315452 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（1 ) 發明背景 本發明係有關于一種洗濯衣物之標籤（也稱爲“洗衣貼 條”)之特性，符號（包括條碼），代表不同項目：顧客，洗衣 業者，清洗之衣物等資訊，從洗衣業者收到衣物，將其繫 在衣物上以在洗後歸還顧客，一種洗濯衣物之標籤片張及 其製造方法。 本發明特別係有關于一種洗濯衣物之標籤，其包括細 長的其體，及其一面的兩相對端提供黏層，該洗濯標藏以 穿過和相結合黏層之相對兩端，使標籤成爲一環圈繫在待 洗之衣物上。洗濯標籤繫上後，此衣物將乾洗或水洗。 相關技術 目前主要使用的洗濯衣物之標籤，通常包括一張抗水 紙基體，且標籤繫在洗濯物件上，及其一端具有一釘書針。 此情況下有一缺點，即訂書針可能會鉤住其它衣物，造成 它們的損壞。 日本專利説明書號碼Jikkai Hei 2-111178提出一種洗 濯衣物之標籤，其包括一細長的基體，及其相對端具有黏 層，將其穿過待洗物件，且黏層相結合以形成一環圈。標 籤繫上後，衣物將乾洗之。本案之目的在于使基體上之塑 膠薄膜層成薄片且在薄膜層上形成一黏層。 上述之習知技術的目的是盡可能的防止乾洗溶劑穿透 具有薄膜層的黏層。黏厝之實例限制在天然橡膠，苯乙烯 一丁二烯橡膠、多乙烯醇、乙烯酸樹脂。 在洗衣界，祝污垢的程度決定衣物用乾洗、水洗或先 (請先閲讀背面之注意事項再填寫本頁)315452 A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (1) Background of the invention The present invention relates to the characteristics of a label (also known as "laundry stickers") for washing clothes (including barcodes) , On behalf of different items: customers, laundry operators, washed clothing and other information, received laundry from the laundry industry, tied it to the clothing to return to customers after washing, a label sheet for washing clothing and its manufacturing method. The invention particularly relates to a label for washing clothes, which includes an elongated body, and two opposite ends of one side thereof provide an adhesive layer. The washing label is hidden through the opposite ends of the bonding adhesive layer, so that the label becomes A loop is attached to the clothes to be washed. After the washing label is attached, the clothes will be dry-cleaned or washed. Related Technology The label of washing clothes currently mainly used includes a sheet of water-resistant paper, and the label is attached to the washing object and has a staple at one end. In this case, there is a disadvantage that the staples may catch other clothes and cause them to be damaged. Japanese Patent Specification No. Jikkai Hei 2-111178 proposes a label for washing clothes, which includes an elongated base body, and an adhesive layer at opposite ends thereof, which is passed through the object to be washed, and the adhesive layers are combined to form a loop. After the label is attached, the clothes will be dry-cleaned. The purpose of this case is to make the plastic film layer on the substrate into a thin layer and form an adhesive layer on the film layer. The purpose of the above-mentioned conventional technology is to prevent the dry-cleaning solvent from penetrating the adhesive layer having the film layer as much as possible. Examples of adhesion are limited to natural rubber, styrene-butadiene rubber, polyvinyl alcohol, and vinyl acid resin. In the laundry industry, the degree of dirt is determined by dry cleaning, washing or first (please read the precautions on the back before filling this page)
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-1T 線 本紙張尺度逍用中國國家標準（CNS ) A4规格（210X297公釐） 315452 A7 B7 五、發明説明（2 ) 乾洗再水洗來處理。近來，最後一種組合洗濯處理逐漸增 加0 因此’洗瑕標藏之黏廣要求抗溶劑及抗水。本發明近 來研究頬示習知技術並無揭露具有抗溶劑及抗水、' 且習知技術僅解決標篯構造的問題，並非’ 已發現薄膜層的供應並非完善的解決。 本發明之目的係提供-種洗濯衣物之標藏，其 及抗水之功能極佳，以致能承受水洗和乾洗；及一 衣物之標藏的製造方法。 種洗灌 發明摘要 爲了克服上述問題，提供-種洗灌衣物之標藏 括-細長的基館，及其-側之相對端的黏層，將 部洗漆衣物，然後附著兩黏層，使成p = 洗濯衣物上，處理洗濯衣物，其特徵有 τ紙繁在 該黏廣由抗溶劑黏廣和抗水黏廣所構成且該黏 體之一側不同地方上形成。 曰仫ι 該基雜以紙製爲宜，且在基體上形成一液體 抗溶綱和抗水黏層，成在液體浸透防二 該液體浸透防止看，以具抗熱性之丙稀 成較佳，其無黏性且在溫度不高過18(rc下，、g乳劑製 該抗溶劑黏以形成在基體末端上較佳’,1會軟化。 層形成在相對于該抗溶劑層的内部。 孩抗水黏 較佳實施例中，該抗溶谢和抗水黏層，形成在基以 II - 1— · · ----=Γ--i<---^1裝-- *-% (請先閲讀背面之注意事項再填寫本頁) 線 經濟部中央樣準局貝工消费合作社印装 本紙張财S S家蘇（CNS ) A4胁（210X297公 經濟部中央棋準局員工消费合作社印製 315452 A7 _____B7 五、發明説明（3) 一側的一端上，且抗水黏層亦形成在及其同側的另一端 上，在此位置以致當標籤以黏層相結合成環圈時，之後形 成的抗水黏層朝向抗水黏廣。 上述之複數標箴，彼此並排，且暫時黏在經過片張可 撕處理之可撕片張。製造每張洗濯標籤片張首先的程序， 包括一細長的基體，及其一側之相對端上的黏層，將其穿 過待洗衣物之局部，然後在黏層上黏合，俾成一環圏，且 當標籤繫在待洗衣物上，此待洗衣物將處理，其步驟包括 當輸送可撕捲紙時，塗第一黏膠在雙面撕開處理的連 續捲紙上，其上形成在寬方向隔開之連續黏條，且乾後拿 起捲紙；提供加有第一黏膠的捲紙捲； 另一方面，塗第二黏膠在未加工的基體捲紙上，其上 形成在寬方向隔開之連續黏條，乾燥之，提供加有第二黏 膠的基體捲紙捲； 該第一黏膠之捲紙重疊在第二黏膠之基體捲紙上，俾 該第一和第二黏層置于同側内； 然後拿起重鲞捲紙，進入半成品捲筒； 從該半成品捲筒傳遞捲紙；及 、形成具有和經平坦片張操作的標蕺相同尺寸之縱切口 之基體，以提供包括撕紙上並排標藏的洗濯標籤片張。 製造洗濯標藏片張的第二個方法，包括細長的基體， 一側<相對端上之黏層，標籤穿過洗濯衣物之局部，然後 黏看彼此黏著，俾標藏成環狀，且當標藏繫上洗濯衣物處 理洗灌物件，包括步驟如下： 6-1T line This paper scale is used Chinese national standard (CNS) A4 specification (210X297mm) 315452 A7 B7 V. Description of invention (2) Dry cleaning and then washing. Recently, the last combination of washing treatments has gradually increased by 0. Therefore, the viscosity of the 'clean spots' standard requires extensive resistance to solvents and water. The present invention's recent research on the conventional technology does not disclose that it has solvent resistance and water resistance, and the conventional technology only solves the problem of the mark structure, not that it has been found that the supply of the thin film layer is not a perfect solution. The object of the present invention is to provide a standard collection of laundry, which has excellent water resistance and can withstand washing and dry cleaning; and a method for manufacturing the standard collection of clothing. In order to overcome the above problems, we provide a standard collection of washing and irrigation clothes including an elongated base, and the adhesive layer on the opposite end of the side, wash the clothing, and then attach the two adhesive layers to make p = Washing clothes, processing washing clothes, characterized by τ paper complex formed by the solvent resistance and water resistance adhesion, and formed on different places on one side of the adhesive body. The base is preferably made of paper, and a liquid anti-solvent class and a water-resistant adhesive layer are formed on the substrate, so as to prevent the liquid from penetrating. The liquid is prevented from seeping, preferably with heat-resistant acrylic. It is non-tacky and at a temperature not higher than 18 ° C, it is better for the anti-solvent viscosity of the emulsion to form on the end of the substrate. It will soften. The layer is formed inside the anti-solvent layer. In the preferred embodiment of the anti-water adhesion, the anti-dissolution and anti-water adhesion layer is formed on the basis of II-1-· ---- = Γ--i < --- ^ 1 device-*-% ( Please