TW201837125A - Anti-mosquito and pest control water-based coating and the method making the same - Google Patents
Anti-mosquito and pest control water-based coating and the method making the same Download PDFInfo
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- TW201837125A TW201837125A TW106112427A TW106112427A TW201837125A TW 201837125 A TW201837125 A TW 201837125A TW 106112427 A TW106112427 A TW 106112427A TW 106112427 A TW106112427 A TW 106112427A TW 201837125 A TW201837125 A TW 201837125A
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- essential oil
- resin
- composite resin
- based paint
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 230000001442 anti-mosquito Effects 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000000576 coating method Methods 0.000 title abstract description 23
- 239000011248 coating agent Substances 0.000 title abstract description 17
- 241000607479 Yersinia pestis Species 0.000 title abstract 5
- 239000000341 volatile oil Substances 0.000 claims abstract description 109
- 239000000805 composite resin Substances 0.000 claims abstract description 59
- 239000002904 solvent Substances 0.000 claims abstract description 21
- 239000003973 paint Substances 0.000 claims description 37
- 229910010293 ceramic material Inorganic materials 0.000 claims description 36
- 239000003292 glue Substances 0.000 claims description 35
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000011368 organic material Substances 0.000 claims description 13
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 9
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 5
- LNOLJFCCYQZFBQ-BUHFOSPRSA-N (ne)-n-[(4-nitrophenyl)-phenylmethylidene]hydroxylamine Chemical compound C=1C=C([N+]([O-])=O)C=CC=1C(=N/O)/C1=CC=CC=C1 LNOLJFCCYQZFBQ-BUHFOSPRSA-N 0.000 claims description 4
- 241000218645 Cedrus Species 0.000 claims description 4
- 244000223760 Cinnamomum zeylanicum Species 0.000 claims description 4
- 235000005979 Citrus limon Nutrition 0.000 claims description 4
- 244000131522 Citrus pyriformis Species 0.000 claims description 4
- 244000166675 Cymbopogon nardus Species 0.000 claims description 4
- 235000018791 Cymbopogon nardus Nutrition 0.000 claims description 4
- 241000208152 Geranium Species 0.000 claims description 4
- 241000721662 Juniperus Species 0.000 claims description 4
- 244000178870 Lavandula angustifolia Species 0.000 claims description 4
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 4
- 244000246386 Mentha pulegium Species 0.000 claims description 4
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 4
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 4
- 235000010676 Ocimum basilicum Nutrition 0.000 claims description 4
- 240000007926 Ocimum gratissimum Species 0.000 claims description 4
- 240000002505 Pogostemon cablin Species 0.000 claims description 4
- 235000011751 Pogostemon cablin Nutrition 0.000 claims description 4
- 229920003180 amino resin Polymers 0.000 claims description 4
- 235000017803 cinnamon Nutrition 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 4
- 235000001050 hortel pimenta Nutrition 0.000 claims description 4
- 239000001102 lavandula vera Substances 0.000 claims description 4
- 235000018219 lavender Nutrition 0.000 claims description 4
- 239000005011 phenolic resin Substances 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 244000004281 Eucalyptus maculata Species 0.000 claims description 3
- 244000223014 Syzygium aromaticum Species 0.000 claims description 3
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 2
- 150000007524 organic acids Chemical class 0.000 description 10
- 239000000243 solution Substances 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 7
- 125000003342 alkenyl group Chemical group 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 6
- 125000001188 haloalkyl group Chemical group 0.000 description 6
- 241000255925 Diptera Species 0.000 description 5
- 125000000304 alkynyl group Chemical group 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 125000006239 protecting group Chemical group 0.000 description 4
- 238000003980 solgel method Methods 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229920000578 graft copolymer Polymers 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000010436 fluorite Substances 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 239000000077 insect repellent Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000010634 clove oil Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- GQYHUHYESMUTHG-UHFFFAOYSA-N lithium niobate Chemical compound [Li+].[O-][Nb](=O)=O GQYHUHYESMUTHG-UHFFFAOYSA-N 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- UORVCLMRJXCDCP-UHFFFAOYSA-N propynoic acid Chemical compound OC(=O)C#C UORVCLMRJXCDCP-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052950 sphalerite Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
本發明係有一種水性塗料，其特別有關於一種具有精油氣味的防蚊蟲水性塗料。 The present invention is directed to an aqueous coating which is particularly useful in an anti-mosquito waterborne coating having an essential oil odor.
