例中，使用CDM 83導電計 (Radiometer Copenhaguen)及其 CDC 304 型電池測量導電:。 實例1 此實例有關自乙酸鈽及氯化鈽與鹽酸之混合物製備夂八 散液。 口 ，布分
(請先閱讀背面之注意事_填寫本頁) •裝 訂·· ----- 聲 500695 A7 B7_ 五、發明說明（5 ) 含49.29% Ce02氧化物（0.957莫耳Ce )之334克乙酸鈽（III) 及89.9克含45.90% Ce02 (亦即0.24莫耳Ce)之CeCl3添加 至燒杯中，接著添加已藉添加500毫升蒸館水稀釋之357 克之36%濃鹽酸（即3.52莫耳之HC1)。開始攪拌。以脱礦 水使達2000毫升。繼續攪拌直至獲得肉眼可見之透明度。 所得混合物濃度約〇·6Μ Ce及（H/Ce)莫耳比爲2.9。 此固體於包括下列之連續裝置中沉澱： -設有槳攪動器（調整至400 rpm)之1升反應器，0.5升 水進料及設有pH調節泵設定至pH 8.7之電極； -兩個進料漏斗，一個含有上述鈽鹽溶液及另一個含有 10N氨溶液。 乙酸鈽溶液流速固定在約500毫升/分鐘及氨流速調整至 可調節pH。接著於243分鐘内添加2000毫升鈽鹽混合物 及600毫升10 N氨。 測定鈽沉澱產生等級爲9 1 %。 藉4500 rpm離心10分鐘自母液中分離沉殿物。在1000 T鍛燒樣品使Ce02氧化物含量測定爲27.7%。 藉添加水分散沉澱物獲得0.25M Ce分散液。攪拌15分 鐘接著再度離心。進行兩次依序操作。 100毫升0.25 M Ce分散液以脱礦水稀釋至300毫升。使 用3 KD膜進行超過濾而濃縮至100毫升。超過濾進行3 次。最終超過濾期間藉超過濾至34毫升而補充濃度。 所得分散液樣品蒸發及在1〇〇〇 °C鍛燒獲得最終Ce02濃 度爲60克/升。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閲讀背面之注意事填寫本頁) -裝----l·---訂--------7» . 經濟部智慧財產局員工消費合作社印製 500695 A7 B7_ 五、發明說明（6 ) 膠體分散液呈現透明。分散液pH爲5。N〇3含量少於 80 ppm。總計之Ce ΙΙΙ/Ce比例爲1 · 8 % (使用化學方法測量） 及分散液導電度爲〇.7mS/cm。 實例2 此實例有關自乙酸鈽及乙酸製備鈽分散液。 416.5克之含49.29% Ce02氧化物之乙酸鈽（III) (1.19莫耳 Ce )添加至燒杯中，接著添加144克濃乙酸（亦即2.4莫耳 CH3COOH)(已藉添力口 100毫升脱礦水稀釋）。開始攪拌。 以脱礦水使達2400毫升。繼續攪拌直至獲得肉眼可見之透 明度。所得混合物Ce濃度約0.5 Μ及（H/Ce)莫耳比爲:2。 如實例1所述般於連續相中沉澱固體。 接著於270分鐘内添加2400毫升乙酸鈽溶液及2120毫升 測定鈽沉澱產生等級爲95.7%。 藉4500 rpm離心10分鐘自母液中分離沉澱物。在1000 °C鍛燒樣品使Ce02氧化物含量測定爲23.4%。 藉添加水分散沉澱物獲得0.25 M Ce分散液。攪拌15分 鐘接著再度離心。進行兩次依序操作。 100毫升0.25 M Ce分散液以脱礦水稀釋至300毫升及在 空氣中攪拌隔夜。使用3 KD膜進行超過濾而濃縮至100毫 升。超過濾進行3次。最終超過濾期間藉超過濾至34毫 升而補充濃度。 所得分散液樣品蒸發及在1000 °C鍛燒獲得最終Ce02濃 度爲57克/升。 -9- 本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐) (請先閱讀背面之注意事_填寫本頁) 裝 tv-------- 經濟部智慧財產局員工消費合作社印製 500695 A7 B7_ 五、發明說明（7 ) 膠體分散液呈現透明。分_散液pH爲4.7。 (請先閱讀背面之注意事3填寫本頁) N〇3含量少於80 ppm。總計之Ce ΙΙΙ/Ce比例爲1.9%及分 散液導電度爲0.9 mS/cm。膠體大小爲3奈米。 實例3 此實例説明本發明分散液之抗-UV性質。以波長爲函數 測量直接傳導。 該等傳導測量使用配置有樣品厚度2毫米之石英管之 Perkin Elmer λ 900 UV-可見光分光譜計進行。藉測量與參 考質（無膠體分散液之起始原料）相關之傳導強度而決定直 接傳導値。 膠體分散液樣品以脱礦水稀釋獲得終濃度爲3重量％之 Ce02 0 藉下列値使所得傳導曲線特性化： 在400奈米10%傳導。 在418奈米50%傳導。 在455奈米80%傳導。 經濟部智慧財產局員工消費合作社印製 -10- 本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐)
Claims (1)
- 第089124466號專利申 ^文申請專利範圍11| 鴨…丨 …丨 申請專利範圍 7請案 ’ A8 正♦告月本 -------- B8 C8 4' 1? U 41 1·種合物〇散液’其特徵為其氧化鈽濃度至少 50克/升，其*(ΙΙί)離子含量相對於鈽總含量為至少 ㈣’其導電度至多5ms/em，其阳在4至8範圍且係由 平均粒徑至多15奈米之顆粒所構成。 2·如申請專利範圍第1項之 刀欢硬’其中其濃度至少1〇〇 克/升。 3.如申5青專利範圍第1或2項少八也、、 _步i :¾ 2員心分散硬，其中其鈽m離子 含量至少1 %。 4·如申請專利範圍第1項之分散液 含量少於80 ppm。 5.如申請專利範圍第1項之分散液 mS/cm 〇 6·如申請專利範圍第5項之分散液 mS/cm ° 7.如申請專利範圍第1項之分散液 8·如申請專利範圍第1項之分散液 /水可相容溶劑混合物或由有機溶劑所構成 9· 一種製備如申請專利範圍第i、2、4、$、、 之膠體分散液之方法，其包含下列步驟·· -製備一種鈽111鹽； -將該鈽鹽與鹼反應以形成沈澱物； 在該鈽鹽中或在與鹼反應過程中加入酸，其加入田 使得H + / c e之莫耳比例超過1 ; 量 -將得自；^殿反應之沈澱物再分散於水中。 _ 1 _ 本紙張尺度巧巾®國家鮮(CNS) __A4規格(21G x 297公寶） 其中其硝酸根陰離子 其中其導電度至多 其中其導電度至多 2 其中其連續相為水 其中其連續相係由 水 或8工貢 為 500695 A8 六、申請專利範圍 —~—-—-_ 義'‘ 10·如申請專利範圍第9項夕士、土 , , _貝足万法，其中沉澱物再分散於水 中後，所得分散液藉超過濾純化。 1L如申請專利範圍第9項之方法，其中miI鹽係乙酸魄 或氯化物。 1 12. 如申請專利範圍第9項之方法，其中該酸為乙酸或场 酸。 I 13. 如中請專利範圍第9項之方法’其中反應係以連續製程 進行。 *· m 14. 一種製備膠體分散液之方法，其中連續相係由水/水可 相容溶劑混合物或由有機溶劑所構成，其特徵為有機 k 溶劑添加至由申請專利範圍第9項之方法所製得之水性 分散液中，接著蒸餾移除水，或分散液以超過濾膜處 a l 理而連續移除水。 iy 15·如申請專利範圍第丨項之分散液，係用於製備聚合物 • * 膜、化妝品組合物、觸媒尤其是汽車後燃機、潤滑劑 或陶瓷，其中使用基材作為抗腐蝕劑。 巍 16·如申請專利範圍第9項之方法，其中所得之分散液係 用於製備聚合物膜、化妝品組合物、觸媒尤其是汽車 後燃機、潤滑劑或陶瓷，其中使用基材作為抗腐蝕 劑。 -2 - 本紙張尺度適用中國國家標準(CNS) A4規格(210X 297公釐)