read the precautions on the back and then fill out this page) The Ministry of Economic Affairs, Central Bureau of Standards, Pui Kung Consumer Cooperative Printed Paper Cai SS Su (CNS) A4 threat (printed by 210X297, Ministry of Economic Affairs, Central Bureau of Chess Bureau, Consumer Cooperative 315452 A7 _____B7 5. Description of the invention (3) One end on one side, and the water-resistant adhesive layer is also formed on the other end on the same side, at this position so that when the label is combined with the adhesive layer to form a ring, after The formed water-resistant adhesive layer is wide toward the water-resistant adhesive. The above plural standard symbols are placed side by side and temporarily adhered to the sheet after tearing treatment Tearable sheet. The first procedure for manufacturing each washable label sheet includes a slender base and the adhesive layer on the opposite end of one side, passing it through the part of the laundry, and then bonding on the adhesive layer , To form a ring, and when the label is attached to the laundry, the laundry will be processed. The steps include when conveying the tearable roll paper, applying the first adhesive on the continuous roll paper that is torn up on both sides. It is formed with continuous adhesive strips spaced apart in the width direction, and after drying, the roll paper is picked up; a roll paper roll with a first glue is provided; on the other hand, a second glue is coated on the raw substrate roll paper, Continuous adhesive strips spaced apart in the width direction are formed thereon, and dried to provide a base roll of paper with a second adhesive; the roll of the first sticky paper is superimposed on the base of the second roll, so that The first and second adhesive layers are placed on the same side; then pick up the heavy roll paper and enter the semi-finished roll; transfer the roll paper from the semi-finished roll; and, form the same size as the standard sheet-operated label The base of the longitudinal cut to provide washing including the side by side marks on the tear paper The second method of making a lamination label sheet, including an elongated substrate, an adhesive layer on one side < the opposite end, the label passing through the laundered clothing part, and then sticking to each other to hide the label It is ring-shaped, and when washing clothes on the standard collection system, the steps are as follows: 6
(請先閲讀背面之注意事項再填寫本頁) 裝_ 訂 線 經濟部中央揉隼局員工消費合作社印裝 315452 A7 B7 五、發明説明（4) 當输送第一單面可撕處理捲紙時，塗第一黏膠在單面 撕開處理的連續捲紙上，其上形成在寬方向隔開之連續黏 條，且在基體捲紙上重疊捲紙，乾後拿起重疊捲紙； 另一方面，塗第二黏膠在未加工的基體捲紙上，其上 形成在寬方向隔開之連續黏條，乾燥之以提供第二黏膠覆 加重疊基體捲紙； 該第一黏膠覆加捲紙，重疊在該第二黏膠所塗之未加 工的捲紙上，俾該第一和第二黏層位于同側上； 從該基體捲紙撕開該第一單面撕開捲紙，以供給基體 片張至附著位置； 該基體捲紙黏于該第二黏膠覆加之重疊捲紙上，拿起 捲紙進入半成品捲筒； 從該半成品捲筒傳遞捲紙；及 形成具有和經平坦片張操作的標蕺相同尺寸之縱切口 之基體，以提供包括撕紙上之並排標籤之洗濯標籤片張。 本發明之洗濯衣物之標籤，用于乾洗及水洗，極爲有 利。 洗灌衣物之標籤，包括細長的基體，例如抗水紙製基 體，及其一側上端部之黏層。標藏穿過局部待洗物件:例如: 鈕扣孔，衣領商標，之後，黏層彼此附著，俾成環狀。當 標籤繫在待洗物件上後，清洗處理，例如乾洗及水洗。 根據本發明，該黏層包括抗溶劑黏層及抗水黏層，形 成在基體之不同地方上。 因此，即使在乾洗期間使用溶劑，抗水黏膠之黏著力 (請先閲讀背面之注意事項再填寫本頁) .裝 訂 線 本紙張尺度逍用中國國家標準（CNS ) A4規格（210X2?7公釐） 經濟部中央揉準局貞工消費合作社印裝 315452 五、發明説明（5) 將降低，抗溶劑黏膠將維持必贫 ^, 眾的連結力。其後，雖然用 于水洗，抗溶劑黏膠之黏著力陰 , 降低，抗水黏膠將維持必愛 <連結力。因此，整個清洗期間，洗灌㈣料會脱落需 :使由于和溶劑或水接觸，使得黏著力降低，在 水接_束後’_未溶解于溶劑或水，: 向回復原來的黏著力。因此，根據本發明，即使其它^ 黏著力降低’但由于黏層之黏著力，標藏維持環狀，防： 標藏脱落。若乾洗完成，抗水黏著力將回復，當用于 時，標籤能持久。所以，本發明之結構能有效地作用。 曾經研究抗溶劑黏層重整在抗水黏廣上。若因接每冷 劑或水，使得黏廣之一之黏著力降低，例如，抗水黏^ 黏著力降低，可能因環圏無支撐而發生黏層間分離。結果， 無法執行最初的作用。 ’ 本發明較佳爲抗溶劑形成在基體末端上，及其内倒形 成抗水黏層。以環圈連結之標籤，在末端比在内側容易^ 落。因此，因爲先以乾洗處理，所以爲了防土脱落，抗溶 劑黏層形成在基體的末端。 & 本發明的較佳實施例中，抗溶劑黏層和抗水黏層形成 在基體一側上之一端，在基體之同側另一端上，亦形成抗 水黏層，當標箴以相對兩端黏著成環狀時，抗水黏屬朝向 之前的抗水黏層。因此，當使用洗濯標籤時，抗水黏層彼 此重疊，顯出抗水黏層所謂的自黏。 水洗持續一段期間30至60分鐘，較乾洗時間约5至 1〇分鐘長，以致連結力大爲降低。從抗水黏層塗在基敢， 丰纸張尺i逍用中國国家榡準（CNS) Μ见^_ (21〇><297公董） ----£--------Ν——裳—— -t {碕先閑讀背面之注意事¾再填寫本頁〕 -訂 經濟部中央揉準局員工消費合作杜印製 315452 A7 B7 五、發明説明（6) 經過充足時間後，以產品遞送到洗衣店。經過這段時間， 抗水黏膠在基體浸溼，以致黏層堅固地連結基體，因爲抗 水黏層相互地顯出自黏，自連結力很大。因此，預防脱落 之連結力，較洗衣者先黏抗水黏層至相對環圏基體就使用 之連結力大。結果，能得到耐水洗之標籤。 另一方面，若黏層在基體之相對兩端形成，由于黏層 的存在，將難以穿過鈕扣孔。雖然黏層形成在標籤之單一 端較易于進入鈕扣孔，但在標籤之另一端要塗抗水黏層， 使水洗時可持久。能只形成一抗溶劑黏膠，得到抗乾洗之 效果。而另一端只形成抗水黏層，但不形成抗溶劑黏層； 能融合容易進入鈕扣孔及抗水洗兩優點。 鍫于降低成本，基體以紙製較佳。紙製基體能印刷不 同項目之資訊，較塑膠片張爲佳。 以這樣的方式，紙製基體有很大的好處。與這個對照 下，甚至抗水紙張也使用紙製基體，而乾洗及水洗用之液 體將貫穿紙製基體，將降低抗溶劑及抗水黏層之連結力。 因此，在紙製基體上形成液體穿透防止層，且在液體 穿透防止層上形成抗溶劑和抗木黏層較佳。 液體穿透防止層具抗熱性且黏力較佳，在溫度不高于 180 °C下，不會軟化。具這些物理特性的材料，包括溶劑 型多元酯，多元酯塑膠及丙烯酸樹脂乳劑等等。尤其，赛 于丙烯酸樹脂乳劑頬似黏層，最好挑選丙烯酸樹脂乳劑。 而材料顯出黏力將阻礙穿過鈕扣孔。因爲在洗灌完成後可 能需整燙，需避免由于熱熨斗的熱力，使黏膠軟化，造成 本紙張尺度逍用中國國家揉準（CNS ) A4規格（210X297公釐） , ^ ΐ ^ 訂 ^線 -** (請先閲讀背面之注意事項再填寫本頁) 315452 經濟部中央揉準局員工消費合作社印製 A7 B7 五、發明説明（7) 洗淨之衣物變髒。因此，挑選具抗熱性之材料，在溫度不 高過180 °C下，不致軟化。 洗灌標箴片張包括複數洗濯標箴，彼此並排且暫時連 結在可撕處理片張。洗衣店從撕紙上撕去每張洗濯標籤， 且繫在待洗衣物上。 圖式之簡單説明 第1圖是立體圖，其繪示本發明之洗濯標籤之第一基 本實施例； 第2圏是縱斷面圖，其繪示洗濯衣物上之洗濯標籤的 附著： 第3圖是平面圖，其繪示覆加黏層之修正版； 第4圖是平面圖，其繪示覆加黏層之另一修正版； 第5圖是立體圖，其繪示本發明之洗濯標籤之第二基 本實施例； 第6圖是立體圖，其繪示第5圖之洗濯衣物之標蕺； 第7圏是縱斷面圖，其繪示洗濯衣物之標箴的附著； 第8圖是概要圖，其繪示本發明之第一基本實施例之 洗灌標籤的第一製造方法之第一步驟； 第9周是概要圖，其繪示第8圖之製造方法的第二步 驟； 第10圖是説明圖，其繪示平坦紙張操作； 第11圖是立體圖，其繪示黏膠之覆加方法； 第12圖是立體圖，其繪示黏膠之另一覆加方法； 第13圖是概要圖，其繪示本發明之第二基本實施例之 本紙張尺度適用中國國家揉準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) 裝- 經濟部中央樣準局貝工消費合作社印裝 *15452 五、發明説明（8 / 洗灌標籤的第二製造方法之第一步碌； 第14圖是概要圖，其績示第13®的方法之第二步樣； 第15圖是概要阐，其繪示第13圖的方法之第三步驟； 第16圖是平面圖’其繪示平坦紙張方法； 第17圖是縱斷面圖，其繪示本發明之洗灌標籤之第三 基本實施例； 第18圖是説明® ’其繪示視爲洗灌㈣之-例； 第19圖是説明圖，其績示視爲標箴之另-例； 第20圖是説明圏，其繪示視爲標藏之再一例；及 第21圖是平面圖，其繪示在標箴之一側上操作。 實施例的説明 本發明將以實施例配合圖式，作更進一步描述。 基本實施例1 參考第1和第2圖，其繪示本發明之洗濯衣物之標籤 T。標籤T包括紙1之細長抗水基體，及其上一端之不同 地方，所形成之抗溶劑黏層和抗水黏層。 本發明之較佳實施例中，基體丨之末端上，形成抗溶 劑黏層2，且層2之内側之基體上，形成抗水黏層3 因爲在使用前，露出黏層2和3，處理標籤τ將不容 易，所以標籤Τ將暫時黏上可撕紙張4。在使用標籤τ時， 才撕去可撕開紙張4。然後在標籤τ之端部上，穿過待洗 物件例如襯衫的鈕扣孔，且黏層2和3在另一端部結合使 標籤成一環圏。標藏繫上待洗物件後，衣物將乾洗或水洗。 知看第2圖，當標藏成環.形，一端部容易從另一端部 (請先閲讀背面之注意事項再填寫本頁) 裝 11 經濟部中央梂準局貝工消費合作杜印裝 A7 、__________B7 五、發明説明（9) 撕開。首先以乾洗處理。因此，抗溶劑黏層2形成在基體 1之末端側，且抗水黏層3形成在廣2之内側内。然而， 層2和層3能根據黏劑的選擇，互換位置。 如第3圖所繪示，黏層2和3沿著長度，以g形形成 在標篯T之上。再者，黏層2和3也能以第4圖所繪示的 點方式形成。黏層2和3在基體1上不同地方所形成之棑 列並無限制。黏層2和3就所在之不同位置，能部分重疊（， 但一黏層完全包括在另一黏層内除外）。標藏τ之尺寸和形 狀大約依據應用來挑選。洗濯標箴大約寬1公分、長8公 分之尺寸最常用。 基本實施例2 雖然上述之實施例中，抗溶劑黏層2和抗水黏層3， 沿著長度之一端形成在基體1上，但最好抗溶劑黏曆2和 抗水黏層3Α，形成在基體1之一端，而抗水黏層3Β形成 在基體之另一端，俾當使用標籤成環狀時，抗水層3Β面 向抗水層3Α，如第5圖到第7所繪。第7圖繪示附在衣 物（衣物未圖示）上》 當基體1爲紙製時，在基體之一側上，形成液體浸透 防止層5 ’其上形成黏層2，3Α和3Β爲較佳。