台灣地處亞熱帶，一年四季都會有蚊蟲。特別是在炎熱夏日，幾乎是蚊蟲肆虐的季節。目前市場上的驅蚊噴劑型產品使用防蚊精油加水稀釋做成噴劑，使用的時效都不夠長。 Taiwan is located in the subtropical zone and has mosquitoes throughout the year. Especially on hot summer days, it is almost a season of mosquitoes. At present, the insect repellent spray type products on the market are diluted with anti-mosquito essential oil and water to make a spray, and the aging time is not long enough.
如果可以直接在居家的牆壁或家具上塗上長效的塗料，將可以克服上述問題。塗料所涵蓋的範圍較廣，包含傳統的油性塗料(即油漆)、以及合成樹脂為主要原料生產的溶劑型塗料和水性塗料等等。傳統所使用的塗料是以油脂和天然樹脂為主要原料，目前並逐漸利用成本較低的合成樹脂作為塗料的主要原料。塗料可以用不同的施工方式塗覆在物件表面，於乾燥後形成黏附牢固且具有強度的連續性固態薄膜。早期塗料大多以植物油為主要原料，因此被稱為油漆。油漆是油性塗料的俗稱，以有機溶劑為介質或高固體、無溶劑的油性漆，通常由液態展色劑和固體顏料組成。然而，傳統的塗料多含有大量有機物，具有令人不舒服的強烈氣味，且由於分子過大與化學性質，與精油幾乎無法互溶。 If you can apply long-lasting paint directly to your home's walls or furniture, you will be able to overcome the above problems. Coatings cover a wide range of traditional oil-based coatings (ie, paints), as well as solvent-based coatings and water-based coatings produced from synthetic resins. The coatings used in the past are mainly oils and natural resins, and the low-cost synthetic resins are currently being used as the main raw materials for coatings. The coating can be applied to the surface of the article by different application methods to form a solid film with a strong adhesion and strength after drying. Most of the early paints used vegetable oil as the main raw material, so it was called paint. Paint is a common name for oil-based paints. It is an organic solvent or a high-solid, solvent-free oil paint. It is usually composed of a liquid developer and a solid pigment. However, conventional paints contain a large amount of organic matter, have an unpleasant strong odor, and are almost incompatible with essential oils due to excessive molecular and chemical properties.
有鑑於此，有必要提出一種具有防蚊蟲水性塗料與 其製程方法。 In view of this, it is necessary to propose a water-repellent coating with anti-mosquito and a process method thereof.
本發明主要在提供一種防蚊蟲水性塗料，採用環保無毒的製程，且使用安全方便，可以在物品上長效地發出淡淡清香的氣味，提昇住家防蚊蟲的效果。 The invention mainly provides an anti-mosquito water-based paint, adopts an environmentally-friendly and non-toxic process, and is safe and convenient to use, and can emit a light and fragrant smell on the article for a long time, thereby improving the anti-mosquito effect of the home.
為達本發明之主要目的，本發明提出一種防蚊蟲水性塗料，包含一精油與一複合樹脂膠所形成，並溶於一溶劑中形成該防蚊蟲水性塗料；其中該精油在該精油與該複合樹脂膠的整體重量的比例是介於1%至10%之間；以及該複合樹脂膠在該精油與該複合樹脂膠的整體重量的比例是介於99%至90%之間，該複合樹脂膠係由一有機材料與一無機奈米陶瓷材料經由化學接枝所形成，該複合樹脂膠之該無機奈米陶瓷材料之粉體尺寸係介於10奈米至100奈米之間。 In order to achieve the main object of the present invention, the present invention provides an anti-mosquito water-based paint comprising an essential oil and a composite resin glue, and is dissolved in a solvent to form the anti-mosquito water-based paint; wherein the essential oil is compounded with the essential oil The ratio of the overall weight of the resin glue is between 1% and 10%; and the ratio of the composite resin glue to the total weight of the essential oil and the composite resin glue is between 99% and 90%, the composite resin The glue is formed by chemical grafting of an organic material and an inorganic nano ceramic material, and the inorganic nano ceramic material of the composite resin has a powder size of between 10 nm and 100 nm.