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| FR9914576A FR2801298B1 (fr) | 1999-11-19 | 1999-11-19 | Dispersion colloidale d'un compose de cerium et contenant du cerium iii, procede de preparation et utilisation |
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| TW500695B true TW500695B (en) | 2002-09-01 |
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| TW089124466A TW500695B (en) | 1999-11-19 | 2000-12-29 | Colloidal dispersion of a cerium compound, process for preparing the same and process for predaring the same wherein the continuous phase is constituted by a water/water-miscible solvent mixture or by an organic solvent |
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| EP (1) | EP1265815B1 (zh) |
| JP (1) | JP3950691B2 (zh) |
| KR (1) | KR100487453B1 (zh) |
| CN (1) | CN1212882C (zh) |
| AT (1) | ATE288403T1 (zh) |
| BR (1) | BR0015685A (zh) |
| CA (1) | CA2391946C (zh) |
| DE (1) | DE60017948T2 (zh) |
| FR (1) | FR2801298B1 (zh) |
| MX (1) | MXPA02004948A (zh) |
| NO (1) | NO20022374L (zh) |
| RU (1) | RU2228295C2 (zh) |
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| FR2831177B1 (fr) | 2001-10-22 | 2005-02-18 | Rhodia Elect & Catalysis | Dispersion colloidale et poudre colorees de cerium ou de cerium et de titane, de zirconium, d'aluminium ou d'une terre rare, leur procede de preparation et leur utilisation |
| US7294211B2 (en) | 2002-01-04 | 2007-11-13 | University Of Dayton | Non-toxic corrosion-protection conversion coats based on cobalt |
| US7235142B2 (en) | 2002-01-04 | 2007-06-26 | University Of Dayton | Non-toxic corrosion-protection rinses and seals based on cobalt |
| EP1472319A1 (en) | 2002-01-04 | 2004-11-03 | University Of Dayton | Non-toxic corrosion protection pigments based on cobalt |
| DE10337199A1 (de) * | 2003-08-13 | 2005-03-10 | Degussa | Ceroxidpulver |
| JP5013671B2 (ja) * | 2004-12-28 | 2012-08-29 | 日揮触媒化成株式会社 | 金属酸化物ゾルの製造方法および金属酸化物ゾル |
| US10041176B2 (en) | 2005-04-07 | 2018-08-07 | Momentive Performance Materials Inc. | No-rinse pretreatment methods and compositions |
| FR2905371B1 (fr) * | 2006-08-31 | 2010-11-05 | Rhodia Recherches & Tech | Composition a reductibilite elevee a base d'un oxyde de cerium nanometrique sur un support, procede de preparation et utilisation comme catalyseur |
