SK287425B6 - Odsírovacie činidlo a spôsob odsírenia roztaveného železa - Google Patents

Odsírovacie činidlo a spôsob odsírenia roztaveného železa Download PDF

Info

Publication number: SK287425B6
Authority: SK; Slovakia
Prior art keywords: desulfurizing agent; heat; absorbing composition; calcium; reactive
Prior art date: 2000-04-10

Application number

SK448-2001A

Other languages

English (en)

Slovak (sk)

Other versions

SK4482001A3 (en

Inventor

Thomas H. Bieniosek

Gerald R. Zebrowski

Original Assignee

Magnesium Technologies Corporation

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-04-10

Filing date

2001-04-03

Publication date

2010-09-07

2001-04-03 Application filed by Magnesium Technologies Corporation filed Critical Magnesium Technologies Corporation

2001-12-03 Publication of SK4482001A3 publication Critical patent/SK4482001A3/sk

2010-09-07 Publication of SK287425B6 publication Critical patent/SK287425B6/sk

Links

239000003795 chemical substances by application Substances 0.000 title claims abstract description 264
239000011777 magnesium Substances 0.000 title claims description 131
229910052749 magnesium Inorganic materials 0.000 title claims description 130
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims description 127
238000006477 desulfuration reaction Methods 0.000 title abstract description 24
230000023556 desulfurization Effects 0.000 title abstract description 24
230000003009 desulfurizing effect Effects 0.000 claims abstract description 243
239000002245 particle Substances 0.000 claims abstract description 198
239000000203 mixture Substances 0.000 claims abstract description 167
229910000805 Pig iron Inorganic materials 0.000 claims abstract description 129
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 75
238000000034 method Methods 0.000 claims abstract description 63
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 47
229910052742 iron Inorganic materials 0.000 claims abstract description 35
150000001875 compounds Chemical class 0.000 claims abstract description 26
229910052717 sulfur Inorganic materials 0.000 claims description 46
239000011593 sulfur Substances 0.000 claims description 46
239000002893 slag Substances 0.000 claims description 30
229910000616 Ferromanganese Inorganic materials 0.000 claims description 27
DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 claims description 27
229910001567 cementite Inorganic materials 0.000 claims description 26
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
229910052799 carbon Inorganic materials 0.000 claims description 24
229940043430 calcium compound Drugs 0.000 claims description 22
150000001674 calcium compounds Chemical class 0.000 claims description 22
239000011230 binding agent Substances 0.000 claims description 20
230000008569 process Effects 0.000 claims description 19
239000005997 Calcium carbide Substances 0.000 claims description 17
239000007787 solid Substances 0.000 claims description 17
CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 claims description 17
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 15
WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 15
238000002844 melting Methods 0.000 claims description 15
230000008018 melting Effects 0.000 claims description 15
239000010436 fluorite Substances 0.000 claims description 14
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 12
235000008733 Citrus aurantifolia Nutrition 0.000 claims description 11
235000011941 Tilia x europaea Nutrition 0.000 claims description 11
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 11
239000000292 calcium oxide Substances 0.000 claims description 11
150000002430 hydrocarbons Chemical class 0.000 claims description 11
239000004571 lime Substances 0.000 claims description 11
150000005846 sugar alcohols Polymers 0.000 claims description 11
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 10
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 10
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
239000001110 calcium chloride Substances 0.000 claims description 10
229910001628 calcium chloride Inorganic materials 0.000 claims description 10
ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 10
229910001610 cryolite Inorganic materials 0.000 claims description 10
229930195733 hydrocarbon Natural products 0.000 claims description 10
PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 10
239000011248 coating agent Substances 0.000 claims description 9
238000000576 coating method Methods 0.000 claims description 8
230000008020 evaporation Effects 0.000 claims description 8
238000001704 evaporation Methods 0.000 claims description 8
229910000861 Mg alloy Inorganic materials 0.000 claims description 6
229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
239000003153 chemical reaction reagent Substances 0.000 claims description 6
239000001257 hydrogen Substances 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
229910052757 nitrogen Inorganic materials 0.000 claims description 6
150000003377 silicon compounds Chemical class 0.000 claims description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 5
BWKDLDWUVLGWFC-UHFFFAOYSA-N calcium;azanide Chemical compound [NH2-].[NH2-].[Ca+2] BWKDLDWUVLGWFC-UHFFFAOYSA-N 0.000 claims description 5
XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 claims description 5
UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 5
239000010459 dolomite Substances 0.000 claims description 5
229910000514 dolomite Inorganic materials 0.000 claims description 5
239000010434 nepheline Substances 0.000 claims description 5
229910052664 nepheline Inorganic materials 0.000 claims description 5
RAFRTSDUWORDLA-UHFFFAOYSA-N phenyl 3-chloropropanoate Chemical compound ClCCC(=O)OC1=CC=CC=C1 RAFRTSDUWORDLA-UHFFFAOYSA-N 0.000 claims description 5
229940072033 potash Drugs 0.000 claims description 5
229910052700 potassium Inorganic materials 0.000 claims description 5
239000011591 potassium Substances 0.000 claims description 5
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 5