較佳地，該無機奈米陶瓷材料係選自奈米氧化鋁、奈米氧化矽與奈米氧化鈦所組成之族群。 Preferably, the inorganic nano ceramic material is selected from the group consisting of nano alumina, nano cerium oxide and nano titanium oxide.
為達本發明之次要目的，本發明提出一種防蚊蟲水性塗料的製作方法，包含下列步驟：製備一無機奈米陶瓷材料，該無機奈米陶瓷材料之粉體尺寸係介於10奈米至100奈米之間；混合一有機材料與該無機奈米陶瓷材料形成一複合樹脂膠；混合一精油與該複合樹脂膠並溶於一溶劑中形成一水性塗料；其中該精油在該精油與該複合樹脂膠的整體重量的比例是介於1%至10%之間，且該複合樹脂膠在該精油與該複合樹脂膠的整體重量的比例是介於99%至90%之間。 In order to achieve the secondary object of the present invention, the present invention provides a method for preparing an anti-mosquito water-based paint, comprising the steps of: preparing an inorganic nano-ceramic material having a powder size of 10 nm to Between 100 nm; mixing an organic material and the inorganic nano ceramic material to form a composite resin glue; mixing an essential oil with the composite resin glue and dissolving in a solvent to form an aqueous coating; wherein the essential oil is in the essential oil The ratio of the overall weight of the composite resin glue is between 1% and 10%, and the ratio of the composite resin glue to the total weight of the essential oil and the composite resin glue is between 99% and 90%.
較佳地，該無機奈米陶瓷材料係選自奈米氧化鋁、 奈米氧化矽與奈米氧化鈦所組成之族群。 Preferably, the inorganic nano ceramic material is selected from the group consisting of nano alumina, nano cerium oxide and nano titanium oxide.
藉由本發明之防蚊蟲水性塗料與其製程方法，人工的化學性精油與天然的植物性精油經可以輕易地融入到複合樹脂內。該防蚊蟲水性塗料採用環保低污染的製程方法，所有的材料都不具毒性，且製作方式簡單迅速，使用該防蚊蟲水性塗料於物品、家具或建築物牆壁上，可以持續發出淡淡的精油，特別是植物的氣味，防止各種蚊蟲的靠近，進而提高生活的品質。 By the anti-mosquito water-based paint of the present invention and the process method thereof, the artificial chemical essential oil and the natural plant essential oil can be easily incorporated into the composite resin. The anti-mosquito water-based paint adopts an environmentally-friendly and low-pollution process method, all materials are not toxic, and the production method is simple and rapid, and the anti-mosquito water-based paint can be used to continuously emit a light essential oil on the wall of articles, furniture or buildings, in particular It is the smell of plants, preventing the proximity of various mosquitoes and improving the quality of life.
為讓本發明之上述和其他目的、特徵、和優點能更明顯易懂，下文特舉數個較佳實施例，並配合所附圖式，作詳細說明如下。 The above and other objects, features, and advantages of the present invention will become more apparent and understood.
圖1顯示本發明之防蚊蟲水性塗料的製程流程圖。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a flow chart showing the process of the anti-mosquito water-based paint of the present invention.
雖然本發明可表現為不同形式之實施例，但附圖所示者及於本文中說明者係為本發明可之較佳實施例。熟習此項技術者將瞭解，本文所特定描述且在附圖中繪示之裝置及方法係考量為本發明之一範例，非限制性例示性實施例，且本發明之範疇僅由申請專利範圍加以界定。結合一例示性實施例繪示或描述之特徵可與其他實施例之儲特徵進行結合。此等修飾及變動將包括於本發明之範疇內。 While the invention may be embodied in a variety of forms, the embodiments shown in the drawings and illustrated herein are the preferred embodiments of the invention. Those skilled in the art will appreciate that the devices and methods specifically described herein and illustrated in the drawings are considered as an example of the invention, non-limiting exemplary embodiments, and the scope of the invention Defined. Features illustrated or described in connection with an exemplary embodiment may be combined with the storage features of other embodiments. Such modifications and variations are intended to be included within the scope of the invention.
