TW200424271A - Silver pigments - Google Patents
Silver pigments Download PDFInfo
- Publication number
- TW200424271A TW200424271A TW093107978A TW93107978A TW200424271A TW 200424271 A TW200424271 A TW 200424271A TW 093107978 A TW093107978 A TW 093107978A TW 93107978 A TW93107978 A TW 93107978A TW 200424271 A TW200424271 A TW 200424271A
- Authority
- TW
- Taiwan
- Prior art keywords
- silver
- pigment
- flakes
- patent application
- pigments
- Prior art date
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 118
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 43
- 239000004332 silver Substances 0.000 title claims abstract description 43
- 239000000203 mixture Substances 0.000 claims abstract description 36
- 238000000576 coating method Methods 0.000 claims abstract description 33
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000010410 layer Substances 0.000 claims abstract description 28
- 239000000976 ink Substances 0.000 claims abstract description 22
- 238000007639 printing Methods 0.000 claims abstract description 21
- 239000000758 substrate Substances 0.000 claims abstract description 20
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 238000002360 preparation method Methods 0.000 claims abstract description 15
- 239000004033 plastic Substances 0.000 claims abstract description 13
- 229920003023 plastic Polymers 0.000 claims abstract description 13
- 239000002537 cosmetic Substances 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 8
- 239000011521 glass Substances 0.000 claims abstract description 7
- 238000004040 coloring Methods 0.000 claims abstract description 5
- 235000013305 food Nutrition 0.000 claims abstract description 5
- 239000002019 doping agent Substances 0.000 claims abstract description 4
- 238000009472 formulation Methods 0.000 claims abstract description 4
- 238000010330 laser marking Methods 0.000 claims abstract description 4
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 3
- 239000011241 protective layer Substances 0.000 claims abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 34
- 229910052681 coesite Inorganic materials 0.000 claims description 11
- 229910052906 cristobalite Inorganic materials 0.000 claims description 11
- 229910052682 stishovite Inorganic materials 0.000 claims description 11
- 229910052905 tridymite Inorganic materials 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- -1 flakes Substances 0.000 claims description 6
- 239000008187 granular material Substances 0.000 claims description 6
- 239000000123 paper Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000011449 brick Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 239000013615 primer Substances 0.000 claims description 2
- 239000002987 primer (paints) Substances 0.000 claims description 2
- 239000012736 aqueous medium Substances 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 230000003301 hydrolyzing effect Effects 0.000 claims 1
- 238000010422 painting Methods 0.000 claims 1
- 238000005979 thermal decomposition reaction Methods 0.000 claims 1
- 239000003973 paint Substances 0.000 abstract description 4
- 239000003814 drug Substances 0.000 abstract 1
- 239000012071 phase Substances 0.000 description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 21
- 238000003756 stirring Methods 0.000 description 21
- 239000002994 raw material Substances 0.000 description 20
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000010445 mica Substances 0.000 description 17
- 229910052618 mica group Inorganic materials 0.000 description 17
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 16
- 239000008367 deionised water Substances 0.000 description 16
