TW466597B - Method to form the high resistive resistor of mixed-signal IC by laser annealing - Google Patents
Method to form the high resistive resistor of mixed-signal IC by laser annealing Download PDFInfo
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46 659 7 五、發明說明(1) ---- 5 -1發明領域: 本發明係有關於在混合訊號積體電路中形成電阻器的 方法特別是形成一具有高電阻的電阻器,該電阻器在應 用上可減^裝置在待機狀態時的電力消耗。 5-2發明背景·· 應用在非同步數位用戶專線(Asymmetric Digital46 659 7 V. Description of the invention (1) ---- 5 -1 Field of invention: The present invention relates to a method for forming a resistor in a mixed-signal integrated circuit, in particular to forming a resistor with high resistance. The device can reduce the power consumption of the device when it is in standby. 5-2 Background of the Invention ·· Applied to Asymmetric Digital Subscriber Line
Subscriber Line,ADSL)寬頻服務上的混合訊號(mixed signal)積體電路需具有高電阻電性的電阻器,以減少裝 置在待機狀態時的電力消耗。一般而言,電阻器如需具有 高電阻電性’必須在製程中將植入電阻器的摻質劑量降低 。然而’摻質的低劑量及深度在半導體製程中不易控制’ 推質易受到製程的影響而產生向外擴散及植入深度過深等 現象’進而降低電阻器的電性品質,因此,控制摻質的劑 量及深度對高電阻的電阻器而言是非常重要的。 一般製作混合訊號積體電路中電阻器的方法如第一A 圖所示’首先提供一底材101、一 p井1〇2,一 N井103、一 隔離元件11 0及一犧牲氧化層111。一第一多晶矽層1 2 〇沉 積在犧牲氧化詹Π1上,接著以覆毯式子植入 的方式將摻質iso植入第一多晶矽層120中。在此的第一多Subscriber Line (ADSL) mixed-signal integrated circuits on broadband services need high-resistance electrical resistors to reduce power consumption when the device is in standby. Generally speaking, if the resistor needs to have high resistance electrical properties, the dopant dose of the implanted resistor must be reduced in the manufacturing process. However, 'the low dose and depth of dopant is not easy to control in the semiconductor process.' Pushing mass is easily affected by the process and causes phenomena such as outward diffusion and excessively deep implant depth ', thereby reducing the electrical quality of the resistor. Therefore, the dopant is controlled. Qualitative dose and depth are very important for high resistance resistors. The general method for making a resistor in a mixed-signal integrated circuit is shown in Figure A. 'First, a substrate 101, a p-well 102, an N-well 103, an isolation element 110, and a sacrificial oxide layer 111 are provided. . A first polycrystalline silicon layer 120 is deposited on the sacrificial oxide layer 111, and then doped iso is implanted into the first polycrystalline silicon layer 120 by blanket implantation. First here
4 6 659 7 _ 五、發明說明(2) 晶矽層120是用以作為電阻器及電容器的下極板(bottom electrode),而摻質180的劑量則依電阻器的特性需要而 定β 一已經圖案轉移的遮罩1 3 〇,遮住第一多晶矽層1 2 0中 用以製作電阻器的位置’作為摻質181的植入遮罩,如第 一 Β圖所示。一般而言’利用摻質180及摻質181兩者劑量 的加成作用來達到電容器所需的特性要求。 其次,以傳統的方法將遮罩1 3 0移除後,將整個晶圓 放入熱爐中進行回火的步驟。接著,將電阻器及電容器的 圖案轉移至第一多晶矽層1 2〇 ’並對第一多晶矽層1 2 0進行 蝕刻的步驟,便形成一電阻器140及一電容器的下極板141 如第一 C圖所示。 以下在此底材 1〇1上完成一電晶體及一電容器,由於 此些形成的步驟為此一領域人士所習知,故在此並不加以 詳述°參照第一 D圖’以適當的方法形成了 一電晶體及一 電容器。電容器至少包含了下極板141及上極板142,而電 晶體的閘極1 4 3及上極板1 4 2皆以一第二多晶矽層為組成材 料。 然而上述傳統的方法如用在製作高電阻的電阻器時, 卻會產生許多的缺點。主要的缺點就是高電阻電性的控制4 6 659 7 _ V. Description of the invention (2) The crystalline silicon layer 120 is used as the bottom electrode of the resistor and capacitor, and the dose of dopant 180 depends on the characteristics of the resistor. Β- The mask 1330, which has been pattern-transferred, covers the position of the resistor used to make the resistor in the first polycrystalline silicon layer 120 as the implantation mask of dopant 181, as shown in the first figure B. Generally speaking, the additive properties of dopant 180 and dopant 181 are used to achieve the required characteristics of the capacitor. Secondly, after the mask 130 is removed in a conventional manner, the entire wafer is placed in a hot furnace for tempering. Next, the pattern of the resistor and the capacitor is transferred to the first polycrystalline silicon layer 120 ′ and the first polycrystalline silicon layer 120 is etched to form a resistor 140 and a lower plate of the capacitor. 