抗溶劑黏 層2和抗水黏層3Α、3Β分別形成在液體浸透防止層上。 液體浸透防止層以丙烯酸樹脂乳劑製成較佳，無黏 性，且具抗熱性，在溫度不高于180 °C下，不會軟化。 第一製造方法（利用雙面可撕紙張)標籤T，特別是第1 圖所繪示者’能如下所製出：當輸送兩端皆經過碎鲷可撕處 <請先閲讀背面之注意ί項再填寫本貫) • fc-.- --1 ί 0 - 1 -裝. 訂 本紙張尺度適用中國因家棣準（CNS) A4規格（21〇χ297公釐） 經濟部中央橾準局負工消費合作社印装 315452 A7 ________ B7 五了發明説明（1$ ~ ~ 理之可撕片$10之捲紙時，如第8圏所繪示，捲紙不斷地 經由覆加機器11 ’塗上第一黏膠，例如，抗水黏膠3沿著 長度，以條隔開方式加入。在捲紙用乾燥器12使乾後拿 起，以提供第一黏膠覆加捲紙捲。雖然黏膠以條方式，塗 在同一圖上(標示在第9圖），黏膠未顯出條纹。 另一方面，如第9圖所繪示，當從捲2〇輸送基體捲紙 1，連續地經由覆加機器21之裝置塗上第二黏膠，例如， 抗溶劍黏膝2沿著長度，以條隔開方式塗上。在捲紙乾燥 後，第一黏膠從捲13覆上捲紙，且第二抗溶劑黏膠從捲 20覆上捲紙’此一捲紙由重要捲23彼此重疊，俾第一和 第二黏層3和2在同側上，因爲半成品捲24拿起重疊捲 紙。此情況下，在覆加和重疊位置，捲紙已完成排成直線， 俾第一和第二黏層2和3，彼此相鄰近。 其後，傳遞半成品捲24之捲紙。基體割成標籤τ，經 由平坦紙張操作，在可撕紙張上，每個皆具預定尺寸。基 體1A捲紙（包括黏層）除可撕紙張4A外，提供縱切口 s， 且沿著切割線C切割，成爲標篯T之長度，以提供每個具 預定長度之重疊紙張。重疊紙張包括可撕紙張4，具預定 尺寸應用複數標籤。 在使用標篯T，每張標箴A撕去可撕紙張4，且在所 需資訊寫上後，繫上待洗衣物。 合適的覆加機用來塗上黏膠。間斷的覆加機30，如第 11歯所繪示，爲較好之使用。當使用此型之覆加機，難以 以條覆加。因此，黏膠之阻塞以薄膜31例如多元酯薄膜形 本紙張尺度逍用中國國家標準（CNS ) Μ規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) .裝. 、π 經濟部中央梂準局貝工消費合作杜印袋 A7 ______ B7 __ 五、發明説明（12) 成。縱切口 3 la在寬方向以隔開方式形成。黏膠塗在縱切 口 31a之間。 或者，如第12圖所繪示使用，幕狀覆加劑之覆加頂端 32A和32B在寬方向排列。此情況下，從覆加頂端32A和 32B塗上黏膠，俾彼此部分重疊。其餘覆加劑，諸如氣刀 覆加劑，影印版覆加劑，刀覆加劑，滾筒覆加劑，雖未舉 例，但皆可使用。 第二製造方法（利用單面可撕紙張） 在第一製造方法，使用雙面可撕處理紙張。而使用雙 面紙張有若干問題。第一，當不同項目資訊，在標籤成爲 成品後，印在洗濯標箴之外側上，由于雙面可撕紙張之背 側的長頁，難以導引排成列。第二，因爲基體i通過乾燥 機之間，從第9圖可明顯看出，將發生整個寬度，收縮約 3mm。在先前所塗的抗水黏膠3和抗溶劑黏膠2之間，發 生寬度方向位置之錯排。 第三，因爲黏膠3和2分別黏在張力調整滾筒14，25 上，如虛線所類示，需拿起捲紙以旁通捲筒。結果，良好 張力控制很困難。 反之’使用單面撕紙如下文描述，能較佳地完成製造。 將描述有關第5至第7圖之洗濯標籤之製造。首先， 當基體捲紙1從捲40傳遞，如第13圖所繪示，液體穿透 防止層5藉由接觸覆加機41，覆加在大體上整個表面，通 過乾燥機42間使乾燥。其後，因爲基體捲43拿起基體捲 紙1A。 本紙張从速財s s家(210><297公釐） Ί. ； ^ 裝 訂 ,線 (請先閱讀背面之注意Ϋ項再填寫本頁) A7 315452 B7 五、發明説明（13) 其後，第一單面可撕處理捲紙從第14圖顯示之捲筒輸 送，第一黏膠3A，3B由覆加機21，不斷地在寬度方向， 以條隔開方式塗上。在乾後，從基體捲43傳遞之基體捲紙 1A上將重疊，然後拿起以提供第一黏膠覆加捲紙捲45。 另一方面，當第二單面可撕處理捲紙，如第15圖所繪 示，從捲筒46傳遞，第2黏膠2在寬度方向，以條隔開方 式，不斷地塗在捲紙上；且乾燥之以提供第二黏膠覆加重 疊捲紙。第一黏膠覆加重疊捲紙從捲筒45傳遞。第一單面 撕紙44，從覆有第一黏膠3A，3B之基體捲紙1A撕除。 在塗加位置上只供應基體紙張1A，在圖例中，基體捲紙 1A黏在第二黏膠覆加重疊捲紙的重疊捲筒23，且因爲半 成品捲筒，拿起重疊織物。 捲紙不用合成半成品捲筒47,因爲大體上類似第1製 造方法。捲筒切割標籤T，由照像版操作每個皆具預定尺 寸，如第16圖所繪示，提供包括標蕺T塗上第二撕紙之重 疊捲紙。即，形成具縱切口之捲紙，在標藏T之寬度隔開。 經由沿切割線C切割捲紙，在標籤T之長度隔開，重疊紙 張在左、右方向具預定長度。 雖然，抗溶劑黏膠和抗水黏膠包括上述已知之黏膠， 丙烯黏膠能較佳地使用。尤其，交鏈型黏膠更佳。水洗使 用溶劑型異氰酸鑒交鏈丙烯酸黏膠。乾洗使用水可溶解的 環氧交鏈丙烯酸黏膠。所塗黏膠之數量爲：乾覆加膜之厚 度10至ΙΟΟμπι，20至50μιη更佳，且覆加重量爲10至 70g/m2，尤其是30至50g/m2更佳。 本紙張尺度逍用中國國家標準（CNS ) A4規格（210X297公釐） ------^--i 1裝------訂-----《線 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央揉準局員工消費合作社印策 A7 A7 經濟部中央揉率局员工消費合作社印裝 b/ 五、發明説明（14) 鑒于成本，雖然本發明之基體以紙製較佳，但薄膜、 拆開的織物或薄片片張也可使用。用于書寫的特性，標藏 上之符號或條碼代表不同項目的資訊，而就可書寫性來 説，紙製效果較佳。爲了增加抗水和抗溶劑和可書寫力， 塗上或注入不同處理藥劑在未塗黏膠的基體面上。 上述液體穿透防止層5,也可充做用于黏看2、3A和 3B之底塗層。若處理乾洗和水洗之組合，液體穿透防止層 能抗tricrene和水。因爲用于整燙之黏層具有較佳抗熱性， 抗熱丙稀酸乳劑，尤其是抗熱丙稀酸乳劑交鍵甲搭液較 佳。特別地，抗熱材料包括單獨不同的丙烯酸酯或甲基丙 烯酸聚合物，或加有醋酸乙烯、苯乙烯、丙烯睛、丙稀酸 胺、丙烯酸、甲基丙烯酸之共聚物。 液體穿透防止層5之覆加層重量爲3至20g/m2較佳， 最佳爲3至10g/m2。 液體透防止層5能以塑膠薄片層6代替或一同形成， 如第17圖所繪示，在紙製基體1之相對側上，没有形成黏 層之側上成形。因爲聚乙烯會因熨斗之熱而熔化，所以薄 片層6之材料以抗熱性佳之聚丙烯爲較佳。薄片廣6在熱 熔化下，能黏合在紙製基體上或適合的熱炫化黏膠。 '〆 第18至20圖爲第5圖之第二基本實施例，在洗濯標 籤上資訊之識^一例，顯示 代表不同資訊項之條碼和件數，分別在標篯中心摺線的左 邊和右邊上。第18(B)圖爲標籤條碼和件數，在標藏之左 邊。第18(C)圖爲分別在左邊和右邊上的標藏名字和件數。 16 本紙張尺度適用中國國家揉準（CNS ) A4规格（2丨〇><297公釐 . ^~~ n J— ^ 裝 II 訂 (線 (請先閲讀背面之注意事項再填寫本頁) 315452 經濟部中央搮準局員工消費合作社印製 A7 B7 五、發明説明（15) 此識別能在第1圖的第一基本實施例的洗濯標籤上，同樣 地實施。此例在第19和20圖。在第21圖，標籤一端斜切， 使標箴能容易地插入。本發明之標籤不侷限于這些圖示説 明。 如上描述，考慮成本，弩曲特性及碰觸，基體以紙製 較佳。然而，水洗時這種洗濯標篯不能完全防止水穿透， 且在洗衣機内將遭受強大的切變力水流。結果，紙製基體 内可能發生層間分離。 若標籤之相對端彼此重疊，且以釘書針固定，問題較 少，因爲訂書針將防止洗濯標籤從衣物脱落。與此對照， 洗濯標箴僅以黏膠繫在衣物上，沒使用訂書針。紙之特性 (内部結合）[參考標準TAPPIUM-403,584]在紙製基體Z軸 方向（垂直表面之方向）之活動脱落強度以2.5至4.Okg/cm 較佳，尤其是3.0至3.5kg-cm。浸溼後之強度[JIS P 8135] 以4.5至6.5較佳，而縱的方向（製紙方向）和3.0至5.0更 佳，側面的方向3.8至4.5kg更佳。 實驗例 從實驗例中，本發明之優點將更清楚。 實驗例1: 之前的範例以丙烯酸交鏈型黏膠較佳。不同的實驗使 用此型的黏膠處理。 如表1所示，商業上可從5業者得到全部9種黏膠， 改變硬化劑之數量，塗用于紙製基體上。其後，紙製基體 切割成尺寸爲1公分*8公分之長方形標籤。 17 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） " I丨-ΊΓ--1丨裝-------訂-----1線 (請先閲讀背面之注意事項再填寫本頁) A7 ----B7 五、發明説明（16) 測量13種標藏，關于其抗水洗及抗乾洗。試劑包括 0.5%高分子清潔劑，〇·5〇/〇過碳酸破，及〇 5%甲基硅酸鹽 蛤，按照JIS L 0844之Α-4及Α_5決定抗乾洗性。使用由 Japan Energy有限公司所預製之石油溶劑“WHITE Nl〇”， 決定如下處理實驗之抗性：指吞樣本彼此黏著，且浸于液 «I内。液It藉由磁挽器挽動30秒。然後樣本從液雜取出。 結果在表1標示，X代表樣本顯㈣積分開，△代表樣本 面積没分開’但明顯地降低結合力，而ο代表樣本面積没 分開》且大體上没有降低結合力。 結果顯出沒有一種樣本符合所有的需要。 — 1 -----------^ ——裝— β ^ * (請先閱讀背面之注意事項再填寫本頁) 經濟部中央揉準局貝工消費合作社印裝 樣本 _號碼 黏镠 硬化劑 (數量） ia. A&.—. 「 一- - 玩通氣乙 烯 抚溶膠 抗鲶水 ii 1 A Co.Sl 2.0 Δ — w--- 〇 異氰酸盪 交鏈 2 3 4 B Co.SI 1.0 1.5 2.0 X X X X X X 〇 〇 〇 異氰酸籃 交鍵 5 B Co.S2 X 3Γ~~ 〇 自交鍵乳 0 C Co.Sl 1.7 △~〇 Δ^Ο~ 〇 異氰酸逢 交鍵 7 8 9 10 C Co.S2 D Co.Sl~ 0.5 1.0 2.0 L5 ' Δ 〇 g_ Δ 〇 x- X △ Δ_ 〇 水環氧基 交鏈 交鐽 11 DCo.S2 0.24 X X~~~ 〇 異氰酸蘯 12 E Co S 1 2.0 X *x 0 異氰酸鹽 13 E Co.S2 2.0 X X 〇 異氰酸鹽 交鏠 L----1(Please read the precautions on the back before filling out this page) Packing _ 315452 A7 B7 Printed by the Employees ’Cooperative of the Central Knead Falcon Bureau of the Ministry of Economic Affairs 5. Description of the invention (4) When conveying the first single-sided tearable roll paper , Apply the first adhesive on the continuous roll paper with one-sided tearing process, and form continuous sticky strips separated in the width direction, and overlap the roll paper on the base roll paper, and pick up the overlap roll paper after drying; , Apply the second adhesive on the raw substrate roll paper, and form continuous adhesive strips spaced apart in the width direction on it, and dry it to provide the second adhesive cover plus the overlapping substrate roll paper; the first adhesive cover plus roll Paper, overlaid on the raw roll paper coated with the second adhesive, so that the first and second adhesive layers are on the same side; tear the first single-sided tear roll paper from the base roll paper, to The substrate sheet is supplied to the attachment position; the substrate roll paper is adhered to the overlapping roll paper covered by the second adhesive, and the roll paper is picked up to enter a semi-finished product roll; the roll paper is transferred from the semi-finished product roll; The base of the longitudinal cut of the same size with the operation of Zhang is Washing label sheet comprising a label of the sheets side by side on the tear. The laundry label of the present invention is very useful for dry cleaning and washing. Labels for washing and irrigating clothing include an elongated substrate, such as a water-repellent paper substrate, and an adhesive layer on the upper end of one side. The mark goes through the local items to be washed: for example: button holes, collar marks, and then, the adhesive layers are attached to each other in a loop. After the label is attached to the object to be washed, it is cleaned, such as dry cleaning and water washing. According to the present invention, the adhesive layer includes a solvent-resistant adhesive layer and a water-resistant adhesive layer, which are formed on different parts of the substrate. Therefore, even if the solvent is used during dry cleaning, the adhesion of the water-resistant adhesive (please read the precautions on the back before filling in this page). The paper size of the binding line is used in the Chinese National Standard (CNS) A4 specification (210X2? 