- 229910021641 deionized water Inorganic materials 0.000 description 16
- 239000000377 silicon dioxide Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 229910003074 TiCl4 Inorganic materials 0.000 description 9
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Substances [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 9
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 9
- 239000000460 chlorine Substances 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 8
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 8
- 239000000499 gel Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 239000004408 titanium dioxide Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 239000003086 colorant Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 235000019359 magnesium stearate Nutrition 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- 239000002304 perfume Substances 0.000 description 5
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 5
- 239000002356 single layer Substances 0.000 description 5
- 239000000454 talc Substances 0.000 description 5
- 235000012222 talc Nutrition 0.000 description 5
- 229910052623 talc Inorganic materials 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229960003415 propylparaben Drugs 0.000 description 4
- ZYECOAILUNWEAL-NUDFZHEQSA-N (4z)-4-[[2-methoxy-5-(phenylcarbamoyl)phenyl]hydrazinylidene]-n-(3-nitrophenyl)-3-oxonaphthalene-2-carboxamide Chemical compound COC1=CC=C(C(=O)NC=2C=CC=CC=2)C=C1N\N=C(C1=CC=CC=C1C=1)/C(=O)C=1C(=O)NC1=CC=CC([N+]([O-])=O)=C1 ZYECOAILUNWEAL-NUDFZHEQSA-N 0.000 description 3
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000004166 Lanolin Substances 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 235000019388 lanolin Nutrition 0.000 description 3
- 229940039717 lanolin Drugs 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 238000007645 offset printing Methods 0.000 description 3
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 3
- 229960004063 propylene glycol Drugs 0.000 description 3
- 235000013772 propylene glycol Nutrition 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- FLPJVCMIKUWSDR-UHFFFAOYSA-N 2-(4-formylphenoxy)acetamide Chemical compound NC(=O)COC1=CC=C(C=O)C=C1 FLPJVCMIKUWSDR-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 2
- 241001553290 Euphorbia antisyphilitica Species 0.000 description 2
- 229920000106 Liquid crystal polymer Polymers 0.000 description 2
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 235000004443 Ricinus communis Nutrition 0.000 description 2
- 240000000528 Ricinus communis Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 229940050390 benzoate Drugs 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
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- 235000019646 color tone Nutrition 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
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- PXDJXZJSCPSGGI-UHFFFAOYSA-N hexadecanoic acid hexadecyl ester Natural products CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
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- 229910052749 magnesium Inorganic materials 0.000 description 2
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- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
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- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
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- HEOCBCNFKCOKBX-RELGSGGGSA-N (1s,2e,4r)-4,7,7-trimethyl-2-[(4-methylphenyl)methylidene]bicyclo[2.2.1]heptan-3-one Chemical compound C1=CC(C)=CC=C1\C=C/1C(=O)[C@]2(C)CC[C@H]\1C2(C)C HEOCBCNFKCOKBX-RELGSGGGSA-N 0.000 description 1