141 as shown in the first figure C. In the following, a transistor and a capacitor are completed on this substrate 101. Since the formation steps are known to those skilled in the art, they are not described in detail here. The method forms a transistor and a capacitor. The capacitor includes at least a lower electrode plate 141 and an upper electrode plate 142, and the gate electrodes 143 and the upper electrode plates 142 of the transistors are each composed of a second polycrystalline silicon layer. However, the conventional method described above, when used in the manufacture of high-resistance resistors, has many disadvantages. The main disadvantage is the high resistance electrical control
第5頁 4 6 659 7 五、發明說明(3) ,傳統方法中離子植入及回火的步驟皆會造成不穩定的電 阻電性^在離子植入步驟階段可能造成摻質的深度過深, 而回火階段則可能造成摻質向外擴散,進而造成高電阻電 性的不易控制。 5 - 3發明目的及概述: 鑒於上述之發明背景中,傳統製作高電阻電阻器的諸 多缺點,本發明提供一在混合訊號積體電路中形成電阻器 的方法。在此方法中,利用雷射回火來代替一般熱爐回火 ,能有較佳的能量及反應時間控制。 本發明的另一目的在提供於混合訊號積體電路中形成 一具有高電阻電性之電阻器的方法。在此方法中,利用雷 射回火的步驟可同時得到一高電阻電性的電阻器及一具低 伏特係數(voltage coefficient)的電容器。 本發明的再一目的在提供於混合訊號積體電路中形成 一具有高電阻電性之電阻器及一電容器的方法。在此方法 中,雷射回火步驟所形成的介電層很薄,故很容易移除, 不會降低電容器的電容。 根據以上所述之目的,在本發明中,揭露一形成混合Page 5 4 6 659 7 V. Description of the Invention (3) Both the steps of ion implantation and tempering in the traditional method will cause unstable electrical resistance ^ At the stage of ion implantation, the depth of the dopant may be too deep However, the tempering stage may cause the dopants to diffuse outward, which in turn will cause difficult control of high resistance electrical properties. 5-3 Purpose and Summary of the Invention: In view of the above-mentioned backgrounds of the invention, many shortcomings of traditional high-resistance resistor manufacturing, the present invention provides a method for forming a resistor in a mixed signal integrated circuit. In this method, laser tempering is used instead of general furnace tempering, which has better energy and reaction time control. Another object of the present invention is to provide a method for forming a resistor with high electrical resistance in a mixed signal integrated circuit. In this method, a step of laser tempering can be used to simultaneously obtain a high-resistance electrical resistor and a capacitor with a low voltage coefficient. It is still another object of the present invention to provide a method for forming a resistor and a capacitor with high electrical resistance in a mixed signal integrated circuit. In this method, the dielectric layer formed by the laser tempering step is thin, so it can be easily removed without reducing the capacitance of the capacitor. According to the above-mentioned purpose, in the present invention, a forming mixture is disclosed
46 659 7 五、發明說明(4) 訊號積體電路中之電阻器及電容器的方法,此方法提供一 半導體結構’首先在半導體結構上沉積—第一多晶矽層, 並在第一多晶矽層中植入離子。接著,在第一多晶矽層上 以雷射回火的方法長出一妙化物層如氮化矽及氧化矽層, 此矽化物層的厚度可經由雷射的能量及操作時間得到良好 的控制。隨後,在第一多晶矽層上進行圖案移轉,移轉一 電阻器及一電容器之下極板的圖案至第—多晶矽層上。之 後’在電容器之下極板上形成一介電層,並在半導體結構 及介電層上沉積一第二多晶矽層。另一方面,在第二多晶 矽層上進行圖案移轉,移轉電容器之一上極板的圖案至第 二多晶矽層’上極板是位於該下極板的正上方,最後完成 一電容器與一電阻器的結構》 5~4發明詳細說明: 本發明的半導體設計可被廣泛地應用到許多半導體設 計中’並且可利用許多不同的半導體材料製作,當本發明 以一較佳實施例來說明本發明方法時,習知此領域的人士 應有的認知是許多的步驟可以改變,材料及雜質也可替換 ’這些一般的替換無疑地亦不脫離本發明的精神及範脅。 