本發明將揭示一種防蚊蟲水性塗料，包含一精油與一複合樹脂膠並溶於一溶劑中所形成。在此整體重量的比例定義如下：設該精油重量是X克，與該複合樹脂膠的重量是Y克，則 該精油與該複合樹脂膠的整體重量是(X+Y)克，該精油在該精油與該複合樹脂膠的整體重量的比例是X/(X+Y)，且該複合樹脂膠在該精油與該複合樹脂膠的整體重量的比例是Y/(X+Y)。該精油在該精油與該複合樹脂膠的整體重量的比例是介於1%至10%之間。該複合樹脂膠在該精油與該複合樹脂膠的整體重量的比例是介於99%至90%之間。較佳地，該精油在該精油與該複合樹脂膠的整體重量的比例是介於5%至10%之間。該複合樹脂膠在該精油與該複合樹脂膠的整體重量的比例是介於95%至90%之間。該溶劑係選自下列族群：水、甲醇、乙醇、丙醇及異丙醇之組合。 The invention will disclose an anti-mosquito water-based paint comprising an essential oil and a composite resin glue and dissolved in a solvent. The ratio of the overall weight is defined as follows: if the weight of the essential oil is X grams, and the weight of the composite resin glue is Y grams, the overall weight of the essential oil and the composite resin glue is (X+Y) grams, and the essential oil is The ratio of the essential oil to the total weight of the composite resin glue is X/(X+Y), and the ratio of the composite resin glue to the total weight of the essential oil and the composite resin glue is Y/(X+Y). The ratio of the essential oil to the total weight of the essential oil and the composite resin glue is between 1% and 10%. The ratio of the composite resin to the total weight of the essential oil and the composite resin is between 99% and 90%. Preferably, the ratio of the essential oil to the total weight of the essential oil and the composite resin glue is between 5% and 10%. The ratio of the composite resin to the total weight of the essential oil and the composite resin is between 95% and 90%. The solvent is selected from the group consisting of water, methanol, ethanol, propanol and isopropanol.
該複合樹脂膠係由一有機材料與一無機奈米陶瓷材料經由化學接枝所形成，該複合樹脂膠之該無機奈米陶瓷材料之粉體尺寸係介於10奈米至100奈米之間。該無機奈米陶瓷材料係選自奈米氧化鋁、奈米氧化矽與奈米氧化鈦所組成之族群。該有機材料選自環氧樹脂、壓克力樹脂、矽氧樹脂、氟碳樹脂、酸醇樹脂、氨基樹脂、酚醛樹脂與丙烯酸樹脂所組成之族群。該無機奈米陶瓷材料係使用溶膠凝膠法所製備。 The composite resin adhesive is formed by chemical grafting an organic material and an inorganic nano ceramic material, and the inorganic nano ceramic material has a powder size of between 10 nm and 100 nm. . The inorganic nano ceramic material is selected from the group consisting of nano alumina, nano cerium oxide and nano titanium oxide. The organic material is selected from the group consisting of epoxy resin, acrylic resin, oxime resin, fluorocarbon resin, acid alcohol resin, amino resin, phenolic resin and acrylic resin. The inorganic nano ceramic material was prepared by a sol-gel method.
該精油是天然的植物性精油，選自下列族群之一或多種：檸檬精油、薄荷精油、天竺葵精油、羅勒精油、香茅精油、丁香精油、杜松精油、肉桂精油、香柏木精油、尤加利精油、薰衣草精油、廣藿香精油等。 This essential oil is a natural botanical essential oil selected from one or more of the following groups: lemon essential oil, peppermint essential oil, geranium essential oil, basil essential oil, citronella essential oil, clove oil, juniper essential oil, cinnamon essential oil, cedar essential oil, Eucalyptus Essential oils, lavender essential oils, patchouli essential oils, etc.