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- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
- C09C1/0021—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a core coated with only one layer having a high or low refractive index
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
- C09C1/0084—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound containing titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1004—Interference pigments characterized by the core material the core comprising at least one inorganic oxide, e.g. Al2O3, TiO2 or SiO2
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/102—Interference pigments characterized by the core material the core consisting of glass or silicate material like mica or clays, e.g. kaolin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1062—Interference pigments characterized by the core material the core consisting of an organic compound, e.g. Liquid Crystal Polymers [LCP], Polymers or natural pearl essence
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
- C09C2200/301—Thickness of the core
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
- C09C2200/302—Thickness of a layer with high refractive material
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Cosmetics (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
⑴ 玖、發明說明 【發明所屬之技術領域】 本發明係關於以薄片狀透明的低折射指數底質爲基礎 之銀干擾顏料，及係關於其於塗漆、塗料、印刷墨水、安 全印刷墨水、塑膠、作爲塑膠和紙的雷射標記中之摻雜物 、作爲食品和藥品應用和化粧品調合物中之著色添加物之 使用。 【先前技術】 光澤或效杲顏料用於許多工業，特別是用於汽車修整 、裝飾用塗層、塑膠、塗漆、印刷墨水和化粧品調合物。 因爲其顏色表現，光澤顏料（其與角度有關地使顏色 變化於不同干擾色之間）是汽車修整和有價文件防僞特別 感興趣者。 以無機物爲基礎的珠光顏料特別重要。珠光顏料製自 無機薄片狀載體以高折射指數層（通常是氧化層）塗覆。這 些顏料的顏色由介質/氧化物或氧化物/介質介面的波長 選擇性部分反射和反射或穿透的光之干擾造成。 這些顏料的干擾色由氧化物層厚度決定。銀顏料色調 由（就光學觀點）單一高折射指數層（其光學厚度導致可見 光範圍內的最大反射値（一級）於約5 00奈米處）產生。人類 眼睛看到的此波長是綠色。但在其波長軸上的此最大値的 強度曲線相當寬，使得許多光被反射穿透人眼觀察到爲非 常亮但無色的可見光區域。 (2) 根據薄層光學的已知規則，特別是就光學組件塗層而 言，高和低折射指數交替的多層排列的反射光強度比單層 高得多。因此，相較於丁丨〇2單層系統，將Ti〇2 - Si〇2 -T i 0 2層系統施用於雲母顆粒會使反射光強度提高約6 0 %。 據此，因千擾而反射的光更顯著，預料此類型的多層系統 有強烈和亮的反射色。此類型顏料述於DE 1 96 1 8 5 69 A1 〇 以前技術提出以雲母薄片爲基礎的銀顏料，其層厚度 的散射極寬並因此具有相關於干擾色的自然行爲。因此， 具有單一高折射指數雲母塗層的珠光顏料代表單層光學系 統，即，由局折射指數金屬氧化物層的層厚度決定干擾色 。因此，雲母/金屬氧化物銀顏料的顏色設計自由度非常 侷限。 此外，雲母顆粒因其層結構而在其表面具有不規則性 ，此造成散射並因此減低產物的透明率和色澤品質。此外 ，雲母或多過少地具有顯著的灰棕主體顏色此性質進一 步降低透明率並以所不欲方式影響應用介質的吸收色。 此外，由，如，EP 1 2 1 3 3 3 0A1已經知道引發銀色印象 的多層顏料。這些顏料例中，T i 0 2 - S i 0 2 · T i 〇 2層序列S i 0 2 層非常薄（約5 0奈米）會減低顏色強度。這些顏料類似於以 雲母爲基礎的單層銀顏料，提供的顏色設計自由度非常小 且具有雲母作爲底質的前述缺點。 [發明內容】 (3) 因此，本發明的目的是要提出一種銀色干擾顏料，其 特點特別在於高透明率、純白主體顏色和獨特銀色效果的 顏色設計可能性。 令人驚訝地，已經發現到，特定經Ti 〇2薄層塗覆的 透明低折射指數薄片（如：Si0.2薄片）會給人銀色印象。此 藉由以厚度與薄片極爲吻合的Ti〇2層塗覆薄片而得。 相較於EP 1 2 1 3 3 3 0 A1之經單層塗覆之以雲母爲基礎的 銀顏料和干擾顏料，根據本發明之顏料具下列性質： -於應用介質中的極佳透明性 -純白主體顏色 -非常亮的銀色干擾色。 除了這些性質之外，根據本發明之顏料與已知干擾顏 料的區別在於下列特徵： -強烈閃爍性 -可調整的色調 -色調的角度依存性。 藉由調整Ti02層厚度和藉由選擇不同厚度的透明薄 片（如：Si〇2薄片），該色調的變化範圍廣泛，且不會損及 干擾顏料的印象。 本發明因此係關於一種以透明低折射指數的薄片狀底 質爲基礎的銀干擾顏料，其具有包含層厚5 -3 00奈米之 Ti〇2的高折射指數塗層，和任意外在保護層。 本發明另係關於根據本發明之銀顏料 於塗漆、塗料、印刷墨水' 安全印刷墨水、塑膠、底 -7- (4) 漿、陶瓷材料、玻璃、引晶塗覆、作爲塑膠和紙的雷射標 記中的摻雜物、作爲食品和藥品應用和化粧品調合物中之 者色添加物方面之使用。根據本發明之顏料另亦適用以製 備顏料組成物及用以製備無水製劑，如：顆粒、片、九、 磚.·等。此無水製劑特別適用於印刷墨水和化粧品調合物 〇 用於根據本發明之干擾顏料的適當底質是折射指數 <1.9的底質，如：WO93 /08 23 7中所描述的薄片狀Si02薄 片。此外，除了該S i 〇2薄片以外，嫻於此技術者已知的 許多薄片狀透明底質（如：ai2〇3薄片、玻璃薄片和薄片狀 塑膠粒）亦適用。極佳的底質是S i 0 2薄片。此特別性質（如 :可調整的色調，特別是其角度依存性）源自於狹窄的厚 度分佈定義的平均密度。 因此，以底質薄片厚度的平均層厚計，其標準偏差應 S 2 0 %，以S 1 0 %爲佳，S 5 °/。特別佳。 未要求底質尺寸並可視特別應用而定。通常，薄片狀 透明底質的平均厚度介於0.02和10微米之間，以介於〇·〇3 和5微米之間爲佳，特別是介於0.05和3微米之間。另兩維 的尺寸通常介於1和450微米之間，以介於2和2 00微米之間 爲佳，特別是介於5和100微米之間。 爲達到純銀色效果和與角度有關的色調，各薄片的平 均厚度之標準偏差^ 20%有其重要性。 ’ 底質的縱橫比（直徑/厚度比）以卜1 0 0 0爲佳’特別是 3 - 5 00，極佳者是5 - 2 0 0。 (5) (5)200424271