再者’本發明谷易在整體互補式金氧半導體中使用, 也可用在絕緣層上有石夕soi( silicon 〇n insulat〇r)上;46 659 7 V. Description of the invention (4) Method of resistors and capacitors in a signal integrated circuit, this method provides a semiconductor structure 'first deposited on the semiconductor structure-a first polycrystalline silicon layer, and Ions are implanted in the silicon layer. Next, a magic material layer such as silicon nitride and silicon oxide layer is grown on the first polycrystalline silicon layer by laser tempering. The thickness of the silicide layer can be obtained by laser energy and operation time. control. Subsequently, pattern transfer is performed on the first polycrystalline silicon layer, and the pattern of the electrode plate under a resistor and a capacitor is transferred to the first polycrystalline silicon layer. Thereafter, a dielectric layer is formed on the electrode plate below the capacitor, and a second polycrystalline silicon layer is deposited on the semiconductor structure and the dielectric layer. On the other hand, pattern transfer is performed on the second polycrystalline silicon layer, and the pattern of the upper electrode plate of one of the capacitors is transferred to the second polycrystalline silicon layer. The upper electrode plate is located directly above the lower electrode plate, and is finally completed. Structure of a Capacitor and a Resistor "5 ~ 4 Invention Detailed Description: The semiconductor design of the present invention can be widely used in many semiconductor designs' and can be made with many different semiconductor materials. When the present invention is implemented in a preferred way When explaining the method of the present invention by examples, those who are familiar with this field should recognize that many steps can be changed, and materials and impurities can be replaced. These general replacements undoubtedly do not depart from the spirit and scope of the present invention. Furthermore, the present invention is easy to use in the overall complementary metal-oxide semiconductor, and it can also be used on the insulating layer with silicon soin (silon insulat).
第7頁 46659 7 五、發明說明(5) 應有 因此,當本發明以與互補式金氧半導體配合說明時, 認知本發明可應用到廣泛的設計中。 其次’本發明用示意圖詳細描述如下,在詳述本 實施例時’表示半導體結構的剖面圖在半導體製程中 依一般比例作局部放大以利說明,然不應以此作為有限= 的認知《此外,在實際的製作中,應包含長度、寬度二 度的三維空間尺寸》 木 在 高電阻 半導體 植入離 出一矽 經由雷 一多晶 本發明方法中,揭露 電阻器的方法,此方 結構上沉積一第一多 子。接著,在第一多 化物層如氮化 射的能量及操 矽層上進行圖 F極板的圖案至第一 板上形成一介電層, 二多晶石夕層。另一方 ,移轉電容器之一上 ,上極板是位 辑包括上述閘 於該下 極。 矽及氧 作時間 案移轉 多晶珍 並在半 面,在 極板及 極板的 一形成混 法提供~ 晶妙層, 晶石夕層上 化矽層, 得到良好 ,移轉一 層上。之 導體結構 第二多晶 一閘極的 正上方, 合訊號 半導體 並在第 以雷射 此碎化 的控制 電阻器 後,在 及介電 $夕層上 圖案至 最後完 積體電路中之 結構,首先在 一多晶矽層中 方法長 厚度可 ,在第 及一電容器之 電容器之下極 層上沉積一第 進行圖案移轉 第二多晶珍層 成一電晶體結 回火的 物層的 。隨後 在一較佳實施例中,參照第二Α圖,首先提供—半導Page 7 46659 7 V. Description of the invention (5) Due to this, when the invention is described in conjunction with a complementary metal-oxide semiconductor, it is recognized that the invention can be applied to a wide range of designs. Secondly, “The present invention is described in detail with a schematic diagram below, and when this embodiment is described in detail.” The cross-sectional view showing the semiconductor structure is partially enlarged in the semiconductor manufacturing process at a general scale for the convenience of explanation. In actual production, it should include three-dimensional space dimensions of two degrees in length and width. In the method of the present invention, a method of exposing a resistor in a high-resistance semiconductor implanted with a silicon via a thunder-polycrystalline structure is disclosed. Deposit a first son. Next, the pattern of the F electrode plate is performed on the first polymer layer such as nitrided energy and