7 %) Printed 315452 of the Zhengong Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs V. Description of the invention (5) It will be reduced, and the solvent-resistant adhesive will remain impoverished ^, the public's connection. Afterwards, although it is used for washing with water, the adhesive strength of the solvent-resistant adhesive decreases, and the water-resistant adhesive will maintain the binding strength. Therefore, during the entire cleaning period, the irrigation and irrigation materials will fall off: the contact force will be reduced due to contact with the solvent or water. After the water is connected, it will not be dissolved in the solvent or water, and the original adhesion force will be restored. Therefore, according to the present invention, even if the adhesive force of the other adhesives is reduced, the mark remains ring-shaped due to the adhesive force of the adhesive layer, preventing: the mark from falling off. If dry cleaning is completed, the water-resistant adhesion will be restored, and when used, the label will last. Therefore, the structure of the present invention can effectively function. I have studied the reforming of the solvent-resistant adhesive layer on the water-resistant adhesive layer. If the coolant or water is connected, the adhesive strength of one of the adhesives will be reduced. For example, the water-resistant adhesive ^ adhesive strength will decrease, and the separation of the adhesive layers may occur due to the unsupported ring. As a result, the original role cannot be performed. In the present invention, it is preferred that the solvent-resistant layer is formed on the end of the substrate, and that the water-resistant adhesive layer is formed inside. A label connected by a loop is easier to fall at the end than at the inside. Therefore, because dry cleaning is applied first, in order to prevent the soil from falling off, a solvent-resistant adhesive layer is formed at the end of the substrate. & In the preferred embodiment of the present invention, the solvent-resistant adhesive layer and the water-resistant adhesive layer are formed on one end on one side of the substrate, and the water-resistant adhesive layer is also formed on the other end on the same side of the substrate. When the two ends stick to form a ring, the water-resistant adhesive belongs to the previous water-resistant adhesive layer. Therefore, when the washing label is used, the water-resistant adhesive layer overlaps with each other, showing the so-called self-adhesiveness of the water-resistant adhesive layer. The washing lasts for a period of 30 to 60 minutes, which is about 5 to 10 minutes longer than the dry cleaning time, so that the bonding power is greatly reduced. From the water-resistant adhesive layer coated on Kigan, Feng paper ruler I used the Chinese National Standard (CNS) Μ ^ _ (21〇 > < 297 Gongdong) ---- £ ------ --Ν—— 體 —— -t {Jian first read the notes on the back ¾ fill in this page] -Subscribe to the consumer cooperation of the Ministry of Economic Affairs Central Bureau of Printing and Printing 315452 A7 B7 V. Description of the invention (6) After sufficient time, deliver the product to the laundry. After this period of time, the water-resistant adhesive soaked in the substrate, so that the adhesive layer was firmly connected to the substrate, because the water-resistant adhesive layer showed self-adhesion to each other, and the self-bonding force was great. Therefore, the connection force to prevent falling off is greater than the one used by the laundry to stick the water-resistant adhesive layer to the ring base. As a result, a water-resistant label can be obtained. On the other hand, if the adhesive layer is formed on the opposite ends of the substrate, it will be difficult to pass through the button hole due to the presence of the adhesive layer. Although the adhesive layer is formed on the single end of the label, it is easier to enter the button hole, but the other end of the label should be coated with a water-resistant adhesive layer to make it durable when washed. Only a solvent-resistant adhesive can be formed to obtain the anti-dry cleaning effect. At the other end, only a water-resistant adhesive layer is formed, but no solvent-resistant adhesive layer is formed; it has the advantages of being easy to enter into the button hole and being resistant to water washing. In order to reduce costs, the substrate is preferably made of paper. Paper substrates can print information on different items, which is better than plastic sheets. In this way, the paper substrate has great advantages. In contrast to this, even water-resistant paper uses a paper substrate, and the liquid for dry cleaning and washing will penetrate the paper substrate, which will reduce the bonding power of the solvent-resistant and water-resistant adhesive layers. Therefore, it is preferable to form a liquid penetration preventing layer on the paper substrate, and to form a solvent-resistant and wood-resistant adhesive layer on the liquid penetration preventing layer. The liquid penetration prevention layer has heat resistance and better