TiCh層和底質（Si 〇2)厚度會影響顏料的光學性質。必 須精確設定層厚度並與底質薄片的平均厚度相配伍。Ti〇2 層厚度以5-3 00奈米爲佳，1 0-200奈米較佳，特別是μι 50奈米。 根據本發明之顏料可以相當簡單的方法製自：在經精 密分割的薄片狀底質上形成具定義厚度和光滑表面的高折 射指數Ti〇2干擾層。此Ti02可爲金紅石形式或銳鈦形式 。此Ti02以金紅石修飾形式爲佳。特別佳者是經金紅石 層塗覆的Si02薄片。 適當底質是所有無機和有機透明材料，其爲經精密分 割之厚度分佈窄的薄片形式。適當有機底質特別是聚合物 ，如：聚酯（如：PET)、聚碳酸酯、聚醯亞胺和聚異丁烯 酸酯。 特別佳者是以Si02、A1203爲基礎的干擾材料，所有 具薄片狀外觀的單晶和經二氧化鈦薄層塗覆的玻璃薄片。
此金屬氧化物層以藉含水化學法施用爲佳，其可使用 發展用以製備珠光顏料的含水塗覆法。此類方法述於，如 :DE 14 67 468、DE 19 59 988、DE 20 09 566、DE 22 14 545 ^ DE 2 2 15 191、DE 22 44 298、DE 23 1 3 331、DE 2 5 22 5 72、DE 31 37 808、DE 31 37 809、DE 3 1 51 343 、DE 3 1 51 354、DE 3 1 51 355、DE 3 2 11 602、DE 32 3 5 0 1 7及其他專利文件和嫻於此技術者已知的其他文獻。 水性塗覆法中，底質顆粒懸浮於水中’ 一或多種可水 解的鈦鹽於適用於水解的PH添加，後者之選擇使得金屬 (6) 氧化物或使得金屬氧化物水合物直接沉澱於薄片上且無明 顯的二次沉澱發生。此pH通常藉同時輸入鹼和/或酸而 維持穩定。之後分離顏料，淸洗及於5 0 - 1 5 0 °C乾燥，有須 要時’鍛燒0.5-3小時，可視存在的塗層而選擇最適合的 鍛燒溫度。通常，鍛燒溫度介於2 5 0和1 0 0 0 °C之間，以介 於3 5 0和9 5 0 °C之間爲佳。 塗覆亦可於流化床反應器中藉氣相塗覆進行，其可爲 ，如，相當於使用EP 0 045 851 A1和EP 0 106 235 A1中 提出之用以製備珠光顏料的方法。 顏料的色調變化範圍寬廣，藉選擇不同覆蓋量或自其 得到的層厚度而維持銀色效果。於肉眼或測量技巧對照下 ’藉由趨近所欲顏色，純粹因選擇的量而細部調整某些色 調。 爲提高光、水和天候安定性，視應用範圍，通常建議 對經處理的顏料施以後塗覆或後處理。適當後塗覆或後處 理方法述於，如，德國專利案第22 15 191號、DE-A 31 51 354、DE-A 32 35 017 和 DE-A 33 34 598。此後塗覆另提 高化學安定性或簡化顏料操作，特別是摻入各式各樣介質 中。爲改善潤濕性、分散性和/或與應用介質之配伍性， ai2o3或以02或混合物或其混合相的功能性塗層可施用於 顏料表面。此外，描述可以使用有機或合倂的有機/無機 後塗覆，如：矽烷，此述於EP0090259、EP 0 634 45 9、 WO99/5 7204、W096/32446、WO99/5 7204 、US 5,7 5 9,2 5 5 、US5,571;851 、 WO01/92425 或於 J.J .Pongee,Philips -10 - (7)
Technical Review，Vol.4.45No.3,81 和 P.H.Harding J.c.Ber g ： J.Adhesion Sci.Teclinol.Vol.l 1，Νο·4，ρρ.471-493。 根據本發明之銀顏料簡單且容易操作。此顏料可藉簡 單攪入方式摻入施用系統中。不須複雜的硏磨和分散顏料 〇 因爲根據本發明之顏料合倂高光澤和高透明率及純白 主體顏色，它們特別能夠有效用於各式各樣應用介質，不 會明顯影響吸收顏色性質。 無庸贅言’用於各式各樣應用上，干擾顏料亦可有利 地以與有機染料、有機顏料或其他顏料（如：透明和無光 澤白色、彩色和黑色顏料）及與薄片狀氧化鐵、有機顏料 、全息（holographic)顏料、LCP(液晶聚合物）和慣用的透 明彩色和黑色光澤顏料（以經金屬氧化物塗覆的雲母和 SiCh薄片爲基礎）··等之混合物形式使用。此干擾顏料可以 任何比例與市售顏料和塡料混合。 各式各樣應用中，根據本發明之顏料亦可與任何類型 的其他著色劑（如··有機和/或無機吸收顏料和染料）、多 層干擾顏料（如：Timiron®、SicoperaI®(BASF AG)、
Chroma-Flair®(Flex Products Inc·))、BiOCl 顏料、珠光 顏料或金屬顏料（如：Eckart)倂用。對於混合比例和濃度 無限制。 根據本發明之顏料可以與多種顏色系統（以塗漆、塗 料和印刷墨水爲佳）相配伍。例如，用以製備印刷墨水， 凹版印刷、膠版印刷、平版印刷或平版上光、多種黏合劑 -11 - (8) (特別是市售水溶性黏合劑，如，BASF、Marabu、Prol]、
Sericol、Hartmann、Gebr.Schmidt、Sicpa、Aarberg、 Siegberg、GSB-Wahl、Follmann、Ru co 或 Coats Screen INKS GmbH)適用。此印刷墨水可爲以水爲基礎或以溶劑 爲基礎者。此顏料可進一步適用於紙和塑膠的雷射標記及 用於農業應用（如：溫室罩布）及用於布篷著色。 根據本發明之銀顏料可用於表面塗料、印刷墨水、塑 膠、農用罩布、引晶塗覆、食品著色、底漿、藥品塗料或 嫌 化粧品調合物（如：唇膏、指甲油、粉餅、洗髮精、爽身 粉和凝膠）。以系統的固體總含量計，顏料混合物於欲著 色的應用系統中之濃度通常介於0.1和70重量％之間，以介 於0.1和50重量％之間爲佳，特別是介於0.5和10重量％之間 。此通常視特定應用而定。 根據本發明之銀顏料含量爲0.01至50重量％(特別是 〇·1至7重量％)的塑膠之特點在於特別閃耀的效果。 在表面塗料（特別是汽車塗料）應用中，銀顏料亦用於 _ 三塗覆系統，其用量是0.1 -1 0重量％，以1至3重量％爲佳 〇 表面塗料中，根據本發明之顏料的優點在於，藉單塗 覆整理（單塗覆系統或二塗覆系統中的底塗）便可達到目標 光澤。相較於包含以雲母爲基礎之多層塗料的修整物代替 本根據本發明之顏料之時，包含根據本發明之顏料的修整 物具更淸澈深度效果和更顯著的光澤效果。 根據本發明之銀顏料可以有利地用於裝飾和保養用化 -12 - (9) 粧品。使用濃度由洗髮精中的〇 · 〇〗重量％至爽身粉中的〗〇 〇 重蓋％。以銀顏料與球狀塡料（如：si〇2)之混合物爲例， 在S周合物中之濃度可爲〇 . 〇 i _ 7 〇重量％。化粧品（如：指甲 油、唇賞、粉餅、洗髮精、爽身粉和凝膠）的特點在於特 別感興趣的光澤效果。藉根據本發明之顏料之助，指甲油 中閃燦效果明顯比慣用指甲油來得高。此外，根據本發明 之銀顏料可用於沐浴添加物、牙膏和食品整理（如··物質 者色和/或煮沸的甜品）之塗覆、w i n e g u m (如··膠凍物件 、胡桃糖果、甘草、糕餅、棒棒糖、泡沬飲料、蘇打·.等） 或作爲塗料（如：於藥用上，用於標準和經塗覆的錠）。 根據本發明之顏料可以進一步與市售塡料混合。可提 及的塡料有，如：天然和合成雲母、單純或經摻雜的蜜胺 樹脂、滑石、玻璃、高嶺土、錨、鎂 '銘、鋅的氧化物或 氫氧化物、BiOCl、硫酸鋇、硫酸鈣、碳酸鈣、碳酸鎂、 碳和這些物質的物理或化學組合。對於塡料形狀無特別限 制。根據需求，其可爲，如，薄片狀、球狀或針狀。 · 根據本發明之顏料當然也可以與任何類型的化粧品原 料及輔助劑倂於調合物中。這些特別包括，油、脂、蠘、 成膜劑、防腐劑和用以決定技術性質的輔助劑（如：稠化 劑和流變添加劑（如：膨潤土、水輝石、二氧化矽、矽酸 ’ 鈣、凝膠、高分子量碳水化合物和/或界面活性劑））。 包含根據本發明之顏料的調合物可屬於親脂、親水或 疏水類型。以具有不連續含水和非水相的非均相調合物爲 例，根據本發明之顏料以兩相之一存在或分佈於兩相中。 -13- (10) 調合物的PH値可介於1和1 4之間，以介於2和1 1之間 爲佳，介於5和8之間特別佳。 未限制根據本發明之顏料於調合物中之濃度。視應用 而定，可介於洗除產品，如：沐浴膠）和】〇〇%(如： 用於特別應用的光澤效果物件）之間。
根據本發明之顏料亦可進一步與化粧活性成份合倂。 適當活性成份有，如，昆蟲驅除劑、uv A/B C保護用濾物 (如：OMC、B3和MBC)、抗老化活性成份、維生素和其 衍生物（如：維生素A、C、E··等）、自身曬黑劑（如：DHA ，特別是赤蘚酮糖）和其他化粧活性成份（如：沒藥醇、 LPO、ectoin、emblica、尿囊素、類生物黃驗素和它們的 衍生物）。