silicon layer to form a dielectric layer and two polycrystalline silicon layers on the first plate. On the other hand, on one of the transfer capacitors, the upper plate is a bit including the above gate on the lower pole. The silicon and oxygen are transferred over time and the polycrystalline silicon is provided on the half surface by a mixed method of the polar plate and the polar plate. The crystal layer is formed on the crystal layer, and the silicon layer is formed on the crystal layer, which is well transferred. The conductor structure is directly above the second polycrystalline gate. After the signal semiconductor is combined with the first control resistor, it is patterned on the dielectric layer and the final integrated circuit structure. First, a method of long thickness may be used in a polycrystalline silicon layer. A first polycrystalline layer is deposited on the electrode layer under the capacitor of the first and first capacitors, and the second polycrystalline layer is patterned into a tempered material layer. Then, in a preferred embodiment, referring to the second A diagram,
466597 五、發明說明(6) 體底材1、一 P井2’ 一 N井3、一隔離元件10及一犧牲氧化 層1卜一第一多晶矽層2 0沉積在犧牲氧化層11 1上,接著 以覆毯式(blanket)離子植入的方式將摻質(圖上未示)植 入第一多晶矽層20中。其次,一已經圖案轉移的遮罩3〇, 遮住第一多晶矽層20中用以製作電阻器的位置,作為捧質 81的植入遮罩。在此的第一多晶矽層20是用以作為電阻器 及電容器的下極板(bolitoin electrode),另一方面,覆毯 式植入摻質的劑量依電阻器的特性需要而定,而利用覆毯 式植入摻質及摻質81兩者劑量的加成作用來達到電容器所 需的特性要求〇 ° 其次的步驟為本發明的重點,如第二B圖所示,先以 適當的方法移除遮罩30’接著,以激光雷射(excijner laser)取代熱爐’對晶圓進行回火的步驟。相較於熱爐回 火’雷射回火的能量及操作時間可以得到良好的控制,而 此回火的步驟是在一充滿氮氣、笑氣、一氧化氮、氧氣及 臭氧的環境中進行。 在雷射回火的步驟中,在第一多晶矽層20表面形成一 矽化物層5卜此矽化物層可以是氮化矽或氡化矽。必須加 以說明的是’藉由調整雷射的能量及操作時間可以準確控 制矽化物層51的厚度。再者,將電阻器及電容器的圖案轉 移至第一多晶矽層20 ’並對第一多晶矽層20進行蝕刻的步 驟’便形成一電阻器40及一電容器的下極板42如第二C圖466597 V. Description of the invention (6) Body substrate 1, a P well 2 ', an N well 3, an isolation element 10, and a sacrificial oxide layer 1 a first polycrystalline silicon layer 2 0 deposited on the sacrificial oxide layer 11 1 Then, a dopant (not shown) is implanted into the first polycrystalline silicon layer 20 by blanket ion implantation. Secondly, a mask 30 that has been pattern transferred covers the position of the resistor in the first polycrystalline silicon layer 20 to be used as an implantation mask of the substrate 81. Here, the first polycrystalline silicon layer 20 is used as a lower electrode (bolitoin electrode) of a resistor and a capacitor. On the other hand, the dose of a blanket implant dopant depends on the characteristics of the resistor, and The blanket type implant dopant and dopant 81 are added to achieve the required characteristics of the capacitor. The second step is the focus of the present invention. As shown in Figure 2B, The method removes the mask 30 ', and then the laser furnace (excijner laser) is used instead of the heating furnace' to temper the wafer. Compared with hot furnace tempering, the energy and operating time of laser tempering can be well controlled, and the tempering step is performed in an environment full of nitrogen, laughing gas, nitric oxide, oxygen and ozone. In the laser tempering step, a silicide layer is formed on the surface of the first polycrystalline silicon layer 20. The silicide layer may be silicon nitride or silicon halide. It must be explained that the thickness of the silicide layer 51 can be accurately controlled by adjusting the laser energy and operation time. Furthermore, the step of transferring the pattern of the resistor and the capacitor to the first polycrystalline silicon layer 20 ′ and etching the first polycrystalline silicon layer 20 ′ forms a resistor 40 and a lower plate 42 of a capacitor as in the first step. Figure C