adhesion, and will not soften at a temperature not higher than 180 ° C. Materials with these physical properties include solvent-based polyesters, polyester plastics, and acrylic resin emulsions. In particular, it is best to choose acrylic resin emulsions for acrylic resin emulsions like sticky layers. The sticky force of the material will prevent it from passing through the button hole. Because ironing may be necessary after washing and irrigation, it is necessary to avoid the softening of the adhesive due to the heat of the hot iron, which will cause the paper size to be used in the Chinese National Standard (CNS) A4 specification (210X297 mm), ^ Ι ^ Order ^ Line-** (please read the precautions on the back before filling in this page) 315452 Printed A7 B7 by the Employee Consumer Cooperative of the Central Bureau of Economic Cooperation of the Ministry of Economic Affairs 5. Invention Instructions (7) Washed clothes become dirty. Therefore, choose materials with heat resistance that will not soften at a temperature not higher than 180 ° C. The irrigation and irrigation standard sheets include a plurality of washing and labeling sheets, side by side and temporarily connected to the tearable sheet. The laundry removes each washing label from the torn paper and attaches it to the laundry. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a perspective view showing the first basic embodiment of the washing label of the present invention; FIG. 2 is a longitudinal sectional view showing the attachment of the washing label on the washing clothes: FIG. 3 It is a plan view showing a modified version covered with an adhesive layer; FIG. 4 is a plan view showing another modified version covered with an adhesive layer; FIG. 5 is a perspective view showing the second washing label of the present invention Basic embodiment; FIG. 6 is a perspective view showing the standard of washing clothes in FIG. 5; 7th ring is a longitudinal sectional view showing the attachment of standard clothes in washing clothes; FIG. 8 is a schematic view, It shows the first step of the first manufacturing method of the washing and filling label of the first basic embodiment of the present invention; Week 9 is a schematic diagram, which shows the second step of the manufacturing method of FIG. 8; FIG. 10 is Explanatory drawing showing the operation of flat paper; Figure 11 is a perspective view showing a method of applying adhesive; Figure 12 is a perspective view showing another method of applying adhesive; Figure 13 is a schematic view , Which shows that the paper standard of the second basic embodiment of the present invention is suitable for Chinese national kneading. (CNS) A4 specification (210X297mm) (please read the notes on the back before filling in this page) Packing-Printed by the Central Sample Bureau of the Ministry of Economic Affairs Beigong Consumer Cooperative * 15452 Fifth, invention description (8 / washing and filling label) The first step of the second manufacturing method; Figure 14 is a schematic diagram showing the second step of the 13th method; Figure 15 is a schematic diagram showing the third step of the 13th method ; Figure 16 is a plan view 'which shows a flat paper method; Figure 17 is a longitudinal section view, which shows a third basic embodiment of the irrigation label of the present invention; Figure 18 is an illustration ®' It shows the view It is an example of washing and irrigation; Figure 19 is an explanatory diagram, and its performance is regarded as another example of standard Zhen; Figure 20 is an illustration, and its illustration is regarded as another example of standard collection; and Figure 21 is The plan view, which is illustrated on one side of the standard. The description of the embodiments of the present invention will be further described in conjunction with the drawings. Basic Embodiment 1 Referring to FIGS. 1 and 2, which depicts the present invention The label T for washing clothes. The label T consists of an elongated water-resistant substrate of paper 1 and different places on the upper end The solvent-resistant adhesive layer and the water-resistant adhesive layer are formed. In a preferred embodiment of the present invention, a solvent-resistant adhesive layer 2 is formed on the end of the substrate, and a water-resistant adhesive layer 3 is formed on the substrate inside the layer 2 because Before use, the adhesive layers 2 and 3 are exposed, and handling the label τ will not be easy, so the label T will temporarily be attached to the tearable paper 4. When the label τ is used, the tearable paper 4 is only torn off. At the end, pass through the button hole of the item to be washed, such as a shirt, and the adhesive layers 2 and 3 are combined at the other end to make the label form a ring. After the item to be washed is placed on the mark, the clothes will be dry-cleaned or washed. 2 Picture, when the mark is hidden in a ring shape, one end is easy to get from the other end (please read the precautions on the back and then fill out this page). Pack 11 The Central Bureau of Economic Affairs, Ministry of Economic Affairs, Shell Industry Consumer Cooperation Du Printing Pack A7, __________B7 3. Description of the invention (9) Tear open. Dry clean first. Therefore, the solvent-resistant adhesive layer 2 is formed on the end side of the base body 1, and the water-resistant adhesive layer 3 is formed inside the can 2. However, Layer 2 and Layer 3 can switch positions depending on the choice of adhesive. As shown in FIG. 3, the adhesive layers 2 and 3 are formed on the mark T in a g-shape along the length. Furthermore, the adhesive layers 2 and 3 can also be formed in the manner of dots shown in FIG. The formation of the adhesive layers 2 and 3 in the substrate 1 in different places is not limited. Adhesive layers 2 and 3 are located at different positions and can partially overlap (except that one adhesive layer is completely included in the other adhesive layer). The size and shape of the marked τ will be selected according