已經證實，黏合劑系統的表面塗料和用於凹版印刷、 膠版印刷或網版印刷的印刷墨水或作爲印刷墨水先質者之 著色中，根據本發明之干擾顏料以高度著色糊、顆粒、九 粒··等形式使用特別有效。此顏料於墨水中的摻雜量通常 是2 · 3 5重量％，以5 - 2 5重量％爲佳，特別是8 - 2 0重量％。膠 版印刷墨水的顏料含量可局至4 0重量％或以上。印刷墨水 先質（如：顆粒、九粒、磚··等形式）除了黏合劑和添加劑 以外’包含高至9 8重量％根據本發明之顏料。包含根據本 發明之顏料的印刷墨水的銀色調純度高於慣用效果顏料。 根據本發明之顏料的顆粒厚度相當小，因此，印刷性質特 別良好。 根據本發明之千擾顏料因此適用以製備可流動的顏料 - 14 - (11) 組成物和無水製劑，特別是印刷墨水，包含一或多種根據 本發明之銀顏料、黏合劑和任意一或多種添加劑。 本發明因此亦係關於包含根據本發明之銀顏料之調合 物。 下列實例用以解釋本發明，但不限制本發明。. 【實施方式】 實例 實例1 :顏色由綠色經由紅紫至金綠的銀顏料 100克 Si02薄片（顆粒尺寸5-50微米，平均厚度4 5 0奈 米，厚度標準偏差：5%)懸浮於2升去離子水中並於劇烈攪 拌加熱至80°C。12克SnCl4x5H20和40毫升氫氯酸（37%)於 360毫升去離子水中之溶液於ρΗ1·6以4毫升/分鐘速率引 至此混合物中。之後，370毫升TiCl4溶液（400克TiCl4/ 升）於ρΗ1·6以2毫升/分鐘速率引入。添加 SnCl4x5H2〇 溶液和TiCl4溶液期間內，使用NaOH溶液（32%)維持pH 穩定。之後使用氫氧化鈉溶液（3 2%)將pH調整至5.0，混 合物再攪拌1 5分鐘。 濾除顏料，以20升去離子水淸洗，於1 10 °C乾燥並於 8 5 0 °C鍛燒3 0分鐘。產物是具淡綠色調的銀色干擾顏料， 於一個角度觀察時，其顏色經由紅紫至金綠。 實例2 :顏色由自然銀色經由紅紫至金綠的銀顏料 100克 Si〇2薄片（顆粒尺寸5_50微米，平均厚度450奈 -15- (12) 米，厚度標準偏差：5%)懸浮於2升去離子水中並於劇烈攪 梓加熱至80°C。12克SnCl4x5H20和40毫升氫氯酸（37%)於 360毫升去離子水中之溶液於ρΗ1·6以4毫升/分鐘速率引 至此混合物中。之後，3 5 0毫升 TiCl4溶液（400克TiCl4/ 升）於pH1.6以2毫升/分鐘速率引入。添加 SnCl4x5H20 溶液和TiCl4溶液期間內，使用NaOH溶液（32%)維持pH 穩定。之後使用氫氧化鈉溶液（3 2%)將pH調整至5.0，混 合物再攪拌1 5分鐘。 濾除顏料，以20升去離子水淸洗，於1 10°C乾燥並於 8 5 0 °C鍛燒3 0分鐘。產物是銀色干擾顏料，於一個角度觀 察時，其顏色經由紅紫至金綠。 實例3 :顏色由淡青銀色經由紅至金綠的銀顏料 100克 Si02薄片（顆粒尺寸5-50微米，平均厚度450奈 米，厚度標準偏差：5%)懸浮於2升去離子水中並於劇烈攪 拌加熱至80°C。12克SnCl4x5H20和40毫升氫氯酸（37%)於 3 60毫升去離子水中之溶液於pH 1.6以4毫升/分鐘速率引 至此混合物中。之後，34〇毫升TiCl4溶液（400克TiCl4/ 升）於pHl.6以2毫升/分鐘速率引入。添加 SnCl4x5H20 溶液和TiCl4溶液期間內，使用NaOH溶液（32%)維持pH 穩定。之後使用氫氧化鈉溶液（3 2%)將pH調整至5.0，混 合物再攪拌1 5分鐘。 濾除顏料，以2 0升去離子水淸洗，於1 1 0 °C乾燥並於 8 5 0 °C鍛燒3 0分鐘。產物是銀色干擾顏料，於一個角度觀 - 16- (13) 察時，其顏色經由紅至金綠。 使用例 實例A :閃爍配方 A相 原料 供應商 INCI [%]_ Extender W Merck 雲母，Cl 7 7 8 9 1 ( 9.00 KGa A/Rona® 二氧化鈦） MICRONA®Matte Merck 雲母，Cl 77492( 4.00 Yellow KGaA/Rona® 氧化鐵） MICRONA®Matte Merck 雲母，C I 7 7 4 9 1 ( 0.40 Red KGaA/Rona® 氧化鐵） MICRONA®Matte Merck 雲母，Cl 77499( 0.30 Black KGaA/Rona® 氧化鐵） 得自實例1的顏料 Merck KGaA 4.50 RONASPHERE® Merck 矽石 5.00 KGaA/Rona® -17- (14) B相 原料 供應商 INCI [%] Blanose 7 HF Aqua 1 οn GmbH 纖維素膠 0.20 V e e g υ m Vanderbilt 矽酸鎂鋁 1.00 Texapon K 1296 Cognis GmbH 月桂基硫酸鈉 0.60 Triethanolamine extra pure Merck KGa A/Rona® 三乙醇胺 0.50 T i t r i p 1 e x III Merck KGaA/Rona® EDTA 二鈉 0.25 Methyl 4-hydroxy- Merck 對·羥基苯甲酸甲 0.15 benzoate KGaA/Rona® 酯 1,2-Propanediol Merck KGaA/Rona® 丙二醇 10.90 去離子水 水 42.95
-18- (15)C相 原料 供應商 INCI [%] Isopropyl m y r i s t a t e C o g n i s GmbH 肉豆蔻酸異丙酯 8.00 Liquid paraffin Merck KGaA/Rona® 液態烷烴（礦油） 3.60 C r o d a m o 1 S S Croda GmbH 鯨蠟酯 2.60 Monomuls 60-35C Cognis GmbH 氫化的棕欖甘油 酯 1 .70 Stearic acid Merck KGa A/Rona® 硬脂酸 1.50 EUSOLEX®6 3 00 Merck KGaA/Rona® 4-甲基苯亞甲基 樟腦 1.30 EUSOLEX®4360 Merck KGaA/Rona® 二苯甲酮-3 0.50 R ο n a Care Merck 乙酸生育酚乙酸 0.50 Tocopherol acetate KGaA/Rona® 酯 Magnesium stearate Merck KGaA/Rona® 硬脂酸鎂 0.10 Propyl 4 -hydroxy- Merck 對-羥基苯甲酸丙 0.05 ben z o a t e KGaA/Rona® 酯
-19 - (16) D相 原料 供應商 INCI [%] Perfume oil Fragance 香料 0.20 2 00 5 29 Resources E u x y 1 K 4 0 0 S c h u 1 k e & 苯氧基乙醇，甲基二 0.20 Mayr GmbH 溴戊二腈 製備= 於約7 5 °C熔解和攪拌C相中的所有組份直到全數熔解 爲止。先將B相中的冷水引入，於Blanose中使用Turrax 均化，摻入Veegum中並再度均化。溫熱至75t並於攪拌 時使其他成份溶解於其中。攪入 A相的構份中。於攪拌 時，於75°C添加C相並均化2分鐘。混合物於攪拌時冷卻 至4 0 °C，添加D相。於攪拌時進一步冷卻至室溫並調整 至PH6.0-6.5(例如，使用檸檬酸溶液）。 實例B :沐浴膠 A相 原料 供應商 INCI [%] 得自實例2的 Merck KGaA 0.10 顏料 K e 11 r ο 1 T K e 1 c ο 黃原膠 0.75 去離子水 水 64.95 (17) B相 原料 供應商 INCI [%] Plantacare 2000 UP C o gni s GmbH 十二基葡糖苷 20.00 Texapon ASV 50 C o gni s GmbH Sodium Laureth Sulfate?Lauareth-8 Sulfate，Magnesium Laureth Sulfate5Magmesium Laureth-8 Sulfate，Sodium Oleth Sulfate， Magnesium Oleth Sulfate 3.60 B r ο ：n i d o x L C o g n i s GmbH 丙二醇，5 ·溴-5 -硝基· 1，3 ·二噁烷 0.20 P er furm oil Everest 7 965 8 SB H a a r m a η n & R e i m e r GmbH 香料 0.05 1% FD&C lue N o · 1於水中 BASF AG 水，Cl 42090(FD&C Blue No. 1 ) 0.20