第9頁 46 659 7 五、發明說明(7) 所示。 最後,在底材1、下極板42及電阻器40上先形成一介 電層(圖上未示),此介電層可以是高溫氧化層(high temperature oxide,ΗΤΟ)、氧化物一氮化物一氧化物( oxide-nitride-oxide,ΟΝΟ)或内多晶梦氧化物(interpoly oxide, IPO)。 再者 ,此介電層 形成的 溫度最好不超 過9 0 0°C,以減少熱處理(therma 1 eye 1 i ng)對半導體材 的影響,而介電層的厚度則介於2 0 0到5 0 0埃。此介電層的 作用是在減少氧化作用對電容器及電阻器的趨入侵蝕( encroachment) 〇接著,除了電容器上的介電層外,其餘 的介電層將被移除《然後沉積一第二多晶矽層於底材上, 以隨後圖案移轉及蝕刻步驟形成電容器的上極板43及一問 極44*再以適當的已知方法完成一電晶體如第二d圖所示 在本發明中,由雷射回火的方式在第一多晶矽層表面 形成氮化矽或氧化矽薄層不但可以阻止摻質向外擴散,亦 不會對電容器的電容產生衝擊。 以上所述僅為本發明之較佳實施例而已,並非用以限 定本發明之申請專利範圍;凡其它未脫離本發明所揭示之 精神下所完成之等效改變或修飾’均應包含在下述之申請 專利範圍内。Page 9 46 659 7 V. Description of the invention (7). Finally, a dielectric layer (not shown) is first formed on the substrate 1, the lower electrode plate 42 and the resistor 40. The dielectric layer may be a high temperature oxide (temperatureΤΟ), oxide-nitrogen Oxide-nitride-oxide (ONO) or interpoly oxide (IPO). In addition, the temperature for forming the dielectric layer is preferably not more than 900 ° C, so as to reduce the influence of heat treatment (therma 1 eye 1 i ng) on the semiconductor material, and the thickness of the dielectric layer is between 200 to 5 0 0 Angstroms. The role of this dielectric layer is to reduce the encroachment of capacitors and resistors due to oxidation. Next, in addition to the dielectric layer on the capacitor, the remaining dielectric layers will be removed, and then a second layer is deposited. The polycrystalline silicon layer is formed on the substrate, and the upper electrode plate 43 and the interrogation electrode 44 of the capacitor are formed by the subsequent pattern transfer and etching steps. Then, a transistor is completed by an appropriate known method. In the invention, forming a thin layer of silicon nitride or silicon oxide on the surface of the first polycrystalline silicon layer by means of laser tempering can not only prevent the dopants from diffusing outwards, but also will not have an impact on the capacitance of the capacitor. The above is only a preferred embodiment of the present invention, and is not intended to limit the scope of the patent application of the present invention; any other equivalent changes or modifications made without departing from the spirit disclosed by the present invention shall be included in the following Within the scope of patent application.
466597 圖式簡單說明 第一 A圖至第一 D圓以傳統製程製作一混合訊號積體電 路中的電阻器的簡示圖。 第二A圖至第二])圖為根據本發明製作一混合訊號積體 電路中的電阻器的簡示圖。 主要部分之代表符號’· 1 底材 2 P井 ‘ 3 N井 10 隔離元件 11 犧牲氧化層 2 0 第一多晶石夕層 30 遮罩 40 電阻器 42 下極板 43 上極板 44 閘極 81 摻質 82 氣體 101 底材 102 P 井 103 N 井 1 10 隔離元件466597 Schematic illustration of the first diagram A to the first D circle A conventional diagram for making a resistor in a mixed-signal integrated circuit using a conventional process. Figures 2A to 2]) are schematic diagrams of resistors in a mixed-signal integrated circuit according to the present invention. The main part of the symbol '· 1 substrate 2 P well' 3 N well 10 Isolating element 11 Sacrificial oxide layer 2 0 First polycrystalline layer 30 Mask 40 Resistor 42 Lower plate 43 Upper plate 44 Gate 81 Dopant 82 Gas 101 Substrate 102 P well 103 N well 1 10 Isolation element
46 659 7 圖式簡單說明 111 犧牲氧化層 120 第一多晶矽層 130 遮罩 140 電阻器 141 下極板 142 上極板 14 3 閘極 180 摻質 1 8 1 摻質46 659 7 Brief description of the diagram 111 Sacrificial oxide layer 120 First polycrystalline silicon layer 130 Mask 140 Resistor 141 Lower plate 142 Upper plate 14 3 Gate 180 Dopant 1 8 1 Dopant
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