235000015320 potassium carbonate Nutrition 0.000 claims description 5
239000001103 potassium chloride Substances 0.000 claims description 5
235000011164 potassium chloride Nutrition 0.000 claims description 5
239000000377 silicon dioxide Substances 0.000 claims description 5
229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
235000017550 sodium carbonate Nutrition 0.000 claims description 5
239000011780 sodium chloride Substances 0.000 claims description 5
235000002639 sodium chloride Nutrition 0.000 claims description 5
239000011775 sodium fluoride Substances 0.000 claims description 5
235000013024 sodium fluoride Nutrition 0.000 claims description 5
239000010435 syenite Substances 0.000 claims description 5
UNMYWSMUMWPJLR-UHFFFAOYSA-L Calcium iodide Chemical compound [Ca+2].[I-].[I-] UNMYWSMUMWPJLR-UHFFFAOYSA-L 0.000 claims description 4
CWVZGJORVTZXFW-UHFFFAOYSA-N [benzyl(dimethyl)silyl]methyl carbamate Chemical compound NC(=O)OC[Si](C)(C)CC1=CC=CC=C1 CWVZGJORVTZXFW-UHFFFAOYSA-N 0.000 claims description 4
229940046413 calcium iodide Drugs 0.000 claims description 4
229910001640 calcium iodide Inorganic materials 0.000 claims description 4
150000002431 hydrogen Chemical class 0.000 claims description 4
229910017464 nitrogen compound Inorganic materials 0.000 claims description 4
150000002830 nitrogen compounds Chemical class 0.000 claims description 4
150000002927 oxygen compounds Chemical class 0.000 claims description 4
239000000126 substance Substances 0.000 claims description 4
239000003039 volatile agent Substances 0.000 claims description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
239000011575 calcium Substances 0.000 claims description 3
229910052791 calcium Inorganic materials 0.000 claims description 3
239000002250 absorbent Substances 0.000 claims 1
230000002745 absorbent Effects 0.000 claims 1
230000002708 enhancing effect Effects 0.000 claims 1
229910001021 Ferroalloy Inorganic materials 0.000 abstract description 11
239000000463 material Substances 0.000 abstract description 6
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract description 2
239000005864 Sulphur Substances 0.000 abstract 1
239000007789 gas Substances 0.000 description 27
230000001590 oxidative effect Effects 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 7
239000012159 carrier gas Substances 0.000 description 6
238000002347 injection Methods 0.000 description 6
239000007924 injection Substances 0.000 description 6
239000007788 liquid Substances 0.000 description 6
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
229910000831 Steel Inorganic materials 0.000 description 4
239000006096 absorbing agent Substances 0.000 description 4
150000002680 magnesium Chemical class 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
239000010959 steel Substances 0.000 description 4
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 3
-1 aroundanite Chemical compound 0.000 description 3
238000009835 boiling Methods 0.000 description 3
229910001424 calcium ion Inorganic materials 0.000 description 3
230000000694 effects Effects 0.000 description 3
150000002681 magnesium compounds Chemical class 0.000 description 3
QENHCSSJTJWZAL-UHFFFAOYSA-N magnesium sulfide Chemical compound [Mg+2].[S-2] QENHCSSJTJWZAL-UHFFFAOYSA-N 0.000 description 3
230000004048 modification Effects 0.000 description 3
238000012986 modification Methods 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
239000011358 absorbing material Substances 0.000 description 2
239000000654 additive Substances 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
229910052734 helium Inorganic materials 0.000 description 2
239000001307 helium Substances 0.000 description 2
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
239000003345 natural gas Substances 0.000 description 2
230000009257 reactivity Effects 0.000 description 2
239000000243 solution Substances 0.000 description 2
XWQVQSXLXAXOPJ-QNGMFEMESA-N 4-[[[6-[5-chloro-2-[[4-[[(2r)-1-methoxypropan-2-yl]amino]cyclohexyl]amino]pyridin-4-yl]pyridin-2-yl]amino]methyl]oxane-4-carbonitrile Chemical compound C1CC(N[C@H](C)COC)CCC1NC1=CC(C=2N=C(NCC3(CCOCC3)C#N)C=CC=2)=C(Cl)C=N1 XWQVQSXLXAXOPJ-QNGMFEMESA-N 0.000 description 1
MVXMNHYVCLMLDD-UHFFFAOYSA-N 4-methoxynaphthalene-1-carbaldehyde Chemical compound C1=CC=C2C(OC)=CC=C(C=O)C2=C1 MVXMNHYVCLMLDD-UHFFFAOYSA-N 0.000 description 1
229910000851 Alloy steel Inorganic materials 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910000272 alkali metal oxide Inorganic materials 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910001634 calcium fluoride Inorganic materials 0.000 description 1
JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003245 coal Substances 0.000 description 1
229910021540 colemanite Inorganic materials 0.000 description 1
238000005336 cracking Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000010494 dissociation reaction Methods 0.000 description 1
230000005593 dissociations Effects 0.000 description 1
239000000428 dust Substances 0.000 description 1
239000003623 enhancer Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
230000005294 ferromagnetic effect Effects 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
125000003827 glycol group Chemical group 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
QMQXDJATSGGYDR-UHFFFAOYSA-N methylidyneiron Chemical compound [C].[Fe] QMQXDJATSGGYDR-UHFFFAOYSA-N 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical class [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000005060 rubber Substances 0.000 description 1
SMDQFHZIWNYSMR-UHFFFAOYSA-N sulfanylidenemagnesium Chemical compound S=[Mg] SMDQFHZIWNYSMR-UHFFFAOYSA-N 0.000 description 1
CADICXFYUNYKGD-UHFFFAOYSA-N sulfanylidenemanganese Chemical compound [Mn]=S CADICXFYUNYKGD-UHFFFAOYSA-N 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/02—Dephosphorising or desulfurising
- C21C1/025—Agents used for dephosphorising or desulfurising
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/064—Dephosphorising; Desulfurising
- C21C7/0645—Agents used for dephosphorising or desulfurising