該無機奈米陶瓷材料的高反應性能夠讓該複合樹脂膠與該精油溶於該溶劑中而形成一溶劑，亦即是該防蚊蟲水性塗料是一種溶液狀態。需注意的是，該溶劑並未與該精油和該複合樹脂膠反應，而是作為單純作為溶劑，而讓該防蚊蟲水性塗料作為一種水性溶液。 The high reactivity of the inorganic nano ceramic material enables the composite resin glue and the essential oil to be dissolved in the solvent to form a solvent, that is, the anti-mosquito water-based paint is in a solution state. It should be noted that the solvent is not reacted with the essential oil and the composite resin gel, but as a solvent alone, and the mosquito-repellent water-based paint is used as an aqueous solution.
現請參考圖1，說明本發明之防蚊蟲水性塗料的製程方法，包含下列步驟：步驟S1：製備一無機奈米陶瓷材料，該無機奈米陶瓷材料之粉體尺寸係介於10奈米至100奈米之間；步驟S2：混合一有機材料與該無機奈米陶瓷材料形成一複合樹脂膠；步驟S3：混合一精油與該複合樹脂膠並溶於一溶劑中形成一水性塗料；該精油在該精油與該複合樹脂膠的整體重量的比例是介於1%至10%之間，且該複合樹脂膠在該精油與該複合樹脂膠的整體重量的比例是介於99%至90%之間。較佳地，該精油在該精油與該複合樹脂膠的整體重量的比例是介於5%至10%之間。該複合樹脂膠在該精油與該複合樹脂膠的整體重量的比例是介於95%至90%之間。該溶劑係選自下列族群：水、甲醇、乙醇、丙醇及異丙醇之組合。溶劑的量可以視所需要的稀釋流動程度而決定。 Referring now to Figure 1, a method for preparing an anti-mosquito water-based paint of the present invention comprises the following steps: Step S1: preparing an inorganic nano-ceramic material having a powder size of 10 nm to Step S2: mixing an organic material with the inorganic nano ceramic material to form a composite resin glue; step S3: mixing an essential oil with the composite resin glue and dissolving in a solvent to form an aqueous coating; the essential oil The ratio of the total weight of the essential oil to the composite resin glue is between 1% and 10%, and the ratio of the composite resin glue to the total weight of the essential oil and the composite resin glue is between 99% and 90%. between. Preferably, the ratio of the essential oil to the total weight of the essential oil and the composite resin glue is between 5% and 10%. The ratio of the composite resin to the total weight of the essential oil and the composite resin is between 95% and 90%. The solvent is selected from the group consisting of water, methanol, ethanol, propanol and isopropanol. The amount of solvent can be determined depending on the degree of dilution flow required.
在步驟S1中，該無機奈米陶瓷材料係選自奈米氧化鋁、奈米氧化矽與奈米氧化鈦所組成之族群。且該無機奈米陶瓷材料係使用溶膠凝膠法所製備。 In step S1, the inorganic nano ceramic material is selected from the group consisting of nano alumina, nano cerium oxide and nano titanium oxide. And the inorganic nano ceramic material is prepared by a sol-gel method.
該無機奈米陶瓷材料是使用溶膠凝膠法所製備。因此在該無機奈米陶瓷材料之表面上具有良好的反應能力，能夠與有機材料化學接枝的接枝共聚物。該無機奈米陶瓷材料係選自奈米氧化鋁、奈米氧化矽、奈米氧化鋯與奈米氧化鈦所組成之族群，亦即是該無機奈米陶瓷材料係選自單一的奈米氧化鋁，或單一奈米氧化矽，或單一奈米氧化鈦組成，或者是該無機奈米陶瓷材料可以由奈米氧化鋁、奈米氧化矽與奈米氧化鈦以不同比例搭配所 組成。 The inorganic nano ceramic material is prepared by a sol gel method. Therefore, on the surface of the inorganic nano ceramic material, there is a graft copolymer which has good reaction ability and can be chemically grafted with an organic material. The inorganic nano ceramic material is selected from the group consisting of nano alumina, nano cerium oxide, nano zirconia and nano titanium oxide, that is, the inorganic nano ceramic material is selected from a single nano oxidation. Aluminum, or a single nano-cerium oxide, or a single nano-titanium oxide, or the inorganic nano-ceramic material can be composed of nano alumina, nano-cerium oxide and nano titanium oxide in different ratios.