-21 - (18) C相 原料 供應商 INCI [%] C i r t i c m ο η o h y d r a t e acid Merck KGa A/Rona® 檸檬酸 0.15 去離子水 水 10.00 製備： A相中，將顏料攪入水中。攪拌時，緩慢分散於 Keltril T中，並攪拌直到溶解。於攪拌時，添力□ B和C 相，攪拌直到所有者均勻分佈。調整pH爲6.0至6.4。 實例C :眼線筆凝膠 (19)A相 原料 供應商 INCI Γ % 1 得自實例3的顏料 Merck KGaA 5.〇〇 Xirona®Magic Mauve Merck KGaA/Rona® 石夕石，C I 7 7 8 9 1 ( 二氧化鈦），氧 化錫 1 〇.〇〇 Mica Black Merck KGaA/Rona® Cl 77499(氧化鐵 )， 雲母，Cl 7789 1(二氧化鈦） 5.00 RONASPHERE® Merck KGaA/Rona® 矽石 2.00 Carbopol ETD 2001 B F Goodrich 碳聚合物 0.40 Cirtic acid monohydrate Merck KGaA/Rona® 檸檬酸 0.00 去離子水 水 60.00
-23- (20) B相 原料 供應商 INCI [°/〇] G 1 y e r ο 1 ? anhydrous Merck KGaA/Rona® 甘油 4.00 Triethanolamine extra pure Merck KGaA/Rona® 三乙醇胺 0.90 Lu vi sko 1 V A 64 Powder BASF AG PVP/VA共聚物 2.00 Germaben II ISP Global Technologies 丙二醇，二噁唑烷基 尿素，對·羥基苯甲 酸甲酯，對-羥基苯 甲酸丙酯 1 .00 去離子水 水 9.70 製備： 效果顏料和Ronasphere®分散於A相的水中。使用幾 滴檸檬酸予以酸化以降低黏度，Carbopol於攪拌時分散。 完全溶解之後，緩慢攪入事先溶解的B相中並調整pH爲 7.0至 7.5。 竇例D :眼影 -24- (21) A相 原料 供應商 INCI [%] Xirona®Caribbean Merck 矽石，CI77891(二 45.00 Blue KGaA/Rona® 氧化鈦）， 雲母，氧化錫 Mica Black Merck KGaA/Rona® CI77499(氧化鐵）， 雲母，CI77891(二 氧化鈦） 5.00 得自實例1的顏料 Merck K Ga A 5.00 BIRON®B50 Merck KGaA/Rona® CI77 1 6 3 (氧氯化鉍） 3.00 Colorona®Dark Merck 雲母，CI 7 7 8 9 1 (二 10.00 Blue — ---—_ KGaA/Rona® 氧化鈦）， CI7 7 5 1 0 (亞鐵氰化 鐵） Magni sum stearate Merck KGaA/Rona® 硬脂酸鎂 2.50 White clay(deleted) Merck KGaA/Rona® 高嶺土 5.00 Hubersorb 600 J . M . Η u b e r C o r p. 硬脂酸鈣 0.50 Talc Merck KGaA/Rona® 滑石 11.00 •25- (22) B相 原料 供應商 [%1 Amerchol L 101 Amerchol 羊毛脂醇，烷 ®液（礦油） L / ^ Λ 10.70 Super H a r t ο 1 a η C r o d a GmbH ---iUJ )____ 旨醇 ——---- 1 Λ Λ E wal i n 17 5 1 H . Erhard Wagner GmbH 石蠘油 1 . u u 1 .00 Propyl 4 -hydroxy-benzoate Merck KGaA/Rona® 對-羥基苯甲酸 丙酯 0.10 Perfume oil Elegance#79228 D MF Haarmann & Reimer GmbH 香料 0.20 製備： 合倂及事先混合A相的構份。之後，於攪拌時，將 熔融B相逐滴加至粉末混合物中。以4 0至5 0巴對此粉末施 壓。 實例E :眼影膠 (23) 原料 供應商 INCI _____ X i r ο n a ® I n d i a η Merck KGaA/Rona® 5夕 石 ’ 15.00 Summer C I 7 7 4 9 1 (氧化/ 鐵） 一一 得自實例3的顏 Merck KGaA 5.00 料 RONASPHERE® Merck KGaA/Rona® 矽石 3.00 Carbopol ETD BF Goodrich GmbH 碳聚合物 0.30 2001 citric acid Merck KGaA/Rona® 檸檬酸 0.00 monohydrate 去離子水 水 60.00
-27- (24) B相 原料 供應商 INCI [%] Glycerol,an hydrous Merck KGaA/Rona® 甘油 2.00 G e r m a b e η II ISP Global Technologies 丙二醇 0.20 Triethanolamine extra pure Merck KGaA/Rona® 丙二醇，二噁唑烷 基尿素，對-羥基 苯甲酸甲酯，對-羥基苯甲酸丙酯 0.70 去離子水 水 13.80
製備： 效果顏料和R 0 n a s p h e r e ®分散於A相的水中。使用幾 滴檸檬酸予以酸化以降低黏度’ Carb0P01於攪拌時分散。 完全溶解之後，緩慢攪入事先溶解的B相中。 實例F :眼影 -28- (25)A相 原料 供應商 INCI [%] XironaOCaribbea n Blue Merck KGa A/Rona® 矽石，CI77891(二 氧化鈦）， 雲母，氧化錫 20.00 CoIorona®Dark Blue Merck KG a A/R ona® 雲母，CI77891(二 氧化鈦）， CI775 1 0 (亞鐵氰化 鐵） 5.00 得自實例2的賴料 Merck KGaA 5.00 Talc Merck KGaA/Rona® 滑石 49.50 Potato starch Sudstarke GmbH Solanum Tuberosum( 洋芋澱粉） 7.50 Magnesium stearate Merck KGaA/Rona ㊣ 硬脂酸鎂 2.50
-29- (26) B相 原料 供應商 INCI [%] Isopropyl stearate Cognis GmbH 硬脂酸異丙 酯 9.14 Cetyl palmitate Merck KGaA/Rona® 棕欖酸鯨蠟 酯 0.53 E wal in 17 5 1 H . E r h ar d Wagner GmbH 石蠟油 0.53 Perfume oil Elegance#79228 D MF Haarmann & Reimer GmbH 香料 0.20 Propyl 4-hydroxy-benzoate Merck KGaA/Rona® 對-羥基苯 甲酸丙酯 0.10 製備： 合倂及事先混合A相的構份。之後’於攪拌時，將 熔融B相逐滴加至粉末混合物中。以4 0至5 0巴對此粉末施 壓。 -30- (27) (27) 製備G :指甲油 原料 供應商 INCI [%] 得自實例1的 顏料 Merck KGaA 2.00 Thixotropic International 甲苯、乙酸乙酯、乙酸 98.00 nail varnish Lacquers 丁酯、硝基纖維素、甲 base 1348 S . A. 苯磺醯基醯胺/甲醛樹 脂、苯二甲酸二丁酯、 異丙醇、硬脂基水輝石 、樟腦、丙烯酸酯共聚 物、二苯甲酮-1
製備： 原料與varnish base稱在一起，以人工使用刮板混合 均勻，之後於l〇〇〇rpm攪拌10分鐘。 實例Η :唇彩 -31 - (28) A相 原料 供應商 INCI [%] 得自實例1的顔料 Merck KGaA 雲母，矽石，Cl 77891(二 2.50 氧化欽） Tumii. on®Splendid Merck 矽石，Cl 7 7 8 9 1 (氧化鐵） 5.00 Violet KGaA/Rona® Xirona®Indian Merck 矽石，C17 7 4 9 1 (氧化鐵） 2.50 Summer KGa A/Rona® Rub i s Covapate L e s Ricinus Communis(蓖麻油）， 5.00 W4765 Colorants Cl 15850(D & C Red No.7 ^-------------- W ackherr Calcium Lake)