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

SK448-2001A 2000-04-10 2001-04-03 Odsírovacie činidlo a spôsob odsírenia roztaveného železa SK287425B6 (sk)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US09/546,016 US6352570B1 (en)	2000-04-10	2000-04-10	Magnesium desulfurization agent

Publications (2)

Publication Number	Publication Date
SK4482001A3 SK4482001A3 (en)	2001-12-03
SK287425B6 true SK287425B6 (sk)	2010-09-07

Family

ID=24178512

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK448-2001A SK287425B6 (sk)	2000-04-10	2001-04-03	Odsírovacie činidlo a spôsob odsírenia roztaveného železa

Country Status (14)

Country	Link
US (2)	US6352570B1 (de)
EP (1)	EP1146131B1 (de)
JP (1)	JP3643312B2 (de)
AR (1)	AR027787A1 (de)
AT (1)	ATE331046T1 (de)
BR (1)	BR0101445A (de)
CA (1)	CA2339399C (de)
DE (1)	DE60120824T2 (de)
HK (1)	HK1041611B (de)
MX (1)	MXPA01003305A (de)
NO (1)	NO20011799L (de)
PL (1)	PL198649B1 (de)
SK (1)	SK287425B6 (de)
TW (1)	TW544467B (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6770115B2 (en) *	2002-10-18	2004-08-03	Remacor, Inc.	Process for magnesium granules
US6989040B2 (en) *	2002-10-30	2006-01-24	Gerald Zebrowski	Reclaimed magnesium desulfurization agent
US20050056120A1 (en) *	2003-09-15	2005-03-17	Flores-Morales Jose Ignacio	Desulphurization of ferrous materials using sodium silicate
US20050066772A1 (en) *	2003-09-26	2005-03-31	Flores-Morales Jose Ignacio	Desulphurization of ferrous materials using glass cullet
HUP0400630A2 (en) *	2004-03-23	2006-01-30	Istvan Tamas	New, molecule-size desulphurizing agents consisting of non metallic and metallic components for reducing the sulphur content of iron melts to an ultra low level (0<s%<0,001) and a method for producing said material
US7731778B2 (en) *	2006-03-27	2010-06-08	Magnesium Technologies Corporation	Scrap bale for steel making process
US20080196548A1 (en) *	2007-02-16	2008-08-21	Magnesium Technologies Corporation	Desulfurization puck
JP5413300B2 (ja) *	2010-05-07	2014-02-12	新日鐵住金株式会社	鉱物含有溶鋼脱硫フラックス
JP5930726B2 (ja) *	2012-01-18	2016-06-08	大阪鋼灰株式会社	精錬剤
CN113444853B (zh) *	2021-06-25	2022-11-22	中钢设备有限公司	一种细颗粒Mg-CaO复合脱硫剂及其制备方法、一种铁水预脱硫的方法
CN115094300A (zh) *	2022-05-27	2022-09-23	刘锐	一种铁素体球墨铸铁及其制备方法