to the application. The size of Xiao Biaozhen is about 1 cm wide and 8 cm long. Basic Embodiment 2 Although in the above embodiments, the solvent-resistant adhesive layer 2 and the water-resistant adhesive layer 3 are formed on the substrate 1 along one end of the length, it is preferable that the solvent-resistant adhesive layer 2 and the water-resistant adhesive layer 3A are formed At one end of the base 1, and the water-resistant adhesive layer 3B is formed at the other end of the base, when the label is formed into a ring, the water-resistant layer 3B faces the water-resistant layer 3A, as depicted in FIGS. 5 to 7. Figure 7 shows attached to clothing (clothes not shown) >> When the substrate 1 is made of paper, on one side of the substrate, a liquid permeation prevention layer 5 'is formed on which an adhesive layer 2, 3Α and 3Β are formed good. The solvent-resistant adhesive layer 2 and the water-resistant adhesive layers 3A and 3B are formed on the liquid penetration preventing layer, respectively. The liquid penetration prevention layer is made of acrylic resin emulsion, which is non-sticky and heat-resistant. It will not soften at a temperature not higher than 180 ° C. The first manufacturing method (using double-sided tearable paper) label T, especially the one shown in Figure 1 'can be produced as follows: when both ends of the conveying pass through the tearing place of sea bream < please read the note on the back ί item and fill in the original version) • fc -.- --1 ί 0-1 -installation. The size of the paper is applicable to the China Indigenous Standards (CNS) A4 specification (21〇 × 297 mm) Central Ministry of Economic Affairs 315452 A7 ________ B7 printed by the Negative Consumers Cooperative Co., Ltd. When the description of the invention (1 $ ~ ~ $ 10 of the reasonable tearable sheet, as shown in the 8th circle, the roll paper is continuously coated by the coating machine 11 ' The first adhesive, for example, water-resistant adhesive 3, is added in strips along the length. After the roll paper is dried by the dryer 12, it is picked up to provide the first adhesive coating roll. The glue is applied on the same picture in a stripe manner (marked in Figure 9), and the adhesive does not show streaks. On the other hand, as shown in Figure 9, when the substrate roll paper 1 is transported from the roll 20, continuous The second adhesive is applied by the device of the coating machine 21, for example, the anti-solvent sword stick knee 2 is applied along the length in a stripped manner. After the roll paper is dried, the first The adhesive rolls the roll paper from roll 13, and the second solvent-resistant adhesive rolls roll paper from roll 20. This roll of paper overlaps each other by the important roll 23, so that the first and second adhesive layers 3 and 2 are on the same side , Because the semi-finished roll 24 picks up the overlapping roll paper. In this case, at the overlaying and overlapping positions, the roll paper has been lined up so that the first and second adhesive layers 2 and 3 are adjacent to each other. Thereafter, transfer Roll paper of semi-finished roll 24. The base is cut into labels τ, and each of them has a predetermined size on the tearable paper through a flat paper operation. The base 1A roll paper (including the adhesive layer) provides longitudinal slits in addition to the tearable paper 4A s, and cut along the cutting line C to become the length of the mark T, to provide each overlapped paper with a predetermined length. The overlapped paper includes tearable paper 4, with a predetermined size to apply multiple labels. When using the mark T, each Zhang Biaozhen A tears off the tearable paper 4, and after writing the required information, fasten the laundry. A suitable coating machine is used to apply the glue. The intermittent coating machine 30 is shown in the 11th , For better use. When using this type of coating machine, it is difficult to apply by strip. Therefore, the adhesive For blocking, use the film 31, such as a polyester film, to use the paper standard. The Chinese National Standard (CNS) Μ specification (210X297mm) (please read the precautions on the back before filling out this page). Install., Π Ministry of Economic Affairs The quasi-regular shellfish consumer cooperation du printing bag A7 ______ B7 __ V. Description of the invention (12). The longitudinal slits 3 la are formed in a spaced manner in the width direction. The adhesive is applied between the longitudinal slits 31a. Or, as the 12th As shown in the drawing, the curtain-shaped coating additives are applied with the top ends 32A and 32B arranged in the width direction. In this case, the adhesive tops 32A and 32B are coated with adhesive to partially overlap each other. The remaining coating agents, such as Air knife coating additives, photocopier coating additives, knife coating additives, roller coating additives, although not exemplified, can be used. Second manufacturing method (using single-sided tearable paper) In the first manufacturing method, double-sided tearable paper is used. There are several problems with using double-sided paper. First, when different items of information are printed on the outside of the label after the label is finished, the long pages on the back of the double-sided tearable paper make it difficult to guide the rows. Second, because the substrate i passes between the dryers, it is clear from Figure 9 that the entire width will occur, shrinking by about 3 mm. Between the water-resistant adhesive 3 and the solvent-resistant adhesive 2 previously applied, misalignment in the width direction occurs. Third, because the adhesives 3 and 2 stick to the tension adjustment rollers 14, 25, respectively, as indicated by the dotted line, the roll paper needs to be picked up to bypass the roll. As a result, good tension control is difficult. Conversely, the use of single-sided tear paper as described below can better complete the manufacturing. The manufacturing of the washing label in FIGS. 5 to 7 will be