該無機奈米陶瓷材料之粉體尺寸係介於10奈米至100奈米之間，較佳地，該無機奈米陶瓷材料之粉體尺寸係介於30奈米至50奈米之間。 The inorganic nano ceramic material has a powder size of between 10 nm and 100 nm. Preferably, the inorganic nano ceramic material has a powder size of between 30 nm and 50 nm.
該無機奈米陶瓷材料之結晶構造可為岩鹽型、纖鋅礦型、閃鋅礦型、鈣鈦礦型、複合鈣鈦礦型、層狀鈣鈦礦型、類鈣鈦礦型、鋼玉型、燒綠石型、鈦鐵礦型、金紅石型、尖晶石型、反尖晶石型、螢石型、反螢石型、氯化鈣型、鎢青銅型、鈮酸鋰型、鉭酸鍶型及矽酸鹽型之一。 The crystal structure of the inorganic nano ceramic material may be rock salt type, wurtzite type, sphalerite type, perovskite type, composite perovskite type, layered perovskite type, perovskite type, steel jade type , pyrochlore type, ilmenite type, rutile type, spinel type, anti-spinel type, fluorite type, anti-fluorite type, calcium chloride type, tungsten bronze type, lithium niobate type, tantalum One of the acid type and the citrate type.
該無機奈米陶瓷材料是使用溶膠凝膠法所製備時，利用一奈米陶瓷溶液配合一加熱製程所合成。其中，該奈米陶瓷溶液係由至少一種以上之有機金屬氧化物所組成，並具有一保護基使得該奈米陶瓷溶液得以穩定儲藏。 The inorganic nano ceramic material is prepared by using a nano ceramic solution and a heating process when prepared by a sol-gel method. Wherein, the nano ceramic solution is composed of at least one or more organometallic oxides and has a protecting group for stable storage of the nano ceramic solution.
該有機金屬氧化物之化學式可為(OR)x M-O-M(OR)x、(R)y(OR)x-y M-O-M(OR)x-y(R)y、M(OR)x、M(OR)x-y(R)y及(OR)x M-O-M(OR)x，其中x為陽離子之價數，而y為陰離子之價數。一般而言陽離子之價數係介於1~5之間且陰離子之價數係介於1~6之間。M係可選自鋁(Al)、鐵(Fe)、鈦(Ti)、鋯(Zr)、鉿(Hf)、矽(Si)、銠(Rh)、銫(Cs)、鉑(Pt)、銦(In)、錫(Sn)、金(Au)、鍺(Ge)、銅(Cu)或鉭(Ta)等金屬元素之一。R可為烷(Alkyl)基、烯基(Alkenyl)、芳香基(Aryl)、鹵烷基(Alkylhalide)以及氫(Hydrogen)之一。 The chemical formula of the organometallic oxide may be (OR) x MOM(OR) x , (R) y (OR) xy MOM(OR) xy (R) y , M(OR) x , M(OR) xy (R y and (OR) x MOM(OR) x , where x is the valence of the cation and y is the valence of the anion. Generally, the valence of the cation is between 1 and 5 and the valence of the anion is between 1 and 6. The M system may be selected from the group consisting of aluminum (Al), iron (Fe), titanium (Ti), zirconium (Zr), hafnium (Hf), cerium (Si), rhenium (Rh), cerium (Cs), platinum (Pt), One of metal elements such as indium (In), tin (Sn), gold (Au), germanium (Ge), copper (Cu) or tantalum (Ta). R may be one of an alkyl group, an alkenyl group, an aromatic group (Aryl), a haloalkyl group (Alkylhalide), and hydrogen (Hydrogen).