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SE321095B (de)	1967-06-08	1970-02-23	Jaernfoeraedling Ab
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GB1511246A (en)	1974-04-29	1978-05-17	Materials & Methods Ltd	Process for the manufacture of cast iron
DE2157395A1 (de) *	1971-11-19	1973-05-24	Metallgesellschaft Ag	Mittel zum behandeln von eisenlegierungsschmelzen
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- 2000-04-10 US US09/546,016 patent/US6352570B1/en not_active Expired - Lifetime
2001
- 2001-03-01 TW TW090104729A patent/TW544467B/zh not_active IP Right Cessation
- 2001-03-05 CA CA002339399A patent/CA2339399C/en not_active Expired - Lifetime
- 2001-03-30 MX MXPA01003305A patent/MXPA01003305A/es active IP Right Grant
- 2001-04-03 SK SK448-2001A patent/SK287425B6/sk not_active IP Right Cessation
- 2001-04-06 AT AT01108667T patent/ATE331046T1/de not_active IP Right Cessation
- 2001-04-06 DE DE60120824T patent/DE60120824T2/de not_active Expired - Fee Related
- 2001-04-06 EP EP01108667A patent/EP1146131B1/de not_active Expired - Lifetime
- 2001-04-09 PL PL346962A patent/PL198649B1/pl unknown
- 2001-04-09 AR ARP010101680A patent/AR027787A1/es active IP Right Grant
- 2001-04-09 NO NO20011799A patent/NO20011799L/no not_active Application Discontinuation
- 2001-04-10 JP JP2001110860A patent/JP3643312B2/ja not_active Expired - Fee Related
- 2001-04-11 BR BR0101445-5A patent/BR0101445A/pt not_active Application Discontinuation
- 2001-06-11 US US09/877,388 patent/US6383249B2/en not_active Expired - Lifetime
2002
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Also Published As

Publication number	Publication date
DE60120824D1 (de)	2006-08-03
EP1146131B1 (de)	2006-06-21
JP2001355013A (ja)	2001-12-25
CA2339399C (en)	2006-09-12
ATE331046T1 (de)	2006-07-15
NO20011799D0 (no)	2001-04-09
TW544467B (en)	2003-08-01
NO20011799L (no)	2001-10-11
SK4482001A3 (en)	2001-12-03
US6352570B1 (en)	2002-03-05
CA2339399A1 (en)	2001-10-10
US6383249B2 (en)	2002-05-07
US20010029809A1 (en)	2001-10-18
EP1146131A3 (de)	2002-09-04
EP1146131A2 (de)	2001-10-17
BR0101445A (pt)	2001-12-04
PL346962A1 (en)	2001-10-22
HK1041611B (zh)	2006-10-13
PL198649B1 (pl)	2008-07-31
HK1041611A1 (en)	2002-07-12
JP3643312B2 (ja)	2005-04-27
DE60120824T2 (de)	2007-02-01
AR027787A1 (es)	2003-04-09
MXPA01003305A (es)	2002-03-08

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JP2007302961A (ja)	2007-11-22	含Ｃｒ溶銑の脱硫精錬剤および脱硫方法
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CN1154748C (zh)	2004-06-23	复合型铁水脱硫剂
JP3508550B2 (ja)	2004-03-22	溶銑の脱硫方法
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