| KR101773543B1 (ko) | 2015-06-30 | 2017-09-01 | 유비머트리얼즈주식회사 | 연마 입자, 연마 슬러리 및 연마 입자의 제조 방법 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2857146T1 (de) * | 1977-11-01 | 1980-12-04 | Atomic Energy Authority Uk | Production of dispersions |
| JPH062582B2 (ja) * | 1987-12-02 | 1994-01-12 | 多木化学株式会社 | 結晶質酸化第二セリウムゾル及びその製造法 |
| US4800072A (en) * | 1988-01-14 | 1989-01-24 | Rhone Poulenc, Inc. | Anhydrous cerous nitrate-ammonium nitrate complex and a process for its preparation from ceric ammonium nitrate |
| FR2724331B1 (fr) * | 1994-09-12 | 1996-12-13 | Rhone Poulenc Chimie | Dispersions colloidales d'un compose de cerium a ph eleve et leurs procedes de preparation |
| US5962343A (en) * | 1996-07-30 | 1999-10-05 | Nissan Chemical Industries, Ltd. | Process for producing crystalline ceric oxide particles and abrasive |
-
1999
- 1999-11-19 FR FR9914576A patent/FR2801298B1/fr not_active Expired - Fee Related
-
2000
- 2000-11-17 MX MXPA02004948A patent/MXPA02004948A/es not_active Application Discontinuation
- 2000-11-17 JP JP2001538289A patent/JP3950691B2/ja not_active Expired - Fee Related
- 2000-11-17 RU RU2002116371/15A patent/RU2228295C2/ru not_active IP Right Cessation
- 2000-11-17 AT AT00983380T patent/ATE288403T1/de not_active IP Right Cessation
- 2000-11-17 DE DE60017948T patent/DE60017948T2/de not_active Expired - Lifetime
- 2000-11-17 EP EP00983380A patent/EP1265815B1/fr not_active Expired - Lifetime
- 2000-11-17 BR BR0015685-0A patent/BR0015685A/pt not_active Application Discontinuation
- 2000-11-17 KR KR10-2002-7006396A patent/KR100487453B1/ko not_active IP Right Cessation
- 2000-11-17 CN CNB008158452A patent/CN1212882C/zh not_active Expired - Fee Related
- 2000-11-17 WO PCT/FR2000/003199 patent/WO2001036331A1/fr active IP Right Grant
- 2000-11-17 CA CA002391946A patent/CA2391946C/fr not_active Expired - Fee Related
- 2000-12-29 TW TW089124466A patent/TW500695B/zh not_active IP Right Cessation
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2002
- 2002-05-16 NO NO20022374A patent/NO20022374L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA02004948A (es) | 2003-10-14 |
| DE60017948T2 (de) | 2006-01-19 |
| NO20022374L (no) | 2002-07-11 |
| EP1265815A1 (fr) | 2002-12-18 |
| CA2391946A1 (fr) | 2001-05-25 |
| KR20020070284A (ko) | 2002-09-05 |
| CN1212882C (zh) | 2005-08-03 |
| DE60017948D1 (de) | 2005-03-10 |
| EP1265815B1 (fr) | 2005-02-02 |
| BR0015685A (pt) | 2002-08-06 |
| JP3950691B2 (ja) | 2007-08-01 |
| ATE288403T1 (de) | 2005-02-15 |
| CA2391946C (fr) | 2007-01-23 |
| RU2228295C2 (ru) | 2004-05-10 |
| NO20022374D0 (no) | 2002-05-16 |
| KR100487453B1 (ko) | 2005-05-06 |
| FR2801298A1 (fr) | 2001-05-25 |
| JP2003514744A (ja) | 2003-04-22 |
| CN1391534A (zh) | 2003-01-15 |
| WO2001036331A1 (fr) | 2001-05-25 |
| FR2801298B1 (fr) | 2002-05-03 |
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