described. First, when the substrate roll paper 1 is transferred from the roll 40, as shown in FIG. 13, the liquid penetration preventing layer 5 is applied to substantially the entire surface by contacting the coater 41, and is dried between the dryers 42. Thereafter, because the base roll 43 picks up the base roll paper 1A. This paper is from Suicai's home (210 > < 297mm) Ί.; ^ Binding, thread (please read the note Ϋ on the back before filling in this page) A7 315452 B7 V. Description of invention (13) A single-sided tearable roll paper is transported from the roll shown in Fig. 14, and the first adhesives 3A, 3B are continuously coated by the stripper in the width direction by the coating machine 21. After drying, the substrate roll paper 1A transferred from the substrate roll 43 will overlap, and then picked up to provide the first adhesive coated roll paper 45. On the other hand, when the second single-sided tearable roll paper, as shown in Figure 15, is transferred from the roll 46, the second adhesive 2 is continuously coated on the roll paper in the width direction, separated by strips ; And dried to provide a second adhesive overlay plus overlapping roll paper. The first adhesive coated and overlapped roll paper is transferred from the reel 45. The first single-sided tearing paper 44 is torn off from the base roll paper 1A covered with the first adhesive 3A, 3B. Only the base paper 1A is supplied at the application position. In the illustration, the base roll paper 1A is stuck to the second roll 23 of the second adhesive covering the overlap roll paper, and because of the semi-finished roll, the overlap fabric is picked up. The roll paper does not need a synthetic semi-finished reel 47, because it is basically similar to the first manufacturing method. The roll-cut labels T, each of which has a predetermined size by the photo-plate operation, as shown in FIG. 16, provide a stack of rolled paper including the label T coated with the second tear paper. That is, the roll paper formed with the longitudinal slits is separated by the width of the mark T. By cutting the roll paper along the cutting line C, separated by the length of the label T, the overlapped paper has a predetermined length in the left and right directions. Although solvent-resistant adhesives and water-resistant adhesives include the above-mentioned known adhesives, acrylic adhesives can be preferably used. In particular, cross-linked viscose is better. Water-washing uses solvent-based isocyanate cross-linked acrylic viscose. Dry-cleaning uses water-soluble epoxy cross-linked acrylic viscose. The amount of adhesive applied is: the thickness of the dry coating film is 10 to 100 μm, preferably 20 to 50 μm, and the coating weight is 10 to 70 g / m2, especially 30 to 50 g / m2. This paper standard uses the Chinese National Standard (CNS) A4 specification (210X297mm) ------ ^-i 1 pack ------ order ----- "line (please read the back of the first (Notes to fill out this page) A7 A7 Employee Consumer Cooperative of the Central Kneading Bureau of the Ministry of Economic Affairs A7 A7 Employee Consumer Cooperative of the Central Kneading Rate Bureau of the Ministry of Economic Affairs b / V. Description of the invention (14) Given the cost, although the substrate of the present invention is paper The preparation is better, but films, unwoven fabrics or sheet sheets can also be used. The characteristics used for writing, the symbols or barcodes on the mark represent the information of different items, and in terms of writeability, the paper is better. In order to increase water resistance, solvent resistance and writeability, different treatment agents are coated or injected on the uncoated substrate surface. The above-mentioned liquid penetration preventing layer 5 can also be used as an undercoat layer for sticking to 2, 3A and 3B. If a combination of dry cleaning and water washing is handled, the liquid penetration prevention layer is resistant to tricrene and water. Because the adhesive layer used for ironing has better heat resistance, heat-resistant acrylic acid emulsions, especially heat-resistant acrylic acid emulsions, are better. In particular, the heat-resistant materials include individually different acrylate or methacrylic acid polymers, or copolymers added with vinyl acetate, styrene, acrylonitrile, acrylic amine, acrylic acid, methacrylic acid. The coating weight of the liquid penetration preventing layer 5 is preferably 3 to 20 g / m2, and most preferably 3 to 10 g / m2. The liquid permeation preventing layer 5 can be replaced with a plastic sheet layer 6 or formed together. As shown in FIG. 17, on the opposite side of the paper substrate 1, the side on which the adhesive layer is not formed is formed. Since the polyethylene will melt due to the heat of the iron, the material of the sheet layer 6 is preferably polypropylene with good heat resistance. The thin sheet 6 can be glued to a paper substrate or a suitable hot dazzling adhesive when it is melted by heat. '〆 Figures 18 to 20 are the second basic embodiment of Figure 5, an example of information recognition on the washing label ^ an example, showing the bar code and the number of pieces representing different information items, respectively on the left and right of the center line . Figure 18 (B) shows the label barcode and the number of items, on the left side of the mark. Figure 18 (C) shows the name and number of the collection on the left and right, respectively. 