-32- (29) B相 原料 供應商 INCI [%] Foralyn 5020-F Hercules BV 氫化的松脂酸甲酯 20.00 Adeps Lanae Henry Lamotte GmbH 羊毛脂 18.00 Castor oil Henry Lamotte GmbH Ricinus Communis(蓖麻油） 13.75 Foral 85-E Hercules BV 氫化的松脂酸甘油酯 12.00 Jij oba oil Gustav Heess GmbH B u X u s C h i n e n s i s (荷荷巴油） 5.00 Eusolex®2292 Merck KGaA/Rona® 乙基己基甲氧基肉桂酸酯， BHT 3.00 Antaron V-216 ISP Global Technologies PVP/十六烯共聚物 4.00 Candelilla Wax 2039L Kahl & Co. Candelilla Cera(Candelilla 蠘 ) 3.50 Amerchol L 101 Amerchol 羊毛脂醇，烷烴液（礦油） 3.00 Rohagit S Rohm GmbH 丙烯酸酯共聚物 1.50 Beewax white Merck KGaA/Rona® Cera A]ba(蜂蠟） 1.00 Propyl 4- hydroxy benzoate Merck KGaA/Rona® 對·羥基苯甲酸丙酯 0.10 Oxynex®K liquid Merck KGaA/Rona® PEG-8，生育酚，棕欖酸抗壞 血酯，抗壞血酸，檸檬酸 0.05 -33- (30) C相
原料 供應商 INCI [°/〇] Fragrance H a a r m a η η & R e i m e r 香料 0.10 Tendresse#75418C GmbH 製備： B相所有組份（除了 Foral 85-E以外）溫熱至80°C並於 攪拌時緩慢添加Foral 85-E。將A相和C相加至熔融的B 相中。將均勻的熔融物倒入5 0 °C的模具中。 -34-
Claims (1)
- ⑴ 拾、申請專利範圍 1 · 一種以低折射指數的透明薄片狀底質爲基礎的銀顏 料，其特徵在於其具有包含層厚5-3 00奈米之Ti02的高折 射指數塗層及任意的外在保護層。 2 ·如申請專利範圍第1項之銀顏料，其中透明薄片是 Si〇2薄片、Ah〇3薄片、聚合物薄片、單晶或玻璃薄片。 3 ·如申請專利範圍第2項之銀顏料，其中透明薄片是 Si02薄片。 φί 4 _如申請專利範圍第1至3項中任一項之銀顏料，其中 各薄片的平均厚度在標準偏差$ 2 0 %的範圍內。 5·如申請專利範圍第1項之銀顏料，其中Ti〇2爲金紅 石形態。 6 · —種製備如申請專利軔圍第1至5項中任一項之銀顏 料之方法，其特徵在於底質之塗覆藉含水化學法利用金·屬 鹽於水性介質中之水解性分解或利用CVD或PVD法之熱 分解而實施。 馨 7 ·如申請專利範圍第1項之銀顏料之用於塗漆、塗料 、印刷墨水、安全印刷墨水、塑膠、底漿、陶瓷材料、玻 璃 '引晶塗覆（seed coating)、作爲塑膠和紙的雷射標記中 的摻雜物、作爲食品和藥品應用和化粧品調合物中之著色 添加物，及製備顏料組成物和無水製劑的用途。 8 · —種顏料組成物，其包含一或多種黏合劑、任意地 一或多種添加劑和一或多種如申請專利範圍第1項之銀顏 料。 -% - (2) 9 · 一種無水製劑，如：九粒、顆粒、片和磚，其包含 如申請專利範圍第1項之銀顏料。-36- 柒、（一）、本案指定代表圖為··無 (二）、本代表圖之元件代表符號簡單說明··捌、本案若有化學式時，請揭示最能顯示發明特徵的化學 式： 4K j \\\-4 -
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10313978A DE10313978A1 (de) | 2003-03-27 | 2003-03-27 | Silberpigment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200424271A true TW200424271A (en) | 2004-11-16 |
Family
ID=32892318
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW093107978A TW200424271A (en) | 2003-03-27 | 2004-03-24 | Silver pigments |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7344590B2 (zh) |
| EP (1) | EP1469041B1 (zh) |
| JP (1) | JP2004292815A (zh) |
| KR (1) | KR20040084998A (zh) |
| CN (1) | CN100513492C (zh) |
| DE (1) | DE10313978A1 (zh) |
| ES (1) | ES2545901T3 (zh) |
| TW (1) | TW200424271A (zh) |
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| DE102004052544A1 (de) * | 2004-02-09 | 2005-08-25 | Merck Patent Gmbh | Interferenzpigmente |
| EP1564261B1 (de) * | 2004-02-09 | 2016-05-25 | Merck Patent GmbH | Interferenzpigmente |
| DE102004024455A1 (de) * | 2004-05-14 | 2005-12-08 | Merck Patent Gmbh | Polychrome Pigmente |
| DE102005001997A1 (de) * | 2005-01-17 | 2006-07-20 | Merck Patent Gmbh | Effektpigmente mit starkem Farbtop |
| GB0502166D0 (en) * | 2005-02-02 | 2005-03-09 | Effectology Ltd | Ink-jet printing process |
| CA2537732A1 (en) * | 2005-04-06 | 2006-10-06 | Jds Uniphase Corporation | High chroma optically variable colour-shifting glitter |
| US20060272534A1 (en) * | 2005-06-03 | 2006-12-07 | Daniel Lieberman | Systems and methods for printing surface relief structures |
| US20070207927A1 (en) * | 2006-03-01 | 2007-09-06 | Rosa Fred C | Polymer based seed coating |
| DE102006014095A1 (de) | 2006-03-24 | 2007-09-27 | Merck Patent Gmbh | Glasplättchen und deren Verwendung als transparenter Füllstoff |
| WO2007117004A1 (ja) * | 2006-04-07 | 2007-10-18 | Nippon Sheet Glass Company, Limited | 光輝性顔料およびその製造方法、該光輝性顔料を含む化粧料、塗料、インク、または樹脂組成物 |
| FR2908634A1 (fr) * | 2006-11-17 | 2008-05-23 | Oreal | Composition cosmetique couvrante |
| US20080268003A1 (en) * | 2006-11-17 | 2008-10-30 | L'oreal | Covering cosmetic composition |