將調配完之該奈米陶瓷溶液加入有機酸中，藉由有機酸調整該奈米陶瓷溶液之PH值(酸鹼值)，使PH值介於3至11之間，較佳地，係介於4至10之間。該有機酸之催化與水進行縮 合反應後形成具有化學接枝之保護基之膠狀的複合樹脂膠，該化學接枝之保護基將使得該複合樹脂膠得以穩定儲藏。 Adding the prepared nano ceramic solution to the organic acid, adjusting the pH value (pH value) of the nano ceramic solution by an organic acid to make the pH between 3 and 11, preferably, Between 4 and 10. The catalysis of the organic acid and the condensation reaction with water form a gel-like composite resin gel having a chemically grafted protective group, and the chemically grafted protecting group allows the composite resin gel to be stably stored.
較佳地，該有機酸通式可為R-(COOH)、(HO)-R-(COOH)、(HOOC)-R-(COOH)及(R1O),(R2O)-(POOH)。R可為烷基、烯基、芳香基、鹵烷基或氫或炔基之一。若R為烷基，該有機酸為烷酸；若R為烯基，該有機酸為烯酸；若R為芳香基，該有機酸為芳香酸；若R為鹵烷基，該有機酸為鹵烷酸；若R為氫，該有機酸為甲酸；若R為炔基，該有機酸為炔酸。而該無機酸可為鹽酸、硝酸或硫酸之一。 Preferably, the organic acid is of the formula R-(COOH), (HO)-R-(COOH), (HOOC)-R-(COOH) and (R 1 O), (R 2 O)-( POOH). R may be one of an alkyl group, an alkenyl group, an aryl group, a haloalkyl group or a hydrogen or alkynyl group. If R is an alkyl group, the organic acid is an alkanoic acid; if R is an alkenyl group, the organic acid is an olefinic acid; if R is an aromatic group, the organic acid is an aromatic acid; and if R is a haloalkyl group, the organic acid is Haloalkanic acid; if R is hydrogen, the organic acid is formic acid; if R is alkynyl, the organic acid is acetylenic acid. The inorganic acid may be one of hydrochloric acid, nitric acid or sulfuric acid.
較佳地，該化學接枝之保護基化學式為A-(CO-B-CO)-C，可使得該奈米陶瓷溶液得以穩定儲藏。其中，A係可為烷基、烯基、芳香基、鹵烷基、氫以及炔基之一。B係可為烷基、烯基、芳香基、鹵烷基、氫以及炔基之一。C係可為烷基、烯基、芳香基、鹵烷基、氫以及炔基之一。 Preferably, the chemically grafted protecting group has the chemical formula A-(CO-B-CO)-C, which enables stable storage of the nano ceramic solution. Among them, the A system may be one of an alkyl group, an alkenyl group, an aromatic group, a haloalkyl group, a hydrogen group, and an alkynyl group. The B system may be one of an alkyl group, an alkenyl group, an aromatic group, a haloalkyl group, a hydrogen group, and an alkynyl group. The C system may be one of an alkyl group, an alkenyl group, an aromatic group, a haloalkyl group, a hydrogen group, and an alkynyl group.
本發明中，主要的技術特徵是在於該複合樹脂膠之材料係由水，有機材料與無機奈米陶瓷材料經由化學接枝所形成膠狀接枝共聚物(Graft copolymers)之複合樹脂膠。該接枝共聚物在結構上屬於支化聚合物，具有主鏈，以及較長的支鏈，且主鏈和支鏈是由不同的結構單元組成。在本發明中，不同的結構單元係使用不同的有機材料與無機奈米陶瓷材料。 In the present invention, the main technical feature is that the material of the composite resin glue is a composite resin glue of Graft copolymers formed by chemical grafting of water, an organic material and an inorganic nano ceramic material. The graft copolymer is structurally a branched polymer having a main chain and a longer branch, and the main chain and the branch are composed of different structural units. In the present invention, different structural units use different organic materials and inorganic nano ceramic materials.
在步驟S2中，該有機材料選自環氧樹脂、壓克力樹脂、矽氧樹脂、氟碳樹脂、酸醇樹脂、氨基樹脂、酚醛樹脂與丙烯酸樹脂所組成之族群。 In step S2, the organic material is selected from the group consisting of epoxy resin, acrylic resin, oxime resin, fluorocarbon resin, acid alcohol resin, amino resin, phenol resin and acrylic resin.