16 This paper scale is applicable to China National Standard (CNS) A4 (2 丨 〇 < 297mm. ^ ~~ n J— ^ Binding II binding (line (please read the precautions on the back before filling this page ) 315452 A7 B7 printed by the Employee Consumer Cooperative of the Central Department of Economics of the Ministry of Economic Affairs 5. Description of the invention (15) This identification can be implemented in the same way on the washing label of the first basic embodiment of FIG. 1. Figure 20. In Figure 21, one end of the label is chamfered so that the standard can be easily inserted. The label of the present invention is not limited to these illustrations. As described above, considering the cost, crossbow characteristics and touch, the substrate is made of paper It is better. However, this washing mark can't completely prevent the water from penetrating during washing, and will suffer a strong shear force water flow in the washing machine. As a result, layer separation may occur in the paper substrate. If the opposite ends of the labels overlap each other , And fixed with staples, the problem is less, because the staples will prevent the washing label from falling out of the clothing. In contrast, the washing label is only attached to the clothing with viscose, and the staple is not used. The characteristics of paper ( Internal combination) [reference standard TAPPIUM -403,584] The movable shedding strength in the Z-axis direction (the direction perpendicular to the surface) of the paper substrate is preferably 2.5 to 4.0 kg / cm, especially 3.0 to 3.5 kg-cm. Strength after wetting [JIS P 8135] It is preferably 4.5 to 6.5, while the longitudinal direction (paper making direction) and 3.0 to 5.0 are more preferred, and the side direction is 3.8 to 4.5 kg. Experimental Examples From the experimental examples, the advantages of the present invention will be more clear. Experimental Example 1 : The previous example is better with acrylic cross-linking adhesive. Different experiments use this type of adhesive treatment. As shown in Table 1, all 9 types of adhesives are commercially available from 5 vendors, changing the amount of hardener, Coated on paper substrate. Afterwards, the paper substrate is cut into rectangular labels with a size of 1 cm * 8 cm. 17 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) " I 丨- ΊΓ--1 丨 installed ------- order ----- 1 line (please read the precautions on the back before filling in this page) A7 ---- B7 5. Description of the invention (16) 13 kinds of measurements Standard collection, regarding its resistance to water washing and dry cleaning. Reagents include 0.5% polymer detergent, 〇5〇 / 〇Percarbonic acid broken, and 〇5% methyl silicate For clams, the dry cleaning resistance is determined in accordance with A-4 and A_5 of JIS L 0844. Using the petroleum solvent "WHITE Nl〇" pre-made by Japan Energy Co., Ltd., the resistance of the treatment experiment is determined as follows: the swallowing samples stick to each other and are soaked In liquid «I. Liquid It is pulled by a magnetic puller for 30 seconds. Then the sample is taken out of the liquid impurities. The results are shown in Table 1, X represents the sample display and integral, △ represents the sample area is not separated 'but significantly reduced The binding force, and ο means that the sample area is not separated ”and does not substantially reduce the binding force. The results show that no one sample meets all needs. — 1 ----------- ^ —— 装 — β ^ * (Please read the precautions on the back before filling in this page) Printed sample_Number Sticky Lutetium hardener (quantity) ia. A & .—. "One--Play Ventilation Ethylene Fossil Sol Anti-catfish ii 1 A Co.Sl 2.0 Δ — w --- 〇Isocyanic acid swing chain 2 3 4 B Co .SI 1.0 1.5 2.0 XXXXXX 〇〇〇 isocyanate basket cross bond 5 B Co.S2 X 3Γ ~~ 〇 self-crosslinking milk 0 C Co.Sl 1.7 △ ~ 〇Δ ^ Ο ~ 〇isocyanate cross bond 7 8 9 10 C Co.S2 D Co.Sl ~ 0.5 1.0 2.0 L5 'Δ 〇g_ Δ 〇x- X △ Δ_ 〇Water epoxy cross-linked cross-linked 11 DCo.S2 0.24 XX ~~~ 〇Isocyanate 12 E Co S 1 2.0 X * x 0 isocyanate 13 E Co. S2 2.0 XX 〇Isocyanate crossover L ---- 1
例驗 X 8 1Α 訂 Λ線 本紙張尺度逍用中國國家榡準（CNS ) Α4规格（210X25»7公釐） 修正0ί期:85.0以〆 第84110987號説明書修正買 1 五、發明説明（17 一挑選樣本6和9來製造第1圖繪示之標籤，實驗77 顯不較佳疋結果。相似的貧驗樣本顯示不會發生分離。因 此，目前的生產機器依照上述之製造方法製造許多樣本。 請 先 閲 讀 背 面 意 事 項 再' 填 本 頁 ^上，標蕺穿過5G件衣物的纽扣孔，將之乾洗7分鐘和 水洗40分鐘。標藏皆不分開。 實驗例3: 一挑選樣本6和9來製造第1圈繪示之標籤，貧驗 顯π較佳《結果。相似的實驗顯示樣本不會發生分離。實 際上，洗灌標蕺穿過50件衣物的紐扣孔，以更嚴苛的情 況’將之乾洗15分鐘和水浩如公拉樓 顯千出兹Μ ρ 第1圖之洗濯標藏 ^出乾洗後，並無分離。而水洗後兩張標_示分離。 第5和第6圖之洗濯標藏沒有分離。 實驗例4: 訂 挑選樣本6和9來製造第i圖緣示之標藏，實驗i中 =較佳之結果。相似的實驗顯示樣本不會發生分離。實 際，洗灌標籤穿過1〇〇件衣物的紐扣孔，％件只乾洗 刀鐘，另5〇件只水洗議分鐘。每件乾洗皆沒發生分離。 ^據本發明，提供—種抗溶劑和抗水性優良之洗灌標 載，其可乾洗且/或水洗處理。 19 本紙張你(2獻297公羡Examination X 8 1Α set Λ line paper size to use the Chinese National Standard (CNS) Α4 specifications (210X25 »7mm) Amendment 0ί: 85.0 amended to buy according to 〆No. 84110987 1 V. Invention description (17 One sample 6 and 9 were selected to make the label shown in Figure 1. Experiment 77 showed poor results. Similar poorly tested samples showed no separation. Therefore, the current production machine makes many samples according to the above-mentioned manufacturing method . Please read the notes on the back before 'fill in this page ^, mark the button hole through 5G pieces of clothing, dry it for 7 minutes and wash it for 40 minutes. The standard collection is not separated. Experimental example 3: one select sample 6 Use 9 to make the label shown in the first circle. The poor test shows π is better. Results. Similar experiments show that the sample will not separate. In fact, the washing and irrigation standard passes through the button hole of 50 pieces of clothing to make it more strict Severe conditions' dry cleaning for 15 minutes and Shui Haoru Gongla Lou Xianqianzi M ρ The washing mark of Figure 1 is stored ^ After dry cleaning, there is no separation. The two marks after washing are separated. There is no separation from the wash pool in Figure 6. Experimental Example 4: Order Choose samples 6 and 9 to make the label shown in the edge of Figure i. Experiment i = better result. Similar experiments show that the samples will not separate. In fact, the irrigation label passes through the button hole of 100 pieces of clothing. % Of the pieces are only dry-cleaning knife clocks, and the other 50 pieces are only water-washing minutes. There is no separation of each piece of dry-cleaning. ^ According to the present invention, a washing and filling standard with excellent solvent resistance and water resistance is provided, which can be dry cleaned and / or Washing treatment. 19 paper you (2 offer 297 public envy