| FR2908639A1 (fr) * | 2006-11-17 | 2008-05-23 | Oreal | Composition cosmetique comportant au moins un pigment interferentiel multicouche et au moins un pigment reflechissant a reflet metallique |
| FR2908633A1 (fr) * | 2006-11-17 | 2008-05-23 | Oreal | Composition cosmetique couvrante, blanche dans la masse, et revelant une couleur a l'application |
| FR2908640B1 (fr) * | 2006-11-17 | 2012-12-07 | Oreal | Composition cosmetique couvrante |
| US20080226574A1 (en) * | 2006-11-17 | 2008-09-18 | L'oreal | Line of cosmetic compositions |
| EP2093260A1 (de) | 2008-02-20 | 2009-08-26 | Eckart GmbH | Effektpigmente basierend auf künstlich hergestellten Substraten mit enger Grössenverteilung |
| KR101110273B1 (ko) * | 2008-09-05 | 2012-02-13 | (주)석경에이티 | 티타니아 나노입자의 제조방법 |
| CN102361625A (zh) * | 2009-03-31 | 2012-02-22 | 富士胶片株式会社 | 化妆品 |
| DE102009037935A1 (de) | 2009-08-19 | 2011-02-24 | Eckart Gmbh | Hochglänzende Mehrschichtperlglanzpigmente mit silberner Interferenzfarbe und enger Größenverteilung und Verfahren zu deren Herstellung |
| CN102391687B (zh) * | 2011-09-05 | 2013-08-28 | 福州坤彩精化有限公司 | 金属银涂布的玻璃基效果颜料及其制备方法 |
| DE102012102165A1 (de) * | 2012-03-14 | 2013-10-02 | Eckart Gmbh | Kompositpartikel, Verfahren zu deren Herstellung und Verwendung derselben |
| CN102920611B (zh) * | 2012-11-14 | 2014-07-02 | 李伟成 | 金粉及其制备方法 |
| US9168393B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| US9168209B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| US9320687B2 (en) | 2013-03-13 | 2016-04-26 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| US9168394B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| JP2016220643A (ja) * | 2015-06-02 | 2016-12-28 | 有限会社カムカンパニー | 棒状マカロン |
| KR101876199B1 (ko) * | 2017-04-21 | 2018-08-03 | 씨큐브 주식회사 | 복합 백색 안료 및 그 제조 방법 |
| US11274211B2 (en) * | 2017-04-27 | 2022-03-15 | Nippon Sheet Glass Company, Limited | Glitter pigment having electromagnetic wave transmission properties, composition including the pigment, and painted product including the pigment |
| CN107953641A (zh) * | 2017-12-27 | 2018-04-24 | 太仓金煜电子材料有限公司 | 一种半透印刷复合胶带及其生产方法 |
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| JP3702742B2 (ja) * | 1999-04-28 | 2005-10-05 | 日本板硝子株式会社 | 真珠光沢顔料およびその製造方法並びに真珠光沢顔料を配合した化粧料 |
| DE10061178A1 (de) * | 2000-12-07 | 2002-06-20 | Merck Patent Gmbh | Silberfarbenes Glanzpigment |
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| TWI292773B (en) | 2001-05-09 | 2008-01-21 | Merck Patent Gmbh | Effect pigments based on coated glass flakes |
-
2003
- 2003-03-27 DE DE10313978A patent/DE10313978A1/de not_active Withdrawn
-
2004
- 2004-03-09 ES ES04005556.8T patent/ES2545901T3/es not_active Expired - Lifetime
- 2004-03-09 EP EP04005556.8A patent/EP1469041B1/de not_active Revoked
- 2004-03-23 JP JP2004083749A patent/JP2004292815A/ja active Pending
- 2004-03-24 TW TW093107978A patent/TW200424271A/zh unknown
- 2004-03-26 KR KR1020040020623A patent/KR20040084998A/ko not_active Application Discontinuation
- 2004-03-26 CN CN200410031286.6A patent/CN100513492C/zh not_active Expired - Fee Related
- 2004-03-29 US US10/811,143 patent/US7344590B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN100513492C (zh) | 2009-07-15 |
| EP1469041A3 (de) | 2010-07-07 |
| US7344590B2 (en) | 2008-03-18 |
| ES2545901T3 (es) | 2015-09-16 |
| DE10313978A1 (de) | 2004-10-07 |
| KR20040084998A (ko) | 2004-10-07 |
| US20040221770A1 (en) | 2004-11-11 |
| CN1542058A (zh) | 2004-11-03 |
| EP1469041B1 (de) | 2015-05-27 |
| EP1469041A2 (de) | 2004-10-20 |
| JP2004292815A (ja) | 2004-10-21 |
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