在步驟S3中，該精油是天然的植物性精油，選自下列族群之一：檸檬精油、薄荷精油、天竺葵精油、羅勒精油、 香茅精油、丁香精油、杜松精油、肉桂精油、香柏木精油、尤加利精油、薰衣草精油、廣藿香精油等。由於該複合樹脂膠使用奈米等級的無機奈米陶瓷材料，能夠對其他溶劑或溶劑產生很好的融合，因此該複合樹脂膠與該精油形成水性塗料。 In step S3, the essential oil is a natural botanical essential oil selected from one of the following groups: lemon essential oil, peppermint essential oil, geranium essential oil, basil essential oil, citronella essential oil, clove essential oil, juniper essential oil, cinnamon essential oil, cedar essential oil , eucalyptus essential oil, lavender essential oil, patchouli essential oil, etc. Since the composite resin paste uses a nano-grade inorganic nano ceramic material to produce a good fusion with other solvents or solvents, the composite resin gel forms an aqueous coating with the essential oil.
由於該無機奈米陶瓷材料之粉體尺寸在奈米等級，能夠對材料的氫鍵具有良好的鍵結反應，因此該複合樹脂膠能夠與該精油形成很好鍵結。此外，該無機奈米陶瓷材料能夠讓該複合樹脂膠與該精油溶於該溶劑中而形成一溶液，亦即是防蚊蟲水性塗料是一種溶液狀態。該溶劑係選自下列族群：水、甲醇、乙醇、丙醇及異丙醇之組合。 Since the inorganic nano ceramic material has a powder size at a nanometer level and has a good bonding reaction to the hydrogen bond of the material, the composite resin gel can form a good bond with the essential oil. In addition, the inorganic nano ceramic material can dissolve the composite resin glue and the essential oil in the solvent to form a solution, that is, the anti-mosquito water-based paint is in a solution state. The solvent is selected from the group consisting of water, methanol, ethanol, propanol and isopropanol.
藉由本發明之防蚊蟲水性塗料與其製程方法，人工的化學性精油與天然的植物性精油經可以輕易地融入到複合樹脂內。該防蚊蟲水性塗料採用環保低污染的製程方法，所有的材料都不具毒性。塗佈的方式不限於刷塗、噴塗、滾印等。 By the anti-mosquito water-based paint of the present invention and the process method thereof, the artificial chemical essential oil and the natural plant essential oil can be easily incorporated into the composite resin. The anti-mosquito water-based paint adopts an environmentally-friendly and low-pollution process, and all materials are not toxic. The manner of coating is not limited to brushing, spraying, scrolling, and the like.
在使用該水性塗料時，只要將該水性塗料塗佈在物一件的表面，例如塗佈在家具的表面，或居家牆壁的表面，使用自然風乾方式，該水性塗料即能與物件的表面形成一層保護膜，且自然風乾後的塗料厚度約1微米至100微米之間。該水性塗料製作方式簡單迅速，且使用該防蚊蟲水性塗料於物品、家具或建築物牆壁上，可以持續發出淡淡的精油，特別是植物的氣味，防止各種蚊蟲的靠近，進而提高生活的品質。 When the aqueous coating is used, the aqueous coating can be formed on the surface of the article by applying the aqueous coating to the surface of the article, for example, on the surface of the furniture, or on the surface of a home wall, using a natural air drying method. A protective film and a naturally air-dried coating thickness between about 1 micron and 100 microns. The water-based paint is produced in a simple and rapid manner, and the use of the mosquito-resistant water-based paint on the walls of articles, furniture or buildings can continuously emit a light essential oil, especially the smell of plants, to prevent the proximity of various mosquitoes, thereby improving the quality of life.
雖然本發明已以前述較佳實施例揭示，然其並非用以限定本發明，任何熟習此技藝者，在不脫離本發明之精神和範圍內，當可作各種之更動與修改。如上述的解釋，都可以作各型式的修正與變化，而不會破壞此發明的精神。因此本發明之保護 範圍當視後附之申請專利範圍所界定者為準。 While the present invention has been described in its preferred embodiments, it is not intended to limit the scope of the invention, and various modifications and changes can be made without departing from the spirit and scope of the invention. As explained above, various modifications and variations can be made without departing from the spirit of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.
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